45 1001 Wennberg, Paul California Institute of Technology Gas Phase Methyl Hydrogen Peroxide from DC-8 TC4 1 1 2007 08 08 2011 09 07 0 start_UTC, s 3 1 1 1 999999 999999 999999 stop_UTC, s mid_UTC, s MHP, pptv 0 28 PI_CONTACT_INFO: Address: California Institute of Technology. MC 150-21. 1200 E. California Blvd, Pasadena, CA, 91125. Phone: (626) 395-2447. Fax: (626) 585-1917. email: wennberg@gps.caltech.edu PLATFORM: NASA DC-8 airborne laboratory. LOCATION: Aircraft location data in file TN_20070808.DC8. ASSOCIATED_DATA: N/A INSTRUMENT_INFO: Chemical Ionization Mass Spectrometer. Direct measurements in ambient air. DATA_INFO: Measurements are reported as 1.0 sec averages and in units of pptv. CAUTION: Do not extrapolate data outside of given time interval as these are discrete measurements. Calibration was conducted ~once per hour during the flight using MHP obtained from a diffusion vial of hydrogen peroxide held at constant temperature. Absolute calibration is currently estimated and will be confirmed after the conclusion of the mission. Zeros were conducted ~3 times per hour by passing ambient air through a filter containing alumina coated with Pd and nylon wool coated with NaHCO3. Sensitivity, and thus uncertainty, varies significantly with ambient [H2O]. UNCERTAINTY: +-(80% of measurement value + 150 pptv) ULOD_FLAG: 7777777 ULOD_VALUE: N/A LLOD_FLAG: 8888888 LLOD_VALUE: N/A; N/A; N/A; DM_CONTACT_INFO: John Crounse. California Institute of Technology. Department of Chemistry and Chemical Engineering. MC 150-21. 1200 E. California Blvd. Pasadena, CA 91125. Phone: (626) 395-6868. Fax: (626) 585-1917. email: crounjd@caltech.edu. PROJECT_INFO: TC4 study; 13 July-13 August 2007; Study of cloud processing and tropical convection processes STIPULATIONS_ON_USE: Use of these data requires PI notification and adherence to the TC4 data protocol. OTHER_COMMENTS: N/A REVISION: R1 R1: ULOD and LLOD flags changed to positive values, to conform to Ames format 2.1 specifications. R0: Preliminary Data Revision 0. Water correction has been applied using CIT-CIMS water. Reduction code T.A.A. start_UTC stop_UTC mid_UTC MHP 43411.11 43412.11 43411.61 1694.7 44135.63 44136.63 44136.13 895.7 44146.33 44147.33 44146.83 1320.6 44194.80 44195.80 44195.30 919.0 44205.89 44206.89 44206.39 1023.1 44252.92 44253.92 44253.42 873.6 44263.81 44264.81 44264.31 558.8 44312.24 44313.24 44312.74 974.1 44323.49 44324.49 44323.99 925.8 44370.53 44371.53 44371.03 887.8 44381.47 44382.47 44381.97 660.3 44428.52 44429.52 44429.02 426.2 44439.22 44440.22 44439.72 366.4 44486.48 44487.48 44486.98 438.0 44497.04 44498.04 44497.54 334.0 44544.58 44545.58 44545.08 402.3 44555.53 44556.53 44556.03 449.4 44602.56 44603.56 44603.06 187.0 44613.11 44614.11 44613.61 150.8 44867.65 44868.65 44868.15 365.7 44878.39 44879.39 44878.89 361.8 44925.74 44926.74 44926.24 350.7 44936.47 44937.47 44936.97 469.0 44983.52 44984.52 44984.02 187.5 44994.41 44995.41 44994.91 117.9 45042.21 45043.21 45042.71 143.9 45052.93 45053.93 45053.43 113.1 45099.96 45100.96 45100.46 198.2 45110.90 45111.90 45111.40 198.9 45158.80 45159.80 45159.30 354.9 45169.33 45170.33 45169.83 357.7 45216.53 45217.53 45217.03 448.9 45227.09 45228.09 45227.59 596.5 45274.15 45275.15 45274.65 418.2 45285.04 45286.04 45285.54 544.4 45332.49 45333.49 45332.99 421.1 45343.05 45344.05 45343.55 539.9 45390.43 45391.43 45390.93 545.8 45400.97 45401.97 45401.47 526.7 45448.20 45449.20 45448.70 495.0 45458.78 45459.78 45459.28 570.3 45506.55 45507.55 45507.05 460.3 45517.11 45518.11 45517.61 464.4 45564.33 45565.33 45564.83 506.0 45575.41 45576.41 45575.91 640.7 46309.74 46310.74 46310.24 580.1 46320.68 46321.68 46321.18 698.3 46368.09 46369.09 46368.59 709.9 46379.00 46380.00 46379.50 715.9 46426.21 46427.21 46426.71 596.0 46437.30 46438.30 46437.80 847.2 46484.34 46485.34 46484.84 776.5 46494.87 46495.87 46495.37 821.6 46542.10 46543.10 46542.60 642.3 46552.84 46553.84 46553.34 426.7 46600.06 46601.06 46600.56 650.0 46610.77 46611.77 46611.27 715.8 46658.19 46659.19 46658.69 669.8 46668.73 46669.73 46669.23 517.3 46716.16 46717.16 46716.66 690.4 46726.72 46727.72 46727.22 566.8 47249.62 47250.62 47250.12 838.5 47260.17 47261.17 47260.67 845.3 47307.92 47308.92 47308.42 536.0 47318.47 47319.47 47318.97 630.8 47365.64 47366.64 47366.14 478.4 47376.37 47377.37 47376.87 638.8 47423.75 47424.75 47424.25 626.6 47434.28 47435.28 47434.78 510.3 47481.86 47482.86 47482.36 583.2 47492.75 47493.75 47493.25 680.3 47539.83 47540.83 47540.33 537.1 47550.39 47551.39 47550.89 603.1 47597.97 47598.97 47598.47 621.8 47608.70 47609.70 47609.20 661.4 47655.99 47656.99 47656.49 723.7 47666.63 47667.63 47667.13 846.1 47713.86 47714.86 47714.36 671.9 47724.42 47725.42 47724.92 733.7 47976.82 47977.82 47977.32 534.5 47987.74 47988.74 47988.24 613.3 48034.92 48035.92 48035.42 641.4 48045.65 48046.65 48046.15 556.2 48093.03 48094.03 48093.53 545.5 48103.55 48104.55 48104.05 696.9 48150.78 48151.78 48151.28 594.8 48161.52 48162.52 48162.02 460.8 48208.73 48209.73 48209.23 627.8 48219.26 48220.26 48219.76 528.8 48266.68 48267.68 48267.18 521.8 48277.24 48278.24 48277.74 599.3 48324.46 48325.46 48324.96 582.2 48335.38 48336.38 48335.88 672.2 48382.61 48383.61 48383.11 604.2 48393.15 48394.15 48393.65 559.0 48440.18 48441.18 48440.68 500.4 48450.91 48451.91 48451.41 557.3 48497.95 48498.95 48498.45 516.1 48508.68 48509.68 48509.18 518.1 48555.73 48556.73 48556.23 323.6 48566.46 48567.46 48566.96 311.4 48614.06 48615.06 48614.56 405.3 48624.78 48625.78 48625.28 568.1 48671.80 48672.80 48672.30 534.1 48682.71 48683.71 48683.21 421.4 48936.62 48937.62 48937.12 469.9 48947.16 48948.16 48947.66 523.2 48994.57 48995.57 48995.07 649.3 49005.87 49006.87 49006.37 570.1 49053.26 49054.26 49053.76 564.5 49063.97 49064.97 49064.47 498.0 49112.28 49113.28 49112.78 557.7 49123.20 49124.20 49123.70 702.8 49170.20 49171.20 49170.70 618.6 49181.10 49182.10 49181.60 846.4 49228.71 49229.71 49229.21 576.6 49239.26 49240.26 49239.76 546.6 49286.80 49287.80 49287.30 683.1 49297.36 49298.36 49297.86 771.1 49344.92 49345.92 49345.42 610.7 49355.60 49356.60 49356.10 652.1 49402.83 49403.83 49403.33 627.8 49413.91 49414.91 49414.41 658.7 49461.47 49462.47 49461.97 551.7 49472.72 49473.72 49473.22 634.0 49519.74 49520.74 49520.24 810.0 49530.64 49531.64 49531.14 565.7 49577.68 49578.68 49578.18 620.3 49588.25 49589.25 49588.75 672.1 49635.64 49636.64 49636.14 595.0 49646.18 49647.18 49646.68 706.9 49694.32 49695.32 49694.82 716.8 49705.23 49706.23 49705.73 757.1 49752.27 49753.27 49752.77 664.4 49763.00 49764.00 49763.50 495.4 49810.41 49811.41 49810.91 566.0 49821.54 49822.54 49822.04 520.9 49868.90 49869.90 49869.40 518.2 49879.66 49880.66 49880.16 642.5 49926.89 49927.89 49927.39 642.4 49937.43 49938.43 49937.93 595.5 49984.61 49985.61 49985.11 573.7 49995.36 49996.36 49995.86 585.8 50042.91 50043.91 50043.41 603.9 50053.65 50054.65 50054.15 496.1 50100.88 50101.88 50101.38 531.1 50111.42 50112.42 50111.92 600.8 50159.03 50160.03 50159.53 543.4 50169.93 50170.93 50170.43 569.1 50727.63 50728.63 50728.13 631.5 50738.17 50739.17 50738.67 691.2 50785.48 50786.48 50785.98 645.6 50796.28 50797.28 50796.78 581.8 50843.89 50844.89 50844.39 432.2 50854.60 50855.60 50855.10 539.7 50901.83 50902.83 50902.33 651.8 50912.94 50913.94 50913.44 837.7 50960.53 50961.53 50961.03 656.6 50971.80 50972.80 50972.30 704.0 51019.75 51020.75 51020.25 604.3 51030.29 51031.29 51030.79 653.3 51077.70 51078.70 51078.20 626.5 51088.44 51089.44 51088.94 652.5 51135.81 51136.81 51136.31 478.8 51146.36 51147.36 51146.86 711.6 51193.40 51194.40 51193.90 568.2 51204.51 51205.51 51205.01 427.4 51459.63 51460.63 51460.13 504.3 51470.17 51471.17 51470.67 576.7 51517.22 51518.22 51517.72 552.1 51527.95 51528.95 51528.45 531.8 51575.37 51576.37 51575.87 513.2 51586.50 51587.50 51587.00 374.3 51633.90 51634.90 51634.40 511.3 51644.82 51645.82 51645.32 642.5 51692.03 51693.03 51692.53 414.5 51702.57 51703.57 51703.07 542.6 51750.36 51751.36 51750.86 536.6 51760.91 51761.91 51761.41 564.2 51808.45 51809.45 51808.95 426.7 51819.18 51820.18 51819.68 409.4 51867.65 51868.65 51868.15 419.1 51878.56 51879.56 51879.06 393.0 51925.76 51926.76 51926.26 442.8 51936.31 51937.31 51936.81 405.3 51983.52 51984.52 51984.02 457.7 51994.25 51995.25 51994.75 419.4 52041.47 52042.47 52041.97 407.9 52052.01 52053.01 52052.51 501.8 52099.57 52100.57 52100.07 420.9 52110.14 52111.14 52110.64 453.4 52157.51 52158.51 52158.01 449.3 52168.24 52169.24 52168.74 459.2 52898.50 52899.50 52899.00 409.1 52909.02 52910.02 52909.52 372.9 52956.03 52957.03 52956.53 553.8 52966.93 52967.93 52967.43 516.1 53014.51 53015.51 53015.01 545.7 53025.24 53026.24 53025.74 554.4 53072.27 53073.27 53072.77 468.8 53082.82 53083.82 53083.32 510.4 53130.03 53131.03 53130.53 509.0 53140.58 53141.58 53141.08 508.1 53187.81 53188.81 53188.31 582.0 53198.70 53199.70 53199.20 592.8 53245.72 53246.72 53246.22 482.9 53256.26 53257.26 53256.76 582.9 53303.48 53304.48 53303.98 540.4 53314.05 53315.05 53314.55 527.9 53842.82 53843.82 53843.32 522.2 53853.53 53854.53 53854.03 566.0 53901.45 53902.45 53901.95 539.3 53912.67 53913.67 53913.17 626.8 53959.94 53960.94 53960.44 431.1 53970.68 53971.68 53971.18 510.9 54017.72 54018.72 54018.22 430.9 54028.26 54029.26 54028.76 412.5 54075.27 54076.27 54075.77 467.9 54085.99 54086.99 54086.49 505.6 54133.23 54134.23 54133.73 448.0 54143.96 54144.96 54144.46 431.8 54192.07 54193.07 54192.57 431.5 54202.81 54203.81 54203.31 520.0 54249.86 54250.86 54250.36 513.0 54260.59 54261.59 54261.09 566.8 54307.58 54308.58 54308.08 474.6 54318.29 54319.29 54318.79 453.4 54576.21 54577.21 54576.71 263.5 54586.76 54587.76 54587.26 310.7 54634.70 54635.70 54635.20 277.6 54645.95 54646.95 54646.45 262.0 54693.91 54694.91 54694.41 335.2 54704.64 54705.64 54705.14 390.7 54752.79 54753.79 54753.29 354.0 54763.87 54764.87 54764.37 360.4 54811.64 54812.64 54812.14 303.9 54822.37 54823.37 54822.87 330.5 54870.49 54871.49 54870.99 371.2 54881.20 54882.20 54881.70 400.7 54929.53 54930.53 54930.03 308.0 54940.09 54941.09 54940.59 379.0 54987.46 54988.46 54987.96 403.5 54998.00 54999.00 54998.50 305.6 55045.22 55046.22 55045.72 422.5 55055.80 55056.80 55056.30 410.6 55102.83 55103.83 55103.33 426.7 55113.91 55114.91 55114.41 336.8 55161.12 55162.12 55161.62 360.8 55171.84 55172.84 55172.34 348.1 55218.84 55219.84 55219.34 405.9 55229.56 55230.56 55230.06 404.5 55277.50 55278.50 55278.00 328.8 55288.60 55289.60 55289.10 311.5 55548.61 55549.61 55549.11 426.0 55559.13 55560.13 55559.63 562.1 55606.53 55607.53 55607.03 457.0 55617.61 55618.61 55618.11 490.2 55665.22 55666.22 55665.72 438.5 55676.13 55677.13 55676.63 488.3 55723.36 55724.36 55723.86 511.7 55734.09 55735.09 55734.59 626.7 55781.10 55782.10 55781.60 383.3 55792.02 55793.02 55792.52 433.8 55839.06 55840.06 55839.56 565.2 55849.60 55850.60 55850.10 596.6 55897.01 55898.01 55897.51 562.2 55907.57 55908.57 55908.07 645.2 55955.15 55956.15 55955.65 391.3 55966.06 55967.06 55966.56 510.9 56013.26 56014.26 56013.76 543.6 56023.99 56024.99 56024.49 584.7 56071.56 56072.56 56072.06 767.2 56082.45 56083.45 56082.95 602.2 56129.51 56130.51 56130.01 762.5 56140.59 56141.59 56141.09 902.3 56187.83 56188.83 56188.33 911.8 56198.60 56199.60 56199.10 880.5 56245.56 56246.56 56246.06 857.6 56256.09 56257.09 56256.59 732.5 56303.32 56304.32 56303.82 498.8 56314.06 56315.06 56314.56 517.1 56360.95 56361.95 56361.45 339.4 56371.84 56372.84 56372.34 704.8 56419.46 56420.46 56419.96 498.6 56430.38 56431.38 56430.88 796.8 56478.15 56479.15 56478.65 710.5 56489.06 56490.06 56489.56 578.3 56536.63 56537.63 56537.13 613.1 56547.39 56548.39 56547.89 1019.8 56594.59 56595.59 56595.09 820.6 56605.49 56606.49 56605.99 631.7 56652.55 56653.55 56653.05 656.1 56663.29 56664.29 56663.79 534.6 56710.31 56711.31 56710.81 614.9 56720.84 56721.84 56721.34 702.8 56767.84 56768.84 56768.34 676.7 56778.38 56779.38 56778.88 753.9 57317.64 57318.64 57318.14 535.7 57328.56 57329.56 57329.06 741.7 57375.81 57376.81 57376.31 963.9 57386.57 57387.57 57387.07 729.1 57433.45 57434.45 57433.95 701.0 57444.02 57445.02 57444.52 922.5 57491.60 57492.60 57492.10 1709.8 57502.36 57503.36 57502.86 1335.8 57549.73 57550.73 57550.23 1597.2 57560.63 57561.63 57561.13 769.0 57608.75 57609.75 57609.25 1162.3 57619.65 57620.65 57620.15 2152.4 57666.73 57667.73 57667.23 1616.4 57677.64 57678.64 57678.14 1696.3 57725.06 57726.06 57725.56 1195.1 57736.31 57737.31 57736.81 960.4 57783.34 57784.34 57783.84 1590.3 57794.26 57795.26 57794.76 972.6 59894.65 59895.65 59895.15 1092.2 59905.36 59906.36 59905.86 2173.3 60428.65 60429.65 60429.15 647.6 60439.56 60440.56 60440.06 755.8 60486.59 60487.59 60487.09 1185.8 60497.31 60498.31 60497.81 958.1 60544.88 60545.88 60545.38 1045.3 60555.78 60556.78 60556.28 1465.6 60602.65 60603.65 60603.15 1106.2 60613.40 60614.40 60613.90 1128.4 60660.45 60661.45 60660.95 977.7 60670.99 60671.99 60671.49 689.9 60718.92 60719.92 60719.42 699.8 60729.45 60730.45 60729.95 789.2 60776.63 60777.63 60777.13 1004.7 60787.22 60788.22 60787.72 642.2 60834.26 60835.26 60834.76 919.3 60845.18 60846.18 60845.68 672.5 60892.95 60893.95 60893.45 671.5 60903.68 60904.68 60904.18 524.6 61159.64 61160.64 61160.14 224.3 61170.53 61171.53 61171.03 240.2 61218.12 61219.12 61218.62 280.0 61228.85 61229.85 61229.35 229.3 61275.84 61276.84 61276.34 224.8 61286.38 61287.38 61286.88 287.3 61333.62 61334.62 61334.12 193.4 61344.69 61345.69 61345.19 219.0 61392.24 61393.24 61392.74 242.3 61402.95 61403.95 61403.45 234.9 61450.21 61451.21 61450.71 212.8 61461.33 61462.33 61461.83 213.1 61508.54 61509.54 61509.04 192.8 61519.27 61520.27 61519.77 96.9 61566.66 61567.66 61567.16 162.2 61577.41 61578.41 61577.91 192.0 61625.02 61626.02 61625.52 228.8 61635.77 61636.77 61636.27 280.7 61683.36 61684.36 61683.86 164.8 61694.10 61695.10 61694.60 269.7 61741.50 61742.50 61742.00 196.8 61752.45 61753.45 61752.95 164.6 61799.96 61800.96 61800.46 237.9 61810.54 61811.54 61811.04 397.0 61857.75 61858.75 61858.25 245.5 61868.31 61869.31 61868.81 196.0 62129.85 62130.85 62130.35 186.7 62140.60 62141.60 62141.10 262.2 62188.00 62189.00 62188.50 146.5 62199.07 62200.07 62199.57 152.3 62247.16 62248.16 62247.66 135.1 62258.09 62259.09 62258.59 167.5 62305.47 62306.47 62305.97 223.2 62316.21 62317.21 62316.71 136.9 62363.78 62364.78 62364.28 142.9 62374.32 62375.32 62374.82 171.9 62421.35 62422.35 62421.85 128.8 62431.91 62432.91 62432.41 169.8 62479.30 62480.30 62479.80 213.0 62490.01 62491.01 62490.51 223.9 62537.39 62538.39 62537.89 245.4 62548.27 62549.27 62548.77 244.1 62595.34 62596.34 62595.84 127.5 62606.43 62607.43 62606.93 142.2 62653.68 62654.68 62654.18 343.2 62664.61 62665.61 62665.11 366.0 62712.21 62713.21 62712.71 182.8 62722.77 62723.77 62723.27 172.5 62770.16 62771.16 62770.66 97.8 62780.92 62781.92 62781.42 137.6 62828.69 62829.69 62829.19 92.1 62839.25 62840.25 62839.75 194.5 62887.23 62888.23 62887.73 159.9 62898.11 62899.11 62898.61 201.1 62945.35 62946.35 62945.85 142.7 62956.26 62957.26 62956.76 214.5 63003.31 63004.31 63003.81 155.3 63014.02 63015.02 63014.52 118.1 63061.26 63062.26 63061.76 228.0 63072.00 63073.00 63072.50 245.3 63119.60 63120.60 63120.10 214.6 63130.68 63131.68 63131.18 299.1 63178.11 63179.11 63178.61 213.4 63189.02 63190.02 63189.52 239.6 63236.07 63237.07 63236.57 193.6 63247.37 63248.37 63247.87 236.6 63294.78 63295.78 63295.28 157.3 63305.49 63306.49 63305.99 243.6 63353.45 63354.45 63353.95 272.0 63364.18 63365.18 63364.68 221.2 63911.79 63912.79 63912.29 227.1 63922.69 63923.69 63923.19 257.2 63970.07 63971.07 63970.57 265.7 63980.97 63981.97 63981.47 195.8 64028.18 64029.18 64028.68 320.1 64039.07 64040.07 64039.57 367.7 64086.64 64087.64 64087.14 357.7 64097.50 64098.50 64098.00 282.9 64145.10 64146.10 64145.60 190.4 64155.99 64156.99 64156.49 266.7 64203.35 64204.35 64203.85 548.0 64214.67 64215.67 64215.17 372.0 64263.37 64264.37 64263.87 560.9 64274.27 64275.27 64274.77 500.5 64321.49 64322.49 64321.99 718.0 64332.43 64333.43 64332.93 672.7 64588.62 64589.62 64589.12 381.2 64599.87 64600.87 64600.37 406.7 64647.93 64648.93 64648.43 380.2 64658.82 64659.82 64659.32 374.9 64707.16 64708.16 64707.66 239.0 64718.07 64719.07 64718.57 171.8 64766.33 64767.33 64766.83 192.3 64777.23 64778.23 64777.73 215.2 64825.91 64826.91 64826.41 240.1 64837.21 64838.21 64837.71 271.7 64884.99 64885.99 64885.49 195.2 64895.53 64896.53 64896.03 253.5 64943.11 64944.11 64943.61 176.3 64953.83 64954.83 64954.33 170.0 65001.42 65002.42 65001.92 103.3 65012.69 65013.69 65013.19 148.4 65059.65 65060.65 65060.15 107.1 65107.80 65108.80 65108.30 73.3 65118.88 65119.88 65119.38 138.9 65167.44 65168.44 65167.94 58.4 65178.34 65179.34 65178.84 57.8 65227.21 65228.21 65227.71 22.3 65238.15 65239.15 65238.65 32.5 65286.49 65287.49 65286.99 79.7 65297.35 65298.35 65297.85 35.4 65345.13 65346.13 65345.63 41.4 65355.87 65356.87 65356.37 44.8 66098.03 66099.03 66098.53 90.1 66109.11 66110.11 66109.61 89.6 66157.10 66158.10 66157.60 46.3 66167.94 66168.94 66168.44 65.2 66215.16 66216.16 66215.66 62.1 66226.08 66227.08 66226.58 71.2 66274.01 66275.01 66274.51 111.5 66285.10 66286.10 66285.60 81.0 66333.03 66334.03 66333.53 149.9 66344.09 66345.09 66344.59 146.3 66391.89 66392.89 66392.39 115.9 66402.44 66403.44 66402.94 128.0 66450.19 66451.19 66450.69 288.7 66460.90 66461.90 66461.40 354.6 66508.32 66509.32 66508.82 259.3 66519.57 66520.57 66520.07 305.0 67044.63 67045.63 67045.13 2261.1 67055.17 67056.17 67055.67 2543.2 67102.89 67103.89 67103.39 3755.9 67113.62 67114.62 67114.12 2193.7 67161.33 67162.33 67161.83 4517.6 67172.26 67173.26 67172.76 4286.8 67219.87 67220.87 67220.37 5249.3 67230.78 67231.78 67231.28 8434.2 67278.01 67279.01 67278.51 4679.5 67289.11 67290.11 67289.61 5098.9 67337.07 67338.07 67337.57 7233.5 67348.17 67349.17 67348.67 2923.8 68738.64 68739.64 68739.14 5171.1 68749.37 68750.37 68749.87 5667.2 68797.13 68798.13 68797.63 3173.4 68808.24 68809.24 68808.74 1898.3 68856.37 68857.37 68856.87 2851.7 68867.48 68868.48 68867.98 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