37 1001 ELKINS, JAMES; FAHEY, DAVID; GILLIGAN, JONATHAN; VOLK, CLAUS MICHAEL; DUTTON, GEOFF ; BARING, THOMAS; WAMSLEY, PAULA U.S. DEPT OF COMMERCE, NOAA / CMDL / NITROUS OXIDE AND HALOCARBONS DIVISION ACATS IV, ER-2 ASHOE 1 1 1994 04 03 1995 05 22 0 ELAPSED TIME IN SECONDS FROM 00:00:00 GMT ON SAMPLE DATE 20 1.0 1.0 1.0 1.0 1.0 1.0 1.0 1.0 1.0 1.0 1.0 1.0 1.0 1.0 1.0 1.0 1.0 1.0 1.0 1.0 99999 99999 99999 99999 99999 99999 99999 99999 99999 99999 99999 99999 99999 99999 99999 99999 99999 99999 99999 99999 MIXING RATIO CFC-11 (PPT) CFC-11 ERROR 1 S.D. (PPT) MIXING RATIO CFC-113 (PPT) CFC-113 ERROR 1 S.D. (PPT) MIXING RATIO CH3CCl3 (PPT) CH3CCl3 ERROR 1 S.D. (PPT) MIXING RATIO CCl4 (PPT) CCl4 ERROR 1 S.D. (PPT) MIXING RATIO N2O (PPB) N2O ERROR 1 S.D. (PPB) MIXING RATIO SF6 (PPT) SF6 ERROR 1 S.D. (PPT) MIXING RATIO CFC-12 (PPT) CFC-12 ERROR 1 S.D. (PPT) MIXING RATIO H1211 (PPT) H1211 ERROR 1 S.D. (PPT) MIXING RATIO H2 (PPB) H2 ERROR 1 S.D. (PPB) MIXING RATIO CH4 (PPB) CH4 ERROR 1 S.D. (PPB) 2 Final calibrations applied. Time corrected for pump delay using O3 data from Proffitt et al. 1 GMTs CFC11 CFC11e CFC113 CFC113e CH3CCl3 CH3CCl3e CCl4 CCl4e N2O N2Oe SF6 SF6e CFC12 CFC12e H1211 H1211e H2 H2e CH4 CH4e 73107 267.3 0.7 90.6 3.9 115.7 0.8 108.9 1.6 307.0 3.7 99999 99999 567.7 3.3 99999 99999 99999 99999 99999 99999 73286 267.3 0.7 89.7 3.7 119.0 0.8 109.4 1.6 301.2 3.6 99999 99999 526.7 3.0 99999 99999 99999 99999 99999 99999 73466 265.7 0.7 88.1 3.5 115.7 0.8 110.1 1.5 299.5 3.6 99999 99999 545.0 3.3 99999 99999 99999 99999 1784 130 73826 252.2 0.6 83.8 3.0 112.1 0.8 103.1 1.4 290.5 3.5 99999 99999 529.3 3.2 99999 99999 99999 99999 1834 123 74007 198.0 0.4 69.0 1.9 86.4 0.7 77.5 1.3 259.2 3.0 99999 99999 438.5 2.6 99999 99999 99999 99999 1561 115 74187 217.3 0.5 70.6 1.9 96.1 0.7 86.4 1.3 273.8 3.2 99999 99999 464.3 2.7 99999 99999 99999 99999 1691 116 74547 189.4 0.4 62.3 1.6 81.2 0.7 74.6 1.2 253.7 2.9 99999 99999 412.3 2.4 99999 99999 99999 99999 1682 114 74726 203.9 0.4 66.7 1.7 88.7 0.7 80.3 1.3 265.1 3.1 99999 99999 436.4 2.5 99999 99999 99999 99999 1744 116 74907 194.4 0.4 64.4 1.6 82.7 0.7 74.5 1.2 260.8 3.0 99999 99999 424.5 2.4 99999 99999 99999 99999 1685 115 75267 154.5 0.3 52.3 1.3 63.5 0.7 56.5 1.1 235.0 2.7 99999 99999 371.3 2.2 99999 99999 99999 99999 1580 114 75447 156.6 0.3 54.8 1.3 64.8 0.7 58.3 1.1 235.4 2.7 99999 99999 373.8 2.2 99999 99999 99999 99999 1414 111 75627 168.4 0.3 56.8 1.4 71.0 0.7 61.7 1.1 243.4 2.8 99999 99999 388.9 2.2 99999 99999 99999 99999 1504 113 76167 186.3 0.4 61.3 1.5 79.6 0.7 73.0 1.2 256.5 2.9 99999 99999 413.8 2.3 99999 99999 99999 99999 1500 112 76347 215.6 0.5 68.0 1.7 92.7 0.7 86.3 1.3 275.6 3.2 99999 99999 460.9 2.6 99999 99999 99999 99999 1669 114 76527 222.3 0.5 71.2 1.9 97.1 0.7 86.0 1.3 280.0 3.3 99999 99999 470.5 2.6 99999 99999 99999 99999 1681 113 76886 226.9 0.5 72.6 2.0 99.0 0.7 89.8 1.3 282.0 3.3 99999 99999 477.4 2.7 99999 99999 99999 99999 1673 109 77066 229.3 0.5 72.9 2.0 98.4 0.7 92.3 1.3 285.3 3.3 99999 99999 487.2 2.7 99999 99999 99999 99999 1562 106 77247 215.5 0.5 69.7 1.8 93.3 0.7 83.5 1.3 276.9 3.2 99999 99999 463.9 2.6 99999 99999 99999 99999 1606 106 77607 205.6 0.4 66.5 1.6 87.5 0.7 79.2 1.2 267.9 3.1 99999 99999 441.2 2.5 99999 99999 99999 99999 1598 106 77787 222.2 0.5 69.3 1.8 96.8 0.7 83.5 1.3 278.0 3.3 99999 99999 460.1 2.6 99999 99999 99999 99999 1611 108 77967 175.7 0.4 55.2 1.3 74.2 0.7 64.6 1.1 243.1 2.8 99999 99999 392.7 2.2 99999 99999 99999 99999 1393 105 78327 168.1 0.3 53.0 1.2 70.9 0.7 62.4 1.1 238.4 2.7 99999 99999 375.6 2.2 99999 99999 99999 99999 1469 110 78507 159.7 0.3 53.0 1.2 67.5 0.7 58.1 1.1 233.1 2.6 99999 99999 363.3 2.1 99999 99999 99999 99999 1510 113 78686 159.9 0.3 52.0 1.2 67.6 0.7 59.9 1.1 235.9 2.7 99999 99999 369.4 2.2 99999 99999 99999 99999 1461 115 79226 188.8 0.4 58.4 1.3 80.9 0.7 74.2 1.2 257.0 3.0 99999 99999 420.4 2.4 99999 99999 99999 99999 1674 126 79407 184.9 0.4 56.8 1.3 79.5 0.7 70.0 1.2 256.8 3.0 99999 99999 411.0 2.3 99999 99999 99999 99999 1636 126 79587 175.0 0.4 52.6 1.2 74.7 0.7 68.4 1.2 250.0 2.9 99999 99999 400.4 2.3 99999 99999 99999 99999 1718 130 79947 166.8 0.3 50.2 1.2 69.8 0.7 63.6 1.2 244.9 2.8 99999 99999 387.6 2.2 99999 99999 99999 99999 1647 130 80126 174.8 0.4 54.1 1.2 73.8 0.7 65.3 1.2 248.3 2.8 99999 99999 394.6 2.3 99999 99999 99999 99999 1671 131 80306 172.5 0.4 54.0 1.2 72.0 0.7 66.5 1.2 246.6 2.8 99999 99999 400.0 2.3 99999 99999 99999 99999 1595 129 80667 164.8 0.3 51.7 1.2 69.1 0.7 63.5 1.2 239.2 2.7 99999 99999 382.7 2.2 99999 99999 99999 99999 1641 131 80847 165.6 0.3 51.9 1.2 70.7 0.7 59.9 1.1 238.4 2.7 99999 99999 386.4 2.2 99999 99999 99999 99999 1576 130 81027 168.1 0.4 51.4 1.2 72.0 0.7 64.1 1.2 239.3 2.7 99999 99999 384.9 2.2 99999 99999 99999 99999 1698 134 81386 168.0 0.4 52.4 1.2 72.3 0.7 61.7 1.1 239.4 2.7 99999 99999 380.9 2.2 99999 99999 99999 99999 1643 131 81567 167.8 0.4 52.5 1.2 70.6 0.7 61.5 1.1 238.5 2.7 99999 99999 384.6 2.2 99999 99999 99999 99999 1614 128 81747 169.8 0.4 53.0 1.2 72.1 0.7 63.0 1.2 242.6 2.7 99999 99999 390.0 2.2 99999 99999 99999 99999 1615 126 82286 175.4 0.4 55.6 1.3 75.5 0.7 65.2 1.2 246.4 2.8 99999 99999 394.0 2.2 99999 99999 99999 99999 1480 117 82647 171.6 0.4 55.1 1.3 74.6 0.7 63.4 1.2 243.1 2.7 99999 99999 386.7 2.2 99999 99999 99999 99999 1824 121 83007 172.7 0.4 54.0 1.3 74.3 0.7 66.2 1.2 240.4 2.7 99999 99999 395.6 2.2 99999 99999 99999 99999 1631 113 83187 172.5 0.4 56.1 1.3 74.7 0.7 63.4 1.2 241.3 2.7 99999 99999 390.2 2.2 99999 99999 99999 99999 1566 112 83367 176.7 0.4 56.3 1.3 77.1 0.7 66.1 1.2 242.8 2.7 99999 99999 396.8 2.2 99999 99999 99999 99999 99999 99999 83727 194.0 0.4 59.6 1.4 84.6 0.7 77.4 1.2 257.3 2.9 99999 99999 423.4 2.4 99999 99999 99999 99999 1626 112 84087 215.0 0.5 67.5 1.7 94.7 0.8 83.3 1.3 271.6 3.1 99999 99999 456.9 2.5 99999 99999 99999 99999 1463 108 84446 222.4 0.5 69.5 1.8 97.6 0.8 87.1 1.3 280.2 3.3 99999 99999 467.1 2.6 99999 99999 99999 99999 1691 112 84626 227.8 0.5 70.6 1.8 101.6 0.8 91.0 1.3 282.1 3.3 99999 99999 474.3 2.6 99999 99999 99999 99999 1659 113 84807 226.8 0.5 70.8 1.8 101.2 0.8 90.2 1.3 280.9 3.3 99999 99999 477.3 2.7 99999 99999 99999 99999 1642 113 85347 208.2 0.5 65.2 1.6 91.8 0.7 82.6 1.3 265.4 3.1 99999 99999 444.3 2.5 99999 99999 99999 99999 1680 117 85526 243.3 0.6 75.9 2.2 108.7 0.8 99.4 1.4 288.3 3.4 99999 99999 492.8 2.8 99999 99999 99999 99999 1688 119 85706 245.9 0.6 76.7 2.3 115.0 0.8 104.1 1.5 286.5 3.4 99999 99999 480.8 2.7 99999 99999 99999 99999 99999 99999 86067 261.2 0.6 81.7 2.7 116.7 0.8 109.3 1.5 295.0 3.5 99999 99999 516.4 2.9 99999 99999 99999 99999 1836 125 86247 262.0 0.6 82.5 2.8 114.4 0.8 116.5 1.6 296.4 3.5 99999 99999 520.9 3.0 99999 99999 99999 99999 1869 126 86427 261.8 0.6 82.5 2.8 113.4 0.8 116.6 1.6 294.3 3.5 99999 99999 516.3 2.9 99999 99999 99999 99999 1861 125 86786 249.6 0.6 80.5 2.6 112.3 0.8 108.1 1.5 288.9 3.4 99999 99999 492.6 2.8 99999 99999 99999 99999 1757 123 86967 243.4 0.6 78.6 2.5 110.3 0.8 99.3 1.4 282.9 3.3 99999 99999 501.0 2.8 99999 99999 99999 99999 1711 121 87147 240.4 0.6 77.8 2.4 108.0 0.8 99.4 1.4 283.3 3.3 99999 99999 492.3 2.7 99999 99999 99999 99999 1600 119 87507 229.5 0.5 74.1 2.1 103.8 0.8 89.0 1.3 280.5 3.3 99999 99999 476.6 2.6 99999 99999 99999 99999 1674 121 87686 218.6 0.5 70.6 1.9 100.1 0.8 84.1 1.3 275.0 3.2 99999 99999 463.5 2.5 99999 99999 99999 99999 1665 121 87866 220.3 0.5 71.0 1.9 99.5 0.8 83.4 1.3 277.3 3.2 99999 99999 468.2 2.6 99999 99999 99999 99999 1791 124 88407 219.9 0.5 70.9 1.9 99.2 0.8 80.0 1.2 277.4 3.2 99999 99999 462.1 2.5 99999 99999 99999 99999 1605 120 88587 219.4 0.5 70.7 1.9 97.3 0.8 83.9 1.3 277.1 3.2 99999 99999 456.5 2.5 99999 99999 99999 99999 1762 123 88766 218.5 0.5 69.7 1.8 97.8 0.8 83.0 1.3 274.2 3.2 99999 99999 471.5 2.6 99999 99999 99999 99999 1790 124 89127 214.6 0.5 68.6 1.8 95.1 0.8 79.0 1.2 273.5 3.1 99999 99999 462.0 2.5 99999 99999 99999 99999 1705 122 89307 214.6 0.5 68.9 1.8 96.4 0.8 79.8 1.2 274.2 3.1 99999 99999 460.4 2.5 99999 99999 99999 99999 1740 123 89487 215.7 0.5 69.8 1.8 96.0 0.8 81.4 1.3 275.5 3.2 99999 99999 467.3 2.5 99999 99999 99999 99999 1711 123 89846 214.3 0.5 68.6 1.8 95.9 0.8 80.7 1.3 277.0 3.2 99999 99999 469.4 2.6 99999 99999 99999 99999 1770 127 90026 198.5 0.4 63.9 1.6 88.2 0.7 70.6 1.2 265.3 3.0 99999 99999 440.5 2.4 99999 99999 99999 99999 1709 128 90207 207.3 0.5 66.6 1.7 92.2 0.8 75.0 1.2 271.7 3.1 99999 99999 457.2 2.5 99999 99999 99999 99999 1538 126 90567 185.5 0.4 60.8 1.5 82.5 0.7 67.1 1.2 257.9 2.9 99999 99999 423.9 2.3 99999 99999 99999 99999 99999 99999 90747 166.6 0.4 54.8 1.3 74.5 0.7 61.2 1.2 241.0 2.7 99999 99999 387.0 2.2 99999 99999 99999 99999 1517 129 90926 125.2 0.3 44.2 1.1 53.7 0.7 42.0 1.1 216.0 2.3 99999 99999 333.6 2.0 99999 99999 99999 99999 1431 127 91467 125.8 0.3 44.0 1.1 53.3 0.7 40.1 1.1 218.2 2.4 99999 99999 333.7 2.0 99999 99999 99999 99999 1471 128 91646 122.6 0.3 43.4 1.1 52.6 0.7 39.7 1.1 217.0 2.4 99999 99999 330.2 2.0 99999 99999 99999 99999 1519 128 91827 116.7 0.3 42.2 1.1 49.7 0.7 38.4 1.1 214.5 2.3 99999 99999 318.8 1.9 99999 99999 99999 99999 1336 123 92186 115.6 0.3 41.8 1.1 56.1 0.7 37.4 1.1 214.2 2.3 99999 99999 323.2 2.0 99999 99999 99999 99999 1545 127 92367 125.4 0.3 43.5 1.1 54.3 0.7 41.3 1.1 219.1 2.4 99999 99999 333.3 2.0 99999 99999 99999 99999 1455 126 92547 125.1 0.3 43.5 1.1 56.0 0.7 43.6 1.1 216.1 2.4 99999 99999 333.0 2.0 99999 99999 99999 99999 1351 124 92906 128.4 0.3 44.3 1.1 56.5 0.7 43.1 1.1 219.8 2.4 99999 99999 336.0 2.0 99999 99999 99999 99999 1574 128 93086 131.6 0.3 43.9 1.1 57.8 0.7 44.1 1.1 221.9 2.4 99999 99999 338.4 2.0 99999 99999 99999 99999 1485 126 93266 135.8 0.3 46.0 1.1 56.7 0.7 46.1 1.1 226.1 2.5 99999 99999 347.0 2.0 99999 99999 99999 99999 1525 126 93627 133.8 0.3 44.9 1.1 59.4 0.7 43.9 1.1 224.4 2.5 99999 99999 344.9 2.0 99999 99999 99999 99999 1543 124 93807 129.1 0.3 43.8 1.1 56.7 0.7 43.2 1.1 222.5 2.5 99999 99999 337.9 2.0 99999 99999 99999 99999 1441 121 93987 124.1 0.3 42.6 1.1 54.2 0.7 42.5 1.1 220.5 2.4 99999 99999 331.2 2.0 99999 99999 99999 99999 1360 118 94527 135.9 0.3 44.9 1.1 61.6 0.7 48.8 1.1 224.4 2.5 99999 99999 349.0 2.0 99999 99999 99999 99999 1401 117 94707 134.5 0.3 44.7 1.1 59.9 0.7 46.3 1.1 223.5 2.5 99999 99999 352.0 2.1 99999 99999 99999 99999 1368 116 94887 133.6 0.3 44.1 1.1 60.7 0.7 45.3 1.1 223.8 2.5 99999 99999 343.7 2.0 99999 99999 99999 99999 1466 118 95246 116.7 0.3 40.7 1.1 54.7 0.7 38.8 1.1 212.9 2.3 99999 99999 329.6 2.0 99999 99999 99999 99999 1399 119 95426 127.0 0.3 43.0 1.1 60.5 0.7 41.4 1.1 218.7 2.4 99999 99999 341.6 2.0 99999 99999 99999 99999 1491 122 95607 127.9 0.3 43.5 1.1 61.0 0.7 41.4 1.1 222.9 2.5 99999 99999 341.7 2.0 99999 99999 99999 99999 1365 121 95967 123.3 0.3 42.7 1.1 54.2 0.7 39.1 1.1 219.2 2.4 99999 99999 335.1 2.0 99999 99999 99999 99999 1538 127 96147 124.2 0.3 44.0 1.1 54.3 0.7 43.5 1.1 220.1 2.4 99999 99999 336.7 2.0 99999 99999 99999 99999 1439 125 96326 123.8 0.3 44.6 1.1 54.0 0.7 40.4 1.1 219.0 2.4 99999 99999 335.4 2.0 99999 99999 99999 99999 1240 122 96687 120.2 0.3 42.9 1.1 51.9 0.7 40.4 1.1 214.8 2.4 99999 99999 331.7 2.0 99999 99999 99999 99999 1458 127 96867 116.4 0.3 42.6 1.1 51.1 0.7 38.6 1.1 211.6 2.3 99999 99999 332.4 2.0 99999 99999 99999 99999 1435 126 97047 120.9 0.3 44.3 1.1 53.1 0.7 39.3 1.1 216.2 2.4 99999 99999 340.0 2.0 99999 99999 99999 99999 1406 125 97587 96.9 0.3 38.9 1.0 42.6 0.7 29.2 1.1 200.9 2.2 99999 99999 295.1 1.9 99999 99999 99999 99999 1292 122 97767 106.7 0.3 41.0 1.1 47.8 0.7 33.1 1.1 209.3 2.3 99999 99999 319.3 2.0 99999 99999 99999 99999 1317 121 97947 103.7 0.3 39.3 1.0 47.0 0.7 34.7 1.1 204.8 2.2 99999 99999 308.2 1.9 99999 99999 99999 99999 1309 120 98307 150.1 0.3 48.3 1.1 68.2 0.7 52.1 1.2 236.4 2.6 99999 99999 373.8 2.1 99999 99999 99999 99999 1451 122 98486 156.2 0.3 50.4 1.2 72.4 0.7 54.7 1.2 240.4 2.7 99999 99999 377.8 2.1 99999 99999 99999 99999 1494 122 98666 156.3 0.3 50.0 1.2 72.5 0.7 53.3 1.2 240.8 2.7 99999 99999 381.5 2.1 99999 99999 99999 99999 1513 122 99027 176.2 0.4 54.1 1.2 79.3 0.8 68.6 1.3 248.6 2.8 99999 99999 393.0 2.2 99999 99999 99999 99999 1496 122 99207 205.9 0.5 61.0 1.4 91.7 0.8 81.6 1.4 265.6 3.0 99999 99999 431.1 2.3 99999 99999 99999 99999 1605 125 99387 210.1 0.5 62.0 1.5 96.7 0.8 84.8 1.4 265.1 3.0 99999 99999 430.4 2.3 99999 99999 99999 99999 1495 122 99746 266.9 0.7 78.9 2.4 121.4 0.9 114.3 1.6 99999 99999 99999 99999 99999 99999 99999 99999 99999 99999 99999 99999 99927 271.3 0.7 83.2 2.8 121.9 0.9 112.5 1.6 99999 99999 99999 99999 99999 99999 99999 99999 99999 99999 99999 99999 100107 274.1 0.7 82.4 2.8 120.7 0.9 118.4 1.7 99999 99999 99999 99999 99999 99999 99999 99999 99999 99999 99999 99999