37 1001 ELKINS, JAMES; FAHEY, DAVID; GILLIGAN, JONATHAN; VOLK, CLAUS MICHAEL; DUTTON, GEOFF ; BARING, THOMAS; WAMSLEY, PAULA U.S. DEPT OF COMMERCE, NOAA / CMDL / NITROUS OXIDE AND HALOCARBONS DIVISION ACATS IV, ER-2 ASHOE 1 1 1994 02 18 1995 05 20 0 ELAPSED TIME IN SECONDS FROM 00:00:00 GMT ON SAMPLE DATE 20 1.0 1.0 1.0 1.0 1.0 1.0 1.0 1.0 1.0 1.0 1.0 1.0 1.0 1.0 1.0 1.0 1.0 1.0 1.0 1.0 99999 99999 99999 99999 99999 99999 99999 99999 99999 99999 99999 99999 99999 99999 99999 99999 99999 99999 99999 99999 MIXING RATIO CFC-11 (PPT) CFC-11 ERROR 1 S.D. (PPT) MIXING RATIO CFC-113 (PPT) CFC-113 ERROR 1 S.D. (PPT) MIXING RATIO CH3CCl3 (PPT) CH3CCl3 ERROR 1 S.D. (PPT) MIXING RATIO CCl4 (PPT) CCl4 ERROR 1 S.D. (PPT) MIXING RATIO N2O (PPB) N2O ERROR 1 S.D. (PPB) MIXING RATIO SF6 (PPT) SF6 ERROR 1 S.D. (PPT) MIXING RATIO CFC-12 (PPT) CFC-12 ERROR 1 S.D. (PPT) MIXING RATIO H1211 (PPT) H1211 ERROR 1 S.D. (PPT) MIXING RATIO H2 (PPB) H2 ERROR 1 S.D. (PPB) MIXING RATIO CH4 (PPB) CH4 ERROR 1 S.D. (PPB) 2 Final calibrations applied. Time corrected for pump delay using O3 data from Proffitt et al. 1 GMTs CFC11 CFC11e CFC113 CFC113e CH3CCl3 CH3CCl3e CCl4 CCl4e N2O N2Oe SF6 SF6e CFC12 CFC12e H1211 H1211e H2 H2e CH4 CH4e 58042 99999 99999 99999 99999 99999 99999 99999 99999 99999 99999 99999 99999 99999 99999 99999 99999 99999 99999 99999 99999 58222 99999 99999 99999 99999 99999 99999 99999 99999 99999 99999 99999 99999 99999 99999 99999 99999 99999 99999 99999 99999 58582 99999 99999 99999 99999 99999 99999 99999 99999 99999 99999 99999 99999 99999 99999 99999 99999 99999 99999 99999 99999 58762 99999 99999 99999 99999 99999 99999 99999 99999 99999 99999 99999 99999 99999 99999 99999 99999 99999 99999 99999 99999 59122 242.1 0.8 99999 99999 111.4 1.8 98.8 2.7 99999 99999 99999 99999 474.8 11.7 99999 99999 99999 99999 99999 99999 59302 212.6 0.7 99999 99999 98.1 1.7 85.2 2.5 99999 99999 99999 99999 430.6 10.6 99999 99999 99999 99999 99999 99999 59662 188.8 0.7 99999 99999 89.0 1.7 73.8 2.4 99999 99999 99999 99999 380.0 9.4 99999 99999 99999 99999 99999 99999 59842 171.7 0.7 99999 99999 79.0 1.6 63.6 2.3 99999 99999 99999 99999 385.7 9.6 99999 99999 99999 99999 99999 99999 60202 169.1 0.7 99999 99999 75.4 1.6 64.2 2.2 99999 99999 99999 99999 395.6 10.1 99999 99999 99999 99999 99999 99999 60382 169.7 0.7 99999 99999 77.3 1.6 62.9 2.2 99999 99999 99999 99999 403.2 10.3 99999 99999 99999 99999 99999 99999 60742 168.4 0.7 99999 99999 75.7 1.6 62.6 2.2 99999 99999 99999 99999 401.2 10.4 99999 99999 99999 99999 99999 99999 60922 107.3 0.7 99999 99999 48.2 1.5 37.5 2.0 99999 99999 99999 99999 326.4 8.3 99999 99999 99999 99999 99999 99999 61282 111.7 0.7 99999 99999 49.4 1.5 38.5 2.0 99999 99999 99999 99999 321.6 8.2 99999 99999 99999 99999 99999 99999 61462 104.3 0.7 99999 99999 45.4 1.5 35.7 2.0 99999 99999 99999 99999 306.2 7.8 99999 99999 99999 99999 99999 99999 61822 103.8 0.7 99999 99999 44.2 1.5 35.7 2.0 99999 99999 99999 99999 314.5 8.0 99999 99999 99999 99999 99999 99999 62002 106.1 0.7 99999 99999 46.7 1.5 36.7 2.0 99999 99999 99999 99999 315.5 8.0 99999 99999 99999 99999 99999 99999 62362 118.4 0.7 99999 99999 51.3 1.5 42.0 2.0 99999 99999 99999 99999 319.1 8.0 99999 99999 99999 99999 99999 99999 62542 117.5 0.7 99999 99999 53.2 1.5 38.8 2.0 99999 99999 99999 99999 99999 99999 99999 99999 99999 99999 99999 99999 62902 106.4 0.7 99999 99999 44.5 1.5 36.9 2.0 99999 99999 99999 99999 321.1 8.0 99999 99999 99999 99999 99999 99999 63082 101.0 0.7 99999 99999 42.4 1.5 33.6 2.0 99999 99999 99999 99999 314.8 7.7 99999 99999 99999 99999 99999 99999 63442 95.2 0.7 99999 99999 42.8 1.5 30.6 2.0 99999 99999 99999 99999 299.8 7.3 99999 99999 99999 99999 99999 99999 63622 92.9 0.7 99999 99999 40.8 1.5 28.4 2.0 99999 99999 99999 99999 283.8 6.9 99999 99999 99999 99999 99999 99999 63982 100.5 0.7 99999 99999 46.8 1.5 33.9 2.0 99999 99999 99999 99999 293.3 7.1 99999 99999 99999 99999 99999 99999 64162 101.5 0.7 99999 99999 45.0 1.5 33.9 2.0 99999 99999 99999 99999 307.3 7.4 99999 99999 99999 99999 99999 99999 64522 97.8 0.7 99999 99999 41.0 1.5 32.1 2.0 99999 99999 99999 99999 298.0 7.1 99999 99999 99999 99999 99999 99999 64702 97.8 0.7 99999 99999 44.1 1.5 34.4 2.1 99999 99999 99999 99999 288.6 6.9 99999 99999 99999 99999 99999 99999 65062 103.4 0.7 99999 99999 48.1 1.5 35.1 2.1 99999 99999 99999 99999 291.5 6.9 99999 99999 99999 99999 99999 99999 65242 113.9 0.7 99999 99999 49.0 1.5 38.0 2.1 99999 99999 99999 99999 317.8 7.6 99999 99999 99999 99999 99999 99999 65602 93.3 0.7 99999 99999 41.0 1.5 32.1 2.0 99999 99999 99999 99999 291.6 6.9 99999 99999 99999 99999 99999 99999 65782 96.9 0.7 99999 99999 44.5 1.5 32.5 2.0 99999 99999 99999 99999 282.5 6.7 99999 99999 99999 99999 99999 99999 66142 125.6 0.7 99999 99999 54.0 1.5 42.1 2.1 99999 99999 99999 99999 335.8 8.1 99999 99999 99999 99999 99999 99999 66322 129.3 0.7 99999 99999 57.9 1.5 45.6 2.1 99999 99999 99999 99999 350.3 8.5 99999 99999 99999 99999 99999 99999 66682 123.8 0.7 99999 99999 54.0 1.5 45.1 2.1 99999 99999 99999 99999 329.8 8.0 99999 99999 99999 99999 99999 99999 66862 121.6 0.7 99999 99999 57.4 1.5 40.8 2.1 99999 99999 99999 99999 320.6 7.8 99999 99999 99999 99999 99999 99999 67222 108.6 0.7 99999 99999 50.9 1.5 36.4 2.0 99999 99999 99999 99999 323.5 7.9 99999 99999 99999 99999 99999 99999 67402 90.7 0.7 99999 99999 39.3 1.5 29.4 2.0 99999 99999 99999 99999 303.8 7.4 99999 99999 99999 99999 99999 99999 67762 99.2 0.7 99999 99999 46.4 1.5 31.3 2.0 99999 99999 99999 99999 302.4 7.4 99999 99999 99999 99999 99999 99999 67942 110.8 0.7 99999 99999 50.3 1.5 38.9 2.1 99999 99999 99999 99999 334.6 8.3 99999 99999 99999 99999 99999 99999 68302 141.9 0.7 99999 99999 64.8 1.5 54.5 2.2 99999 99999 99999 99999 378.1 9.6 99999 99999 99999 99999 99999 99999 68482 130.9 0.7 99999 99999 60.1 1.5 51.9 2.2 99999 99999 99999 99999 354.3 8.9 99999 99999 99999 99999 99999 99999 68842 91.9 0.7 99999 99999 42.0 1.5 30.0 2.0 99999 99999 99999 99999 294.7 7.3 99999 99999 99999 99999 99999 99999 69022 93.4 0.7 99999 99999 43.3 1.5 31.7 2.0 99999 99999 99999 99999 303.1 7.6 99999 99999 99999 99999 99999 99999 69382 93.1 0.7 99999 99999 42.8 1.4 33.2 2.0 99999 99999 99999 99999 307.2 7.7 99999 99999 99999 99999 99999 99999 69562 85.4 0.7 99999 99999 38.8 1.4 27.7 2.0 99999 99999 99999 99999 292.3 7.3 99999 99999 99999 99999 99999 99999 69922 60.4 0.7 99999 99999 27.8 1.4 19.2 1.9 99999 99999 99999 99999 246.6 6.1 99999 99999 99999 99999 99999 99999 70102 64.3 0.7 99999 99999 28.7 1.4 19.1 1.9 99999 99999 99999 99999 252.3 6.2 99999 99999 99999 99999 99999 99999 70462 62.7 0.7 99999 99999 28.8 1.4 21.0 1.9 99999 99999 99999 99999 246.0 6.0 99999 99999 99999 99999 99999 99999 70642 57.4 0.7 99999 99999 27.5 1.4 14.9 1.9 99999 99999 99999 99999 237.4 5.7 99999 99999 99999 99999 99999 99999 71002 24.2 0.8 99999 99999 15.4 1.4 99999 99999 99999 99999 99999 99999 179.2 4.3 99999 99999 99999 99999 99999 99999 71182 26.7 0.8 99999 99999 15.4 1.4 99999 99999 99999 99999 99999 99999 186.4 4.4 99999 99999 99999 99999 99999 99999 71542 17.9 0.9 99999 99999 99999 99999 99999 99999 99999 99999 99999 99999 146.2 3.4 99999 99999 99999 99999 99999 99999 71722 14.0 0.9 99999 99999 10.1 1.4 5.9 -1.0 99999 99999 99999 99999 130.4 3.1 99999 99999 99999 99999 99999 99999 72082 134.9 0.6 99999 99999 64.7 1.5 47.6 2.0 99999 99999 99999 99999 337.9 8.2 99999 99999 99999 99999 99999 99999 72262 171.4 0.6 99999 99999 77.3 1.5 65.8 2.1 99999 99999 99999 99999 380.4 9.3 99999 99999 99999 99999 99999 99999 72622 190.8 0.7 99999 99999 91.1 1.6 74.5 2.2 99999 99999 99999 99999 383.6 9.4 99999 99999 99999 99999 99999 99999 72802 136.3 0.6 99999 99999 59.7 1.4 49.4 2.0 99999 99999 99999 99999 333.1 8.1 99999 99999 99999 99999 99999 99999 73162 137.9 0.6 99999 99999 62.0 1.4 46.9 1.9 99999 99999 99999 99999 351.6 8.6 99999 99999 99999 99999 99999 99999 73342 92.5 0.6 99999 99999 42.6 1.4 28.1 1.8 99999 99999 99999 99999 295.2 7.2 99999 99999 99999 99999 99999 99999 73702 65.2 0.7 99999 99999 28.9 1.3 19.7 1.8 99999 99999 99999 99999 252.7 6.2 99999 99999 99999 99999 99999 99999 73882 56.8 0.7 99999 99999 24.4 1.3 14.9 1.8 99999 99999 99999 99999 241.8 5.9 99999 99999 99999 99999 99999 99999 74242 46.3 0.7 99999 99999 20.5 1.3 12.2 1.8 99999 99999 99999 99999 236.9 5.9 99999 99999 99999 99999 99999 99999 74422 51.2 0.7 99999 99999 21.7 1.3 13.8 1.8 99999 99999 99999 99999 249.2 6.2 99999 99999 99999 99999 99999 99999 74782 50.8 0.7 99999 99999 24.3 1.3 15.3 1.8 99999 99999 99999 99999 241.9 6.1 99999 99999 99999 99999 99999 99999 74962 54.6 0.7 99999 99999 25.4 1.3 15.0 1.8 99999 99999 99999 99999 248.4 6.3 99999 99999 99999 99999 99999 99999 75322 92.8 0.6 99999 99999 41.2 1.4 27.9 1.8 99999 99999 99999 99999 301.5 7.7 99999 99999 99999 99999 99999 99999 75502 76.9 0.7 99999 99999 33.5 1.4 23.3 1.8 99999 99999 99999 99999 285.5 7.2 99999 99999 99999 99999 99999 99999 75862 58.2 0.7 99999 99999 28.5 1.4 15.4 1.8 99999 99999 99999 99999 259.9 6.5 99999 99999 99999 99999 99999 99999 76042 72.9 0.7 99999 99999 30.1 1.4 21.6 1.8 99999 99999 99999 99999 282.5 7.1 99999 99999 99999 99999 99999 99999 76402 69.7 0.7 99999 99999 30.0 1.4 21.0 1.8 99999 99999 99999 99999 265.8 6.6 99999 99999 99999 99999 99999 99999 76582 85.3 0.7 99999 99999 38.0 1.4 25.0 1.8 99999 99999 99999 99999 285.7 7.1 99999 99999 99999 99999 99999 99999 76942 85.1 0.7 99999 99999 36.4 1.4 24.5 1.8 99999 99999 99999 99999 295.0 7.3 99999 99999 99999 99999 99999 99999 77122 79.9 0.7 99999 99999 33.5 1.4 24.5 1.8 99999 99999 99999 99999 306.0 7.5 99999 99999 99999 99999 99999 99999 77482 51.8 0.7 99999 99999 23.6 1.4 15.2 1.8 99999 99999 99999 99999 250.2 6.0 99999 99999 99999 99999 99999 99999 77662 44.8 0.7 99999 99999 21.5 1.4 13.7 1.8 99999 99999 99999 99999 230.7 5.5 99999 99999 99999 99999 99999 99999 78022 38.4 0.8 99999 99999 21.5 1.4 99999 99999 99999 99999 99999 99999 216.6 5.2 99999 99999 99999 99999 99999 99999 78202 57.9 0.7 99999 99999 25.4 1.4 16.7 1.8 99999 99999 99999 99999 254.0 6.1 99999 99999 99999 99999 99999 99999 78562 63.2 0.7 99999 99999 27.8 1.4 20.7 1.9 99999 99999 99999 99999 277.7 6.7 99999 99999 99999 99999 99999 99999 78742 52.7 0.7 99999 99999 27.6 1.4 15.2 1.8 99999 99999 99999 99999 259.7 6.3 99999 99999 99999 99999 99999 99999 79102 37.8 0.8 99999 99999 21.0 1.4 99999 99999 99999 99999 99999 99999 223.2 5.4 99999 99999 99999 99999 99999 99999 79282 52.4 0.7 99999 99999 24.6 1.4 11.7 1.9 99999 99999 99999 99999 248.8 6.1 99999 99999 99999 99999 99999 99999 79642 73.7 0.7 99999 99999 38.2 1.4 22.5 1.9 99999 99999 99999 99999 281.2 7.0 99999 99999 99999 99999 99999 99999 79822 72.5 0.7 99999 99999 30.9 1.4 22.2 1.9 99999 99999 99999 99999 291.5 7.2 99999 99999 99999 99999 99999 99999 80182 51.8 0.7 99999 99999 26.0 1.4 15.6 1.9 99999 99999 99999 99999 255.4 6.3 99999 99999 99999 99999 99999 99999 80362 53.5 0.7 99999 99999 26.5 1.4 15.2 1.9 99999 99999 99999 99999 257.1 6.4 99999 99999 99999 99999 99999 99999 80722 50.7 0.7 99999 99999 24.2 1.4 14.2 1.9 99999 99999 99999 99999 246.5 6.1 99999 99999 99999 99999 99999 99999 80902 57.6 0.7 99999 99999 99999 99999 16.7 1.9 99999 99999 99999 99999 254.8 6.2 99999 99999 99999 99999 99999 99999 81262 52.4 0.7 99999 99999 24.2 1.4 15.3 1.9 99999 99999 99999 99999 245.0 5.9 99999 99999 99999 99999 99999 99999 81442 45.8 0.8 99999 99999 22.4 1.4 10.6 1.9 99999 99999 99999 99999 235.8 5.7 99999 99999 99999 99999 99999 99999 81802 62.4 0.7 99999 99999 29.7 1.4 99999 99999 99999 99999 99999 99999 265.5 6.4 99999 99999 99999 99999 99999 99999 81982 57.8 0.7 99999 99999 25.8 1.4 16.0 1.9 99999 99999 99999 99999 250.4 6.0 99999 99999 99999 99999 99999 99999 82342 36.4 0.8 99999 99999 16.6 1.3 99999 99999 99999 99999 99999 99999 214.4 5.0 99999 99999 99999 99999 99999 99999 82522 36.1 0.8 99999 99999 99999 99999 99999 99999 99999 99999 99999 99999 217.9 5.1 99999 99999 99999 99999 99999 99999 82882 39.1 0.8 99999 99999 21.5 1.3 9.4 1.8 99999 99999 99999 99999 227.9 5.3 99999 99999 99999 99999 99999 99999 83062 35.5 0.8 99999 99999 20.5 1.3 9.3 1.8 99999 99999 99999 99999 220.4 5.1 99999 99999 99999 99999 99999 99999 83422 43.8 0.8 99999 99999 19.4 1.3 14.8 1.8 99999 99999 99999 99999 218.7 5.1 99999 99999 99999 99999 99999 99999 83602 42.7 0.8 99999 99999 21.0 1.3 13.2 1.8 99999 99999 99999 99999 228.1 5.4 99999 99999 99999 99999 99999 99999 83962 75.7 0.7 99999 99999 35.6 1.3 22.0 1.8 99999 99999 99999 99999 295.0 7.1 99999 99999 99999 99999 99999 99999 84142 172.7 0.7 99999 99999 76.8 1.5 63.0 2.1 99999 99999 99999 99999 425.5 10.8 99999 99999 99999 99999 99999 99999 84502 245.9 0.8 99999 99999 108.0 1.7 99.7 2.5 99999 99999 99999 99999 494.5 13.1 99999 99999 99999 99999 99999 99999 84682 224.9 0.7 99999 99999 99.4 1.6 87.6 2.3 99999 99999 99999 99999 453.3 11.9 99999 99999 99999 99999 99999 99999 85042 276.2 0.9 99999 99999 99999 99999 99999 99999 99999 99999 99999 99999 515.5 14.1 99999 99999 99999 99999 99999 99999 85222 281.0 0.9 99999 99999 99999 99999 99999 99999 99999 99999 99999 99999 534.0 14.7 99999 99999 99999 99999 99999 99999 85582 274.2 0.9 99999 99999 99999 99999 99999 99999 99999 99999 99999 99999 520.3 14.4 99999 99999 99999 99999 99999 99999 85762 272.5 0.8 99999 99999 99999 99999 99999 99999 99999 99999 99999 99999 555.9 15.7 99999 99999 99999 99999 99999 99999 86122 239.6 0.8 99999 99999 99999 99999 99999 99999 99999 99999 99999 99999 99999 99999 99999 99999 99999 99999 99999 99999