41 1001 Wennberg, Paul California Institute of Technology Gas Phase Peroxyacetic Acid from DC-8 TC4 1 1 2007 08 10 2007 08 11 0 start_UTC, s 3 1 1 1 999999 999999 999999 stop_UTC, s mid_UTC, s PAA, pptv 0 24 PI_CONTACT_INFO: Address: California Institute of Technology. MC 150-21. 1200 E. California Blvd, Pasadena, CA, 91125. Phone: (626) 395-2447. Fax: (626) 585-1917. email: wennberg@gps.caltech.edu PLATFORM: NASA DC-8 airborne laboratory. LOCATION: Aircraft location data in file TN_20070810.DC8. ASSOCIATED_DATA: N/A INSTRUMENT_INFO: Chemical Ionization Mass Spectrometer. Direct measurements in ambient air. DATA_INFO: Measurements are reported as 0.5 sec averages and in units of pptv. CAUTION: Do not extrapolate data outside of given time interval as these are discrete measurements. Calibration was conducted ~once per hour during the flight using H2O2 and HNO3 calibrants, and proxied to PAA using laboratory calibrations. Absolute calibration was obtained in the laboratory by collection in water and subsequent wet chemistry. Zeros were conducted ~3 times per hour by passing ambient air through a filter containing nylon wool coated with NaHCO3. UNCERTAINTY: +-(50% of measuremlent value + 30 pptv) ULOD_FLAG: -7777 ULOD_VALUE: N/A LLOD_FLAG: -8888 LLOD_VALUE: N/A; N/A; N/A; DM_CONTACT_INFO: John Crounse. California Institute of Technology. Department of Chemistry and Chemical Engineering. MC 150-21. 1200 E. California Blvd. Pasadena, CA 91125. Phone: (626) 395-6868. Fax: (626) 585-1917. email: crounjd@caltech.edu. PROJECT_INFO: TC4 study; 13 July-13 August 2007; Study of cloud processing and tropical convection processes STIPULATIONS_ON_USE: Use of these data requires PI notification and adherence to the TC4 data protocol. OTHER_COMMENTS: N/A REVISION: R0 R0: Preliminary Data Revision 0. Water correction has been applied using CIT-CIMS water. Reduction code 1.5 start_UTC(s) stop_UTC(s) mid_UTC(s) PAA(pptv) 53338.91 53339.41 53339.16 98.9 53352.84 53353.34 53353.09 91.5 53366.84 53367.34 53367.09 68.5 53380.72 53381.22 53380.97 76.0 53394.72 53395.22 53394.97 85.0 53408.72 53409.22 53408.97 94.4 53422.72 53423.22 53422.97 99.5 53436.72 53437.22 53436.97 118.4 53450.72 53451.22 53450.97 106.0 53464.72 53465.22 53464.97 98.4 53478.84 53479.34 53479.09 71.9 53492.72 53493.22 53492.97 103.6 53506.72 53507.22 53506.97 90.5 53520.78 53521.28 53521.03 79.5 53534.72 53535.22 53534.97 108.0 53548.72 53549.22 53548.97 70.2 53562.72 53563.22 53562.97 90.4 53576.72 53577.22 53576.97 66.6 53590.72 53591.22 53590.97 77.0 53604.72 53605.22 53604.97 69.9 53618.72 53619.22 53618.97 93.1 53632.78 53633.28 53633.03 56.8 53646.78 53647.28 53647.03 60.8 53660.72 53661.22 53660.97 57.8 53674.72 53675.22 53674.97 72.2 53688.72 53689.22 53688.97 69.6 53702.72 53703.22 53702.97 83.1 53716.72 53717.22 53716.97 76.6 53730.72 53731.22 53730.97 76.0 53744.72 53745.22 53744.97 77.3 53758.72 53759.22 53758.97 86.7 53772.78 53773.28 53773.03 65.8 53786.72 53787.22 53786.97 82.8 53800.72 53801.22 53800.97 70.8 53814.72 53815.22 53814.97 67.2 53828.72 53829.22 53828.97 80.0 53842.72 53843.22 53842.97 102.0 53856.78 53857.28 53857.03 65.9 53870.72 53871.22 53870.97 83.3 53884.72 53885.22 53884.97 75.1 53898.72 53899.22 53898.97 83.0 53912.72 53913.22 53912.97 82.9 53926.78 53927.28 53927.03 62.3 53940.72 53941.22 53940.97 67.6 53954.72 53955.22 53954.97 102.9 53968.72 53969.22 53968.97 130.1 53982.72 53983.22 53982.97 90.8 53996.78 53997.28 53997.03 68.7 55900.47 55900.97 55900.72 99.0 55914.47 55914.97 55914.72 98.0 55928.53 55929.03 55928.78 96.4 55942.47 55942.97 55942.72 93.8 55956.47 55956.97 55956.72 113.1 55970.53 55971.03 55970.78 97.6 55984.53 55985.03 55984.78 74.0 55998.47 55998.97 55998.72 102.3 56012.53 56013.03 56012.78 132.6 56026.47 56026.97 56026.72 108.9 56040.47 56040.97 56040.72 95.5 56109.34 56109.84 56109.59 63.1 56123.34 56123.84 56123.59 69.6 56137.41 56137.91 56137.66 55.5 56151.41 56151.91 56151.66 58.8 56165.34 56165.84 56165.59 85.1 56179.34 56179.84 56179.59 71.1 56193.22 56193.72 56193.47 76.4 56207.22 56207.72 56207.47 82.9 56446.09 56446.59 56446.34 48.7 56460.09 56460.59 56460.34 65.7 56474.09 56474.59 56474.34 75.0 56488.16 56488.66 56488.41 69.7 56502.09 56502.59 56502.34 79.0 56516.09 56516.59 56516.34 83.3 56530.09 56530.59 56530.34 69.0 56544.09 56544.59 56544.34 60.2 56558.16 56558.66 56558.41 80.8 56572.16 56572.66 56572.41 82.1 56586.09 56586.59 56586.34 72.7 56600.16 56600.66 56600.41 78.1 56614.09 56614.59 56614.34 53.3 56656.09 56656.59 56656.34 80.4 56670.09 56670.59 56670.34 57.2 56684.09 56684.59 56684.34 81.9 56698.09 56698.59 56698.34 91.0 56712.09 56712.59 56712.34 71.1 56726.09 56726.59 56726.34 100.6 56740.09 56740.59 56740.34 77.7 56754.09 56754.59 56754.34 61.5 56768.09 56768.59 56768.34 68.0 56782.16 56782.66 56782.41 109.9 56796.09 56796.59 56796.34 74.9 56810.09 56810.59 56810.34 102.7 56824.09 56824.59 56824.34 73.0 56838.16 56838.66 56838.41 97.7 56852.09 56852.59 56852.34 89.6 56866.09 56866.59 56866.34 57.6 56880.09 56880.59 56880.34 86.7 56922.09 56922.59 56922.34 82.0 57019.84 57020.34 57020.09 62.6 57033.91 57034.41 57034.16 39.8 57047.84 57048.34 57048.09 55.4 57061.84 57062.34 57062.09 53.8 57075.91 57076.41 57076.16 45.6 57089.91 57090.41 57090.16 66.7 57103.91 57104.41 57104.16 59.7 57117.84 57118.34 57118.09 54.4 57131.84 57132.34 57132.09 43.7 57145.84 57146.34 57146.09 67.1 57159.91 57160.41 57160.16 66.8 57173.91 57174.41 57174.16 78.2 57187.84 57188.34 57188.09 49.1 57201.84 57202.34 57202.09 62.2 57215.84 57216.34 57216.09 48.2 57229.84 57230.34 57230.09 68.6 57243.91 57244.41 57244.16 59.7 57257.84 57258.34 57258.09 57.6 57271.84 57272.34 57272.09 58.4 57285.84 57286.34 57286.09 53.5 57299.84 57300.34 57300.09 53.7 57313.84 57314.34 57314.09 58.8 57327.84 57328.34 57328.09 63.7 57341.84 57342.34 57342.09 53.0 57446.91 57447.41 57447.16 60.3 57460.84 57461.34 57461.09 56.7 57474.91 57475.41 57475.16 65.1 57488.72 57489.22 57488.97 63.2 57502.78 57503.28 57503.03 57.8 57516.72 57517.22 57516.97 48.9 57530.72 57531.22 57530.97 62.1 57544.78 57545.28 57545.03 66.7 57558.72 57559.22 57558.97 50.0 57572.72 57573.22 57572.97 55.7 57586.72 57587.22 57586.97 68.4 57600.72 57601.22 57600.97 54.9 57614.78 57615.28 57615.03 40.6 57628.78 57629.28 57629.03 69.0 57642.78 57643.28 57643.03 49.1 57656.72 57657.22 57656.97 53.1 57670.72 57671.22 57670.97 56.9 57684.72 57685.22 57684.97 74.4 57698.72 57699.22 57698.97 64.3 57712.72 57713.22 57712.97 53.5 57726.72 57727.22 57726.97 70.4 57740.72 57741.22 57740.97 81.4 57754.72 57755.22 57754.97 62.9 57768.72 57769.22 57768.97 90.8 57782.72 57783.22 57782.97 65.5 57796.78 57797.28 57797.03 31.9 57810.72 57811.22 57810.97 57.5 57824.78 57825.28 57825.03 66.2 57838.78 57839.28 57839.03 88.5 57852.72 57853.22 57852.97 72.5 57866.78 57867.28 57867.03 40.1 57880.72 57881.22 57880.97 67.8 57894.72 57895.22 57894.97 63.7 57908.72 57909.22 57908.97 56.8 57922.72 57923.22 57922.97 61.1 57936.78 57937.28 57937.03 53.9 57950.78 57951.28 57951.03 62.5 57964.72 57965.22 57964.97 75.1 57978.72 57979.22 57978.97 79.4 57992.72 57993.22 57992.97 72.6 58006.72 58007.22 58006.97 54.5 58020.72 58021.22 58020.97 71.1 58034.72 58035.22 58034.97 67.0 58048.72 58049.22 58048.97 54.8 58062.72 58063.22 58062.97 65.2 58076.78 58077.28 58077.03 45.7 58090.72 58091.22 58090.97 47.6 58104.72 58105.22 58104.97 47.1 58118.72 58119.22 58118.97 49.3 58132.72 58133.22 58132.97 54.8 58146.72 58147.22 58146.97 53.5 58160.72 58161.22 58160.97 64.5 58174.72 58175.22 58174.97 62.7 58188.72 58189.22 58188.97 55.1 58202.78 58203.28 58203.03 47.9 58216.72 58217.22 58216.97 74.8 58230.72 58231.22 58230.97 52.0 58244.72 58245.22 58244.97 59.5 58258.72 58259.22 58258.97 92.6 58272.72 58273.22 58272.97 97.3 58286.72 58287.22 58286.97 58.0 58300.72 58301.22 58300.97 70.9 58314.72 58315.22 58314.97 78.6 58328.78 58329.28 58329.03 52.2 58342.78 58343.28 58343.03 57.2 58446.84 58447.34 58447.09 27.1 58460.84 58461.34 58461.09 26.3 58474.84 58475.34 58475.09 29.3 58488.84 58489.34 58489.09 25.8 58502.84 58503.34 58503.09 22.5 58516.84 58517.34 58517.09 34.9 58530.84 58531.34 58531.09 28.4 58544.84 58545.34 58545.09 21.7 58558.84 58559.34 58559.09 28.1 58572.78 58573.28 58573.03 33.4 58614.91 58615.41 58615.16 19.7 58628.84 58629.34 58629.09 25.4 58642.84 58643.34 58643.09 28.6 58656.84 58657.34 58657.09 26.5 58670.78 58671.28 58671.03 24.7 58684.78 58685.28 58685.03 17.9 58698.72 58699.22 58698.97 27.2 58712.72 58713.22 58712.97 31.1 58726.78 58727.28 58727.03 21.2 58740.84 58741.34 58741.09 37.6 58754.91 58755.41 58755.16 34.4 58768.84 58769.34 58769.09 43.6 58782.72 58783.22 58782.97 24.6 58796.78 58797.28 58797.03 25.1 58810.72 58811.22 58810.97 33.4 58824.78 58825.28 58825.03 24.3 58838.78 58839.28 58839.03 52.8 58852.78 58853.28 58853.03 30.8 58866.72 58867.22 58866.97 37.5 58880.84 58881.34 58881.09 29.4 58894.72 58895.22 58894.97 30.1 58908.72 58909.22 58908.97 44.7 58922.72 58923.22 58922.97 23.4 58936.78 58937.28 58937.03 42.5 58950.72 58951.22 58950.97 18.8 58964.72 58965.22 58964.97 20.1 58978.72 58979.22 58978.97 18.0 58992.72 58993.22 58992.97 23.2 59006.72 59007.22 59006.97 24.8 59020.78 59021.28 59021.03 28.0 59034.72 59035.22 59034.97 15.4 59048.72 59049.22 59048.97 13.4 59062.72 59063.22 59062.97 26.1 59076.72 59077.22 59076.97 21.6 59090.72 59091.22 59090.97 20.2 59104.78 59105.28 59105.03 14.6 59118.78 59119.28 59119.03 14.9 59132.72 59133.22 59132.97 18.8 59146.72 59147.22 59146.97 17.9 59160.72 59161.22 59160.97 16.8 59174.72 59175.22 59174.97 17.1 59202.72 59203.22 59202.97 21.3 59216.72 59217.22 59216.97 11.4 59230.72 59231.22 59230.97 17.2 59244.72 59245.22 59244.97 25.7 59258.78 59259.28 59259.03 18.5 59272.72 59273.22 59272.97 16.9 59286.72 59287.22 59286.97 16.2 59300.72 59301.22 59300.97 20.0 59314.72 59315.22 59314.97 20.8 59328.72 59329.22 59328.97 11.9 59342.72 59343.22 59342.97 8.1 59915.84 59916.34 59916.09 25.5 59929.91 59930.41 59930.16 44.5 59943.84 59944.34 59944.09 20.3 59957.84 59958.34 59958.09 28.5 59971.84 59972.34 59972.09 39.1 59985.84 59986.34 59986.09 28.4 59999.84 60000.34 60000.09 31.9 60013.91 60014.41 60014.16 21.3 60027.84 60028.34 60028.09 42.7 60041.91 60042.41 60042.16 51.5 60055.84 60056.34 60056.09 26.1 60069.84 60070.34 60070.09 42.6 60083.84 60084.34 60084.09 49.9 60097.91 60098.41 60098.16 52.0 60111.84 60112.34 60112.09 37.5 60125.91 60126.41 60126.16 47.1 60139.84 60140.34 60140.09 48.5 60153.84 60154.34 60154.09 35.8 60167.84 60168.34 60168.09 38.3 60181.84 60182.34 60182.09 48.4 60195.78 60196.28 60196.03 40.8 60209.84 60210.34 60210.09 65.2 60223.84 60224.34 60224.09 35.3 60237.84 60238.34 60238.09 52.6 60251.84 60252.34 60252.09 63.0 60265.84 60266.34 60266.09 94.1 60279.84 60280.34 60280.09 123.7 60293.78 60294.28 60294.03 101.8 60307.72 60308.22 60307.97 159.4 60321.78 60322.28 60322.03 110.6 60335.72 60336.22 60335.97 177.6 60349.78 60350.28 60350.03 142.9 60363.84 60364.34 60364.09 160.6 60377.84 60378.34 60378.09 125.4 60391.84 60392.34 60392.09 110.5 60405.78 60406.28 60406.03 71.0 60419.78 60420.28 60420.03 106.0 60433.72 60434.22 60433.97 103.3 60475.72 60476.22 60475.97 111.9 60489.72 60490.22 60489.97 111.0 60503.91 60504.41 60504.16 125.0 60517.72 60518.22 60517.97 120.5 60531.72 60532.22 60531.97 126.6 60545.72 60546.22 60545.97 94.6 60559.78 60560.28 60560.03 111.0 60573.72 60574.22 60573.97 126.9 60587.72 60588.22 60587.97 151.6 60601.72 60602.22 60601.97 121.3 60615.72 60616.22 60615.97 97.7 60629.72 60630.22 60629.97 109.6 60643.78 60644.28 60644.03 91.0 60657.72 60658.22 60657.97 118.2 60671.72 60672.22 60671.97 117.7 60685.72 60686.22 60685.97 121.4 60699.72 60700.22 60699.97 132.1 60713.78 60714.28 60714.03 96.2 60727.72 60728.22 60727.97 93.8 60741.72 60742.22 60741.97 108.9 60755.72 60756.22 60755.97 116.6 60769.72 60770.22 60769.97 103.1 60783.78 60784.28 60784.03 147.4 60797.72 60798.22 60797.97 153.9 60811.72 60812.22 60811.97 124.2 60916.84 60917.34 60917.09 98.7 60930.84 60931.34 60931.09 128.1 60944.84 60945.34 60945.09 87.4 60958.84 60959.34 60959.09 102.8 60972.84 60973.34 60973.09 117.9 60986.91 60987.41 60987.16 108.2 61000.84 61001.34 61001.09 92.7 61014.84 61015.34 61015.09 93.4 61028.84 61029.34 61029.09 107.1 61042.91 61043.41 61043.16 128.5 61056.84 61057.34 61057.09 107.3 61098.84 61099.34 61099.09 89.8 61112.84 61113.34 61113.09 111.6 61126.84 61127.34 61127.09 133.9 61140.84 61141.34 61141.09 140.9 61154.91 61155.41 61155.16 126.2 61168.72 61169.22 61168.97 87.8 61182.72 61183.22 61182.97 110.9 61196.78 61197.28 61197.03 111.1 61210.84 61211.34 61211.09 116.7 61224.84 61225.34 61225.09 104.2 61238.84 61239.34 61239.09 106.2 61252.91 61253.41 61253.16 133.3 61266.91 61267.41 61267.16 103.4 61280.72 61281.22 61280.97 109.8 61294.72 61295.22 61294.97 90.4 61308.72 61309.22 61308.97 107.3 61322.72 61323.22 61322.97 100.6 61336.72 61337.22 61336.97 121.6 61350.84 61351.34 61351.09 113.4 61364.84 61365.34 61365.09 113.7 61378.72 61379.22 61378.97 122.5 61392.72 61393.22 61392.97 137.8 61406.72 61407.22 61406.97 126.1 61420.78 61421.28 61421.03 150.5 61434.72 61435.22 61434.97 87.1 61448.72 61449.22 61448.97 144.8 61462.72 61463.22 61462.97 97.0 61476.72 61477.22 61476.97 124.5 61490.72 61491.22 61490.97 125.7 61504.72 61505.22 61504.97 135.4 61518.78 61519.28 61519.03 151.9 61532.72 61533.22 61532.97 134.2 61546.78 61547.28 61547.03 113.9 61560.72 61561.22 61560.97 125.2 61574.78 61575.28 61575.03 117.7 61588.78 61589.28 61589.03 99.8 61602.78 61603.28 61603.03 92.3 61616.78 61617.28 61617.03 110.3 61630.72 61631.22 61630.97 162.5 61644.72 61645.22 61644.97 234.4 61658.72 61659.22 61658.97 239.1 61672.78 61673.28 61673.03 197.9 61686.72 61687.22 61686.97 219.6 61700.72 61701.22 61700.97 204.9 61714.78 61715.28 61715.03 184.1 61728.72 61729.22 61728.97 191.9 61742.72 61743.22 61742.97 175.0 61756.72 61757.22 61756.97 210.1 61770.78 61771.28 61771.03 248.4 61784.78 61785.28 61785.03 195.4 61798.72 61799.22 61798.97 204.1 61812.78 61813.28 61813.03 171.8 61917.84 61918.34 61918.09 231.2 61931.84 61932.34 61932.09 179.8 61945.84 61946.34 61946.09 208.8 61959.84 61960.34 61960.09 201.8 61973.84 61974.34 61974.09 159.0 61987.84 61988.34 61988.09 172.9 62001.84 62002.34 62002.09 162.0 62015.84 62016.34 62016.09 214.4 62029.72 62030.22 62029.97 222.2 62043.72 62044.22 62043.97 221.5 62057.84 62058.34 62058.09 212.5 62071.84 62072.34 62072.09 159.9 62085.84 62086.34 62086.09 186.8 62099.84 62100.34 62100.09 235.8 62113.84 62114.34 62114.09 230.1 62127.84 62128.34 62128.09 248.1 62141.72 62142.22 62141.97 248.9 62155.72 62156.22 62155.97 246.6 62169.72 62170.22 62169.97 250.9 62183.72 62184.22 62183.97 238.6 62197.78 62198.28 62198.03 218.5 62211.91 62212.41 62212.16 188.3 62225.91 62226.41 62226.16 188.0 62239.91 62240.41 62240.16 229.2 62253.72 62254.22 62253.97 236.5 62267.78 62268.28 62268.03 231.2 62281.72 62282.22 62281.97 252.9 62295.78 62296.28 62296.03 241.1 62309.72 62310.22 62309.97 242.9 62323.78 62324.28 62324.03 278.3 62337.72 62338.22 62337.97 278.6 62351.72 62352.22 62351.97 279.2 62365.72 62366.22 62365.97 330.5 62379.72 62380.22 62379.97 298.7 62393.72 62394.22 62393.97 357.1 62407.72 62408.22 62407.97 300.8 62421.72 62422.22 62421.97 309.3 62435.72 62436.22 62435.97 338.4 62449.72 62450.22 62449.97 306.5 62463.72 62464.22 62463.97 337.1 62477.72 62478.22 62477.97 316.7 62491.72 62492.22 62491.97 353.7 62505.72 62506.22 62505.97 334.0 62519.78 62520.28 62520.03 358.8 62533.72 62534.22 62533.97 325.9 62547.78 62548.28 62548.03 353.2 62561.78 62562.28 62562.03 343.3 62575.72 62576.22 62575.97 292.6 62589.72 62590.22 62589.97 282.9 62603.78 62604.28 62604.03 301.6 62617.72 62618.22 62617.97 324.8 62631.72 62632.22 62631.97 282.1 62645.78 62646.28 62646.03 274.4 62659.72 62660.22 62659.97 275.7 62673.72 62674.22 62673.97 317.7 62687.72 62688.22 62687.97 286.3 62701.72 62702.22 62701.97 328.5 62715.72 62716.22 62715.97 337.5 62729.78 62730.28 62730.03 332.4 62743.72 62744.22 62743.97 309.4 62757.72 62758.22 62757.97 302.0 62771.72 62772.22 62771.97 338.0 62785.72 62786.22 62785.97 332.9 62799.78 62800.28 62800.03 291.7 62813.72 62814.22 62813.97 345.1 63052.84 63053.34 63053.09 194.3 63066.84 63067.34 63067.09 158.2 63080.84 63081.34 63081.09 145.0 63094.84 63095.34 63095.09 154.0 63108.91 63109.41 63109.16 155.7 63122.78 63123.28 63123.03 154.2 63136.72 63137.22 63136.97 165.0 63150.78 63151.28 63151.03 177.4 63164.72 63165.22 63164.97 175.3 63178.72 63179.22 63178.97 178.8 63192.84 63193.34 63193.09 215.3 63206.91 63207.41 63207.16 172.7 63220.78 63221.28 63221.03 146.4 63234.72 63235.22 63234.97 183.3 63248.72 63249.22 63248.97 180.0 63262.72 63263.22 63262.97 158.2 63276.78 63277.28 63277.03 135.1 63290.72 63291.22 63290.97 150.4 63304.72 63305.22 63304.97 184.2 63318.78 63319.28 63319.03 165.1 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