43 1001 Wennberg, Paul California Institute of Technology Gas Phase Hydrogen Cyanide from DC-8 TC4 1 1 2007 08 10 2011 09 07 0 start_UTC, s 3 1 1 1 999999 999999 999999 stop_UTC, s mid_UTC, s HCN, pptv 0 26 PI_CONTACT_INFO: Address: California Institute of Technology. MC 150-21. 1200 E. California Blvd, Pasadena, CA, 91125. Phone: (626) 395-2447. Fax: (626) 585-1917. email: wennberg@gps.caltech.edu PLATFORM: NASA DC-8 airborne laboratory. LOCATION: Aircraft location data in file TN_20070810.DC8. ASSOCIATED_DATA: N/A INSTRUMENT_INFO: Chemical Ionization Mass Spectrometer. Direct measurements in ambient air. DATA_INFO: Measurements are reported as 0.5 sec averages and in units of pptv. CAUTION: Do not extrapolate data outside of given time interval as these are discrete measurements. Calibration was conducted ~once per hour during the flight using H2O2 and HNO3 calibrants, and proxied to HCN using laboratory calibrations. Absolute calibration was obtained in the laboratory by FTIR spectroscopy. Zeros were conducted ~3 times per hour by passing ambient air through a filter containing nylon wool coated with NaHCO3. UNCERTAINTY: +-(50% of measuremlent value + 50 pptv) ULOD_FLAG: 7777777 ULOD_VALUE: N/A LLOD_FLAG: 8888888 LLOD_VALUE: N/A; N/A; N/A; DM_CONTACT_INFO: John Crounse. California Institute of Technology. Department of Chemistry and Chemical Engineering. MC 150-21. 1200 E. California Blvd. Pasadena, CA 91125. Phone: (626) 395-6868. Fax: (626) 585-1917. email: crounjd@caltech.edu. PROJECT_INFO: TC4 study; 13 July-13 August 2007; Study of cloud processing and tropical convection processes STIPULATIONS_ON_USE: Use of these data requires PI notification and adherence to the TC4 data protocol. OTHER_COMMENTS: N/A REVISION: R1 R1: ULOD and LLOD flags changed to positive values, to conform to Ames format 2.1 specifications. R0: Preliminary Data Revision 0. Water correction has been applied using CIT-CIMS water. Reduction code 1.5 start_UTC stop_UTC mid_UTC HCN 53333.34 53333.84 53333.59 127.2 53347.34 53347.84 53347.59 111.3 53361.41 53361.91 53361.66 134.1 53375.28 53375.78 53375.53 110.6 53389.28 53389.78 53389.53 94.8 53403.22 53403.72 53403.47 109.3 53417.22 53417.72 53417.47 126.2 53431.22 53431.72 53431.47 130.9 53445.22 53445.72 53445.47 114.6 53459.22 53459.72 53459.47 115.4 53473.34 53473.84 53473.59 123.5 53487.28 53487.78 53487.53 115.3 53501.22 53501.72 53501.47 126.6 53515.28 53515.78 53515.53 123.5 53529.22 53529.72 53529.47 121.3 53543.22 53543.72 53543.47 122.7 53557.22 53557.72 53557.47 117.8 53571.22 53571.72 53571.47 131.1 53585.22 53585.72 53585.47 128.9 53599.22 53599.72 53599.47 119.0 53613.22 53613.72 53613.47 123.9 53627.22 53627.72 53627.47 117.0 53641.22 53641.72 53641.47 122.3 53655.28 53655.78 53655.53 117.6 53669.22 53669.72 53669.47 120.5 53683.28 53683.78 53683.53 137.3 53697.28 53697.78 53697.53 125.2 53711.28 53711.78 53711.53 133.4 53725.22 53725.72 53725.47 124.3 53739.22 53739.72 53739.47 123.1 53753.22 53753.72 53753.47 137.4 53767.22 53767.72 53767.47 130.6 53781.28 53781.78 53781.53 137.0 53795.22 53795.72 53795.47 133.0 53809.22 53809.72 53809.47 132.7 53823.22 53823.72 53823.47 133.4 53837.22 53837.72 53837.47 137.6 53851.22 53851.72 53851.47 136.3 53865.28 53865.78 53865.53 120.8 53879.22 53879.72 53879.47 132.7 53893.22 53893.72 53893.47 124.5 53907.22 53907.72 53907.47 129.6 53921.22 53921.72 53921.47 134.9 53935.22 53935.72 53935.47 134.0 53949.22 53949.72 53949.47 148.2 53963.22 53963.72 53963.47 153.1 53977.22 53977.72 53977.47 127.9 55894.97 55895.47 55895.22 227.9 55908.97 55909.47 55909.22 245.5 55922.97 55923.47 55923.22 223.8 55936.97 55937.47 55937.22 233.0 55950.97 55951.47 55951.22 216.2 55964.97 55965.47 55965.22 230.9 55978.97 55979.47 55979.22 219.6 55992.97 55993.47 55993.22 168.0 56006.97 56007.47 56007.22 202.4 56021.03 56021.53 56021.28 273.2 56034.97 56035.47 56035.22 267.3 56103.84 56104.34 56104.09 228.6 56117.84 56118.34 56118.09 231.8 56131.84 56132.34 56132.09 210.3 56145.91 56146.41 56146.16 240.1 56159.84 56160.34 56160.09 237.0 56173.84 56174.34 56174.09 257.6 56187.72 56188.22 56187.97 292.6 56201.72 56202.22 56201.97 260.6 56440.59 56441.09 56440.84 257.0 56454.66 56455.16 56454.91 300.9 56468.59 56469.09 56468.84 265.5 56482.59 56483.09 56482.84 243.3 56496.59 56497.09 56496.84 232.2 56510.59 56511.09 56510.84 267.5 56524.59 56525.09 56524.84 234.9 56538.66 56539.16 56538.91 249.4 56552.59 56553.09 56552.84 290.9 56566.59 56567.09 56566.84 234.9 56580.59 56581.09 56580.84 252.9 56594.59 56595.09 56594.84 276.0 56608.59 56609.09 56608.84 211.6 56622.59 56623.09 56622.84 262.3 56664.59 56665.09 56664.84 233.3 56678.59 56679.09 56678.84 261.6 56692.59 56693.09 56692.84 290.0 56706.59 56707.09 56706.84 297.3 56720.59 56721.09 56720.84 251.5 56734.59 56735.09 56734.84 240.7 56748.59 56749.09 56748.84 297.8 56762.59 56763.09 56762.84 245.4 56776.66 56777.16 56776.91 245.3 56790.59 56791.09 56790.84 303.3 56804.66 56805.16 56804.91 245.1 56818.66 56819.16 56818.91 247.2 56832.66 56833.16 56832.91 265.3 56846.59 56847.09 56846.84 282.6 56860.59 56861.09 56860.84 300.7 56874.59 56875.09 56874.84 221.5 56888.59 56889.09 56888.84 297.7 57014.34 57014.84 57014.59 227.2 57028.34 57028.84 57028.59 249.5 57042.34 57042.84 57042.59 256.6 57056.41 57056.91 57056.66 299.5 57070.41 57070.91 57070.66 266.8 57084.34 57084.84 57084.59 265.6 57098.34 57098.84 57098.59 237.9 57112.34 57112.84 57112.59 269.6 57126.41 57126.91 57126.66 258.7 57140.34 57140.84 57140.59 256.6 57154.34 57154.84 57154.59 265.1 57168.34 57168.84 57168.59 246.9 57182.34 57182.84 57182.59 295.0 57196.41 57196.91 57196.66 254.4 57210.34 57210.84 57210.59 294.6 57224.34 57224.84 57224.59 264.7 57238.34 57238.84 57238.59 274.9 57252.41 57252.91 57252.66 242.2 57266.41 57266.91 57266.66 299.6 57280.34 57280.84 57280.59 269.9 57294.34 57294.84 57294.59 269.7 57308.41 57308.91 57308.66 278.9 57322.41 57322.91 57322.66 298.9 57336.41 57336.91 57336.66 245.0 57441.34 57441.84 57441.59 260.7 57455.34 57455.84 57455.59 263.7 57469.41 57469.91 57469.66 311.0 57483.28 57483.78 57483.53 248.2 57497.22 57497.72 57497.47 299.0 57511.28 57511.78 57511.53 317.0 57525.22 57525.72 57525.47 289.4 57539.22 57539.72 57539.47 316.5 57553.22 57553.72 57553.47 276.3 57567.28 57567.78 57567.53 284.4 57581.41 57581.91 57581.66 320.6 57595.28 57595.78 57595.53 321.3 57609.22 57609.72 57609.47 264.6 57623.22 57623.72 57623.47 290.8 57637.28 57637.78 57637.53 310.0 57651.28 57651.78 57651.53 285.2 57665.28 57665.78 57665.53 284.8 57679.22 57679.72 57679.47 288.4 57693.22 57693.72 57693.47 322.3 57707.22 57707.72 57707.47 294.7 57721.22 57721.72 57721.47 305.4 57735.28 57735.78 57735.53 279.2 57749.28 57749.78 57749.53 326.0 57763.22 57763.72 57763.47 289.4 57777.22 57777.72 57777.47 270.8 57791.28 57791.78 57791.53 278.9 57805.22 57805.72 57805.47 335.3 57819.22 57819.72 57819.47 270.7 57833.22 57833.72 57833.47 270.7 57847.22 57847.72 57847.47 283.4 57861.22 57861.72 57861.47 273.9 57875.22 57875.72 57875.47 316.6 57889.28 57889.78 57889.53 291.3 57903.22 57903.72 57903.47 285.6 57917.22 57917.72 57917.47 297.0 57931.22 57931.72 57931.47 309.0 57945.22 57945.72 57945.47 290.4 57959.22 57959.72 57959.47 298.4 57973.22 57973.72 57973.47 287.5 57987.22 57987.72 57987.47 262.5 58001.22 58001.72 58001.47 259.1 58015.22 58015.72 58015.47 288.1 58029.28 58029.78 58029.53 276.2 58043.28 58043.78 58043.53 321.2 58057.22 58057.72 58057.47 273.0 58071.22 58071.72 58071.47 266.1 58085.22 58085.72 58085.47 287.8 58099.22 58099.72 58099.47 298.7 58113.28 58113.78 58113.53 296.8 58127.22 58127.72 58127.47 283.0 58141.28 58141.78 58141.53 260.3 58155.22 58155.72 58155.47 277.9 58169.22 58169.72 58169.47 264.4 58183.22 58183.72 58183.47 321.4 58197.22 58197.72 58197.47 265.0 58211.22 58211.72 58211.47 297.3 58225.22 58225.72 58225.47 286.3 58239.22 58239.72 58239.47 272.1 58253.22 58253.72 58253.47 284.4 58267.22 58267.72 58267.47 338.5 58281.22 58281.72 58281.47 330.8 58295.28 58295.78 58295.53 307.9 58309.22 58309.72 58309.47 309.6 58323.22 58323.72 58323.47 302.7 58337.22 58337.72 58337.47 282.6 58441.34 58441.84 58441.59 248.2 58455.34 58455.84 58455.59 239.6 58469.34 58469.84 58469.59 279.3 58483.41 58483.91 58483.66 256.1 58497.34 58497.84 58497.59 259.8 58511.34 58511.84 58511.59 279.6 58525.34 58525.84 58525.59 298.1 58539.34 58539.84 58539.59 259.2 58553.41 58553.91 58553.66 254.6 58567.22 58567.72 58567.47 257.2 58581.34 58581.84 58581.59 244.2 58623.41 58623.91 58623.66 243.5 58637.41 58637.91 58637.66 283.7 58651.34 58651.84 58651.59 262.4 58665.41 58665.91 58665.66 260.1 58679.22 58679.72 58679.47 227.3 58693.22 58693.72 58693.47 256.5 58707.22 58707.72 58707.47 176.2 58721.28 58721.78 58721.53 204.7 58735.34 58735.84 58735.59 208.0 58749.34 58749.84 58749.59 288.9 58763.41 58763.91 58763.66 302.4 58777.22 58777.72 58777.47 262.3 58791.28 58791.78 58791.53 299.4 58805.22 58805.72 58805.47 310.6 58819.22 58819.72 58819.47 278.1 58833.22 58833.72 58833.47 316.6 58847.22 58847.72 58847.47 282.6 58861.28 58861.78 58861.53 328.0 58875.34 58875.84 58875.59 308.1 58889.22 58889.72 58889.47 313.1 58903.28 58903.78 58903.53 322.7 58917.28 58917.78 58917.53 339.8 58931.22 58931.72 58931.47 305.8 58945.22 58945.72 58945.47 311.5 58959.28 58959.78 58959.53 239.2 58973.22 58973.72 58973.47 266.4 58987.28 58987.78 58987.53 305.7 59001.22 59001.72 59001.47 276.7 59015.22 59015.72 59015.47 273.3 59029.28 59029.78 59029.53 253.7 59043.22 59043.72 59043.47 246.1 59057.22 59057.72 59057.47 261.1 59071.22 59071.72 59071.47 256.1 59085.22 59085.72 59085.47 243.9 59099.22 59099.72 59099.47 270.5 59113.22 59113.72 59113.47 234.8 59127.22 59127.72 59127.47 251.7 59141.22 59141.72 59141.47 227.7 59155.22 59155.72 59155.47 259.0 59169.28 59169.78 59169.53 295.2 59183.22 59183.72 59183.47 273.0 59197.22 59197.72 59197.47 256.6 59211.28 59211.78 59211.53 249.5 59225.28 59225.78 59225.53 256.4 59239.22 59239.72 59239.47 265.2 59253.22 59253.72 59253.47 267.5 59267.22 59267.72 59267.47 233.8 59281.22 59281.72 59281.47 255.6 59295.22 59295.72 59295.47 259.4 59309.28 59309.78 59309.53 292.0 59323.22 59323.72 59323.47 270.2 59337.22 59337.72 59337.47 302.2 59910.34 59910.84 59910.59 279.3 59924.34 59924.84 59924.59 312.9 59938.41 59938.91 59938.66 299.6 59952.41 59952.91 59952.66 298.0 59966.41 59966.91 59966.66 260.8 59980.41 59980.91 59980.66 281.2 59994.41 59994.91 59994.66 239.0 60008.34 60008.84 60008.59 296.7 60022.34 60022.84 60022.59 296.2 60036.34 60036.84 60036.59 269.9 60050.34 60050.84 60050.59 286.5 60064.34 60064.84 60064.59 290.3 60078.34 60078.84 60078.59 280.3 60092.34 60092.84 60092.59 330.7 60106.34 60106.84 60106.59 285.9 60120.34 60120.84 60120.59 291.5 60134.34 60134.84 60134.59 261.3 60148.34 60148.84 60148.59 251.9 60162.34 60162.84 60162.59 249.3 60176.34 60176.84 60176.59 267.0 60190.22 60190.72 60190.47 296.6 60204.22 60204.72 60204.47 302.5 60218.34 60218.84 60218.59 335.1 60232.34 60232.84 60232.59 346.8 60246.34 60246.84 60246.59 304.1 60260.34 60260.84 60260.59 338.7 60274.41 60274.91 60274.66 334.7 60288.41 60288.91 60288.66 379.7 60302.28 60302.78 60302.53 359.1 60316.22 60316.72 60316.47 394.7 60330.22 60330.72 60330.47 366.7 60344.28 60344.78 60344.53 437.8 60358.34 60358.84 60358.59 381.2 60372.41 60372.91 60372.66 399.7 60386.34 60386.84 60386.59 339.8 60400.34 60400.84 60400.59 370.3 60414.28 60414.78 60414.53 383.2 60428.22 60428.72 60428.47 359.0 60442.22 60442.72 60442.47 349.2 60484.22 60484.72 60484.47 363.5 60498.22 60498.72 60498.47 341.3 60512.28 60512.78 60512.53 393.9 60526.22 60526.72 60526.47 370.7 60540.22 60540.72 60540.47 338.3 60554.22 60554.72 60554.47 358.3 60568.28 60568.78 60568.53 421.6 60582.22 60582.72 60582.47 360.1 60596.22 60596.72 60596.47 361.7 60610.22 60610.72 60610.47 377.1 60624.22 60624.72 60624.47 374.8 60638.22 60638.72 60638.47 372.8 60652.22 60652.72 60652.47 361.5 60666.22 60666.72 60666.47 338.5 60680.22 60680.72 60680.47 376.7 60694.22 60694.72 60694.47 354.3 60708.22 60708.72 60708.47 374.3 60722.22 60722.72 60722.47 376.0 60736.22 60736.72 60736.47 415.2 60750.22 60750.72 60750.47 366.1 60764.22 60764.72 60764.47 342.1 60778.22 60778.72 60778.47 400.9 60792.22 60792.72 60792.47 362.0 60806.22 60806.72 60806.47 372.5 60911.34 60911.84 60911.59 375.5 60925.34 60925.84 60925.59 375.8 60939.34 60939.84 60939.59 367.0 60953.34 60953.84 60953.59 407.0 60967.41 60967.91 60967.66 381.4 60981.34 60981.84 60981.59 364.1 60995.34 60995.84 60995.59 404.2 61009.34 61009.84 61009.59 392.9 61023.41 61023.91 61023.66 401.6 61037.34 61037.84 61037.59 386.3 61051.34 61051.84 61051.59 375.6 61065.34 61065.84 61065.59 364.2 61107.34 61107.84 61107.59 409.6 61121.34 61121.84 61121.59 406.1 61135.34 61135.84 61135.59 390.7 61149.34 61149.84 61149.59 421.5 61163.28 61163.78 61163.53 451.9 61177.28 61177.78 61177.53 434.7 61191.22 61191.72 61191.47 426.7 61205.34 61205.84 61205.59 439.0 61219.41 61219.91 61219.66 417.0 61233.34 61233.84 61233.59 383.1 61247.34 61247.84 61247.59 382.7 61261.34 61261.84 61261.59 390.5 61275.28 61275.78 61275.53 387.8 61289.22 61289.72 61289.47 397.4 61303.22 61303.72 61303.47 436.0 61317.22 61317.72 61317.47 439.9 61331.22 61331.72 61331.47 434.5 61345.34 61345.84 61345.59 432.0 61359.34 61359.84 61359.59 391.9 61373.34 61373.84 61373.59 411.0 61387.22 61387.72 61387.47 390.2 61401.22 61401.72 61401.47 381.9 61415.22 61415.72 61415.47 369.3 61429.22 61429.72 61429.47 402.7 61443.22 61443.72 61443.47 393.9 61457.22 61457.72 61457.47 403.1 61471.28 61471.78 61471.53 401.2 61485.28 61485.78 61485.53 400.7 61499.22 61499.72 61499.47 394.2 61513.22 61513.72 61513.47 393.3 61527.28 61527.78 61527.53 420.6 61541.22 61541.72 61541.47 410.9 61555.28 61555.78 61555.53 418.1 61569.22 61569.72 61569.47 415.6 61583.28 61583.78 61583.53 391.1 61597.22 61597.72 61597.47 382.4 61611.28 61611.78 61611.53 376.7 61625.22 61625.72 61625.47 386.7 61639.28 61639.78 61639.53 431.4 61653.22 61653.72 61653.47 407.5 61667.28 61667.78 61667.53 443.6 61681.22 61681.72 61681.47 389.6 61695.28 61695.78 61695.53 427.1 61709.22 61709.72 61709.47 381.9 61723.22 61723.72 61723.47 412.8 61737.28 61737.78 61737.53 430.6 61751.22 61751.72 61751.47 396.7 61765.22 61765.72 61765.47 361.0 61779.22 61779.72 61779.47 426.4 61793.22 61793.72 61793.47 378.8 61807.22 61807.72 61807.47 358.2 61912.34 61912.84 61912.59 348.5 61926.34 61926.84 61926.59 466.6 61940.34 61940.84 61940.59 427.5 61954.34 61954.84 61954.59 456.3 61968.41 61968.91 61968.66 383.5 61982.34 61982.84 61982.59 392.7 61996.34 61996.84 61996.59 368.9 62010.41 62010.91 62010.66 480.3 62024.41 62024.91 62024.66 441.7 62038.28 62038.78 62038.53 452.1 62052.41 62052.91 62052.66 513.8 62066.34 62066.84 62066.59 425.4 62080.41 62080.91 62080.66 438.1 62094.41 62094.91 62094.66 436.3 62108.41 62108.91 62108.66 424.1 62122.34 62122.84 62122.59 419.6 62136.28 62136.78 62136.53 430.8 62150.22 62150.72 62150.47 434.7 62164.22 62164.72 62164.47 391.8 62178.22 62178.72 62178.47 450.3 62192.22 62192.72 62192.47 403.1 62206.34 62206.84 62206.59 409.1 62220.34 62220.84 62220.59 422.4 62234.34 62234.84 62234.59 408.1 62248.22 62248.72 62248.47 446.7 62262.22 62262.72 62262.47 411.1 62276.22 62276.72 62276.47 405.9 62290.22 62290.72 62290.47 419.1 62304.28 62304.78 62304.53 402.4 62318.22 62318.72 62318.47 395.7 62332.22 62332.72 62332.47 382.0 62346.34 62346.84 62346.59 418.3 62360.22 62360.72 62360.47 402.2 62374.22 62374.72 62374.47 404.6 62388.28 62388.78 62388.53 432.0 62402.22 62402.72 62402.47 395.5 62416.28 62416.78 62416.53 393.7 62430.28 62430.78 62430.53 429.6 62444.28 62444.78 62444.53 417.6 62458.28 62458.78 62458.53 388.3 62472.22 62472.72 62472.47 408.7 62486.22 62486.72 62486.47 431.7 62500.28 62500.78 62500.53 389.5 62514.22 62514.72 62514.47 419.7 62528.28 62528.78 62528.53 416.3 62542.22 62542.72 62542.47 372.8 62556.22 62556.72 62556.47 431.2 62570.28 62570.78 62570.53 394.3 62584.22 62584.72 62584.47 376.4 62598.22 62598.72 62598.47 385.4 62612.22 62612.72 62612.47 396.7 62626.22 62626.72 62626.47 434.9 62640.22 62640.72 62640.47 419.6 62654.22 62654.72 62654.47 427.8 62668.22 62668.72 62668.47 401.9 62682.22 62682.72 62682.47 382.2 62696.22 62696.72 62696.47 390.1 62710.28 62710.78 62710.53 387.8 62724.22 62724.72 62724.47 372.0 62738.22 62738.72 62738.47 380.5 62752.22 62752.72 62752.47 403.3 62766.22 62766.72 62766.47 413.1 62780.28 62780.78 62780.53 447.6 62794.28 62794.78 62794.53 384.5 62808.22 62808.72 62808.47 365.7 63047.41 63047.91 63047.66 401.7 63061.34 63061.84 63061.59 365.2 63075.34 63075.84 63075.59 377.6 63089.34 63089.84 63089.59 389.2 63103.41 63103.91 63103.66 385.7 63117.22 63117.72 63117.47 412.2 63131.22 63131.72 63131.47 415.3 63145.22 63145.72 63145.47 394.3 63159.22 63159.72 63159.47 421.7 63173.28 63173.78 63173.53 382.0 63187.41 63187.91 63187.66 385.9 63201.34 63201.84 63201.59 386.3 63215.41 63215.91 63215.66 421.5 63229.22 63229.72 63229.47 423.9 63243.22 63243.72 63243.47 425.6 63257.22 63257.72 63257.47 392.9 63271.22 63271.72 63271.47 398.9 63285.22 63285.72 63285.47 406.9 63299.22 63299.72 63299.47 418.2 63313.22 63313.72 63313.47 405.2 63327.22 63327.72 63327.47 380.1 63341.22 63341.72 63341.47 420.9 63355.28 63355.78 63355.53 418.3 63369.22 63369.72 63369.47 428.2 63383.22 63383.72 63383.47 376.4 63397.22 63397.72 63397.47 444.4 63411.28 63411.78 63411.53 401.9 63425.22 63425.72 63425.47 407.5 63439.28 63439.78 63439.53 392.7 63453.28 63453.78 63453.53 453.8 63467.22 63467.72 63467.47 467.4 63481.22 63481.72 63481.47 425.3 63495.22 63495.72 63495.47 395.0 63509.22 63509.72 63509.47 408.4 63523.22 63523.72 63523.47 407.4 63537.22 63537.72 63537.47 375.6 63551.22 63551.72 63551.47 425.0 63565.22 63565.72 63565.47 394.5 63579.28 63579.78 63579.53 424.2 63593.28 63593.78 63593.53 378.3 63607.22 63607.72 63607.47 384.7 63621.22 63621.72 63621.47 404.3 63635.22 63635.72 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