37 1001 ELKINS, JAMES; FAHEY, DAVID; GILLIGAN, JONATHAN; VOLK, CLAUS MICHAEL; DUTTON, GEOFF ; BARING, THOMAS; WAMSLEY, PAULA U.S. DEPT OF COMMERCE, NOAA / CMDL / NITROUS OXIDE AND HALOCARBONS DIVISION ACATS IV, ER-2 ASHOE 1 1 1994 05 28 1995 05 20 0 ELAPSED TIME IN SECONDS FROM 00:00:00 GMT ON SAMPLE DATE 20 1.0 1.0 1.0 1.0 1.0 1.0 1.0 1.0 1.0 1.0 1.0 1.0 1.0 1.0 1.0 1.0 1.0 1.0 1.0 1.0 99999 99999 99999 99999 99999 99999 99999 99999 99999 99999 99999 99999 99999 99999 99999 99999 99999 99999 99999 99999 MIXING RATIO CFC-11 (PPT) CFC-11 ERROR 1 S.D. (PPT) MIXING RATIO CFC-113 (PPT) CFC-113 ERROR 1 S.D. (PPT) MIXING RATIO CH3CCl3 (PPT) CH3CCl3 ERROR 1 S.D. (PPT) MIXING RATIO CCl4 (PPT) CCl4 ERROR 1 S.D. (PPT) MIXING RATIO N2O (PPB) N2O ERROR 1 S.D. (PPB) MIXING RATIO SF6 (PPT) SF6 ERROR 1 S.D. (PPT) MIXING RATIO CFC-12 (PPT) CFC-12 ERROR 1 S.D. (PPT) MIXING RATIO H1211 (PPT) H1211 ERROR 1 S.D. (PPT) MIXING RATIO H2 (PPB) H2 ERROR 1 S.D. (PPB) MIXING RATIO CH4 (PPB) CH4 ERROR 1 S.D. (PPB) 2 Final calibrations applied. Time corrected for pump delay using O3 data from Proffitt et al. 1 GMTs CFC11 CFC11e CFC113 CFC113e CH3CCl3 CH3CCl3e CCl4 CCl4e N2O N2Oe SF6 SF6e CFC12 CFC12e H1211 H1211e H2 H2e CH4 CH4e 72501 261.4 0.4 89.0 2.1 115.2 0.4 109.2 0.5 296.9 2.6 99999 99999 514.8 6.2 99999 99999 99999 99999 99999 99999 72681 252.3 0.4 89.0 2.1 113.7 0.4 105.3 0.5 290.8 2.5 99999 99999 501.4 6.0 99999 99999 99999 99999 99999 99999 72861 255.4 0.4 89.4 2.1 115.2 0.4 106.9 0.5 293.9 2.6 99999 99999 511.3 6.1 99999 99999 99999 99999 99999 99999 73220 213.1 0.3 78.7 1.6 96.2 0.4 85.7 0.4 267.5 2.3 99999 99999 459.2 5.6 99999 99999 99999 99999 1622 20 73401 205.4 0.3 76.0 1.5 92.8 0.4 81.2 0.4 266.0 2.3 99999 99999 445.6 5.5 99999 99999 99999 99999 1634 20 73581 175.3 0.3 66.2 1.2 77.9 0.4 66.7 0.3 248.4 2.2 99999 99999 401.6 5.2 99999 99999 99999 99999 1505 18 73941 148.2 0.3 58.2 1.0 64.1 0.3 53.6 0.3 230.2 2.0 99999 99999 378.4 5.0 99999 99999 99999 99999 1442 17 74121 152.5 0.3 60.2 1.1 66.4 0.3 55.4 0.3 233.1 2.1 99999 99999 377.9 5.0 99999 99999 99999 99999 1465 17 74301 140.0 0.3 56.9 1.0 59.9 0.3 49.8 0.3 229.3 2.0 99999 99999 364.8 5.0 99999 99999 99999 99999 1455 17 74661 166.9 0.3 65.2 1.2 74.2 0.4 61.8 0.3 245.0 2.1 99999 99999 398.3 5.2 99999 99999 99999 99999 1541 19 74841 164.8 0.3 64.2 1.2 71.9 0.3 60.1 0.3 244.9 2.1 99999 99999 398.2 5.2 99999 99999 99999 99999 1534 19 75021 174.4 0.3 67.8 1.3 78.0 0.4 65.1 0.3 251.6 2.2 99999 99999 413.1 5.3 99999 99999 99999 99999 1563 19 75561 175.1 0.3 67.2 1.3 78.8 0.4 65.6 0.3 250.1 2.2 99999 99999 409.7 5.3 99999 99999 99999 99999 1577 20 75741 187.0 0.3 69.2 1.4 84.2 0.4 70.9 0.4 254.6 2.2 99999 99999 418.6 5.4 99999 99999 99999 99999 1644 21 75921 170.1 0.3 65.5 1.2 76.9 0.4 63.5 0.3 246.5 2.2 99999 99999 397.4 5.2 99999 99999 99999 99999 1575 20 76281 169.1 0.3 65.1 1.2 75.0 0.4 62.9 0.3 245.3 2.1 99999 99999 404.2 5.3 99999 99999 99999 99999 1525 19 76461 192.8 0.3 71.2 1.5 87.4 0.4 73.8 0.4 261.6 2.3 99999 99999 428.9 5.4 99999 99999 99999 99999 1621 21 76641 181.3 0.3 68.7 1.4 82.0 0.4 68.6 0.4 254.3 2.2 99999 99999 417.1 5.3 99999 99999 99999 99999 1594 20 77001 161.9 0.3 63.2 1.2 72.7 0.4 59.8 0.3 243.6 2.1 99999 99999 387.7 5.1 99999 99999 99999 99999 1515 19 77181 141.4 0.3 56.6 1.0 62.3 0.3 50.6 0.3 230.5 2.0 99999 99999 363.6 5.0 99999 99999 99999 99999 1467 18 77361 167.3 0.3 65.1 1.3 74.3 0.4 62.1 0.3 244.7 2.1 99999 99999 399.0 5.2 99999 99999 99999 99999 1530 19 77721 181.6 0.3 67.8 1.4 81.9 0.4 69.0 0.4 250.4 2.2 99999 99999 410.7 5.3 99999 99999 99999 99999 1580 20 77900 186.7 0.3 69.7 1.5 83.7 0.4 71.2 0.4 257.9 2.2 99999 99999 422.1 5.4 99999 99999 99999 99999 1598 20 78081 178.0 0.3 67.3 1.4 80.2 0.4 66.3 0.3 99999 99999 99999 99999 404.7 5.2 99999 99999 99999 99999 1572 20 78621 190.1 0.3 69.4 1.5 86.7 0.4 72.9 0.4 264.1 2.3 99999 99999 433.7 5.5 99999 99999 99999 99999 1613 20 78801 180.0 0.3 66.5 1.4 81.2 0.4 68.2 0.4 256.3 2.2 99999 99999 413.4 5.3 99999 99999 99999 99999 1562 19 78981 180.8 0.3 67.3 1.4 81.3 0.4 68.5 0.4 257.1 2.2 99999 99999 420.6 5.4 99999 99999 99999 99999 1549 19 79341 178.5 0.3 66.3 1.4 80.2 0.4 67.9 0.3 256.7 2.2 99999 99999 414.3 5.4 99999 99999 99999 99999 1551 19 79521 189.9 0.3 68.4 1.5 87.0 0.4 72.9 0.4 262.6 2.2 99999 99999 432.4 5.5 99999 99999 99999 99999 1574 20 79701 181.9 0.3 66.4 1.4 82.5 0.4 69.0 0.4 255.2 2.2 99999 99999 399.3 5.3 99999 99999 99999 99999 1562 19 80061 181.8 0.3 67.0 1.4 82.5 0.4 69.2 0.4 256.0 2.2 99999 99999 415.7 5.4 99999 99999 99999 99999 1564 19 80241 163.3 0.3 61.7 1.2 73.0 0.4 61.0 0.3 249.9 2.2 99999 99999 376.1 5.1 99999 99999 99999 99999 1511 19 80421 161.0 0.3 60.7 1.2 72.1 0.4 59.4 0.3 244.5 2.1 99999 99999 383.3 5.2 99999 99999 99999 99999 1477 18 80781 158.4 0.3 60.4 1.1 71.0 0.3 59.0 0.3 245.1 2.1 99999 99999 376.9 5.1 99999 99999 99999 99999 1482 18 80961 168.1 0.3 63.1 1.2 75.2 0.4 62.7 0.3 250.2 2.2 99999 99999 399.3 5.3 99999 99999 99999 99999 1510 19 81141 174.1 0.3 65.1 1.3 78.8 0.4 65.5 0.3 249.8 2.2 99999 99999 407.0 5.3 99999 99999 99999 99999 1540 19 81681 99999 99999 99999 99999 99999 99999 99999 99999 253.4 2.2 99999 99999 99999 99999 99999 99999 99999 99999 1542 19 82041 176.3 0.3 65.7 1.3 79.2 0.4 67.1 0.3 250.4 2.2 99999 99999 407.8 5.4 99999 99999 99999 99999 1537 19 82401 132.9 0.3 53.9 1.0 57.3 0.3 46.4 0.3 225.5 2.0 99999 99999 351.0 5.0 99999 99999 99999 99999 1402 17 82581 137.6 0.3 55.8 1.0 60.4 0.3 48.7 0.3 226.9 2.1 99999 99999 355.8 5.0 99999 99999 99999 99999 1415 17 82761 145.2 0.3 56.7 1.1 63.7 0.3 52.6 0.3 231.0 2.1 99999 99999 351.3 5.0 99999 99999 99999 99999 1446 18 83121 144.5 0.3 57.2 1.1 63.0 0.3 52.0 0.3 226.9 2.1 99999 99999 360.3 5.0 99999 99999 99999 99999 1469 18 83481 151.3 0.3 59.4 1.1 66.4 0.3 54.8 0.3 236.7 2.1 99999 99999 370.6 5.1 99999 99999 99999 99999 1472 18 83841 190.4 0.3 69.6 1.6 84.6 0.4 71.8 0.4 259.9 2.3 99999 99999 428.0 5.5 99999 99999 99999 99999 1595 20 84021 184.0 0.3 67.8 1.5 82.7 0.4 69.6 0.4 255.3 2.2 99999 99999 412.5 5.4 99999 99999 99999 99999 1563 20 84201 136.0 0.3 53.6 1.0 58.7 0.3 48.4 0.3 223.2 2.0 99999 99999 349.4 4.9 99999 99999 99999 99999 1427 18 84741 259.7 0.5 87.9 2.6 117.7 0.5 108.4 0.5 298.7 2.7 99999 99999 515.2 6.3 99999 99999 99999 99999 1797 25 84921 259.1 0.5 86.6 2.5 115.9 0.5 106.9 0.5 295.4 2.7 99999 99999 518.0 6.3 99999 99999 99999 99999 1779 24 85101 259.7 0.5 87.6 2.5 118.4 0.5 108.4 0.5 294.0 2.6 99999 99999 524.0 6.4 99999 99999 99999 99999 1767 24 85461 246.4 0.4 84.9 2.3 112.2 0.4 100.8 0.5 286.3 2.5 99999 99999 498.9 6.1 99999 99999 99999 99999 1746 24 85641 229.1 0.4 79.9 1.9 103.3 0.4 91.8 0.4 279.8 2.5 99999 99999 486.6 6.0 99999 99999 99999 99999 1662 22 85821 194.0 0.3 70.1 1.4 86.3 0.4 74.4 0.4 258.5 2.3 99999 99999 435.5 5.6 99999 99999 99999 99999 1570 20 86181 170.4 0.3 65.5 1.2 75.3 0.4 63.2 0.3 248.7 2.2 99999 99999 398.5 5.3 99999 99999 99999 99999 1515 19 86361 190.3 0.3 70.9 1.5 86.0 0.4 72.3 0.4 258.7 2.3 99999 99999 428.8 5.5 99999 99999 99999 99999 1579 21 86541 189.7 0.3 70.3 1.5 85.9 0.4 72.0 0.4 258.2 2.3 99999 99999 427.7 5.5 99999 99999 99999 99999 1612 21 86901 184.7 0.3 70.1 1.5 83.2 0.4 68.8 0.4 255.9 2.3 99999 99999 425.9 5.5 99999 99999 99999 99999 1565 20 87081 183.6 0.3 68.7 1.4 82.9 0.4 68.1 0.3 254.2 2.3 99999 99999 421.8 5.5 99999 99999 99999 99999 1572 20 87260 166.9 0.3 65.1 1.3 73.8 0.4 60.3 0.3 243.6 2.2 99999 99999 387.2 5.2 99999 99999 99999 99999 1509 19 87801 132.8 0.3 54.0 1.0 57.9 0.3 46.7 0.3 219.8 2.0 99999 99999 345.9 4.9 99999 99999 99999 99999 1399 17 87981 138.1 0.3 55.5 1.0 59.5 0.3 48.7 0.3 225.1 2.0 99999 99999 359.2 5.0 99999 99999 99999 99999 1427 18 88161 143.0 0.3 57.0 1.0 62.5 0.3 50.6 0.3 229.9 2.1 99999 99999 361.2 5.0 99999 99999 99999 99999 1446 18 88521 165.0 0.3 62.8 1.2 73.2 0.4 60.5 0.3 244.4 2.2 99999 99999 396.3 5.3 99999 99999 99999 99999 1528 20 88701 168.8 0.3 63.7 1.2 75.2 0.4 61.7 0.3 247.7 2.2 99999 99999 396.1 5.3 99999 99999 99999 99999 1534 20 88881 164.1 0.3 63.4 1.2 72.3 0.4 59.1 0.3 245.9 2.2 99999 99999 386.7 5.2 99999 99999 99999 99999 1521 19 89241 158.7 0.3 62.0 1.2 69.7 0.3 56.6 0.3 241.6 2.2 99999 99999 390.3 5.3 99999 99999 99999 99999 1505 19 89421 157.1 0.3 60.6 1.1 68.9 0.3 56.6 0.3 240.0 2.1 99999 99999 380.0 5.2 99999 99999 99999 99999 1491 19 89601 164.4 0.3 64.0 1.2 72.1 0.4 60.1 0.3 242.5 2.2 99999 99999 392.8 5.3 99999 99999 99999 99999 1523 19 89961 154.3 0.3 59.7 1.1 68.0 0.3 56.1 0.3 234.9 2.1 99999 99999 380.2 5.2 99999 99999 99999 99999 1494 19 90141 157.7 0.3 60.9 1.2 70.3 0.3 57.0 0.3 238.4 2.1 99999 99999 384.0 5.2 99999 99999 99999 99999 1514 19 90321 153.5 0.3 60.0 1.1 67.9 0.3 55.0 0.3 238.4 2.1 99999 99999 375.0 5.1 99999 99999 99999 99999 1478 19 90861 150.2 0.3 59.4 1.1 65.7 0.3 53.9 0.3 236.2 2.1 99999 99999 372.3 5.1 99999 99999 99999 99999 1467 19 91041 142.6 0.3 56.6 1.0 61.9 0.3 49.9 0.3 233.1 2.1 99999 99999 347.4 5.0 99999 99999 99999 99999 1450 18 91221 143.0 0.3 57.2 1.0 62.4 0.3 50.7 0.3 234.7 2.1 99999 99999 366.3 5.1 99999 99999 99999 99999 1453 18 91581 137.5 0.3 57.0 1.0 59.2 0.3 47.6 0.3 230.5 2.1 99999 99999 361.3 5.0 99999 99999 99999 99999 1453 18 91761 132.7 0.3 55.4 1.0 57.2 0.3 45.8 0.3 229.3 2.1 99999 99999 356.9 5.0 99999 99999 99999 99999 1415 18 91941 141.8 0.3 57.8 1.1 61.4 0.3 49.5 0.3 231.6 2.1 99999 99999 367.8 5.1 99999 99999 99999 99999 1463 19 92301 143.2 0.3 58.6 1.1 61.6 0.3 50.1 0.3 232.7 2.1 99999 99999 377.0 5.1 99999 99999 99999 99999 1470 19 92481 141.9 0.3 58.7 1.1 61.0 0.3 48.7 0.3 232.3 2.1 99999 99999 367.1 5.1 99999 99999 99999 99999 1442 18 92660 143.9 0.3 57.7 1.0 62.5 0.3 49.9 0.3 239.1 2.1 99999 99999 369.4 5.1 99999 99999 99999 99999 1461 19 93021 141.3 0.3 58.6 1.1 61.6 0.3 48.3 0.3 234.6 2.1 99999 99999 374.0 5.1 99999 99999 99999 99999 1464 19 93201 137.4 0.3 57.6 1.1 59.1 0.3 47.3 0.3 232.6 2.1 99999 99999 366.0 5.0 99999 99999 99999 99999 1439 18 93381 131.8 0.3 53.8 1.0 56.2 0.3 44.9 0.3 229.4 2.1 99999 99999 353.9 5.0 99999 99999 99999 99999 1444 18 93921 116.1 0.3 50.5 1.0 48.9 0.3 38.3 0.3 214.6 2.0 99999 99999 329.4 4.8 99999 99999 99999 99999 1372 17 94101 107.3 0.3 47.2 1.0 45.3 0.3 35.5 0.3 209.2 2.0 99999 99999 322.5 4.7 99999 99999 99999 99999 1345 17 94281 100.5 0.3 45.3 1.0 41.6 0.3 32.6 0.3 204.1 1.9 99999 99999 311.6 4.7 99999 99999 99999 99999 1321 17 94641 103.8 0.3 46.3 1.0 43.9 0.3 34.0 0.3 204.3 2.0 99999 99999 319.2 4.7 99999 99999 99999 99999 1302 16 94821 103.2 0.3 46.2 1.0 43.3 0.3 33.4 0.3 207.5 2.0 99999 99999 313.0 4.7 99999 99999 99999 99999 1332 17 95001 99999 99999 43.0 1.0 39.3 0.3 30.2 0.3 201.3 1.9 99999 99999 303.1 4.6 99999 99999 99999 99999 1314 17 95361 106.0 0.3 46.7 1.0 43.9 0.3 34.7 0.3 210.9 2.0 99999 99999 318.1 4.8 99999 99999 99999 99999 1333 17 95541 108.9 0.3 48.8 1.0 45.6 0.3 35.0 0.3 215.0 2.0 99999 99999 325.5 4.8 99999 99999 99999 99999 1326 17 95721 107.3 0.3 47.7 1.0 44.6 0.3 34.7 0.3 213.2 2.0 99999 99999 313.6 4.7 99999 99999 99999 99999 1355 17 96081 99999 99999 99999 99999 99999 99999 99999 99999 212.6 2.0 99999 99999 313.0 4.7 99999 99999 99999 99999 1284 15 96261 99999 99999 99999 99999 99999 99999 99999 99999 217.1 2.0 99999 99999 326.4 4.8 99999 99999 99999 99999 99999 99999 96441 99999 99999 99999 99999 99999 99999 99999 99999 215.1 2.0 99999 99999 328.3 4.9 99999 99999 99999 99999 99999 99999 96981 99999 99999 99999 99999 99999 99999 99999 99999 207.1 2.0 99999 99999 306.7 4.7 99999 99999 99999 99999 99999 99999 97161 99999 99999 99999 99999 99999 99999 99999 99999 203.4 2.0 99999 99999 300.3 4.7 99999 99999 99999 99999 99999 99999 97341 99999 99999 99999 99999 99999 99999 99999 99999 203.5 2.0 99999 99999 296.4 4.7 99999 99999 99999 99999 99999 99999 97701 99999 99999 99999 99999 99999 99999 99999 99999 202.5 2.0 99999 99999 297.6 4.7 99999 99999 99999 99999 99999 99999 97881 99999 99999 99999 99999 99999 99999 99999 99999 208.6 2.0 99999 99999 308.2 4.8 99999 99999 99999 99999 99999 99999 98061 99999 99999 99999 99999 99999 99999 99999 99999 200.7 2.0 99999 99999 276.7 4.6 99999 99999 99999 99999 99999 99999 98421 99999 99999 99999 99999 99999 99999 99999 99999 224.6 2.1 99999 99999 361.3 5.1 99999 99999 99999 99999 99999 99999 98601 99999 99999 99999 99999 99999 99999 99999 99999 259.3 2.3 99999 99999 467.9 5.8 99999 99999 99999 99999 99999 99999 98781 99999 99999 99999 99999 99999 99999 99999 99999 280.6 2.6 99999 99999 505.6 5.9 99999 99999 99999 99999 99999 99999 99141 99999 99999 99999 99999 99999 99999 99999 99999 269.2 2.4 99999 99999 490.4 5.6 99999 99999 99999 99999 99999 99999 99321 99999 99999 99999 99999 99999 99999 99999 99999 276.6 2.5 99999 99999 506.3 5.7 99999 99999 99999 99999 99999 99999 99501 99999 99999 99999 99999 99999 99999 99999 99999 282.6 2.5 99999 99999 524.0 5.8 99999 99999 99999 99999 99999 99999 100041 99999 99999 99999 99999 99999 99999 99999 99999 299.0 2.7 99999 99999 451.4 5.3 99999 99999 99999 99999 99999 99999