43 1001 Wennberg, Paul California Institute of Technology Gas Phase Hydrogen Peroxide from DC-8 TC4 1 1 2007 08 10 2011 09 07 0 start_UTC, s 3 1 1 1 999999 999999 999999 stop_UTC, s mid_UTC, s H2O2, pptv 0 26 PI_CONTACT_INFO: Address: California Institute of Technology. MC 150-21. 1200 E. California Blvd, Pasadena, CA, 91125. Phone: (626) 395-2447. Fax: (626) 585-1917. email: wennberg@gps.caltech.edu PLATFORM: NASA DC-8 airborne laboratory. LOCATION: Aircraft location data in file TN_20070810.DC8. ASSOCIATED_DATA: N/A INSTRUMENT_INFO: Chemical Ionization Mass Spectrometer. Direct measurements in ambient air. DATA_INFO: Measurements are reported as 0.5 sec averages and in units of pptv. CAUTION: Do not extrapolate data outside of given time interval as these are discrete measurements. Calibration was conducted ~once per hour during the flight using H2O2 obtained from vapor pressure over urea hydrogen peroxide held at constant temperature. Absolute calibration was obtained by collection in water and subsequent wet chemistry. Zeros were conducted ~3 times per hour by passing ambient air through a filter containing nylon wool coated with NaHCO3. UNCERTAINTY: +-(50% of measuremlent value + 150 pptv) ULOD_FLAG: 7777777 ULOD_VALUE: N/A LLOD_FLAG: 8888888 LLOD_VALUE: N/A; N/A; N/A; DM_CONTACT_INFO: John Crounse. California Institute of Technology. Department of Chemistry and Chemical Engineering. MC 150-21. 1200 E. California Blvd. Pasadena, CA 91125. Phone: (626) 395-6868. Fax: (626) 585-1917. email: crounjd@caltech.edu. PROJECT_INFO: TC4 study; 13 July-13 August 2007; Study of cloud processing and tropical convection processes STIPULATIONS_ON_USE: Use of these data requires PI notification and adherence to the TC4 data protocol. OTHER_COMMENTS: N/A REVISION: R1 R1: ULOD and LLOD flags changed to positive values, to conform to Ames format 2.1 specifications. R0: Preliminary Data Revision 0. Water correction has been applied using CIT-CIMS water. Reduction code 1.5 start_UTC stop_UTC mid_UTC H2O2 53333.84 53334.34 53334.09 562.5 53347.91 53348.41 53348.16 554.5 53361.84 53362.34 53362.09 472.6 53375.72 53376.22 53375.97 443.1 53389.72 53390.22 53389.97 448.6 53403.72 53404.22 53403.97 638.5 53417.72 53418.22 53417.97 668.5 53431.72 53432.22 53431.97 571.1 53445.72 53446.22 53445.97 635.0 53459.78 53460.28 53460.03 627.1 53473.84 53474.34 53474.09 637.2 53487.78 53488.28 53488.03 663.9 53501.72 53502.22 53501.97 415.1 53515.72 53516.22 53515.97 389.3 53529.72 53530.22 53529.97 663.8 53543.72 53544.22 53543.97 565.1 53557.72 53558.22 53557.97 499.0 53571.72 53572.22 53571.97 348.9 53585.78 53586.28 53586.03 327.2 53599.72 53600.22 53599.97 332.4 53613.78 53614.28 53614.03 358.6 53627.78 53628.28 53628.03 378.2 53641.72 53642.22 53641.97 418.2 53655.72 53656.22 53655.97 438.7 53669.72 53670.22 53669.97 420.7 53683.72 53684.22 53683.97 383.5 53697.72 53698.22 53697.97 413.4 53711.72 53712.22 53711.97 391.8 53725.78 53726.28 53726.03 398.5 53739.72 53740.22 53739.97 462.4 53753.72 53754.22 53753.97 586.7 53767.72 53768.22 53767.97 516.0 53781.78 53782.28 53782.03 830.1 53795.72 53796.22 53795.97 566.5 53809.72 53810.22 53809.97 485.2 53823.72 53824.22 53823.97 443.8 53837.72 53838.22 53837.97 455.9 53851.78 53852.28 53852.03 437.1 53865.78 53866.28 53866.03 528.9 53879.72 53880.22 53879.97 420.3 53893.72 53894.22 53893.97 376.0 53907.78 53908.28 53908.03 277.8 53921.72 53922.22 53921.97 287.1 53935.72 53936.22 53935.97 329.7 53949.72 53950.22 53949.97 311.4 53963.78 53964.28 53964.03 444.6 53977.72 53978.22 53977.97 356.1 53991.72 53992.22 53991.97 302.4 54005.72 54006.22 54005.97 465.5 55895.47 55895.97 55895.72 131.6 55909.53 55910.03 55909.78 115.4 55923.47 55923.97 55923.72 133.2 55937.47 55937.97 55937.72 119.4 55951.53 55952.03 55951.78 91.7 55965.53 55966.03 55965.78 169.5 55979.47 55979.97 55979.72 88.2 55993.47 55993.97 55993.72 46.7 56007.47 56007.97 56007.72 56.8 56021.47 56021.97 56021.72 126.5 56035.47 56035.97 56035.72 101.7 56104.34 56104.84 56104.59 74.3 56118.34 56118.84 56118.59 126.9 56132.34 56132.84 56132.59 66.0 56146.34 56146.84 56146.59 87.8 56160.34 56160.84 56160.59 131.0 56174.34 56174.84 56174.59 148.8 56188.22 56188.72 56188.47 113.8 56202.28 56202.78 56202.53 92.5 56441.16 56441.66 56441.41 145.5 56455.16 56455.66 56455.41 92.8 56469.09 56469.59 56469.34 113.3 56483.09 56483.59 56483.34 95.5 56497.09 56497.59 56497.34 90.6 56511.16 56511.66 56511.41 106.1 56525.16 56525.66 56525.41 82.9 56539.09 56539.59 56539.34 126.8 56553.09 56553.59 56553.34 83.7 56567.09 56567.59 56567.34 85.4 56581.16 56581.66 56581.41 122.0 56595.09 56595.59 56595.34 69.1 56609.09 56609.59 56609.34 80.2 56623.09 56623.59 56623.34 39.9 56665.16 56665.66 56665.41 67.9 56679.16 56679.66 56679.41 71.3 56693.16 56693.66 56693.41 60.9 56707.16 56707.66 56707.41 -1.5 56721.09 56721.59 56721.34 68.3 56735.09 56735.59 56735.34 31.6 56749.16 56749.66 56749.41 9.7 56763.16 56763.66 56763.41 -0.2 56777.16 56777.66 56777.41 28.3 56791.09 56791.59 56791.34 33.5 56805.09 56805.59 56805.34 50.8 56819.09 56819.59 56819.34 50.5 56833.16 56833.66 56833.41 18.8 56847.16 56847.66 56847.41 7.7 56861.09 56861.59 56861.34 66.4 56875.16 56875.66 56875.41 46.3 56889.09 56889.59 56889.34 63.2 57014.84 57015.34 57015.09 48.2 57028.84 57029.34 57029.09 70.9 57042.84 57043.34 57043.09 69.0 57056.84 57057.34 57057.09 64.3 57070.84 57071.34 57071.09 81.3 57084.84 57085.34 57085.09 51.0 57098.91 57099.41 57099.16 55.1 57112.84 57113.34 57113.09 29.0 57126.84 57127.34 57127.09 42.8 57140.91 57141.41 57141.16 81.8 57154.91 57155.41 57155.16 67.5 57168.84 57169.34 57169.09 56.4 57182.84 57183.34 57183.09 81.2 57196.84 57197.34 57197.09 61.6 57210.91 57211.41 57211.16 75.0 57224.91 57225.41 57225.16 55.9 57238.84 57239.34 57239.09 30.6 57252.84 57253.34 57253.09 69.8 57266.84 57267.34 57267.09 48.7 57280.84 57281.34 57281.09 37.7 57294.84 57295.34 57295.09 67.4 57308.84 57309.34 57309.09 71.5 57322.84 57323.34 57323.09 71.2 57336.91 57337.41 57337.16 69.2 57441.84 57442.34 57442.09 36.4 57455.91 57456.41 57456.16 25.2 57469.84 57470.34 57470.09 50.4 57483.72 57484.22 57483.97 24.2 57497.78 57498.28 57498.03 57.9 57511.72 57512.22 57511.97 49.7 57525.72 57526.22 57525.97 71.5 57539.78 57540.28 57540.03 44.8 57553.72 57554.22 57553.97 72.7 57567.72 57568.22 57567.97 46.5 57581.91 57582.41 57582.16 76.7 57595.72 57596.22 57595.97 54.3 57609.72 57610.22 57609.97 63.1 57623.72 57624.22 57623.97 45.6 57637.72 57638.22 57637.97 76.8 57651.72 57652.22 57651.97 107.0 57665.72 57666.22 57665.97 92.1 57679.78 57680.28 57680.03 51.7 57693.72 57694.22 57693.97 52.9 57707.72 57708.22 57707.97 90.8 57721.72 57722.22 57721.97 77.1 57735.72 57736.22 57735.97 72.7 57749.72 57750.22 57749.97 76.5 57763.72 57764.22 57763.97 92.5 57777.72 57778.22 57777.97 38.7 57791.72 57792.22 57791.97 42.1 57805.72 57806.22 57805.97 69.1 57819.72 57820.22 57819.97 19.7 57833.72 57834.22 57833.97 40.7 57847.78 57848.28 57848.03 52.5 57861.72 57862.22 57861.97 51.4 57875.78 57876.28 57876.03 58.2 57889.72 57890.22 57889.97 22.8 57903.72 57904.22 57903.97 37.8 57917.72 57918.22 57917.97 77.4 57931.78 57932.28 57932.03 49.0 57945.78 57946.28 57946.03 46.4 57959.78 57960.28 57960.03 51.1 57973.78 57974.28 57974.03 67.9 57987.78 57988.28 57988.03 24.9 58001.72 58002.22 58001.97 56.6 58015.72 58016.22 58015.97 72.9 58029.72 58030.22 58029.97 24.5 58043.72 58044.22 58043.97 39.0 58057.72 58058.22 58057.97 43.8 58071.72 58072.22 58071.97 51.5 58085.72 58086.22 58085.97 33.8 58099.72 58100.22 58099.97 55.7 58113.78 58114.28 58114.03 26.0 58127.72 58128.22 58127.97 38.5 58141.78 58142.28 58142.03 18.3 58155.72 58156.22 58155.97 32.0 58169.72 58170.22 58169.97 5.3 58183.72 58184.22 58183.97 69.6 58197.72 58198.22 58197.97 13.3 58211.72 58212.22 58211.97 51.2 58225.72 58226.22 58225.97 49.9 58239.72 58240.22 58239.97 43.6 58253.78 58254.28 58254.03 31.6 58267.78 58268.28 58268.03 22.0 58281.72 58282.22 58281.97 76.8 58295.78 58296.28 58296.03 41.6 58309.78 58310.28 58310.03 57.2 58323.72 58324.22 58323.97 70.4 58337.78 58338.28 58338.03 99.1 58441.84 58442.34 58442.09 22.3 58455.84 58456.34 58456.09 30.5 58469.84 58470.34 58470.09 52.8 58483.84 58484.34 58484.09 30.6 58497.84 58498.34 58498.09 60.5 58511.84 58512.34 58512.09 46.8 58525.84 58526.34 58526.09 37.7 58539.84 58540.34 58540.09 47.5 58553.84 58554.34 58554.09 31.2 58567.72 58568.22 58567.97 23.0 58581.84 58582.34 58582.09 12.5 58623.84 58624.34 58624.09 17.3 58637.84 58638.34 58638.09 37.2 58651.84 58652.34 58652.09 33.3 58665.91 58666.41 58666.16 22.9 58679.72 58680.22 58679.97 24.0 58693.72 58694.22 58693.97 21.4 58707.72 58708.22 58707.97 18.0 58721.72 58722.22 58721.97 27.3 58735.84 58736.34 58736.09 19.0 58749.84 58750.34 58750.09 35.7 58763.84 58764.34 58764.09 36.8 58777.72 58778.22 58777.97 39.9 58791.72 58792.22 58791.97 32.0 58805.72 58806.22 58805.97 20.6 58819.72 58820.22 58819.97 41.5 58833.72 58834.22 58833.97 35.7 58847.72 58848.22 58847.97 29.4 58861.72 58862.22 58861.97 60.4 58875.84 58876.34 58876.09 38.8 58889.72 58890.22 58889.97 25.0 58903.78 58904.28 58904.03 33.7 58917.72 58918.22 58917.97 23.4 58931.72 58932.22 58931.97 26.9 58945.72 58946.22 58945.97 5.9 58959.72 58960.22 58959.97 43.1 58973.78 58974.28 58974.03 31.1 58987.78 58988.28 58988.03 17.4 59001.72 59002.22 59001.97 14.4 59015.72 59016.22 59015.97 18.3 59029.78 59030.28 59030.03 43.2 59043.72 59044.22 59043.97 31.9 59057.72 59058.22 59057.97 20.9 59071.72 59072.22 59071.97 49.2 59085.78 59086.28 59086.03 4.5 59099.78 59100.28 59100.03 39.1 59113.72 59114.22 59113.97 37.0 59127.72 59128.22 59127.97 32.1 59141.78 59142.28 59142.03 5.5 59155.72 59156.22 59155.97 56.4 59169.78 59170.28 59170.03 -7.7 59183.72 59184.22 59183.97 41.4 59197.72 59198.22 59197.97 11.5 59211.72 59212.22 59211.97 26.9 59225.72 59226.22 59225.97 8.1 59239.78 59240.28 59240.03 0.9 59253.78 59254.28 59254.03 18.0 59267.72 59268.22 59267.97 38.3 59281.72 59282.22 59281.97 -1.4 59295.72 59296.22 59295.97 36.4 59309.72 59310.22 59309.97 11.2 59323.78 59324.28 59324.03 27.4 59337.72 59338.22 59337.97 -1.7 59910.84 59911.34 59911.09 17.0 59924.84 59925.34 59925.09 34.5 59938.84 59939.34 59939.09 -17.4 59952.84 59953.34 59953.09 32.7 59966.84 59967.34 59967.09 60.5 59980.84 59981.34 59981.09 80.4 59994.84 59995.34 59995.09 112.2 60008.84 60009.34 60009.09 29.5 60022.91 60023.41 60023.16 6.2 60036.91 60037.41 60037.16 43.3 60050.84 60051.34 60051.09 33.3 60064.84 60065.34 60065.09 -7.7 60078.84 60079.34 60079.09 42.1 60092.84 60093.34 60093.09 1.7 60106.84 60107.34 60107.09 13.0 60120.84 60121.34 60121.09 24.5 60134.84 60135.34 60135.09 41.9 60148.84 60149.34 60149.09 27.7 60162.84 60163.34 60163.09 15.9 60176.84 60177.34 60177.09 84.2 60190.78 60191.28 60191.03 59.9 60204.72 60205.22 60204.97 79.9 60218.84 60219.34 60219.09 85.9 60232.91 60233.41 60233.16 7.8 60246.91 60247.41 60247.16 21.5 60260.84 60261.34 60261.09 89.6 60274.84 60275.34 60275.09 108.1 60288.91 60289.41 60289.16 127.4 60302.72 60303.22 60302.97 135.1 60316.72 60317.22 60316.97 172.6 60330.72 60331.22 60330.97 95.8 60344.78 60345.28 60345.03 170.5 60358.84 60359.34 60359.09 127.0 60372.84 60373.34 60373.09 146.7 60386.84 60387.34 60387.09 106.1 60400.78 60401.28 60401.03 49.7 60414.72 60415.22 60414.97 123.3 60428.78 60429.28 60429.03 63.6 60442.78 60443.28 60443.03 105.0 60484.72 60485.22 60484.97 92.0 60498.78 60499.28 60499.03 134.1 60512.72 60513.22 60512.97 143.0 60526.72 60527.22 60526.97 87.2 60540.78 60541.28 60541.03 107.2 60554.72 60555.22 60554.97 117.4 60568.72 60569.22 60568.97 98.9 60582.72 60583.22 60582.97 96.3 60596.78 60597.28 60597.03 75.8 60610.72 60611.22 60610.97 101.9 60624.72 60625.22 60624.97 98.7 60638.72 60639.22 60638.97 92.9 60652.72 60653.22 60652.97 94.7 60666.72 60667.22 60666.97 64.5 60680.72 60681.22 60680.97 87.4 60694.72 60695.22 60694.97 84.8 60708.72 60709.22 60708.97 110.8 60722.72 60723.22 60722.97 86.0 60736.72 60737.22 60736.97 45.3 60750.72 60751.22 60750.97 62.3 60764.72 60765.22 60764.97 74.5 60778.72 60779.22 60778.97 41.3 60792.78 60793.28 60793.03 57.4 60806.72 60807.22 60806.97 62.5 60911.84 60912.34 60912.09 74.4 60925.84 60926.34 60926.09 41.0 60939.84 60940.34 60940.09 43.8 60953.84 60954.34 60954.09 29.0 60967.84 60968.34 60968.09 63.9 60981.84 60982.34 60982.09 44.3 60995.84 60996.34 60996.09 50.0 61009.84 61010.34 61010.09 53.9 61023.91 61024.41 61024.16 53.1 61037.91 61038.41 61038.16 61.7 61051.91 61052.41 61052.16 61.2 61065.84 61066.34 61066.09 68.4 61107.84 61108.34 61108.09 91.0 61121.91 61122.41 61122.16 65.6 61135.91 61136.41 61136.16 29.5 61149.84 61150.34 61150.09 65.4 61163.72 61164.22 61163.97 61.0 61177.78 61178.28 61178.03 73.9 61191.72 61192.22 61191.97 88.6 61205.84 61206.34 61206.09 93.8 61219.84 61220.34 61220.09 105.8 61233.84 61234.34 61234.09 91.8 61247.84 61248.34 61248.09 72.4 61261.84 61262.34 61262.09 103.9 61275.78 61276.28 61276.03 67.3 61289.78 61290.28 61290.03 77.3 61303.72 61304.22 61303.97 119.6 61317.72 61318.22 61317.97 98.2 61331.72 61332.22 61331.97 83.5 61345.84 61346.34 61346.09 89.6 61359.84 61360.34 61360.09 100.9 61373.84 61374.34 61374.09 71.5 61387.72 61388.22 61387.97 35.7 61401.72 61402.22 61401.97 53.7 61415.72 61416.22 61415.97 69.6 61429.78 61430.28 61430.03 68.8 61443.78 61444.28 61444.03 80.5 61457.72 61458.22 61457.97 48.0 61471.72 61472.22 61471.97 69.6 61485.72 61486.22 61485.97 114.5 61499.72 61500.22 61499.97 99.3 61513.72 61514.22 61513.97 100.6 61527.78 61528.28 61528.03 59.3 61541.72 61542.22 61541.97 106.1 61555.72 61556.22 61555.97 96.3 61569.72 61570.22 61569.97 111.3 61583.72 61584.22 61583.97 52.6 61597.72 61598.22 61597.97 108.9 61611.72 61612.22 61611.97 94.7 61625.78 61626.28 61626.03 102.1 61639.72 61640.22 61639.97 87.5 61653.72 61654.22 61653.97 118.7 61667.72 61668.22 61667.97 110.2 61681.72 61682.22 61681.97 114.4 61695.78 61696.28 61696.03 91.9 61709.72 61710.22 61709.97 113.3 61723.72 61724.22 61723.97 109.0 61737.72 61738.22 61737.97 77.3 61751.72 61752.22 61751.97 78.9 61765.72 61766.22 61765.97 82.7 61779.78 61780.28 61780.03 55.5 61793.72 61794.22 61793.97 38.8 61807.78 61808.28 61808.03 77.6 61912.84 61913.34 61913.09 31.7 61926.84 61927.34 61927.09 62.3 61940.84 61941.34 61941.09 53.6 61954.84 61955.34 61955.09 81.4 61968.84 61969.34 61969.09 51.9 61982.84 61983.34 61983.09 68.4 61996.84 61997.34 61997.09 46.7 62010.84 62011.34 62011.09 78.1 62024.84 62025.34 62025.09 61.0 62038.72 62039.22 62038.97 71.7 62052.84 62053.34 62053.09 82.4 62066.84 62067.34 62067.09 83.2 62080.84 62081.34 62081.09 88.3 62094.91 62095.41 62095.16 80.1 62108.84 62109.34 62109.09 107.7 62122.91 62123.41 62123.16 123.2 62136.72 62137.22 62136.97 119.9 62150.72 62151.22 62150.97 55.6 62164.72 62165.22 62164.97 83.4 62178.72 62179.22 62178.97 91.1 62192.78 62193.28 62193.03 59.1 62206.84 62207.34 62207.09 74.1 62220.91 62221.41 62221.16 93.4 62234.84 62235.34 62235.09 86.2 62248.72 62249.22 62248.97 67.5 62262.78 62263.28 62263.03 56.3 62276.72 62277.22 62276.97 96.9 62290.72 62291.22 62290.97 79.1 62304.78 62305.28 62305.03 74.4 62318.72 62319.22 62318.97 78.2 62332.72 62333.22 62332.97 57.0 62346.91 62347.41 62347.16 93.4 62360.72 62361.22 62360.97 78.2 62374.72 62375.22 62374.97 101.3 62388.78 62389.28 62389.03 98.7 62402.72 62403.22 62402.97 91.3 62416.72 62417.22 62416.97 84.8 62430.72 62431.22 62430.97 115.8 62444.72 62445.22 62444.97 104.7 62458.72 62459.22 62458.97 104.5 62472.78 62473.28 62473.03 122.7 62486.72 62487.22 62486.97 101.1 62500.72 62501.22 62500.97 140.0 62514.72 62515.22 62514.97 109.2 62528.72 62529.22 62528.97 120.7 62542.72 62543.22 62542.97 96.7 62556.78 62557.28 62557.03 110.4 62570.72 62571.22 62570.97 107.4 62584.72 62585.22 62584.97 101.6 62598.78 62599.28 62599.03 113.6 62612.78 62613.28 62613.03 104.8 62626.78 62627.28 62627.03 115.2 62640.72 62641.22 62640.97 108.5 62654.72 62655.22 62654.97 129.9 62668.78 62669.28 62669.03 118.4 62682.72 62683.22 62682.97 104.8 62696.78 62697.28 62697.03 84.6 62710.72 62711.22 62710.97 62.7 62724.78 62725.28 62725.03 86.3 62738.72 62739.22 62738.97 104.5 62752.78 62753.28 62753.03 72.2 62766.72 62767.22 62766.97 93.9 62780.72 62781.22 62780.97 69.1 62794.72 62795.22 62794.97 86.4 62808.72 62809.22 62808.97 65.7 63047.84 63048.34 63048.09 82.6 63061.84 63062.34 63062.09 73.2 63075.84 63076.34 63076.09 86.2 63089.84 63090.34 63090.09 107.6 63103.84 63104.34 63104.09 67.7 63117.72 63118.22 63117.97 122.9 63131.72 63132.22 63131.97 123.8 63145.72 63146.22 63145.97 131.6 63159.72 63160.22 63159.97 108.3 63173.78 63174.28 63174.03 81.7 63187.84 63188.34 63188.09 76.9 63201.84 63202.34 63202.09 101.4 63215.84 63216.34 63216.09 98.1 63229.72 63230.22 63229.97 93.1 63243.78 63244.28 63244.03 148.4 63257.72 63258.22 63257.97 99.5 63271.72 63272.22 63271.97 112.9 63285.78 63286.28 63286.03 113.0 63299.72 63300.22 63299.97 117.4 63313.72 63314.22 63313.97 117.5 63327.72 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