43 1001 Wennberg, Paul California Institute of Technology Gas Phase Peroxynitric Acid from DC-8 TC4 1 1 2007 08 10 2011 09 07 0 start_UTC, s 3 1 1 1 999999 999999 999999 stop_UTC, s mid_UTC, s PNA, pptv 0 26 PI_CONTACT_INFO: Address: California Institute of Technology. MC 150-21. 1200 E. California Blvd, Pasadena, CA, 91125. Phone: (626) 395-2447. Fax: (626) 585-1917. email: wennberg@gps.caltech.edu PLATFORM: NASA DC-8 airborne laboratory. LOCATION: Aircraft location data in file TN_20070810.DC8. ASSOCIATED_DATA: N/A INSTRUMENT_INFO: Chemical Ionization Mass Spectrometer. Direct measurements in ambient air. DATA_INFO: Measurements are reported as 0.5 sec averages and in units of pptv. CAUTION: Do not extrapolate data outside of given time interval as these are discrete measurements. Calibration was conducted ~once per hour during the flight using H2O2 and HNO3 calibrants, and proxied to PNA using laboratory calibrations. Absolute calibration was obtained in the laboratory by thermal decomposition and NO2 measurement. Zeros were conducted ~3 times per hour by passing ambient air through a filter containing nylon wool coated with NaHCO3. UNCERTAINTY: +-(100% of measuremlent value + 20 pptv) ULOD_FLAG: 7777777 ULOD_VALUE: N/A LLOD_FLAG: 8888888 LLOD_VALUE: N/A; N/A; N/A; DM_CONTACT_INFO: John Crounse. California Institute of Technology. Department of Chemistry and Chemical Engineering. MC 150-21. 1200 E. California Blvd. Pasadena, CA 91125. Phone: (626) 395-6868. Fax: (626) 585-1917. email: crounjd@caltech.edu. PROJECT_INFO: TC4 study; 13 July-13 August 2007; Study of cloud processing and tropical convection processes STIPULATIONS_ON_USE: Use of these data requires PI notification and adherence to the TC4 data protocol. OTHER_COMMENTS: N/A REVISION: R1 R1: ULOD and LLOD flags changed to positive values, to conform to Ames format 2.1 specifications. R0: Preliminary Data Revision 0. Water correction has been applied using CIT-CIMS water. Reduction code 1.5 start_UTC stop_UTC mid_UTC PNA 53345.84 53346.34 53346.09 31.4 53359.91 53360.41 53360.16 14.5 53373.78 53374.28 53374.03 42.3 53387.72 53388.22 53387.97 27.1 53401.72 53402.22 53401.97 15.3 53415.72 53416.22 53415.97 18.5 53429.78 53430.28 53430.03 31.4 53443.72 53444.22 53443.97 26.2 53457.72 53458.22 53457.97 26.3 53471.72 53472.22 53471.97 23.3 53485.78 53486.28 53486.03 16.8 53499.78 53500.28 53500.03 36.9 53513.72 53514.22 53513.97 7.5 53527.72 53528.22 53527.97 27.8 53541.72 53542.22 53541.97 29.7 53555.78 53556.28 53556.03 23.3 53569.72 53570.22 53569.97 2.7 53583.72 53584.22 53583.97 18.9 53597.78 53598.28 53598.03 29.8 53611.72 53612.22 53611.97 26.4 53625.78 53626.28 53626.03 15.8 53639.72 53640.22 53639.97 22.8 53653.78 53654.28 53654.03 37.0 53667.72 53668.22 53667.97 5.1 53681.72 53682.22 53681.97 14.8 53695.72 53696.22 53695.97 12.1 53709.72 53710.22 53709.97 18.6 53723.72 53724.22 53723.97 17.1 53737.72 53738.22 53737.97 21.2 53751.72 53752.22 53751.97 20.6 53765.72 53766.22 53765.97 25.3 53779.72 53780.22 53779.97 15.4 53793.72 53794.22 53793.97 5.4 53807.72 53808.22 53807.97 22.4 53821.72 53822.22 53821.97 12.6 53835.72 53836.22 53835.97 13.8 53849.78 53850.28 53850.03 19.0 53863.72 53864.22 53863.97 18.1 53877.78 53878.28 53878.03 25.9 53891.72 53892.22 53891.97 23.5 53905.72 53906.22 53905.97 26.7 53919.78 53920.28 53920.03 7.4 53933.78 53934.28 53934.03 11.6 53947.72 53948.22 53947.97 23.1 53961.72 53962.22 53961.97 14.1 55893.53 55894.03 55893.78 54.8 55907.47 55907.97 55907.72 41.0 55921.53 55922.03 55921.78 43.5 55935.47 55935.97 55935.72 51.5 55949.53 55950.03 55949.78 51.1 55963.47 55963.97 55963.72 47.0 55977.47 55977.97 55977.72 40.8 55991.47 55991.97 55991.72 47.4 56005.53 56006.03 56005.78 38.2 56019.47 56019.97 56019.72 53.5 56033.47 56033.97 56033.72 47.7 56102.41 56102.91 56102.66 56.7 56116.34 56116.84 56116.59 42.7 56130.41 56130.91 56130.66 50.3 56144.34 56144.84 56144.59 59.8 56158.34 56158.84 56158.59 51.1 56172.34 56172.84 56172.59 50.3 56186.22 56186.72 56186.47 61.6 56200.22 56200.72 56200.47 45.4 56439.09 56439.59 56439.34 38.5 56453.09 56453.59 56453.34 53.8 56467.09 56467.59 56467.34 56.4 56481.09 56481.59 56481.34 52.3 56495.09 56495.59 56495.34 50.8 56509.09 56509.59 56509.34 50.3 56523.16 56523.66 56523.41 51.5 56537.09 56537.59 56537.34 62.7 56551.09 56551.59 56551.34 40.7 56565.09 56565.59 56565.34 46.2 56579.09 56579.59 56579.34 61.6 56593.09 56593.59 56593.34 45.7 56607.16 56607.66 56607.41 58.5 56621.09 56621.59 56621.34 43.6 56663.09 56663.59 56663.34 67.0 56677.09 56677.59 56677.34 47.0 56691.09 56691.59 56691.34 54.7 56705.09 56705.59 56705.34 53.5 56719.16 56719.66 56719.41 44.3 56733.09 56733.59 56733.34 55.0 56747.09 56747.59 56747.34 51.1 56761.09 56761.59 56761.34 49.0 56775.09 56775.59 56775.34 41.6 56789.09 56789.59 56789.34 42.6 56803.09 56803.59 56803.34 61.6 56817.09 56817.59 56817.34 59.0 56831.09 56831.59 56831.34 68.8 56845.09 56845.59 56845.34 44.8 56859.09 56859.59 56859.34 47.6 56873.16 56873.66 56873.41 62.5 56887.09 56887.59 56887.34 54.6 57012.84 57013.34 57013.09 45.1 57026.91 57027.41 57027.16 45.7 57040.91 57041.41 57041.16 50.6 57054.91 57055.41 57055.16 58.2 57068.91 57069.41 57069.16 52.2 57082.84 57083.34 57083.09 51.0 57096.84 57097.34 57097.09 34.4 57110.84 57111.34 57111.09 39.7 57124.84 57125.34 57125.09 37.6 57138.84 57139.34 57139.09 36.8 57152.84 57153.34 57153.09 41.7 57166.91 57167.41 57167.16 53.8 57180.84 57181.34 57181.09 36.8 57194.84 57195.34 57195.09 35.7 57208.84 57209.34 57209.09 34.2 57222.84 57223.34 57223.09 30.4 57236.84 57237.34 57237.09 33.4 57250.91 57251.41 57251.16 28.9 57264.84 57265.34 57265.09 23.7 57278.84 57279.34 57279.09 20.5 57292.84 57293.34 57293.09 23.4 57306.84 57307.34 57307.09 26.8 57320.84 57321.34 57321.09 30.7 57334.91 57335.41 57335.16 33.9 57439.91 57440.41 57440.16 45.4 57453.84 57454.34 57454.09 43.4 57467.84 57468.34 57468.09 44.1 57481.72 57482.22 57481.97 44.5 57495.72 57496.22 57495.97 43.3 57509.78 57510.28 57510.03 56.2 57523.72 57524.22 57523.97 41.8 57537.72 57538.22 57537.97 53.6 57551.78 57552.28 57552.03 50.2 57565.72 57566.22 57565.97 46.9 57579.78 57580.28 57580.03 48.0 57593.72 57594.22 57593.97 43.0 57607.72 57608.22 57607.97 43.5 57621.72 57622.22 57621.97 43.9 57635.72 57636.22 57635.97 60.1 57649.72 57650.22 57649.97 57.7 57663.72 57664.22 57663.97 65.6 57677.72 57678.22 57677.97 63.1 57691.78 57692.28 57692.03 73.2 57705.72 57706.22 57705.97 63.4 57719.78 57720.28 57720.03 60.0 57733.72 57734.22 57733.97 52.2 57747.78 57748.28 57748.03 54.6 57761.78 57762.28 57762.03 70.3 57775.72 57776.22 57775.97 72.2 57789.72 57790.22 57789.97 45.9 57803.72 57804.22 57803.97 41.9 57817.72 57818.22 57817.97 46.8 57831.72 57832.22 57831.97 48.3 57845.72 57846.22 57845.97 47.3 57859.72 57860.22 57859.97 52.1 57873.72 57874.22 57873.97 52.6 57887.78 57888.28 57888.03 46.5 57901.72 57902.22 57901.97 51.8 57915.72 57916.22 57915.97 59.0 57929.72 57930.22 57929.97 52.2 57943.72 57944.22 57943.97 52.4 57957.72 57958.22 57957.97 60.2 57971.78 57972.28 57972.03 53.8 57985.78 57986.28 57986.03 40.2 57999.72 58000.22 57999.97 51.0 58013.72 58014.22 58013.97 49.3 58027.72 58028.22 58027.97 45.4 58041.72 58042.22 58041.97 44.4 58055.72 58056.22 58055.97 40.4 58069.72 58070.22 58069.97 31.0 58083.78 58084.28 58084.03 53.2 58097.72 58098.22 58097.97 35.7 58111.72 58112.22 58111.97 50.3 58125.72 58126.22 58125.97 39.2 58139.72 58140.22 58139.97 34.3 58153.72 58154.22 58153.97 38.8 58167.72 58168.22 58167.97 35.3 58181.72 58182.22 58181.97 40.6 58195.72 58196.22 58195.97 48.6 58209.78 58210.28 58210.03 37.7 58223.78 58224.28 58224.03 30.2 58237.72 58238.22 58237.97 39.7 58251.78 58252.28 58252.03 66.6 58265.72 58266.22 58265.97 60.9 58279.72 58280.22 58279.97 53.7 58293.78 58294.28 58294.03 52.1 58307.72 58308.22 58307.97 51.7 58321.72 58322.22 58321.97 36.7 58335.72 58336.22 58335.97 47.9 58439.84 58440.34 58440.09 31.7 58453.84 58454.34 58454.09 33.2 58467.84 58468.34 58468.09 33.9 58481.84 58482.34 58482.09 25.7 58495.84 58496.34 58496.09 27.0 58509.84 58510.34 58510.09 41.6 58523.84 58524.34 58524.09 30.5 58537.84 58538.34 58538.09 32.5 58551.84 58552.34 58552.09 42.2 58565.72 58566.22 58565.97 28.7 58579.78 58580.28 58580.03 39.7 58621.84 58622.34 58622.09 38.4 58635.84 58636.34 58636.09 40.6 58649.84 58650.34 58650.09 42.0 58663.91 58664.41 58664.16 40.2 58677.72 58678.22 58677.97 33.3 58691.78 58692.28 58692.03 30.7 58705.78 58706.28 58706.03 30.2 58719.72 58720.22 58719.97 25.7 58733.84 58734.34 58734.09 30.3 58747.84 58748.34 58748.09 39.4 58761.84 58762.34 58762.09 42.1 58775.78 58776.28 58776.03 43.3 58789.78 58790.28 58790.03 56.1 58803.78 58804.28 58804.03 50.6 58817.72 58818.22 58817.97 49.9 58831.72 58832.22 58831.97 41.3 58845.72 58846.22 58845.97 52.7 58859.72 58860.22 58859.97 50.2 58873.91 58874.41 58874.16 49.2 58887.78 58888.28 58888.03 55.6 58901.78 58902.28 58902.03 42.2 58915.72 58916.22 58915.97 49.3 58929.72 58930.22 58929.97 42.3 58943.72 58944.22 58943.97 41.3 58957.72 58958.22 58957.97 46.9 58971.72 58972.22 58971.97 46.3 58985.72 58986.22 58985.97 47.8 58999.78 59000.28 59000.03 57.1 59013.78 59014.28 59014.03 39.3 59027.72 59028.22 59027.97 42.3 59041.72 59042.22 59041.97 35.6 59055.78 59056.28 59056.03 33.2 59069.72 59070.22 59069.97 38.2 59083.72 59084.22 59083.97 30.9 59097.72 59098.22 59097.97 36.7 59111.72 59112.22 59111.97 29.2 59125.72 59126.22 59125.97 34.3 59139.72 59140.22 59139.97 33.1 59153.78 59154.28 59154.03 44.0 59167.72 59168.22 59167.97 39.5 59181.72 59182.22 59181.97 39.5 59195.72 59196.22 59195.97 45.5 59209.72 59210.22 59209.97 35.7 59223.72 59224.22 59223.97 34.9 59237.72 59238.22 59237.97 44.0 59251.78 59252.28 59252.03 23.6 59265.72 59266.22 59265.97 39.7 59279.72 59280.22 59279.97 34.7 59293.78 59294.28 59294.03 28.5 59307.78 59308.28 59308.03 34.5 59321.72 59322.22 59321.97 35.9 59335.72 59336.22 59335.97 39.5 59908.84 59909.34 59909.09 37.8 59922.91 59923.41 59923.16 33.7 59936.84 59937.34 59937.09 39.3 59950.84 59951.34 59951.09 43.0 59964.84 59965.34 59965.09 44.2 59978.84 59979.34 59979.09 36.3 59992.91 59993.41 59993.16 47.8 60006.91 60007.41 60007.16 39.0 60020.84 60021.34 60021.09 37.9 60034.91 60035.41 60035.16 35.3 60048.84 60049.34 60049.09 37.8 60062.84 60063.34 60063.09 49.5 60076.84 60077.34 60077.09 26.7 60090.84 60091.34 60091.09 38.0 60104.84 60105.34 60105.09 31.8 60118.84 60119.34 60119.09 29.9 60132.84 60133.34 60133.09 38.0 60146.91 60147.41 60147.16 48.1 60160.84 60161.34 60161.09 40.1 60174.84 60175.34 60175.09 35.2 60188.72 60189.22 60188.97 40.8 60202.72 60203.22 60202.97 59.3 60216.84 60217.34 60217.09 48.1 60230.84 60231.34 60231.09 44.6 60244.91 60245.41 60245.16 53.4 60258.84 60259.34 60259.09 58.4 60272.84 60273.34 60273.09 64.3 60286.84 60287.34 60287.09 79.4 60300.72 60301.22 60300.97 77.9 60314.72 60315.22 60314.97 85.7 60328.72 60329.22 60328.97 78.8 60342.72 60343.22 60342.97 83.7 60356.91 60357.41 60357.16 96.1 60370.84 60371.34 60371.09 88.5 60384.84 60385.34 60385.09 56.0 60398.91 60399.41 60399.16 60.1 60412.72 60413.22 60412.97 56.6 60426.78 60427.28 60427.03 54.5 60440.72 60441.22 60440.97 67.6 60482.72 60483.22 60482.97 65.3 60496.72 60497.22 60496.97 64.5 60510.72 60511.22 60510.97 69.2 60524.72 60525.22 60524.97 57.5 60538.78 60539.28 60539.03 67.8 60552.78 60553.28 60553.03 70.2 60566.72 60567.22 60566.97 62.6 60580.72 60581.22 60580.97 59.9 60594.72 60595.22 60594.97 69.1 60608.78 60609.28 60609.03 66.2 60622.72 60623.22 60622.97 64.1 60636.72 60637.22 60636.97 61.5 60650.72 60651.22 60650.97 62.8 60664.72 60665.22 60664.97 73.4 60678.78 60679.28 60679.03 70.3 60692.72 60693.22 60692.97 69.6 60706.72 60707.22 60706.97 64.6 60720.72 60721.22 60720.97 65.8 60734.72 60735.22 60734.97 72.0 60748.72 60749.22 60748.97 60.0 60762.72 60763.22 60762.97 62.2 60776.78 60777.28 60777.03 79.5 60790.72 60791.22 60790.97 74.6 60804.72 60805.22 60804.97 71.8 60909.84 60910.34 60910.09 58.7 60923.84 60924.34 60924.09 64.2 60937.91 60938.41 60938.16 60.3 60951.84 60952.34 60952.09 63.1 60965.84 60966.34 60966.09 61.0 60979.84 60980.34 60980.09 57.7 60993.84 60994.34 60994.09 72.6 61007.91 61008.41 61008.16 67.0 61021.91 61022.41 61022.16 81.6 61035.84 61036.34 61036.09 74.9 61049.84 61050.34 61050.09 66.2 61063.84 61064.34 61064.09 60.2 61105.84 61106.34 61106.09 63.9 61119.91 61120.41 61120.16 72.3 61133.84 61134.34 61134.09 57.2 61147.84 61148.34 61148.09 83.6 61161.72 61162.22 61161.97 60.0 61175.72 61176.22 61175.97 66.8 61189.72 61190.22 61189.97 65.9 61203.84 61204.34 61204.09 62.6 61217.84 61218.34 61218.09 71.6 61231.91 61232.41 61232.16 73.2 61245.84 61246.34 61246.09 63.8 61259.84 61260.34 61260.09 61.4 61273.72 61274.22 61273.97 76.5 61287.72 61288.22 61287.97 73.8 61301.72 61302.22 61301.97 74.1 61315.78 61316.28 61316.03 72.6 61329.78 61330.28 61330.03 75.8 61343.84 61344.34 61344.09 75.8 61357.91 61358.41 61358.16 75.6 61371.84 61372.34 61372.09 73.3 61385.72 61386.22 61385.97 70.6 61399.72 61400.22 61399.97 82.9 61413.72 61414.22 61413.97 68.5 61427.72 61428.22 61427.97 77.5 61441.78 61442.28 61442.03 63.5 61455.78 61456.28 61456.03 62.7 61469.72 61470.22 61469.97 88.5 61483.72 61484.22 61483.97 77.8 61497.72 61498.22 61497.97 87.0 61511.72 61512.22 61511.97 82.5 61525.72 61526.22 61525.97 75.9 61539.72 61540.22 61539.97 77.2 61553.72 61554.22 61553.97 70.9 61567.78 61568.28 61568.03 75.7 61581.72 61582.22 61581.97 70.2 61595.78 61596.28 61596.03 53.8 61609.72 61610.22 61609.97 59.2 61623.72 61624.22 61623.97 71.8 61637.78 61638.28 61638.03 122.6 61651.72 61652.22 61651.97 145.6 61665.72 61666.22 61665.97 141.1 61679.72 61680.22 61679.97 137.5 61693.78 61694.28 61694.03 117.0 61707.78 61708.28 61708.03 99.4 61721.72 61722.22 61721.97 122.1 61735.72 61736.22 61735.97 111.7 61749.72 61750.22 61749.97 116.3 61763.72 61764.22 61763.97 138.3 61777.72 61778.22 61777.97 115.6 61791.72 61792.22 61791.97 106.3 61805.78 61806.28 61806.03 100.8 61910.84 61911.34 61911.09 117.7 61924.84 61925.34 61925.09 118.5 61938.84 61939.34 61939.09 117.0 61952.84 61953.34 61953.09 112.9 61966.91 61967.41 61967.16 113.4 61980.91 61981.41 61981.16 96.0 61994.91 61995.41 61995.16 100.6 62008.84 62009.34 62009.09 103.6 62022.84 62023.34 62023.09 133.6 62036.72 62037.22 62036.97 135.7 62050.72 62051.22 62050.97 117.8 62064.84 62065.34 62065.09 113.7 62078.91 62079.41 62079.16 99.6 62092.84 62093.34 62093.09 123.5 62106.84 62107.34 62107.09 127.1 62120.84 62121.34 62121.09 146.0 62134.72 62135.22 62134.97 154.4 62148.78 62149.28 62149.03 134.8 62162.72 62163.22 62162.97 159.6 62176.78 62177.28 62177.03 114.0 62190.72 62191.22 62190.97 138.7 62204.84 62205.34 62205.09 112.3 62218.91 62219.41 62219.16 108.2 62232.91 62233.41 62233.16 112.0 62246.72 62247.22 62246.97 143.0 62260.72 62261.22 62260.97 131.9 62274.72 62275.22 62274.97 149.1 62288.72 62289.22 62288.97 128.1 62302.78 62303.28 62303.03 132.3 62316.72 62317.22 62316.97 164.6 62330.72 62331.22 62330.97 143.8 62344.84 62345.34 62345.09 135.6 62358.72 62359.22 62358.97 141.9 62372.78 62373.28 62373.03 158.2 62386.78 62387.28 62387.03 141.2 62400.78 62401.28 62401.03 156.8 62414.72 62415.22 62414.97 160.7 62428.78 62429.28 62429.03 155.5 62442.72 62443.22 62442.97 147.8 62456.72 62457.22 62456.97 165.3 62470.72 62471.22 62470.97 161.8 62484.72 62485.22 62484.97 165.9 62498.78 62499.28 62499.03 147.8 62512.78 62513.28 62513.03 183.5 62526.72 62527.22 62526.97 178.2 62540.72 62541.22 62540.97 173.9 62554.72 62555.22 62554.97 171.5 62568.72 62569.22 62568.97 169.9 62582.72 62583.22 62582.97 192.0 62596.78 62597.28 62597.03 164.5 62610.72 62611.22 62610.97 179.9 62624.72 62625.22 62624.97 185.5 62638.72 62639.22 62638.97 180.8 62652.72 62653.22 62652.97 182.2 62666.72 62667.22 62666.97 191.3 62680.72 62681.22 62680.97 175.4 62694.72 62695.22 62694.97 155.4 62708.78 62709.28 62709.03 160.4 62722.72 62723.22 62722.97 156.0 62736.72 62737.22 62736.97 152.3 62750.78 62751.28 62751.03 150.8 62764.72 62765.22 62764.97 178.3 62778.72 62779.22 62778.97 162.7 62792.72 62793.22 62792.97 158.8 62806.78 62807.28 62807.03 148.5 63045.84 63046.34 63046.09 131.0 63059.84 63060.34 63060.09 111.8 63073.84 63074.34 63074.09 108.3 63087.84 63088.34 63088.09 111.4 63101.84 63102.34 63102.09 95.5 63115.72 63116.22 63115.97 91.2 63129.78 63130.28 63130.03 97.5 63143.72 63144.22 63143.97 99.0 63157.72 63158.22 63157.97 111.2 63171.72 63172.22 63171.97 120.1 63185.72 63186.22 63185.97 113.6 63199.84 63200.34 63200.09 103.3 63213.84 63214.34 63214.09 105.6 63227.78 63228.28 63228.03 113.2 63241.72 63242.22 63241.97 87.4 63255.72 63256.22 63255.97 89.7 63269.78 63270.28 63270.03 91.6 63283.72 63284.22 63283.97 84.3 63297.72 63298.22 63297.97 84.0 63311.72 63312.22 63311.97 92.9 63325.72 63326.22 63325.97 81.2 63339.78 63340.28 63340.03 84.6 63353.72 63354.22 63353.97 105.2 63367.72 63368.22 63367.97 92.2 63381.78 63382.28 63382.03 91.8 63395.72 63396.22 63395.97 94.4 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