37 1001 ELKINS, JAMES; FAHEY, DAVID; GILLIGAN, JONATHAN; VOLK, CLAUS MICHAEL; DUTTON, GEOFF ; BARING, THOMAS; WAMSLEY, PAULA U.S. DEPT OF COMMERCE, NOAA / CMDL / NITROUS OXIDE AND HALOCARBONS DIVISION ACATS IV, ER-2 ASHOE 1 1 1994 05 24 1995 05 21 0 ELAPSED TIME IN SECONDS FROM 00:00:00 GMT ON SAMPLE DATE 20 1.0 1.0 1.0 1.0 1.0 1.0 1.0 1.0 1.0 1.0 1.0 1.0 1.0 1.0 1.0 1.0 1.0 1.0 1.0 1.0 99999 99999 99999 99999 99999 99999 99999 99999 99999 99999 99999 99999 99999 99999 99999 99999 99999 99999 99999 99999 MIXING RATIO CFC-11 (PPT) CFC-11 ERROR 1 S.D. (PPT) MIXING RATIO CFC-113 (PPT) CFC-113 ERROR 1 S.D. (PPT) MIXING RATIO CH3CCl3 (PPT) CH3CCl3 ERROR 1 S.D. (PPT) MIXING RATIO CCl4 (PPT) CCl4 ERROR 1 S.D. (PPT) MIXING RATIO N2O (PPB) N2O ERROR 1 S.D. (PPB) MIXING RATIO SF6 (PPT) SF6 ERROR 1 S.D. (PPT) MIXING RATIO CFC-12 (PPT) CFC-12 ERROR 1 S.D. (PPT) MIXING RATIO H1211 (PPT) H1211 ERROR 1 S.D. (PPT) MIXING RATIO H2 (PPB) H2 ERROR 1 S.D. (PPB) MIXING RATIO CH4 (PPB) CH4 ERROR 1 S.D. (PPB) 2 Final calibrations applied. Time corrected for pump delay using O3 data from Proffitt et al. 1 GMTs CFC11 CFC11e CFC113 CFC113e CH3CCl3 CH3CCl3e CCl4 CCl4e N2O N2Oe SF6 SF6e CFC12 CFC12e H1211 H1211e H2 H2e CH4 CH4e 75239 212.8 0.3 82.4 3.0 94.6 0.5 87.1 0.6 280.4 2.1 99999 99999 438.8 3.3 99999 99999 99999 99999 99999 99999 75420 222.2 0.4 80.4 2.8 99.5 0.5 91.2 0.6 286.9 2.2 99999 99999 466.9 3.4 99999 99999 99999 99999 99999 99999 75600 191.7 0.3 69.8 2.0 84.6 0.5 76.1 0.5 265.5 1.9 99999 99999 425.2 3.2 99999 99999 99999 99999 99999 99999 75959 180.9 0.3 65.9 1.8 79.0 0.4 71.0 0.5 258.0 1.8 99999 99999 411.5 3.1 99999 99999 99999 99999 99999 99999 76139 140.0 0.2 54.3 1.4 57.9 0.4 50.8 0.5 232.6 1.5 99999 99999 357.7 2.8 99999 99999 99999 99999 99999 99999 76320 114.8 0.2 47.3 1.3 45.5 0.4 40.3 0.5 216.0 1.4 99999 99999 318.7 2.7 99999 99999 99999 99999 99999 99999 76680 121.3 0.2 48.2 1.3 48.6 0.4 43.1 0.5 219.3 1.4 99999 99999 334.7 2.8 99999 99999 99999 99999 1354 73 76860 123.3 0.2 49.0 1.3 49.6 0.4 44.4 0.5 220.0 1.4 99999 99999 335.4 2.8 99999 99999 99999 99999 1448 77 77039 105.9 0.2 45.7 1.3 40.8 0.4 37.3 0.4 208.3 1.3 99999 99999 310.1 2.7 99999 99999 99999 99999 1257 68 77580 87.2 0.2 41.1 1.2 31.9 0.4 30.1 0.4 196.0 1.2 99999 99999 289.3 2.6 99999 99999 99999 99999 1256 67 77760 81.4 0.3 39.5 1.2 29.9 0.4 27.5 0.4 193.4 1.2 99999 99999 278.9 2.6 99999 99999 99999 99999 1231 65 77940 81.8 0.3 39.2 1.2 30.6 0.4 28.1 0.4 192.4 1.2 99999 99999 283.5 2.6 99999 99999 99999 99999 1235 65 78299 93.5 0.2 40.9 1.2 34.9 0.4 32.2 0.4 200.7 1.2 99999 99999 297.7 2.6 99999 99999 99999 99999 1191 62 78479 89.6 0.2 41.2 1.2 33.2 0.4 30.5 0.4 197.5 1.2 99999 99999 291.2 2.6 99999 99999 99999 99999 1220 64 78660 80.2 0.3 38.5 1.2 29.2 0.4 27.3 0.4 191.7 1.2 99999 99999 277.9 2.6 99999 99999 99999 99999 1210 63 79020 118.1 0.2 46.6 1.2 48.2 0.4 42.4 0.4 217.2 1.4 99999 99999 329.3 2.7 99999 99999 99999 99999 1265 66 79200 123.4 0.2 47.7 1.2 49.2 0.4 43.5 0.4 220.4 1.4 99999 99999 334.2 2.8 99999 99999 99999 99999 1267 66 79380 131.8 0.2 49.0 1.3 54.8 0.4 47.8 0.4 226.1 1.5 99999 99999 347.2 2.8 99999 99999 99999 99999 1317 69 79740 124.4 0.2 47.7 1.2 50.4 0.4 44.7 0.4 222.1 1.4 99999 99999 341.0 2.8 99999 99999 99999 99999 1304 68 79920 128.7 0.2 48.7 1.2 53.1 0.4 46.8 0.4 225.9 1.5 99999 99999 338.9 2.8 99999 99999 99999 99999 1303 68 80100 134.1 0.2 48.6 1.2 55.8 0.4 49.3 0.4 229.3 1.5 99999 99999 342.0 2.8 99999 99999 99999 99999 1300 68 80639 137.5 0.2 49.0 1.2 57.3 0.4 50.9 0.4 227.7 1.5 99999 99999 349.2 2.8 99999 99999 99999 99999 1295 67 80820 138.8 0.2 49.2 1.2 58.5 0.4 50.4 0.4 228.0 1.5 99999 99999 349.7 2.8 99999 99999 99999 99999 1269 65 81000 139.5 0.2 49.9 1.2 58.1 0.4 51.3 0.5 230.3 1.5 99999 99999 352.4 2.8 99999 99999 99999 99999 1266 65 81359 141.9 0.2 49.6 1.2 60.0 0.4 52.5 0.5 232.6 1.5 99999 99999 356.8 2.9 99999 99999 99999 99999 1304 67 81539 135.8 0.2 47.6 1.2 56.6 0.4 49.7 0.4 228.3 1.5 99999 99999 351.0 2.8 99999 99999 99999 99999 1340 69 81719 103.0 0.2 40.8 1.1 40.0 0.4 35.5 0.4 209.1 1.3 99999 99999 308.9 2.7 99999 99999 99999 99999 1370 71 82080 106.8 0.2 41.5 1.1 41.8 0.4 37.4 0.4 212.0 1.3 99999 99999 321.3 2.7 99999 99999 99999 99999 1444 76 82260 72.9 0.3 34.4 1.0 25.7 0.4 23.9 0.4 187.2 1.1 99999 99999 266.7 2.6 99999 99999 99999 99999 1313 70 82440 97.7 0.2 40.2 1.1 37.7 0.4 33.8 0.4 205.4 1.3 99999 99999 304.2 2.7 99999 99999 99999 99999 1241 66 82799 97.6 0.2 38.5 1.1 38.0 0.4 34.6 0.4 199.9 1.2 99999 99999 301.6 2.7 99999 99999 99999 99999 99999 99999 82980 83.2 0.3 36.6 1.1 31.3 0.4 29.4 0.4 193.6 1.2 99999 99999 284.8 2.6 99999 99999 99999 99999 99999 99999 83160 96.9 0.2 39.8 1.1 37.8 0.4 34.8 0.4 203.8 1.3 99999 99999 301.9 2.7 99999 99999 99999 99999 1394 75 83699 96.7 0.2 40.4 1.1 36.2 0.4 33.9 0.4 203.3 1.2 99999 99999 308.0 2.7 99999 99999 99999 99999 1240 68 84060 86.4 0.2 36.9 1.1 31.8 0.4 29.7 0.4 195.2 1.2 99999 99999 288.7 2.6 99999 99999 99999 99999 1198 66 84420 112.2 0.2 42.7 1.1 44.4 0.4 39.4 0.4 214.7 1.3 99999 99999 319.7 2.7 99999 99999 99999 99999 1202 67 84600 121.3 0.2 45.6 1.2 49.5 0.4 43.1 0.4 219.5 1.4 99999 99999 332.1 2.8 99999 99999 99999 99999 1233 69 84779 104.8 0.2 41.1 1.1 40.7 0.4 36.5 0.4 207.0 1.3 99999 99999 311.5 2.7 99999 99999 99999 99999 1298 73 85140 73.3 0.3 34.7 1.1 26.3 0.4 25.2 0.4 186.1 1.1 99999 99999 271.3 2.6 99999 99999 99999 99999 1209 69 85500 102.7 0.2 39.7 1.1 39.2 0.4 35.4 0.4 203.4 1.2 99999 99999 310.7 2.7 99999 99999 99999 99999 1300 74 85859 93.5 0.2 38.9 1.1 34.9 0.4 32.6 0.4 196.9 1.2 99999 99999 291.6 2.6 99999 99999 99999 99999 1354 77 86039 54.0 0.4 30.0 1.0 17.4 0.5 18.2 0.5 172.7 1.0 99999 99999 241.1 2.5 99999 99999 99999 99999 1189 68 86220 55.4 0.4 30.8 1.0 18.1 0.5 19.5 0.5 176.0 1.0 99999 99999 245.3 2.5 99999 99999 99999 99999 1179 68 86759 66.0 0.3 33.2 1.1 22.2 0.5 22.8 0.4 181.1 1.1 99999 99999 257.4 2.5 99999 99999 99999 99999 1163 67 86939 60.0 0.3 32.4 1.1 19.9 0.5 20.8 0.5 175.5 1.0 99999 99999 250.3 2.5 99999 99999 99999 99999 1177 68 87119 59.0 0.3 32.1 1.1 19.3 0.5 20.1 0.5 175.0 1.0 99999 99999 247.9 2.5 99999 99999 99999 99999 1217 70 87480 59.2 0.3 32.4 1.1 19.8 0.5 20.2 0.5 175.9 1.0 99999 99999 244.3 2.5 99999 99999 99999 99999 1188 69 87660 68.8 0.3 33.4 1.1 23.1 0.4 23.0 0.4 181.7 1.1 99999 99999 264.4 2.5 99999 99999 99999 99999 1106 64 87840 76.7 0.3 36.1 1.1 27.5 0.4 26.0 0.4 186.9 1.1 99999 99999 277.6 2.6 99999 99999 99999 99999 1231 71 88199 76.8 0.3 36.7 1.1 26.8 0.4 26.4 0.4 186.3 1.1 99999 99999 274.6 2.6 99999 99999 99999 99999 1365 79 88380 60.9 0.3 32.8 1.1 19.5 0.5 20.4 0.4 176.6 1.0 99999 99999 252.1 2.5 99999 99999 99999 99999 1208 71 88560 94.1 0.2 39.7 1.1 35.2 0.4 32.5 0.4 201.0 1.2 99999 99999 294.3 2.6 99999 99999 99999 99999 1325 78 88919 115.0 0.2 42.9 1.2 45.0 0.4 41.1 0.4 212.7 1.3 99999 99999 323.6 2.7 99999 99999 99999 99999 1327 78 89099 132.9 0.2 46.7 1.2 54.7 0.4 48.4 0.4 221.4 1.4 99999 99999 342.8 2.8 99999 99999 99999 99999 1389 82 89279 125.7 0.2 44.8 1.2 50.7 0.4 43.6 0.4 219.5 1.4 99999 99999 337.0 2.8 99999 99999 99999 99999 1311 78 89820 70.1 0.3 34.8 1.1 23.0 0.4 23.9 0.4 184.8 1.1 99999 99999 266.5 2.5 99999 99999 99999 99999 99999 99999 89999 86.2 0.2 36.5 1.1 32.6 0.4 30.0 0.4 195.6 1.2 99999 99999 285.8 2.6 99999 99999 99999 99999 1225 72 90180 85.8 0.2 36.5 1.1 32.4 0.4 29.8 0.4 196.8 1.2 99999 99999 284.2 2.6 99999 99999 99999 99999 1221 71 90540 92.8 0.2 40.0 1.1 34.3 0.4 31.9 0.4 200.9 1.2 99999 99999 294.3 2.6 99999 99999 99999 99999 1280 73 90720 92.9 0.2 40.3 1.1 34.8 0.4 31.7 0.4 202.8 1.2 99999 99999 297.6 2.6 99999 99999 99999 99999 1289 72 90900 85.6 0.2 39.2 1.1 31.4 0.4 29.6 0.4 198.0 1.2 99999 99999 289.2 2.6 99999 99999 99999 99999 1144 64 91259 85.0 0.3 37.6 1.1 31.3 0.4 29.7 0.4 196.2 1.2 99999 99999 287.8 2.6 99999 99999 99999 99999 1160 64 91439 86.6 0.2 39.5 1.1 31.5 0.4 29.9 0.4 198.1 1.2 99999 99999 290.3 2.6 99999 99999 99999 99999 1276 70 91620 74.3 0.3 36.6 1.1 26.7 0.4 25.7 0.4 188.8 1.1 99999 99999 273.1 2.6 99999 99999 99999 99999 99999 99999 91980 50.4 0.4 29.7 1.1 15.6 0.5 18.1 0.5 170.2 1.0 99999 99999 240.2 2.5 99999 99999 99999 99999 1077 58 92159 48.4 0.4 30.9 1.1 15.0 0.5 17.3 0.5 171.0 1.0 99999 99999 235.5 2.5 99999 99999 99999 99999 1222 65 92339 61.1 0.3 32.8 1.1 20.3 0.5 21.4 0.4 179.5 1.1 99999 99999 250.6 2.5 99999 99999 99999 99999 1086 58 92880 67.6 0.3 34.3 1.1 23.7 0.4 23.3 0.4 181.8 1.1 99999 99999 263.1 2.5 99999 99999 99999 99999 1018 55 93060 69.3 0.3 34.9 1.1 24.0 0.4 23.7 0.4 187.0 1.1 99999 99999 264.6 2.5 99999 99999 99999 99999 1277 68 93239 68.8 0.3 35.2 1.1 23.1 0.5 23.5 0.4 185.1 1.1 99999 99999 267.7 2.5 99999 99999 99999 99999 1360 73 93599 47.9 0.4 29.7 1.0 15.2 0.5 17.0 0.5 171.7 1.0 99999 99999 240.8 2.5 99999 99999 99999 99999 1215 67 93780 41.3 0.4 27.2 1.0 11.7 0.5 15.5 0.5 164.5 1.0 99999 99999 219.7 2.4 99999 99999 99999 99999 99999 99999 93960 46.2 0.4 29.7 1.0 14.4 0.5 17.3 0.5 170.6 1.0 99999 99999 229.8 2.5 99999 99999 99999 99999 99999 99999 94319 53.7 0.4 31.6 1.0 17.1 0.5 19.1 0.5 175.0 1.1 99999 99999 244.8 2.5 99999 99999 99999 99999 99999 99999 94499 62.6 0.3 32.9 1.1 21.4 0.5 21.8 0.4 182.0 1.1 99999 99999 257.0 2.5 99999 99999 99999 99999 1209 70 94679 74.5 0.3 35.4 1.1 26.6 0.4 24.8 0.4 189.4 1.1 99999 99999 276.0 2.6 99999 99999 99999 99999 1195 69 95040 63.9 0.3 32.0 1.0 21.2 0.5 22.0 0.4 182.7 1.1 99999 99999 260.0 2.6 99999 99999 99999 99999 1150 66 95220 57.7 0.3 31.3 1.0 19.4 0.5 20.3 0.5 177.3 1.1 99999 99999 251.8 2.5 99999 99999 99999 99999 1053 61 95399 65.7 0.3 33.3 1.0 21.9 0.5 22.0 0.4 183.5 1.1 99999 99999 263.5 2.6 99999 99999 99999 99999 1136 65 95940 61.4 0.3 32.7 1.0 20.9 0.5 21.1 0.5 180.9 1.1 99999 99999 254.6 2.5 99999 99999 99999 99999 1058 61 96120 75.1 0.3 35.1 1.0 26.8 0.4 25.7 0.4 191.6 1.2 99999 99999 274.3 2.6 99999 99999 99999 99999 1186 69 96300 78.4 0.3 36.0 1.0 28.3 0.4 26.8 0.4 194.8 1.2 99999 99999 282.9 2.6 99999 99999 99999 99999 1208 71 96659 70.7 0.3 34.4 1.0 25.6 0.5 23.9 0.4 187.7 1.1 99999 99999 269.8 2.6 99999 99999 99999 99999 1288 75 96839 52.7 0.4 31.1 1.0 17.1 0.5 18.3 0.5 173.9 1.0 99999 99999 243.6 2.5 99999 99999 99999 99999 1191 70 97020 40.9 0.4 29.7 1.0 11.8 0.5 15.1 0.5 167.4 1.0 99999 99999 231.0 2.5 99999 99999 99999 99999 1101 65 97380 43.1 0.4 29.6 1.0 12.8 0.5 16.5 0.5 170.2 1.0 99999 99999 232.5 2.5 99999 99999 99999 99999 1175 69 97559 35.7 0.5 27.6 1.0 10.2 0.5 14.5 0.5 163.0 1.0 99999 99999 220.2 2.5 99999 99999 99999 99999 1103 65 97739 45.4 0.4 29.0 1.0 13.8 0.5 16.3 0.5 171.2 1.0 99999 99999 237.2 2.5 99999 99999 99999 99999 1119 65 98100 63.3 0.3 34.0 1.0 21.4 0.5 21.4 0.4 186.8 1.1 99999 99999 264.7 2.6 99999 99999 99999 99999 1217 71 98280 85.1 0.3 39.5 1.1 29.7 0.4 27.3 0.4 206.8 1.3 99999 99999 306.7 2.7 99999 99999 99999 99999 1273 74 98460 85.6 0.2 39.2 1.1 29.9 0.4 27.6 0.4 205.7 1.3 99999 99999 301.4 2.7 99999 99999 99999 99999 1212 71 98999 84.2 0.3 38.8 1.0 30.3 0.4 27.2 0.4 205.5 1.3 99999 99999 300.3 2.7 99999 99999 99999 99999 1282 74 99180 84.6 0.3 38.9 1.1 30.5 0.4 28.0 0.4 206.2 1.3 99999 99999 297.2 2.7 99999 99999 99999 99999 99999 99999 99360 90.1 0.2 39.7 1.1 33.7 0.4 29.2 0.4 208.7 1.3 99999 99999 305.2 2.7 99999 99999 99999 99999 1222 70 99719 83.5 0.3 38.0 1.1 30.7 0.4 27.4 0.4 204.5 1.3 99999 99999 298.9 2.7 99999 99999 99999 99999 1256 71 99899 61.0 0.3 32.7 1.0 21.6 0.5 20.8 0.5 99999 99999 99999 99999 257.3 2.6 99999 99999 99999 99999 1145 65 100079 99.0 0.2 39.7 1.1 38.1 0.4 34.4 0.4 209.4 1.3 99999 99999 312.9 2.7 99999 99999 99999 99999 1333 74 100440 194.2 0.3 59.0 1.4 86.7 0.5 77.3 0.5 263.3 1.9 99999 99999 426.2 3.2 99999 99999 99999 99999 1384 78 100620 158.9 0.2 99999 99999 69.7 0.4 60.7 0.5 242.1 1.6 99999 99999 372.8 2.9 99999 99999 99999 99999 1326 77 100799 188.8 0.3 61.3 1.5 82.3 0.5 74.7 0.5 258.8 1.8 99999 99999 401.9 3.0 99999 99999 99999 99999 1578 93 101160 99999 99999 99999 99999 99999 99999 99999 99999 99999 99999 99999 99999 99999 99999 99999 99999 99999 99999 99999 99999 101340 99999 99999 99999 99999 99999 99999 99999 99999 99999 99999 99999 99999 99999 99999 99999 99999 99999 99999 99999 99999 101520 99999 99999 99999 99999 99999 99999 99999 99999 99999 99999 99999 99999 99999 99999 99999 99999 99999 99999 99999 99999