37 1001 ELKINS, JAMES; FAHEY, DAVID; GILLIGAN, JONATHAN; VOLK, CLAUS MICHAEL; DUTTON, GEOFF ; BARING, THOMAS; WAMSLEY, PAULA U.S. DEPT OF COMMERCE, NOAA / CMDL / NITROUS OXIDE AND HALOCARBONS DIVISION ACATS IV, ER-2 ASHOE 1 1 1994 03 18 1995 05 21 0 ELAPSED TIME IN SECONDS FROM 00:00:00 GMT ON SAMPLE DATE 20 1.0 1.0 1.0 1.0 1.0 1.0 1.0 1.0 1.0 1.0 1.0 1.0 1.0 1.0 1.0 1.0 1.0 1.0 1.0 1.0 99999 99999 99999 99999 99999 99999 99999 99999 99999 99999 99999 99999 99999 99999 99999 99999 99999 99999 99999 99999 MIXING RATIO CFC-11 (PPT) CFC-11 ERROR 1 S.D. (PPT) MIXING RATIO CFC-113 (PPT) CFC-113 ERROR 1 S.D. (PPT) MIXING RATIO CH3CCl3 (PPT) CH3CCl3 ERROR 1 S.D. (PPT) MIXING RATIO CCl4 (PPT) CCl4 ERROR 1 S.D. (PPT) MIXING RATIO N2O (PPB) N2O ERROR 1 S.D. (PPB) MIXING RATIO SF6 (PPT) SF6 ERROR 1 S.D. (PPT) MIXING RATIO CFC-12 (PPT) CFC-12 ERROR 1 S.D. (PPT) MIXING RATIO H1211 (PPT) H1211 ERROR 1 S.D. (PPT) MIXING RATIO H2 (PPB) H2 ERROR 1 S.D. (PPB) MIXING RATIO CH4 (PPB) CH4 ERROR 1 S.D. (PPB) 2 Final calibrations applied. Time corrected for pump delay using O3 data from Proffitt et al. 1 GMTs CFC11 CFC11e CFC113 CFC113e CH3CCl3 CH3CCl3e CCl4 CCl4e N2O N2Oe SF6 SF6e CFC12 CFC12e H1211 H1211e H2 H2e CH4 CH4e 64874 99999 99999 99999 99999 99999 99999 99999 99999 99999 99999 99999 99999 99999 99999 99999 99999 99999 99999 99999 99999 65054 99999 99999 99999 99999 99999 99999 99999 99999 99999 99999 99999 99999 99999 99999 99999 99999 99999 99999 99999 99999 65414 99999 99999 99999 99999 99999 99999 99999 99999 99999 99999 99999 99999 99999 99999 99999 99999 99999 99999 99999 99999 65594 99999 99999 99999 99999 99999 99999 99999 99999 99999 99999 99999 99999 99999 99999 99999 99999 99999 99999 99999 99999 65954 246.6 0.7 85.0 7.7 99999 99999 99.1 1.0 302.5 4.2 99999 99999 485.0 18.0 99999 99999 99999 99999 99999 99999 66134 246.4 0.7 84.3 7.2 109.0 1.5 101.1 1.0 303.9 4.2 99999 99999 485.9 17.9 99999 99999 99999 99999 99999 99999 66494 224.9 0.6 80.0 5.2 106.7 1.4 88.4 0.9 287.4 4.0 99999 99999 428.1 16.4 99999 99999 99999 99999 99999 99999 66674 201.9 0.6 74.5 3.8 91.9 1.3 78.2 0.9 276.5 3.9 99999 99999 408.7 15.8 99999 99999 99999 99999 99999 99999 67034 174.4 0.5 66.9 2.6 81.3 1.3 65.4 0.8 254.6 3.7 99999 99999 369.3 15.0 99999 99999 99999 99999 1371 67 67214 168.0 0.4 66.3 2.5 77.8 1.2 63.0 0.8 254.7 3.6 99999 99999 356.5 14.8 99999 99999 99999 99999 1445 71 67574 147.4 0.4 60.3 2.0 68.0 1.2 54.4 0.7 239.0 3.5 99999 99999 345.1 14.6 99999 99999 99999 99999 1385 70 67754 138.5 0.4 56.9 1.8 63.5 1.2 50.0 0.7 236.7 3.5 99999 99999 360.1 15.0 99999 99999 99999 99999 1418 72 68114 147.3 0.4 59.4 1.9 66.5 1.1 53.6 0.7 225.7 3.4 99999 99999 320.6 14.4 99999 99999 99999 99999 1376 72 68294 142.7 0.4 58.3 1.8 66.5 1.1 51.4 0.7 233.8 3.4 99999 99999 347.6 15.0 99999 99999 99999 99999 1407 74 68654 139.0 0.4 56.2 1.7 62.8 1.1 49.2 0.7 219.6 3.4 99999 99999 346.2 15.3 99999 99999 99999 99999 1624 87 68834 144.8 0.4 59.1 1.8 66.2 1.1 49.8 0.7 240.0 3.5 99999 99999 386.3 16.2 99999 99999 99999 99999 99999 99999 69194 145.4 0.4 58.7 1.8 65.7 1.1 52.6 0.7 239.7 3.5 99999 99999 367.2 16.0 99999 99999 99999 99999 99999 99999 69374 147.5 0.4 56.8 1.7 67.7 1.1 53.8 0.7 236.5 3.5 99999 99999 367.6 16.0 99999 99999 99999 99999 1572 86 69734 152.5 0.4 59.6 1.8 70.2 1.1 55.4 0.7 230.3 3.4 99999 99999 385.4 16.5 99999 99999 99999 99999 1464 80 69914 150.5 0.4 59.3 1.8 68.7 1.1 54.4 0.7 244.1 3.5 99999 99999 383.2 16.5 99999 99999 99999 99999 1498 82 70375 152.6 0.4 59.2 1.7 69.7 1.1 53.8 0.7 252.3 3.6 99999 99999 360.7 16.1 99999 99999 99999 99999 99999 99999 70555 154.5 0.4 60.5 1.8 70.4 1.1 55.0 0.7 259.3 3.7 99999 99999 402.5 17.0 99999 99999 99999 99999 1576 86 70915 144.0 0.4 57.8 1.7 65.2 1.1 51.3 0.7 229.0 3.5 99999 99999 352.3 16.0 99999 99999 99999 99999 1446 80 71095 141.5 0.3 55.3 1.6 64.9 1.1 50.9 0.7 228.5 3.5 99999 99999 349.5 16.0 99999 99999 99999 99999 1467 81 71455 134.9 0.3 54.3 1.5 60.4 1.0 47.7 0.7 223.7 3.4 99999 99999 327.2 15.5 99999 99999 99999 99999 1510 83 71635 136.6 0.3 55.4 1.5 62.1 1.0 48.3 0.7 221.5 3.4 99999 99999 336.5 15.6 99999 99999 99999 99999 1497 82 71995 139.2 0.3 56.5 1.6 64.1 1.0 50.4 0.7 227.5 3.4 99999 99999 344.6 15.6 99999 99999 99999 99999 1441 78 72175 150.2 0.4 58.2 1.6 68.1 1.1 54.7 0.7 236.4 3.5 99999 99999 348.4 15.6 99999 99999 99999 99999 1392 75 72535 134.8 0.3 55.4 1.5 61.7 1.0 48.3 0.7 228.0 3.4 99999 99999 343.6 15.4 99999 99999 99999 99999 1388 75 72715 131.7 0.3 53.4 1.5 60.3 1.0 46.6 0.7 225.7 3.4 99999 99999 337.8 15.2 99999 99999 99999 99999 1316 71 73075 131.9 0.3 54.2 1.5 60.6 1.0 47.2 0.7 233.3 3.4 99999 99999 368.9 15.7 99999 99999 99999 99999 1415 76 73255 135.2 0.3 55.0 1.5 61.4 1.0 48.4 0.7 228.6 3.4 99999 99999 380.1 15.9 99999 99999 99999 99999 1340 72 73615 134.6 0.3 55.9 1.5 62.2 1.1 47.4 0.7 213.8 3.3 99999 99999 354.2 15.3 99999 99999 99999 99999 1331 72 73795 135.2 0.3 54.8 1.5 62.6 1.1 47.7 0.7 222.4 3.4 99999 99999 331.6 14.9 99999 99999 99999 99999 1312 71 74155 141.3 0.3 57.2 1.6 64.8 1.1 49.8 0.7 223.5 3.4 99999 99999 364.9 15.5 99999 99999 99999 99999 99999 99999 74335 143.6 0.3 57.6 1.6 65.2 1.1 50.9 0.7 242.3 3.5 99999 99999 353.6 15.3 99999 99999 99999 99999 1426 76 74695 139.9 0.3 56.4 1.6 64.8 1.1 49.9 0.7 231.5 3.5 99999 99999 341.3 15.0 99999 99999 99999 99999 1331 71 74875 139.7 0.3 55.8 1.5 64.3 1.1 49.1 0.7 218.8 3.4 99999 99999 343.5 15.1 99999 99999 99999 99999 1441 76 75235 138.9 0.3 56.6 1.6 62.0 1.0 48.3 0.7 229.4 3.5 99999 99999 341.2 15.0 99999 99999 99999 99999 1303 68 75415 139.4 0.3 56.2 1.6 63.1 1.0 49.6 0.7 239.3 3.6 99999 99999 346.3 15.1 99999 99999 99999 99999 1463 75 75775 139.6 0.3 55.2 1.5 62.2 1.0 48.6 0.7 220.8 3.5 99999 99999 402.4 16.3 99999 99999 99999 99999 1388 71 75955 139.8 0.3 56.8 1.6 63.2 1.0 48.8 0.7 246.4 3.6 99999 99999 352.4 15.3 99999 99999 99999 99999 1257 65 76315 137.8 0.3 55.7 1.5 62.1 1.0 46.2 0.7 239.1 3.6 99999 99999 346.0 15.3 99999 99999 99999 99999 1386 71 76495 135.1 0.3 53.0 1.4 61.1 1.0 47.0 0.7 227.3 3.5 99999 99999 337.4 15.2 99999 99999 99999 99999 1339 68 76855 131.0 0.3 53.3 1.4 58.9 1.0 44.9 0.7 239.0 3.6 99999 99999 361.6 15.7 99999 99999 99999 99999 1341 69 77035 135.5 0.3 53.7 1.4 61.6 1.0 47.5 0.7 236.7 3.6 99999 99999 338.7 15.3 99999 99999 99999 99999 1359 70 77395 141.7 0.3 56.1 1.5 65.6 1.1 50.1 0.7 243.0 3.6 99999 99999 355.5 15.7 99999 99999 99999 99999 1462 76 77575 139.9 0.3 54.6 1.5 64.1 1.1 49.5 0.7 233.7 3.6 99999 99999 369.0 16.0 99999 99999 99999 99999 1452 76 77935 139.3 0.3 54.2 1.5 62.8 1.1 49.4 0.7 225.8 3.5 99999 99999 357.1 15.8 99999 99999 99999 99999 1516 81 78115 139.2 0.3 53.8 1.4 64.0 1.1 48.8 0.7 237.9 3.6 99999 99999 357.1 15.8 99999 99999 99999 99999 1426 77 78475 145.5 0.4 56.3 1.5 66.7 1.1 51.9 0.7 240.4 3.6 99999 99999 360.4 15.8 99999 99999 99999 99999 1400 77 78655 145.2 0.4 57.3 1.6 65.9 1.1 51.5 0.7 244.5 3.6 99999 99999 359.3 15.8 99999 99999 99999 99999 1485 82 79015 140.6 0.3 54.0 1.4 65.4 1.1 48.9 0.7 222.0 3.4 99999 99999 358.4 15.8 99999 99999 99999 99999 1487 84 79195 136.8 0.3 53.5 1.4 62.2 1.1 47.8 0.7 234.3 3.5 99999 99999 350.5 15.6 99999 99999 99999 99999 1443 82 79555 141.7 0.3 54.5 1.5 65.5 1.1 49.8 0.7 235.6 3.5 99999 99999 362.6 15.8 99999 99999 99999 99999 1455 84 79735 131.6 0.3 53.8 1.4 60.3 1.1 44.3 0.7 210.9 3.3 99999 99999 338.4 15.4 99999 99999 99999 99999 1527 88 80095 134.7 0.3 54.5 1.5 62.7 1.1 47.5 0.7 230.8 3.4 99999 99999 351.9 15.6 99999 99999 99999 99999 1427 83 80275 135.3 0.3 54.2 1.5 62.4 1.1 47.0 0.7 216.0 3.3 99999 99999 358.0 15.8 99999 99999 99999 99999 1484 86 80635 136.2 0.3 55.7 1.5 62.5 1.1 48.2 0.7 230.7 3.4 99999 99999 355.9 15.7 99999 99999 99999 99999 1447 83 80815 135.5 0.3 55.6 1.5 63.0 1.1 47.0 0.7 230.8 3.4 99999 99999 345.4 15.5 99999 99999 99999 99999 1393 80 81175 131.4 0.3 53.7 1.5 61.0 1.1 45.5 0.7 222.8 3.4 99999 99999 346.0 15.5 99999 99999 99999 99999 1468 83 81355 135.4 0.3 54.0 1.5 62.7 1.1 47.7 0.7 226.7 3.4 99999 99999 348.9 15.6 99999 99999 99999 99999 1219 70 81715 133.7 0.3 53.6 1.4 61.7 1.1 45.8 0.7 224.8 3.4 99999 99999 342.6 15.4 99999 99999 99999 99999 1382 79 81895 138.4 0.3 55.4 1.5 65.2 1.1 49.0 0.7 224.6 3.4 99999 99999 351.7 15.6 99999 99999 99999 99999 1422 81 82255 136.7 0.3 54.5 1.5 63.1 1.1 48.1 0.7 226.0 3.4 99999 99999 347.4 15.5 99999 99999 99999 99999 99999 99999 82435 133.1 0.3 56.6 1.6 62.3 1.1 40.0 0.7 223.0 3.4 99999 99999 337.7 15.3 99999 99999 99999 99999 99999 99999 82795 242.3 0.6 86.0 6.1 115.9 1.3 98.7 0.9 281.8 3.8 99999 99999 477.9 18.3 99999 99999 99999 99999 99999 99999 82975 258.4 0.7 91.5 8.9 122.0 1.3 106.6 0.9 290.9 3.9 99999 99999 514.7 19.2 99999 99999 99999 99999 99999 99999 83335 261.2 0.7 88.7 7.5 119.1 1.3 107.8 1.0 310.4 4.1 99999 99999 517.6 19.3 99999 99999 99999 99999 99999 99999 83515 259.5 0.7 99999 99999 126.7 1.4 110.7 1.0 317.3 4.2 99999 99999 520.9 19.4 99999 99999 99999 99999 99999 99999 83875 263.2 0.7 89.0 8.0 129.5 1.4 108.6 1.0 296.9 3.9 99999 99999 533.9 19.7 99999 99999 99999 99999 99999 99999 84055 258.9 0.7 87.3 7.2 122.9 1.4 109.5 1.0 301.1 4.0 99999 99999 527.1 19.5 99999 99999 99999 99999 99999 99999 84415 99999 99999 99999 99999 99999 99999 99999 99999 99999 99999 99999 99999 99999 99999 99999 99999 99999 99999 99999 99999