37 1001 ELKINS, JAMES; FAHEY, DAVID; GILLIGAN, JONATHAN; VOLK, CLAUS MICHAEL; DUTTON, GEOFF ; BARING, THOMAS; WAMSLEY, PAULA U.S. DEPT OF COMMERCE, NOAA / CMDL / NITROUS OXIDE AND HALOCARBONS DIVISION ACATS IV, ER-2 ASHOE 1 1 1994 06 01 1995 05 20 0 ELAPSED TIME IN SECONDS FROM 00:00:00 GMT ON SAMPLE DATE 20 1.0 1.0 1.0 1.0 1.0 1.0 1.0 1.0 1.0 1.0 1.0 1.0 1.0 1.0 1.0 1.0 1.0 1.0 1.0 1.0 99999 99999 99999 99999 99999 99999 99999 99999 99999 99999 99999 99999 99999 99999 99999 99999 99999 99999 99999 99999 MIXING RATIO CFC-11 (PPT) CFC-11 ERROR 1 S.D. (PPT) MIXING RATIO CFC-113 (PPT) CFC-113 ERROR 1 S.D. (PPT) MIXING RATIO CH3CCl3 (PPT) CH3CCl3 ERROR 1 S.D. (PPT) MIXING RATIO CCl4 (PPT) CCl4 ERROR 1 S.D. (PPT) MIXING RATIO N2O (PPB) N2O ERROR 1 S.D. (PPB) MIXING RATIO SF6 (PPT) SF6 ERROR 1 S.D. (PPT) MIXING RATIO CFC-12 (PPT) CFC-12 ERROR 1 S.D. (PPT) MIXING RATIO H1211 (PPT) H1211 ERROR 1 S.D. (PPT) MIXING RATIO H2 (PPB) H2 ERROR 1 S.D. (PPB) MIXING RATIO CH4 (PPB) CH4 ERROR 1 S.D. (PPB) 2 Final calibrations applied. Time corrected for pump delay using O3 data from Proffitt et al. 1 GMTs CFC11 CFC11e CFC113 CFC113e CH3CCl3 CH3CCl3e CCl4 CCl4e N2O N2Oe SF6 SF6e CFC12 CFC12e H1211 H1211e H2 H2e CH4 CH4e 68748 260.5 0.6 91.3 2.3 114.7 0.5 108.7 0.6 295.0 2.4 99999 99999 522.7 7.4 99999 99999 99999 99999 99999 99999 68928 262.2 0.6 92.1 2.4 116.9 0.5 109.6 0.6 295.2 2.4 99999 99999 527.6 7.5 99999 99999 99999 99999 99999 99999 69108 255.0 0.6 90.7 2.3 116.6 0.5 107.1 0.6 291.4 2.3 99999 99999 510.4 7.2 99999 99999 99999 99999 99999 99999 69468 255.8 0.6 91.2 2.4 116.3 0.5 106.7 0.6 291.6 2.3 99999 99999 515.6 7.3 99999 99999 99999 99999 1781 20 69648 217.9 0.5 80.9 1.8 98.7 0.5 87.4 0.5 269.5 2.0 99999 99999 462.2 6.4 99999 99999 99999 99999 1614 17 69828 166.2 0.3 65.9 1.0 73.4 0.5 62.3 0.5 239.5 1.7 99999 99999 391.2 5.3 99999 99999 99999 99999 1479 15 70188 137.6 0.3 57.4 0.8 59.6 0.4 48.9 0.4 224.7 1.5 99999 99999 353.4 4.8 99999 99999 99999 99999 1393 14 70368 133.0 0.3 56.5 0.8 56.9 0.4 47.0 0.4 222.0 1.5 99999 99999 343.7 4.6 99999 99999 99999 99999 1399 14 70548 128.3 0.3 55.2 0.8 54.5 0.4 44.9 0.4 220.5 1.5 99999 99999 336.9 4.5 99999 99999 99999 99999 1384 14 70908 130.4 0.3 55.5 0.8 55.4 0.4 46.0 0.4 221.3 1.5 99999 99999 340.4 4.6 99999 99999 99999 99999 1394 14 71088 134.8 0.3 57.1 0.9 58.0 0.4 48.4 0.4 224.8 1.5 99999 99999 351.0 4.7 99999 99999 99999 99999 1421 14 71268 130.4 0.3 55.5 0.8 55.6 0.4 46.3 0.4 218.4 1.5 99999 99999 336.0 4.5 99999 99999 99999 99999 1385 14 71808 134.7 0.3 57.4 0.9 57.5 0.4 47.5 0.4 221.6 1.5 99999 99999 346.4 4.7 99999 99999 99999 99999 1406 14 71988 127.3 0.3 53.8 0.8 54.0 0.4 44.8 0.4 219.0 1.5 99999 99999 337.6 4.5 99999 99999 99999 99999 1375 14 72168 136.0 0.3 57.2 0.9 58.3 0.4 47.9 0.4 223.4 1.5 99999 99999 352.4 4.7 99999 99999 99999 99999 1392 14 72528 135.3 0.3 57.5 0.9 57.4 0.4 47.5 0.4 224.0 1.5 99999 99999 354.8 4.8 99999 99999 99999 99999 1407 14 72708 134.4 0.3 56.8 0.8 58.0 0.4 47.8 0.4 223.3 1.5 99999 99999 350.8 4.7 99999 99999 99999 99999 1393 14 72888 123.3 0.3 53.1 0.8 52.5 0.4 43.2 0.4 217.1 1.5 99999 99999 334.3 4.4 99999 99999 99999 99999 1348 13 73248 114.6 0.3 50.7 0.8 48.0 0.4 39.1 0.4 211.3 1.4 99999 99999 326.1 4.3 99999 99999 99999 99999 1337 13 73428 117.1 0.3 51.3 0.8 49.6 0.4 40.7 0.4 211.8 1.4 99999 99999 325.6 4.3 99999 99999 99999 99999 1336 13 73608 118.1 0.3 52.1 0.8 49.6 0.4 40.5 0.4 210.7 1.4 99999 99999 333.2 4.4 99999 99999 99999 99999 1341 13 73968 132.1 0.3 57.0 0.9 56.0 0.4 45.5 0.4 221.9 1.5 99999 99999 343.4 4.6 99999 99999 99999 99999 1386 14 74148 114.2 0.3 50.3 0.8 47.8 0.4 38.6 0.4 210.0 1.4 99999 99999 321.5 4.2 99999 99999 99999 99999 1325 13 74328 112.6 0.3 50.0 0.8 47.4 0.4 37.5 0.4 210.7 1.4 99999 99999 320.4 4.2 99999 99999 99999 99999 1321 13 74868 116.1 0.3 52.0 0.8 48.8 0.4 39.4 0.4 212.1 1.4 99999 99999 327.9 4.3 99999 99999 99999 99999 1335 13 75048 131.2 0.3 55.3 0.8 55.3 0.4 45.9 0.4 219.8 1.5 99999 99999 347.1 4.6 99999 99999 99999 99999 1408 14 75228 134.3 0.3 56.7 0.9 56.4 0.4 46.9 0.4 220.3 1.5 99999 99999 348.4 4.6 99999 99999 99999 99999 1397 14 75588 138.6 0.3 56.8 0.9 59.2 0.4 49.5 0.4 222.9 1.5 99999 99999 358.7 4.8 99999 99999 99999 99999 1422 14 75768 137.9 0.3 57.2 0.9 58.5 0.4 48.9 0.4 223.2 1.5 99999 99999 360.9 4.8 99999 99999 99999 99999 1395 14 75948 123.4 0.3 52.6 0.8 52.0 0.4 42.9 0.4 214.9 1.5 99999 99999 336.1 4.4 99999 99999 99999 99999 1362 14 76308 110.5 0.3 48.0 0.8 45.9 0.4 37.8 0.4 207.7 1.4 99999 99999 318.8 4.2 99999 99999 99999 99999 1339 13 76488 133.4 0.3 54.7 0.8 56.3 0.4 46.7 0.4 220.0 1.5 99999 99999 347.7 4.6 99999 99999 99999 99999 1400 14 76668 91.2 0.3 41.7 0.8 37.2 0.4 29.6 0.4 194.3 1.3 99999 99999 293.9 3.9 99999 99999 99999 99999 1245 12 77028 109.1 0.3 46.6 0.8 45.4 0.4 36.8 0.4 203.6 1.4 99999 99999 317.9 4.2 99999 99999 99999 99999 1312 13 77208 93.9 0.3 41.9 0.8 37.6 0.4 30.3 0.4 193.4 1.3 99999 99999 287.6 3.8 99999 99999 99999 99999 1277 13 77388 104.6 0.3 45.1 0.8 42.8 0.4 35.3 0.4 201.8 1.3 99999 99999 312.0 4.1 99999 99999 99999 99999 1294 13 77928 92.1 0.3 41.4 0.8 36.7 0.4 29.6 0.4 197.8 1.3 99999 99999 297.6 3.9 99999 99999 99999 99999 1259 12 78288 81.3 0.3 38.7 0.9 32.8 0.4 25.3 0.4 191.8 1.3 99999 99999 277.8 3.7 99999 99999 99999 99999 1226 12 78648 76.7 0.3 37.7 0.9 30.3 0.4 24.3 0.4 188.3 1.2 99999 99999 279.8 3.7 99999 99999 99999 99999 1209 12 78828 76.0 0.3 37.6 0.9 30.2 0.4 23.7 0.4 187.6 1.2 99999 99999 271.0 3.6 99999 99999 99999 99999 1207 12 79008 41.4 0.4 24.8 1.2 15.1 0.5 11.3 0.5 164.7 1.1 99999 99999 224.7 2.9 99999 99999 99999 99999 1095 11 79368 41.1 0.4 25.3 1.2 15.5 0.5 11.5 0.5 163.5 1.1 99999 99999 218.3 2.9 99999 99999 99999 99999 1102 11 79728 37.4 0.5 24.9 1.2 13.7 0.5 10.2 0.5 161.5 1.1 99999 99999 217.3 2.9 99999 99999 99999 99999 1085 11 80088 39.5 0.4 23.5 1.2 16.2 0.5 10.9 0.5 161.4 1.1 99999 99999 222.9 2.9 99999 99999 99999 99999 1073 10 80268 35.9 0.5 21.3 1.3 13.2 0.5 10.0 0.5 157.9 1.1 99999 99999 208.9 2.8 99999 99999 99999 99999 1073 10 80448 34.7 0.5 22.9 1.2 16.6 0.5 9.8 0.5 158.7 1.1 99999 99999 210.7 2.8 99999 99999 99999 99999 1052 10 80988 31.9 0.5 20.6 1.3 11.9 0.5 8.6 0.5 156.6 1.0 99999 99999 210.5 2.8 99999 99999 99999 99999 1061 10 81168 32.6 0.5 19.3 1.3 11.8 0.5 9.1 0.5 156.2 1.0 99999 99999 207.8 2.7 99999 99999 99999 99999 1056 10 81348 33.0 0.5 20.3 1.3 12.0 0.5 8.2 0.5 157.1 1.0 99999 99999 209.4 2.7 99999 99999 99999 99999 1047 10 81708 30.6 0.5 19.2 1.4 11.3 0.5 8.2 0.5 155.6 1.0 99999 99999 205.9 2.7 99999 99999 99999 99999 1053 10 81888 28.8 0.5 19.4 1.4 10.6 0.5 7.9 0.5 151.1 1.0 99999 99999 207.2 2.7 99999 99999 99999 99999 1057 10 82068 31.2 0.5 19.6 1.3 11.8 0.5 8.7 0.5 154.2 1.0 99999 99999 206.7 2.7 99999 99999 99999 99999 1039 10 82428 33.0 0.5 20.5 1.3 12.2 0.5 9.2 0.5 155.6 1.0 99999 99999 213.7 2.8 99999 99999 99999 99999 1044 10 82608 33.4 0.5 19.8 1.3 20.9 0.5 9.0 0.5 155.5 1.0 99999 99999 212.6 2.8 99999 99999 99999 99999 1062 11 82788 37.3 0.5 21.1 1.3 14.3 0.5 10.6 0.5 158.0 1.1 99999 99999 209.9 2.8 99999 99999 99999 99999 1083 11 83148 69.1 0.3 35.7 1.0 26.2 0.4 21.0 0.4 181.8 1.2 99999 99999 256.3 3.4 99999 99999 99999 99999 1197 12 83328 49.8 0.4 24.1 1.2 18.2 0.5 14.7 0.5 166.8 1.1 99999 99999 233.1 3.1 99999 99999 99999 99999 1083 11 83508 100.2 0.3 44.0 0.8 41.2 0.4 33.4 0.4 201.2 1.3 99999 99999 300.2 4.0 99999 99999 99999 99999 1236 13 84048 47.3 0.4 25.3 1.2 17.5 0.5 13.4 0.5 166.3 1.1 99999 99999 233.3 3.0 99999 99999 99999 99999 1103 11 84228 78.1 0.3 37.2 0.9 32.6 0.4 24.8 0.4 189.9 1.2 99999 99999 270.0 3.5 99999 99999 99999 99999 1203 12 84408 67.5 0.3 33.5 1.0 26.8 0.4 20.5 0.4 182.4 1.2 99999 99999 263.2 3.4 99999 99999 99999 99999 1163 12 84768 45.4 0.4 25.7 1.2 17.5 0.5 12.5 0.5 165.1 1.1 99999 99999 237.2 3.1 99999 99999 99999 99999 1145 12 84948 39.9 0.4 23.4 1.3 14.8 0.5 10.9 0.5 161.2 1.1 99999 99999 225.7 2.9 99999 99999 99999 99999 1093 11 85128 37.5 0.5 23.3 1.3 14.3 0.5 10.2 0.5 158.5 1.1 99999 99999 222.7 2.9 99999 99999 99999 99999 1094 11 85488 32.6 0.5 19.3 1.4 11.9 0.5 8.8 0.5 155.5 1.0 99999 99999 212.8 2.8 99999 99999 99999 99999 1083 11 85668 32.4 0.5 21.3 1.3 12.1 0.5 7.9 0.5 155.9 1.0 99999 99999 215.5 2.8 99999 99999 99999 99999 1074 11 85848 34.8 0.5 21.0 1.3 12.9 0.5 9.4 0.5 160.1 1.1 99999 99999 213.1 2.8 99999 99999 99999 99999 1107 11 86208 36.0 0.5 21.5 1.3 13.3 0.5 9.9 0.5 159.9 1.1 99999 99999 217.4 2.9 99999 99999 99999 99999 1105 11 86388 51.3 0.4 28.4 1.1 19.8 0.5 15.0 0.5 171.7 1.1 99999 99999 236.6 3.1 99999 99999 99999 99999 1139 12 86568 63.8 0.3 33.1 1.0 25.0 0.4 18.8 0.4 180.4 1.2 99999 99999 255.2 3.4 99999 99999 99999 99999 1171 12 87108 61.3 0.3 33.4 1.0 30.5 0.4 18.3 0.4 176.2 1.2 99999 99999 245.1 3.2 99999 99999 99999 99999 1178 12 87288 64.6 0.3 32.9 1.0 25.8 0.4 19.3 0.4 179.8 1.2 99999 99999 256.9 3.4 99999 99999 99999 99999 1177 12 87468 66.0 0.3 33.8 1.0 26.0 0.4 19.6 0.4 182.5 1.2 99999 99999 256.3 3.4 99999 99999 99999 99999 1188 12 87828 74.0 0.3 36.0 1.0 29.1 0.4 22.3 0.4 185.5 1.2 99999 99999 271.6 3.6 99999 99999 99999 99999 1221 13 88008 77.1 0.3 39.0 0.9 31.1 0.4 23.4 0.4 187.2 1.2 99999 99999 282.5 3.7 99999 99999 99999 99999 1227 13 88188 74.4 0.3 36.8 0.9 30.4 0.4 23.5 0.4 183.4 1.2 99999 99999 272.8 3.6 99999 99999 99999 99999 1199 12 88548 65.3 0.3 34.3 1.0 26.1 0.4 20.2 0.4 179.6 1.2 99999 99999 265.0 3.5 99999 99999 99999 99999 1195 12 88728 53.6 0.4 29.3 1.1 20.8 0.5 15.6 0.5 174.2 1.1 99999 99999 236.9 3.1 99999 99999 99999 99999 1164 12 88908 53.2 0.4 29.3 1.1 20.8 0.5 15.4 0.5 173.8 1.1 99999 99999 246.0 3.2 99999 99999 99999 99999 1154 12 89268 70.2 0.3 36.8 0.9 27.7 0.4 21.1 0.4 185.1 1.2 99999 99999 270.1 3.6 99999 99999 99999 99999 1206 13 89448 77.1 0.3 38.3 0.9 31.5 0.4 23.7 0.4 190.0 1.2 99999 99999 275.2 3.6 99999 99999 99999 99999 1225 13 89628 77.1 0.3 38.2 0.9 30.3 0.4 23.3 0.4 189.8 1.2 99999 99999 276.0 3.6 99999 99999 99999 99999 1220 13 90168 97.4 0.3 44.7 0.8 39.8 0.4 31.0 0.4 201.7 1.3 99999 99999 307.9 4.1 99999 99999 99999 99999 1283 14 90348 93.2 0.3 44.6 0.8 38.0 0.4 29.7 0.4 200.6 1.3 99999 99999 286.7 3.8 99999 99999 99999 99999 1292 14 90528 89.9 0.3 41.9 0.8 36.0 0.4 28.2 0.4 200.2 1.3 99999 99999 292.3 3.9 99999 99999 99999 99999 1278 14 90888 79.7 0.3 40.3 0.9 32.1 0.4 24.7 0.4 191.3 1.3 99999 99999 278.5 3.7 99999 99999 99999 99999 1231 13 91068 78.5 0.3 38.9 0.9 31.3 0.4 23.8 0.4 193.1 1.3 99999 99999 277.4 3.6 99999 99999 99999 99999 1241 13 91248 77.7 0.3 38.6 0.9 31.4 0.4 24.1 0.4 191.7 1.3 99999 99999 283.2 3.7 99999 99999 99999 99999 1235 13 91608 83.7 0.3 40.2 0.9 33.8 0.4 26.4 0.4 192.4 1.3 99999 99999 287.2 3.8 99999 99999 99999 99999 1256 13 91788 82.8 0.3 39.9 0.9 33.1 0.4 25.4 0.4 192.8 1.3 99999 99999 286.8 3.8 99999 99999 99999 99999 1239 13 91968 87.1 0.3 42.0 0.8 35.8 0.4 27.5 0.4 195.1 1.3 99999 99999 295.4 3.9 99999 99999 99999 99999 1272 13 92328 73.1 0.3 36.9 0.9 29.0 0.4 22.0 0.4 189.1 1.2 99999 99999 275.5 3.6 99999 99999 99999 99999 1201 13 92508 66.3 0.3 35.9 0.9 26.1 0.4 19.6 0.4 183.9 1.2 99999 99999 259.8 3.4 99999 99999 99999 99999 1187 12 92688 76.9 0.3 37.9 0.9 30.7 0.4 23.6 0.4 191.8 1.3 99999 99999 283.5 3.7 99999 99999 99999 99999 1222 13 93228 89.7 0.3 43.2 0.8 36.1 0.4 28.1 0.4 200.4 1.3 99999 99999 294.6 3.9 99999 99999 99999 99999 1269 13 93408 88.5 0.3 43.0 0.8 35.6 0.4 28.1 0.4 198.3 1.3 99999 99999 290.2 3.8 99999 99999 99999 99999 1244 13 93588 83.6 0.3 41.8 0.8 33.2 0.4 26.5 0.4 192.7 1.3 99999 99999 283.2 3.7 99999 99999 99999 99999 1230 13 93948 74.1 0.3 37.8 0.9 28.6 0.4 22.6 0.4 187.3 1.2 99999 99999 265.7 3.5 99999 99999 99999 99999 1212 13 94128 85.2 0.3 39.5 0.9 34.2 0.4 26.9 0.4 192.8 1.3 99999 99999 288.0 3.8 99999 99999 99999 99999 1213 13 94308 145.1 0.3 57.2 0.9 61.8 0.4 51.8 0.4 229.9 1.6 99999 99999 360.3 4.9 99999 99999 99999 99999 1396 15 94668 221.3 0.5 77.2 1.9 98.8 0.5 88.3 0.5 268.0 2.0 99999 99999 465.7 6.5 99999 99999 99999 99999 1650 20 94848 245.6 0.5 80.3 2.1 110.4 0.5 99.8 0.6 285.5 2.3 99999 99999 506.4 7.3 99999 99999 99999 99999 1748 22 95028 251.3 0.6 84.0 2.3 113.5 0.5 103.2 0.6 285.4 2.3 99999 99999 505.7 7.3 99999 99999 99999 99999 1762 23 95388 261.2 0.6 86.5 2.5 115.0 0.5 105.9 0.6 99999 99999 99999 99999 99999 99999 99999 99999 99999 99999 99999 99999 95568 258.3 0.6 105.7 4.1 114.3 0.5 107.8 0.6 99999 99999 99999 99999 99999 99999 99999 99999 99999 99999 99999 99999 95748 260.6 0.6 87.5 2.5 114.4 0.5 108.6 0.6 99999 99999 99999 99999 99999 99999 99999 99999 99999 99999 99999 99999