37 1001 ELKINS, JAMES; FAHEY, DAVID; GILLIGAN, JONATHAN; VOLK, CLAUS MICHAEL; DUTTON, GEOFF ; BARING, THOMAS; WAMSLEY, PAULA U.S. DEPT OF COMMERCE, NOAA / CMDL / NITROUS OXIDE AND HALOCARBONS DIVISION ACATS IV, ER-2 ASHOE 1 1 1994 04 08 1995 05 22 0 ELAPSED TIME IN SECONDS FROM 00:00:00 GMT ON SAMPLE DATE 20 1.0 1.0 1.0 1.0 1.0 1.0 1.0 1.0 1.0 1.0 1.0 1.0 1.0 1.0 1.0 1.0 1.0 1.0 1.0 1.0 99999 99999 99999 99999 99999 99999 99999 99999 99999 99999 99999 99999 99999 99999 99999 99999 99999 99999 99999 99999 MIXING RATIO CFC-11 (PPT) CFC-11 ERROR 1 S.D. (PPT) MIXING RATIO CFC-113 (PPT) CFC-113 ERROR 1 S.D. (PPT) MIXING RATIO CH3CCl3 (PPT) CH3CCl3 ERROR 1 S.D. (PPT) MIXING RATIO CCl4 (PPT) CCl4 ERROR 1 S.D. (PPT) MIXING RATIO N2O (PPB) N2O ERROR 1 S.D. (PPB) MIXING RATIO SF6 (PPT) SF6 ERROR 1 S.D. (PPT) MIXING RATIO CFC-12 (PPT) CFC-12 ERROR 1 S.D. (PPT) MIXING RATIO H1211 (PPT) H1211 ERROR 1 S.D. (PPT) MIXING RATIO H2 (PPB) H2 ERROR 1 S.D. (PPB) MIXING RATIO CH4 (PPB) CH4 ERROR 1 S.D. (PPB) 2 Final calibrations applied. Time corrected for pump delay using O3 data from Proffitt et al. 1 GMTs CFC11 CFC11e CFC113 CFC113e CH3CCl3 CH3CCl3e CCl4 CCl4e N2O N2Oe SF6 SF6e CFC12 CFC12e H1211 H1211e H2 H2e CH4 CH4e 72243 264.5 0.5 85.8 4.7 116.3 0.9 113.5 0.8 292.2 2.4 99999 99999 574.0 6.7 99999 99999 99999 99999 1767 60 72423 264.6 0.5 87.6 5.0 116.9 0.9 111.8 0.7 287.0 2.4 99999 99999 562.6 6.7 99999 99999 99999 99999 1707 59 72603 257.3 0.5 85.3 4.3 116.4 0.9 108.6 0.7 287.8 2.4 99999 99999 481.2 6.0 99999 99999 99999 99999 1749 60 72963 239.9 0.4 78.3 3.2 108.4 0.8 98.9 0.7 276.9 2.3 99999 99999 483.0 6.0 99999 99999 99999 99999 1616 57 73143 233.9 0.4 76.4 3.0 106.7 0.8 95.4 0.6 273.7 2.2 99999 99999 474.0 6.0 99999 99999 99999 99999 1672 58 73323 245.1 0.5 79.7 3.5 111.3 0.9 100.8 0.7 280.8 2.3 99999 99999 494.3 6.2 99999 99999 99999 99999 1664 58 73683 225.1 0.4 75.5 2.9 102.0 0.8 89.7 0.6 270.8 2.2 99999 99999 460.2 5.9 99999 99999 99999 99999 1617 57 73863 213.1 0.4 71.0 2.5 96.8 0.8 84.7 0.6 265.7 2.1 99999 99999 442.9 5.8 99999 99999 99999 99999 1587 56 74043 211.1 0.4 69.7 2.3 95.6 0.8 83.7 0.6 264.3 2.1 99999 99999 445.2 5.8 99999 99999 99999 99999 1570 56 74403 227.6 0.4 75.1 2.8 103.3 0.8 88.9 0.6 278.2 2.3 99999 99999 475.7 6.1 99999 99999 99999 99999 1659 56 74583 228.7 0.4 74.4 2.7 103.8 0.8 89.8 0.6 278.3 2.3 99999 99999 483.0 6.2 99999 99999 99999 99999 1554 54 74763 191.5 0.3 63.8 1.9 85.4 0.8 72.7 0.6 255.7 2.0 99999 99999 422.4 5.6 99999 99999 99999 99999 1525 53 75303 215.6 0.4 70.1 2.3 96.6 0.8 83.7 0.6 271.5 2.2 99999 99999 460.9 6.0 99999 99999 99999 99999 1621 52 75483 218.2 0.4 71.4 2.4 97.9 0.8 84.5 0.6 273.5 2.2 99999 99999 467.7 6.0 99999 99999 99999 99999 1506 49 75663 191.3 0.3 63.2 1.8 84.9 0.8 72.4 0.6 256.0 2.0 99999 99999 426.0 5.7 99999 99999 99999 99999 1651 50 76023 164.6 0.2 55.4 1.5 71.3 0.7 60.1 0.5 241.1 1.8 99999 99999 386.6 5.3 99999 99999 99999 99999 1258 44 76203 161.4 0.2 55.8 1.5 70.4 0.7 60.0 0.5 237.4 1.8 99999 99999 383.0 5.3 99999 99999 99999 99999 1338 44 76383 157.8 0.2 55.0 1.5 68.3 0.7 57.0 0.5 236.1 1.8 99999 99999 377.5 5.3 99999 99999 99999 99999 1201 43 76743 150.2 0.2 52.3 1.4 64.9 0.7 55.1 0.5 231.9 1.7 99999 99999 361.3 5.2 99999 99999 99999 99999 1506 44 76923 114.3 0.2 45.4 1.3 47.1 0.7 38.5 0.5 211.1 1.5 99999 99999 316.1 4.8 99999 99999 99999 99999 1192 42 77103 112.1 0.2 44.8 1.3 45.5 0.7 37.9 0.5 210.2 1.5 99999 99999 313.3 4.8 99999 99999 99999 99999 1287 42 77463 98.4 0.2 41.9 1.2 39.0 0.7 32.6 0.5 199.2 1.4 99999 99999 293.8 4.7 99999 99999 99999 99999 1153 42 77643 95.1 0.2 41.1 1.2 38.5 0.7 31.3 0.5 196.6 1.4 99999 99999 291.4 4.7 99999 99999 99999 99999 1195 42 77823 90.8 0.2 40.6 1.2 35.5 0.7 29.2 0.5 194.4 1.4 99999 99999 278.9 4.6 99999 99999 99999 99999 1025 42 78363 116.0 0.2 43.6 1.2 47.8 0.7 39.5 0.5 212.0 1.6 99999 99999 321.1 4.8 99999 99999 99999 99999 1059 43 78543 113.8 0.2 43.2 1.2 45.8 0.7 38.5 0.5 210.9 1.6 99999 99999 322.8 4.8 99999 99999 99999 99999 1385 45 78723 114.5 0.2 43.9 1.2 47.1 0.7 38.9 0.5 212.4 1.6 99999 99999 326.6 4.9 99999 99999 99999 99999 1314 45 79083 96.3 0.2 39.4 1.1 38.8 0.7 31.6 0.5 202.5 1.5 99999 99999 309.0 4.8 99999 99999 99999 99999 1143 46 79263 87.6 0.2 38.2 1.1 34.2 0.7 27.8 0.5 197.3 1.4 99999 99999 293.1 4.7 99999 99999 99999 99999 1080 46 79443 95.9 0.2 39.1 1.1 37.8 0.7 31.3 0.5 202.0 1.5 99999 99999 300.3 4.7 99999 99999 99999 99999 1099 47 79803 107.5 0.2 40.8 1.1 44.4 0.7 36.4 0.5 207.3 1.5 99999 99999 316.8 4.8 99999 99999 99999 99999 1389 50 79983 94.3 0.2 38.9 1.1 37.5 0.7 30.5 0.5 197.0 1.4 99999 99999 297.4 4.7 99999 99999 99999 99999 1314 51 80163 96.4 0.2 38.5 1.1 37.5 0.7 31.9 0.5 199.3 1.4 99999 99999 303.6 4.8 99999 99999 99999 99999 1197 51 80523 91.1 0.2 37.4 1.1 36.7 0.7 30.0 0.5 197.3 1.4 99999 99999 293.5 4.7 99999 99999 99999 99999 1231 53 80703 80.4 0.3 36.6 1.1 31.9 0.7 24.3 0.5 189.5 1.3 99999 99999 283.2 4.7 99999 99999 99999 99999 1190 53 80883 75.6 0.3 35.6 1.1 28.2 0.7 23.3 0.5 187.8 1.3 99999 99999 278.6 4.6 99999 99999 99999 99999 1275 54 81423 67.8 0.3 34.7 1.1 25.4 0.7 20.5 0.5 181.9 1.3 99999 99999 261.0 4.5 99999 99999 99999 99999 1197 54 81783 58.2 0.3 33.0 1.1 22.0 0.7 16.4 0.5 174.1 1.2 99999 99999 242.9 4.5 99999 99999 99999 99999 1175 54 82143 56.5 0.4 31.7 1.1 20.8 0.7 15.5 0.5 171.2 1.2 99999 99999 241.7 4.5 99999 99999 99999 99999 1295 54 82323 57.7 0.3 32.9 1.1 20.9 0.7 16.0 0.5 174.2 1.2 99999 99999 250.1 4.5 99999 99999 99999 99999 1053 52 82503 55.0 0.4 31.7 1.1 20.1 0.7 15.5 0.5 170.6 1.2 99999 99999 240.7 4.4 99999 99999 99999 99999 1141 52 82863 68.3 0.3 34.9 1.1 25.2 0.7 19.3 0.5 183.0 1.3 99999 99999 260.9 4.6 99999 99999 99999 99999 1077 51 83223 50.4 0.4 30.6 1.1 17.5 0.7 14.1 0.5 170.0 1.2 99999 99999 233.8 4.4 99999 99999 99999 99999 1121 51 83583 44.8 0.4 30.8 1.1 15.9 0.7 12.1 0.5 169.0 1.2 99999 99999 217.8 4.3 99999 99999 99999 99999 1124 51 83763 41.3 0.4 30.7 1.1 13.7 0.7 10.8 0.5 167.5 1.2 99999 99999 231.3 4.4 99999 99999 99999 99999 725 50 83943 42.5 0.4 30.6 1.1 14.5 0.7 9.4 0.5 167.9 1.2 99999 99999 227.6 4.4 99999 99999 99999 99999 1053 51 84483 109.5 0.2 42.5 1.2 44.0 0.7 36.6 0.5 208.0 1.5 99999 99999 309.9 4.8 99999 99999 99999 99999 1280 52 84663 128.1 0.2 47.8 1.3 53.0 0.7 43.8 0.5 223.7 1.6 99999 99999 345.2 5.1 99999 99999 99999 99999 1357 52 84843 132.1 0.2 48.5 1.3 54.3 0.7 45.0 0.5 226.4 1.7 99999 99999 352.9 5.1 99999 99999 99999 99999 1322 52 85203 107.0 0.2 42.9 1.2 42.7 0.7 34.6 0.5 207.1 1.5 99999 99999 309.3 4.8 99999 99999 99999 99999 1253 51 85383 96.2 0.2 40.8 1.2 38.3 0.7 30.6 0.5 201.8 1.4 99999 99999 293.0 4.7 99999 99999 99999 99999 1209 51 85563 110.7 0.2 43.9 1.2 45.2 0.7 36.6 0.5 210.1 1.5 99999 99999 314.1 4.9 99999 99999 99999 99999 1214 51 85923 161.9 0.2 54.5 1.4 70.2 0.7 59.8 0.5 237.0 1.8 99999 99999 374.2 5.3 99999 99999 99999 99999 99999 99999 86103 187.8 0.3 60.5 1.6 82.6 0.8 71.2 0.5 251.9 1.9 99999 99999 413.2 5.6 99999 99999 99999 99999 1513 54 86283 199.0 0.3 62.3 1.7 87.4 0.8 76.6 0.6 258.8 2.0 99999 99999 422.2 5.6 99999 99999 99999 99999 1488 54 86643 187.6 0.3 58.0 1.6 81.9 0.8 72.5 0.6 250.9 1.9 99999 99999 415.4 5.6 99999 99999 99999 99999 1485 52 86823 148.9 0.2 49.8 1.4 64.1 0.7 53.8 0.5 229.0 1.7 99999 99999 355.2 5.1 99999 99999 99999 99999 99999 99999 87003 154.7 0.2 51.8 1.4 66.2 0.7 56.4 0.5 232.7 1.7 99999 99999 366.3 5.2 99999 99999 99999 99999 1198 50 87543 96.3 0.2 40.5 1.2 37.9 0.7 31.6 0.5 196.1 1.4 99999 99999 293.8 4.7 99999 99999 99999 99999 1550 53 87723 71.5 0.3 34.9 1.2 26.9 0.7 20.7 0.5 182.1 1.3 99999 99999 264.8 4.6 99999 99999 99999 99999 1185 50 87903 65.0 0.3 35.9 1.2 23.7 0.7 19.3 0.5 179.2 1.2 99999 99999 258.9 4.5 99999 99999 99999 99999 99999 99999 88263 51.5 0.4 32.8 1.2 18.2 0.7 14.4 0.5 167.6 1.2 99999 99999 239.4 4.4 99999 99999 99999 99999 99999 99999 88443 50.9 0.4 32.4 1.2 17.1 0.7 13.2 0.5 169.1 1.2 99999 99999 236.2 4.4 99999 99999 99999 99999 1110 51 88623 56.6 0.4 34.2 1.2 19.8 0.7 15.2 0.5 174.8 1.2 99999 99999 252.5 4.5 99999 99999 99999 99999 1060 51 88983 66.2 0.3 36.3 1.2 24.6 0.7 19.8 0.5 180.5 1.3 99999 99999 263.2 4.6 99999 99999 99999 99999 1228 53 89163 69.7 0.3 34.3 1.2 25.5 0.7 20.6 0.5 183.9 1.3 99999 99999 264.4 4.6 99999 99999 99999 99999 1255 54 89343 52.2 0.4 32.2 1.1 18.4 0.7 14.2 0.5 168.9 1.2 99999 99999 233.9 4.4 99999 99999 99999 99999 1104 54 89703 65.2 0.3 34.4 1.1 24.0 0.7 18.9 0.5 178.6 1.3 99999 99999 254.4 4.5 99999 99999 99999 99999 1229 55 89883 49.0 0.4 32.0 1.1 17.3 0.7 12.2 0.5 170.0 1.2 99999 99999 237.0 4.4 99999 99999 99999 99999 1213 56 90063 60.9 0.3 34.1 1.1 22.1 0.7 16.1 0.5 177.1 1.2 99999 99999 248.4 4.5 99999 99999 99999 99999 1262 56 90603 92.8 0.2 40.7 1.2 36.2 0.7 30.2 0.5 199.3 1.4 99999 99999 293.6 4.7 99999 99999 99999 99999 1272 56 90783 93.6 0.2 40.4 1.2 36.6 0.7 29.3 0.5 198.0 1.4 99999 99999 295.6 4.8 99999 99999 99999 99999 1282 56 90963 100.4 0.2 42.7 1.2 40.1 0.7 32.4 0.5 205.0 1.5 99999 99999 302.0 4.8 99999 99999 99999 99999 1285 56 91323 90.0 0.2 39.9 1.2 35.6 0.7 28.3 0.5 197.0 1.4 99999 99999 284.9 4.7 99999 99999 99999 99999 1281 55 91503 76.5 0.3 36.6 1.2 29.1 0.7 23.3 0.5 189.0 1.3 99999 99999 249.1 4.5 99999 99999 99999 99999 1263 55 91683 98.1 0.2 41.5 1.2 38.3 0.7 32.0 0.5 202.9 1.4 99999 99999 303.5 4.8 99999 99999 99999 99999 1274 55 92043 105.5 0.2 43.5 1.2 42.2 0.7 33.4 0.5 207.5 1.5 99999 99999 310.4 4.8 99999 99999 99999 99999 1246 55 92223 101.9 0.2 41.3 1.2 40.5 0.7 31.8 0.5 205.2 1.5 99999 99999 308.7 4.8 99999 99999 99999 99999 1336 56 92403 94.3 0.2 40.2 1.2 36.4 0.7 29.8 0.5 200.0 1.4 99999 99999 295.5 4.7 99999 99999 99999 99999 1200 55 92763 84.2 0.3 37.9 1.2 34.7 0.7 26.0 0.5 193.7 1.4 99999 99999 285.3 4.7 99999 99999 99999 99999 1197 54 92943 80.3 0.3 37.9 1.2 29.6 0.7 24.6 0.5 191.2 1.3 99999 99999 275.5 4.6 99999 99999 99999 99999 1286 55 93123 75.2 0.3 35.8 1.1 28.5 0.7 22.4 0.5 185.5 1.3 99999 99999 271.1 4.6 99999 99999 99999 99999 1097 53 93663 78.6 0.3 36.6 1.1 29.5 0.7 22.9 0.5 187.8 1.3 99999 99999 280.5 4.7 99999 99999 99999 99999 1156 52 93843 81.8 0.3 37.5 1.2 32.0 0.7 25.9 0.5 189.3 1.3 99999 99999 270.8 4.6 99999 99999 99999 99999 1224 52 94023 84.5 0.3 38.9 1.2 32.7 0.7 25.9 0.5 196.2 1.4 99999 99999 285.3 4.7 99999 99999 99999 99999 1198 52 94383 107.6 0.2 43.1 1.2 42.4 0.7 33.6 0.5 208.8 1.5 99999 99999 320.1 4.9 99999 99999 99999 99999 1227 51 94563 178.1 0.3 60.4 1.6 76.6 0.8 63.7 0.5 258.1 2.0 99999 99999 421.5 5.6 99999 99999 99999 99999 1418 52 94743 164.5 0.3 56.1 1.5 69.5 0.7 58.2 0.5 244.6 1.9 99999 99999 397.5 5.4 99999 99999 99999 99999 1372 51 95103 171.0 0.3 57.9 1.6 72.8 0.8 61.1 0.5 249.1 1.9 99999 99999 413.6 5.6 99999 99999 99999 99999 1388 51 95283 161.4 0.2 55.7 1.5 69.2 0.7 57.1 0.5 244.6 1.9 99999 99999 398.7 5.4 99999 99999 99999 99999 1422 51 95463 166.6 0.3 56.5 1.5 70.5 0.7 59.1 0.5 249.4 1.9 99999 99999 406.2 5.5 99999 99999 99999 99999 1438 51 95823 136.5 0.2 48.7 1.3 57.1 0.7 47.1 0.5 227.5 1.7 99999 99999 356.4 5.1 99999 99999 99999 99999 1516 52 96003 150.9 0.2 52.5 1.4 63.6 0.7 52.4 0.5 240.0 1.8 99999 99999 377.8 5.3 99999 99999 99999 99999 1322 51 96183 133.3 0.2 48.5 1.3 56.1 0.7 46.0 0.5 226.2 1.7 99999 99999 354.6 5.1 99999 99999 99999 99999 1299 51 96723 156.1 0.2 54.1 1.4 66.1 0.7 54.9 0.5 241.4 1.8 99999 99999 393.4 5.4 99999 99999 99999 99999 1563 55 96903 164.8 0.3 56.6 1.5 69.6 0.8 58.2 0.5 246.0 1.9 99999 99999 399.9 5.4 99999 99999 99999 99999 1482 54 97083 177.9 0.3 60.3 1.6 75.8 0.8 63.4 0.5 258.9 2.0 99999 99999 431.0 5.7 99999 99999 99999 99999 1670 57 97443 162.9 0.3 56.1 1.5 68.7 0.7 57.0 0.5 247.2 1.9 99999 99999 402.1 5.5 99999 99999 99999 99999 1522 56 97623 178.0 0.3 60.0 1.6 76.7 0.8 63.5 0.5 255.8 2.0 99999 99999 427.7 5.7 99999 99999 99999 99999 1518 56 97803 179.0 0.3 60.5 1.6 76.2 0.8 63.9 0.5 257.4 2.0 99999 99999 437.6 5.8 99999 99999 99999 99999 1669 58 98163 197.2 0.3 64.9 1.8 86.0 0.8 71.8 0.6 265.7 2.1 99999 99999 456.6 5.9 99999 99999 99999 99999 1718 60 98343 201.2 0.3 65.5 1.8 87.3 0.8 75.8 0.6 263.8 2.1 99999 99999 448.6 5.9 99999 99999 99999 99999 1662 59 98523 232.0 0.4 73.1 2.3 102.7 0.8 91.2 0.6 277.8 2.2 99999 99999 490.6 6.3 99999 99999 99999 99999 1625 59 98883 231.6 0.4 73.9 2.4 102.6 0.8 92.9 0.6 272.9 2.2 99999 99999 470.3 6.1 99999 99999 99999 99999 99999 99999 99063 252.9 0.5 80.6 3.2 112.6 0.9 105.6 0.7 285.8 2.4 99999 99999 504.5 6.4 99999 99999 99999 99999 99999 99999 99243 263.7 0.5 87.1 4.4 111.8 0.9 110.0 0.7 293.0 2.5 99999 99999 527.2 6.6 99999 99999 99999 99999 99999 99999 99783 99999 99999 99999 99999 99999 99999 99999 99999 99999 99999 99999 99999 99999 99999 99999 99999 99999 99999 99999 99999 99963 99999 99999 99999 99999 99999 99999 99999 99999 99999 99999 99999 99999 99999 99999 99999 99999 99999 99999 99999 99999