41 1001 Wennberg, Paul California Institute of Technology Gas Phase Nitric Acid from DC-8 TC4 1 1 2007 08 10 2007 08 11 0 start_UTC, s 3 1 1 1 999999 999999 999999 stop_UTC, s mid_UTC, s HNO3, pptv 0 24 PI_CONTACT_INFO: Address: California Institute of Technology. MC 150-21. 1200 E. California Blvd, Pasadena, CA, 91125. Phone: (626) 395-2447. Fax: (626) 585-1917. email: wennberg@gps.caltech.edu PLATFORM: NASA DC-8 airborne laboratory. LOCATION: Aircraft location data in file TN_20070810.DC8. ASSOCIATED_DATA: N/A INSTRUMENT_INFO: Chemical Ionization Mass Spectrometer. Direct measurements in ambient air. DATA_INFO: Measurements are reported as 0.5 sec averages and in units of pptv. CAUTION: Do not extrapolate data outside of given time interval as these are discrete measurements. Calibration was conducted ~once per hour during the flight using isotopically labeled nitric acid evolved from a perm tube held at constant temperature. Absolute calibration was obtained by collection in water and subsequent ion chromatography. Zeros were conducted ~3 times per hour by passing ambient air through a filter containing nylon wool coated with NaHCO3. UNCERTAINTY: +-(50% of measuremlent value + 50 pptv) ULOD_FLAG: -7777 ULOD_VALUE: N/A LLOD_FLAG: -8888 LLOD_VALUE: N/A; N/A; N/A; DM_CONTACT_INFO: John Crounse. California Institute of Technology. Department of Chemistry and Chemical Engineering. MC 150-21. 1200 E. California Blvd. Pasadena, CA 91125. Phone: (626) 395-6868. Fax: (626) 585-1917. email: crounjd@caltech.edu. PROJECT_INFO: TC4 study; 13 July-13 August 2007; Study of cloud processing and tropical convection processes STIPULATIONS_ON_USE: Use of these data requires PI notification and adherence to the TC4 data protocol. OTHER_COMMENTS: N/A REVISION: R0 R0: Preliminary Data Revision 0. Water correction has been applied using CIT-CIMS water. Reduction code 1.5 start_UTC(s) stop_UTC(s) mid_UTC(s) HNO3(pptv) 53343.41 53343.91 53343.66 234.4 53357.34 53357.84 53357.59 226.0 53371.22 53371.72 53371.47 213.1 53385.22 53385.72 53385.47 202.6 53399.22 53399.72 53399.47 207.1 53413.28 53413.78 53413.53 198.1 53427.28 53427.78 53427.53 295.6 53441.28 53441.78 53441.53 274.5 53455.28 53455.78 53455.53 266.9 53469.22 53469.72 53469.47 219.9 53483.22 53483.72 53483.47 185.2 53497.22 53497.72 53497.47 176.7 53511.22 53511.72 53511.47 151.9 53525.28 53525.78 53525.53 169.9 53539.22 53539.72 53539.47 148.4 53553.28 53553.78 53553.53 188.5 53567.22 53567.72 53567.47 164.1 53581.28 53581.78 53581.53 185.2 53595.22 53595.72 53595.47 199.6 53609.28 53609.78 53609.53 182.0 53623.28 53623.78 53623.53 194.6 53637.22 53637.72 53637.47 173.7 53651.28 53651.78 53651.53 195.4 53665.28 53665.78 53665.53 191.7 53679.22 53679.72 53679.47 180.3 53693.22 53693.72 53693.47 206.3 53707.28 53707.78 53707.53 162.3 53721.22 53721.72 53721.47 177.4 53735.22 53735.72 53735.47 219.0 53749.22 53749.72 53749.47 191.9 53763.22 53763.72 53763.47 177.1 53777.22 53777.72 53777.47 196.4 53791.22 53791.72 53791.47 196.6 53805.22 53805.72 53805.47 143.6 53819.28 53819.78 53819.53 136.9 53833.22 53833.72 53833.47 139.0 53847.22 53847.72 53847.47 117.2 53861.28 53861.78 53861.53 245.3 53875.22 53875.72 53875.47 155.1 53889.22 53889.72 53889.47 114.9 53903.28 53903.78 53903.53 92.4 53917.22 53917.72 53917.47 88.8 53931.22 53931.72 53931.47 107.2 53945.22 53945.72 53945.47 97.3 53959.22 53959.72 53959.47 97.9 53973.28 53973.78 53973.53 135.9 55890.97 55891.47 55891.22 21.0 55905.03 55905.53 55905.28 18.2 55918.97 55919.47 55919.22 30.5 55932.97 55933.47 55933.22 15.0 55946.97 55947.47 55947.22 28.2 55960.97 55961.47 55961.22 21.3 55974.97 55975.47 55975.22 16.1 55988.97 55989.47 55989.22 35.8 56002.97 56003.47 56003.22 54.1 56017.03 56017.53 56017.28 40.5 56031.03 56031.53 56031.28 23.2 56099.84 56100.34 56100.09 52.9 56113.84 56114.34 56114.09 33.4 56127.84 56128.34 56128.09 37.7 56141.84 56142.34 56142.09 39.6 56155.84 56156.34 56156.09 16.7 56169.84 56170.34 56170.09 20.7 56183.78 56184.28 56184.03 22.6 56197.78 56198.28 56198.03 33.0 56436.59 56437.09 56436.84 14.8 56450.59 56451.09 56450.84 8.4 56464.59 56465.09 56464.84 22.2 56478.59 56479.09 56478.84 13.2 56492.59 56493.09 56492.84 14.4 56506.59 56507.09 56506.84 48.6 56520.59 56521.09 56520.84 17.7 56534.66 56535.16 56534.91 17.8 56548.59 56549.09 56548.84 47.2 56562.59 56563.09 56562.84 39.1 56576.59 56577.09 56576.84 11.3 56590.59 56591.09 56590.84 44.6 56604.59 56605.09 56604.84 62.0 56618.66 56619.16 56618.91 124.7 56660.59 56661.09 56660.84 106.3 56674.66 56675.16 56674.91 130.8 56688.59 56689.09 56688.84 89.8 56702.59 56703.09 56702.84 88.4 56716.59 56717.09 56716.84 85.4 56730.59 56731.09 56730.84 112.9 56744.59 56745.09 56744.84 161.3 56758.66 56759.16 56758.91 90.9 56772.59 56773.09 56772.84 63.7 56786.59 56787.09 56786.84 156.7 56800.59 56801.09 56800.84 148.4 56814.59 56815.09 56814.84 119.8 56828.59 56829.09 56828.84 134.1 56842.59 56843.09 56842.84 146.3 56856.66 56857.16 56856.91 144.6 56870.59 56871.09 56870.84 89.3 56884.59 56885.09 56884.84 124.9 57010.34 57010.84 57010.59 45.2 57024.34 57024.84 57024.59 18.3 57038.34 57038.84 57038.59 38.7 57052.34 57052.84 57052.59 38.4 57066.34 57066.84 57066.59 31.1 57080.41 57080.91 57080.66 36.8 57094.34 57094.84 57094.59 78.6 57108.34 57108.84 57108.59 60.5 57122.34 57122.84 57122.59 60.6 57136.34 57136.84 57136.59 72.6 57150.41 57150.91 57150.66 55.0 57164.41 57164.91 57164.66 47.0 57178.34 57178.84 57178.59 54.4 57192.41 57192.91 57192.66 96.2 57206.34 57206.84 57206.59 77.8 57220.41 57220.91 57220.66 61.8 57234.34 57234.84 57234.59 69.6 57248.41 57248.91 57248.66 47.9 57262.34 57262.84 57262.59 24.4 57276.34 57276.84 57276.59 16.2 57290.34 57290.84 57290.59 29.6 57304.34 57304.84 57304.59 29.7 57318.34 57318.84 57318.59 13.3 57332.34 57332.84 57332.59 29.3 57437.34 57437.84 57437.59 233.8 57451.34 57451.84 57451.59 256.9 57465.34 57465.84 57465.59 251.7 57479.22 57479.72 57479.47 311.2 57493.28 57493.78 57493.53 297.1 57507.22 57507.72 57507.47 229.3 57521.28 57521.78 57521.53 290.6 57535.22 57535.72 57535.47 319.9 57549.22 57549.72 57549.47 354.7 57563.22 57563.72 57563.47 166.5 57577.28 57577.78 57577.53 230.5 57591.28 57591.78 57591.53 397.9 57605.22 57605.72 57605.47 482.7 57619.22 57619.72 57619.47 303.2 57633.28 57633.78 57633.53 280.8 57647.22 57647.72 57647.47 174.0 57661.28 57661.78 57661.53 106.1 57675.22 57675.72 57675.47 111.4 57689.22 57689.72 57689.47 255.9 57703.22 57703.72 57703.47 72.1 57717.22 57717.72 57717.47 83.3 57731.22 57731.72 57731.47 77.8 57745.28 57745.78 57745.53 70.4 57759.28 57759.78 57759.53 98.0 57773.22 57773.72 57773.47 111.7 57787.22 57787.72 57787.47 138.3 57801.22 57801.72 57801.47 94.4 57815.22 57815.72 57815.47 100.2 57829.22 57829.72 57829.47 63.7 57843.22 57843.72 57843.47 61.9 57857.22 57857.72 57857.47 48.4 57871.22 57871.72 57871.47 37.0 57885.22 57885.72 57885.47 62.1 57899.28 57899.78 57899.53 61.6 57913.22 57913.72 57913.47 44.8 57927.28 57927.78 57927.53 40.3 57941.22 57941.72 57941.47 46.1 57955.28 57955.78 57955.53 62.0 57969.22 57969.72 57969.47 52.7 57983.28 57983.78 57983.53 57.8 57997.22 57997.72 57997.47 55.6 58011.28 58011.78 58011.53 54.1 58025.22 58025.72 58025.47 47.5 58039.28 58039.78 58039.53 90.9 58053.22 58053.72 58053.47 153.8 58067.22 58067.72 58067.47 187.9 58081.22 58081.72 58081.47 236.0 58095.28 58095.78 58095.53 293.7 58109.22 58109.72 58109.47 309.2 58123.28 58123.78 58123.53 326.3 58137.22 58137.72 58137.47 337.4 58151.22 58151.72 58151.47 283.2 58165.22 58165.72 58165.47 297.3 58179.22 58179.72 58179.47 262.9 58193.22 58193.72 58193.47 269.4 58207.22 58207.72 58207.47 240.1 58221.28 58221.78 58221.53 272.7 58235.22 58235.72 58235.47 224.2 58249.22 58249.72 58249.47 190.0 58263.22 58263.72 58263.47 187.1 58277.22 58277.72 58277.47 200.3 58291.22 58291.72 58291.47 239.9 58305.28 58305.78 58305.53 132.2 58319.22 58319.72 58319.47 129.3 58333.22 58333.72 58333.47 153.1 58437.34 58437.84 58437.59 156.3 58451.34 58451.84 58451.59 120.7 58465.41 58465.91 58465.66 159.0 58479.41 58479.91 58479.66 181.0 58493.41 58493.91 58493.66 154.4 58507.34 58507.84 58507.59 178.8 58521.34 58521.84 58521.59 178.6 58535.34 58535.84 58535.59 182.5 58549.34 58549.84 58549.59 169.9 58563.28 58563.78 58563.53 200.1 58577.28 58577.78 58577.53 169.4 58619.34 58619.84 58619.59 180.5 58633.34 58633.84 58633.59 190.6 58647.41 58647.91 58647.66 141.0 58661.34 58661.84 58661.59 164.9 58675.22 58675.72 58675.47 140.0 58689.22 58689.72 58689.47 186.2 58703.28 58703.78 58703.53 189.7 58717.22 58717.72 58717.47 139.9 58731.34 58731.84 58731.59 142.8 58745.34 58745.84 58745.59 122.1 58759.34 58759.84 58759.59 127.4 58773.41 58773.91 58773.66 137.8 58787.22 58787.72 58787.47 145.7 58801.22 58801.72 58801.47 146.8 58815.22 58815.72 58815.47 191.0 58829.22 58829.72 58829.47 206.6 58843.28 58843.78 58843.53 206.4 58857.22 58857.72 58857.47 193.6 58871.22 58871.72 58871.47 222.1 58885.22 58885.72 58885.47 184.7 58899.22 58899.72 58899.47 207.7 58913.22 58913.72 58913.47 222.2 58927.22 58927.72 58927.47 203.4 58941.22 58941.72 58941.47 215.8 58955.28 58955.78 58955.53 217.2 58969.22 58969.72 58969.47 260.9 58983.22 58983.72 58983.47 245.6 58997.22 58997.72 58997.47 238.1 59011.22 59011.72 59011.47 257.5 59025.22 59025.72 59025.47 230.1 59039.22 59039.72 59039.47 227.9 59053.22 59053.72 59053.47 234.0 59067.22 59067.72 59067.47 213.8 59081.22 59081.72 59081.47 215.7 59095.22 59095.72 59095.47 197.4 59109.22 59109.72 59109.47 214.6 59123.22 59123.72 59123.47 214.2 59137.22 59137.72 59137.47 212.1 59151.22 59151.72 59151.47 225.9 59165.22 59165.72 59165.47 223.7 59179.28 59179.78 59179.53 261.5 59193.28 59193.78 59193.53 227.5 59207.28 59207.78 59207.53 251.7 59221.28 59221.78 59221.53 233.7 59235.22 59235.72 59235.47 265.9 59249.28 59249.78 59249.53 231.7 59263.22 59263.72 59263.47 191.1 59277.22 59277.72 59277.47 193.3 59291.22 59291.72 59291.47 254.5 59305.22 59305.72 59305.47 237.4 59319.22 59319.72 59319.47 237.3 59333.28 59333.78 59333.53 217.7 59906.34 59906.84 59906.59 250.0 59920.34 59920.84 59920.59 241.6 59934.34 59934.84 59934.59 231.3 59948.34 59948.84 59948.59 229.0 59962.34 59962.84 59962.59 217.5 59976.34 59976.84 59976.59 201.8 59990.41 59990.91 59990.66 166.0 60004.34 60004.84 60004.59 227.8 60018.41 60018.91 60018.66 173.5 60032.34 60032.84 60032.59 190.4 60046.41 60046.91 60046.66 166.1 60060.34 60060.84 60060.59 176.8 60074.34 60074.84 60074.59 151.1 60088.34 60088.84 60088.59 163.8 60102.34 60102.84 60102.59 168.1 60116.34 60116.84 60116.59 172.0 60130.34 60130.84 60130.59 184.9 60144.34 60144.84 60144.59 187.0 60158.41 60158.91 60158.66 161.6 60172.34 60172.84 60172.59 147.9 60186.22 60186.72 60186.47 160.6 60200.22 60200.72 60200.47 247.6 60214.34 60214.84 60214.59 278.7 60228.34 60228.84 60228.59 237.5 60242.34 60242.84 60242.59 269.8 60256.34 60256.84 60256.59 213.5 60270.34 60270.84 60270.59 203.7 60284.34 60284.84 60284.59 189.2 60298.22 60298.72 60298.47 238.5 60312.22 60312.72 60312.47 196.8 60326.22 60326.72 60326.47 197.1 60340.28 60340.78 60340.53 199.8 60354.34 60354.84 60354.59 181.7 60368.34 60368.84 60368.59 153.8 60382.34 60382.84 60382.59 234.7 60396.41 60396.91 60396.66 308.4 60410.22 60410.72 60410.47 356.3 60424.22 60424.72 60424.47 365.4 60438.28 60438.78 60438.53 193.4 60480.22 60480.72 60480.47 353.8 60494.22 60494.72 60494.47 324.4 60508.34 60508.84 60508.59 335.3 60522.22 60522.72 60522.47 320.6 60536.22 60536.72 60536.47 259.8 60550.22 60550.72 60550.47 320.5 60564.28 60564.78 60564.53 339.4 60578.22 60578.72 60578.47 319.4 60592.22 60592.72 60592.47 276.5 60606.22 60606.72 60606.47 296.8 60620.22 60620.72 60620.47 337.6 60634.22 60634.72 60634.47 383.2 60648.22 60648.72 60648.47 280.6 60662.22 60662.72 60662.47 216.5 60676.22 60676.72 60676.47 279.3 60690.22 60690.72 60690.47 276.3 60704.22 60704.72 60704.47 320.1 60718.22 60718.72 60718.47 419.9 60732.22 60732.72 60732.47 314.7 60746.22 60746.72 60746.47 326.3 60760.28 60760.78 60760.53 341.0 60774.22 60774.72 60774.47 289.3 60788.22 60788.72 60788.47 271.9 60802.22 60802.72 60802.47 259.1 60907.34 60907.84 60907.59 402.4 60921.34 60921.84 60921.59 420.0 60935.41 60935.91 60935.66 477.4 60949.34 60949.84 60949.59 516.3 60963.34 60963.84 60963.59 619.3 60977.34 60977.84 60977.59 648.8 60991.34 60991.84 60991.59 534.3 61005.34 61005.84 61005.59 561.6 61019.34 61019.84 61019.59 670.0 61033.34 61033.84 61033.59 507.2 61047.41 61047.91 61047.66 645.1 61061.34 61061.84 61061.59 434.0 61103.41 61103.91 61103.66 334.9 61117.34 61117.84 61117.59 142.1 61131.34 61131.84 61131.59 135.0 61145.34 61145.84 61145.59 136.3 61159.28 61159.78 61159.53 191.3 61173.22 61173.72 61173.47 496.3 61187.28 61187.78 61187.53 640.9 61201.41 61201.91 61201.66 552.7 61215.41 61215.91 61215.66 400.8 61229.34 61229.84 61229.59 520.9 61243.34 61243.84 61243.59 546.3 61257.34 61257.84 61257.59 485.6 61271.22 61271.72 61271.47 440.9 61285.28 61285.78 61285.53 592.9 61299.28 61299.78 61299.53 675.2 61313.22 61313.72 61313.47 676.9 61327.22 61327.72 61327.47 575.3 61341.22 61341.72 61341.47 587.2 61355.34 61355.84 61355.59 443.1 61369.34 61369.84 61369.59 345.2 61383.22 61383.72 61383.47 314.5 61397.22 61397.72 61397.47 307.5 61411.22 61411.72 61411.47 251.0 61425.22 61425.72 61425.47 245.0 61439.22 61439.72 61439.47 303.9 61453.22 61453.72 61453.47 315.1 61467.22 61467.72 61467.47 324.1 61481.22 61481.72 61481.47 566.6 61495.22 61495.72 61495.47 556.6 61509.22 61509.72 61509.47 549.7 61523.22 61523.72 61523.47 624.2 61537.22 61537.72 61537.47 699.1 61551.22 61551.72 61551.47 708.4 61565.22 61565.72 61565.47 552.3 61579.22 61579.72 61579.47 710.8 61593.22 61593.72 61593.47 683.2 61607.22 61607.72 61607.47 645.8 61621.22 61621.72 61621.47 569.3 61635.22 61635.72 61635.47 393.7 61649.22 61649.72 61649.47 310.0 61663.22 61663.72 61663.47 315.9 61677.22 61677.72 61677.47 306.8 61691.28 61691.78 61691.53 311.0 61705.28 61705.78 61705.53 282.8 61719.22 61719.72 61719.47 325.8 61733.22 61733.72 61733.47 313.5 61747.22 61747.72 61747.47 306.7 61761.28 61761.78 61761.53 295.7 61775.28 61775.78 61775.53 293.7 61789.28 61789.78 61789.53 328.8 61803.22 61803.72 61803.47 300.7 61908.41 61908.91 61908.66 239.4 61922.34 61922.84 61922.59 306.5 61936.41 61936.91 61936.66 293.3 61950.41 61950.91 61950.66 292.5 61964.34 61964.84 61964.59 284.7 61978.34 61978.84 61978.59 217.6 61992.41 61992.91 61992.66 302.1 62006.41 62006.91 62006.66 221.4 62020.41 62020.91 62020.66 303.4 62034.22 62034.72 62034.47 278.4 62048.22 62048.72 62048.47 249.4 62062.34 62062.84 62062.59 266.0 62076.34 62076.84 62076.59 258.6 62090.34 62090.84 62090.59 302.6 62104.41 62104.91 62104.66 318.0 62118.34 62118.84 62118.59 303.8 62132.34 62132.84 62132.59 250.1 62146.22 62146.72 62146.47 256.7 62160.22 62160.72 62160.47 253.9 62174.22 62174.72 62174.47 285.0 62188.28 62188.78 62188.53 291.2 62202.34 62202.84 62202.59 320.0 62216.34 62216.84 62216.59 328.3 62230.41 62230.91 62230.66 367.7 62244.22 62244.72 62244.47 315.2 62258.22 62258.72 62258.47 331.8 62272.22 62272.72 62272.47 312.2 62286.22 62286.72 62286.47 326.2 62300.22 62300.72 62300.47 354.9 62314.22 62314.72 62314.47 319.7 62328.22 62328.72 62328.47 291.9 62342.22 62342.72 62342.47 239.5 62356.22 62356.72 62356.47 259.8 62370.28 62370.78 62370.53 331.8 62384.22 62384.72 62384.47 293.5 62398.28 62398.78 62398.53 285.9 62412.22 62412.72 62412.47 245.0 62426.22 62426.72 62426.47 223.5 62440.22 62440.72 62440.47 201.5 62454.28 62454.78 62454.53 209.6 62468.22 62468.72 62468.47 196.5 62482.22 62482.72 62482.47 196.6 62496.28 62496.78 62496.53 212.6 62510.22 62510.72 62510.47 211.1 62524.22 62524.72 62524.47 303.5 62538.22 62538.72 62538.47 305.0 62552.28 62552.78 62552.53 292.4 62566.22 62566.72 62566.47 352.8 62580.22 62580.72 62580.47 335.5 62594.22 62594.72 62594.47 342.8 62608.28 62608.78 62608.53 336.4 62622.22 62622.72 62622.47 275.3 62636.22 62636.72 62636.47 212.3 62650.22 62650.72 62650.47 202.9 62664.22 62664.72 62664.47 216.5 62678.22 62678.72 62678.47 176.3 62692.28 62692.78 62692.53 315.8 62706.22 62706.72 62706.47 335.9 62720.22 62720.72 62720.47 320.0 62734.22 62734.72 62734.47 296.5 62748.28 62748.78 62748.53 289.0 62762.22 62762.72 62762.47 348.5 62776.28 62776.78 62776.53 346.8 62790.28 62790.78 62790.53 276.7 62804.22 62804.72 62804.47 282.3 63043.34 63043.84 63043.59 142.9 63057.41 63057.91 63057.66 88.3 63071.34 63071.84 63071.59 60.4 63085.34 63085.84 63085.59 76.8 63099.34 63099.84 63099.59 59.9 63113.22 63113.72 63113.47 48.3 63127.22 63127.72 63127.47 52.4 63141.22 63141.72 63141.47 47.6 63155.28 63155.78 63155.53 74.2 63169.22 63169.72 63169.47 93.5 63183.28 63183.78 63183.53 83.2 63197.34 63197.84 63197.59 99.6 63211.34 63211.84 63211.59 80.2 63225.22 63225.72 63225.47 69.9 63239.22 63239.72 63239.47 54.4 63253.28 63253.78 63253.53 62.1 63267.28 63267.78 63267.53 43.9 63281.28 63281.78 63281.53 50.6 63295.22 63295.72 63295.47 48.3 63309.22 63309.72 63309.47 47.6 63323.22 63323.72 63323.47 33.6 63337.22 63337.72 63337.47 39.9 63351.28 63351.78 63351.53 26.6 63365.22 63365.72 63365.47 44.5 63379.22 63379.72 63379.47 41.9 63393.28 63393.78 63393.53 28.8 63407.28 63407.78 63407.53 45.6 63421.22 63421.72 63421.47 93.8 63435.22 63435.72 63435.47 100.4 63449.22 63449.72 63449.47 226.4 63463.22 63463.72 63463.47 134.9 63477.22 63477.72 63477.47 182.3 63491.22 63491.72 63491.47 149.4 63505.22 63505.72 63505.47 285.2 63519.22 63519.72 63519.47 308.4 63533.22 63533.72 63533.47 173.0 63547.22 63547.72 63547.47 71.7 63561.22 63561.72 63561.47 60.8 63575.28 63575.78 63575.53 51.3 63589.22 63589.72 63589.47 51.9 63603.22 63603.72 63603.47 109.0 63617.22 63617.72 63617.47 53.8 63631.28 63631.78 63631.53 59.2 63645.28 63645.78 63645.53 52.4 63659.22 63659.72 63659.47 50.4 63673.22 63673.72 63673.47 56.0 63687.28 63687.78 63687.53 82.6 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