43 1001 Wennberg, Paul California Institute of Technology Gas Phase Nitric Acid from DC-8 TC4 1 1 2007 08 08 2011 09 07 0 start_UTC, s 3 1 1 1 999999 999999 999999 stop_UTC, s mid_UTC, s HNO3, pptv 0 26 PI_CONTACT_INFO: Address: California Institute of Technology. MC 150-21. 1200 E. California Blvd, Pasadena, CA, 91125. Phone: (626) 395-2447. Fax: (626) 585-1917. email: wennberg@gps.caltech.edu PLATFORM: NASA DC-8 airborne laboratory. LOCATION: Aircraft location data in file TN_20070808.DC8. ASSOCIATED_DATA: N/A INSTRUMENT_INFO: Chemical Ionization Mass Spectrometer. Direct measurements in ambient air. DATA_INFO: Measurements are reported as 0.5 sec averages and in units of pptv. CAUTION: Do not extrapolate data outside of given time interval as these are discrete measurements. Calibration was conducted ~once per hour during the flight using isotopically labeled nitric acid evolved from a perm tube held at constant temperature. Absolute calibration was obtained by collection in water and subsequent ion chromatography. Zeros were conducted ~3 times per hour by passing ambient air through a filter containing nylon wool coated with NaHCO3. UNCERTAINTY: +-(50% of measuremlent value + 50 pptv) ULOD_FLAG: 7777777 ULOD_VALUE: N/A LLOD_FLAG: 8888888 LLOD_VALUE: N/A; N/A; N/A; DM_CONTACT_INFO: John Crounse. California Institute of Technology. Department of Chemistry and Chemical Engineering. MC 150-21. 1200 E. California Blvd. Pasadena, CA 91125. Phone: (626) 395-6868. Fax: (626) 585-1917. email: crounjd@caltech.edu. PROJECT_INFO: TC4 study; 13 July-13 August 2007; Study of cloud processing and tropical convection processes STIPULATIONS_ON_USE: Use of these data requires PI notification and adherence to the TC4 data protocol. OTHER_COMMENTS: N/A REVISION: R1 R1: ULOD and LLOD flags changed to positive values, to conform to Ames format 2.1 specifications. R0: Preliminary Data Revision 0. Water correction has been applied using CIT-CIMS water. Reduction code 1.5 start_UTC stop_UTC mid_UTC HNO3 43621.34 43621.84 43621.59 141.3 43635.34 43635.84 43635.59 129.9 43649.41 43649.91 43649.66 153.7 43663.34 43663.84 43663.59 113.8 43677.34 43677.84 43677.59 109.2 43691.34 43691.84 43691.59 106.0 43705.34 43705.84 43705.59 72.5 43719.34 43719.84 43719.59 88.2 43733.41 43733.91 43733.66 81.1 43747.34 43747.84 43747.59 85.5 43761.34 43761.84 43761.59 71.9 43775.34 43775.84 43775.59 69.7 43789.41 43789.91 43789.66 75.5 43803.34 43803.84 43803.59 70.9 43817.34 43817.84 43817.59 102.8 43831.34 43831.84 43831.59 126.6 43845.34 43845.84 43845.59 149.6 43859.28 43859.78 43859.53 149.1 43873.22 43873.72 43873.47 181.6 43887.28 43887.78 43887.53 129.9 43901.34 43901.84 43901.59 125.9 43915.34 43915.84 43915.59 135.1 43929.41 43929.91 43929.66 219.5 43943.34 43943.84 43943.59 179.3 43957.41 43957.91 43957.66 154.8 43971.28 43971.78 43971.53 159.1 43985.22 43985.72 43985.47 290.6 43999.22 43999.72 43999.47 284.8 44013.22 44013.72 44013.47 275.4 44027.22 44027.72 44027.47 296.2 44041.22 44041.72 44041.47 293.1 44055.34 44055.84 44055.59 259.9 44069.34 44069.84 44069.59 258.1 44083.22 44083.72 44083.47 217.4 44097.22 44097.72 44097.47 137.6 44111.22 44111.72 44111.47 124.4 44125.28 44125.78 44125.53 214.0 44139.22 44139.72 44139.47 168.6 44153.22 44153.72 44153.47 180.2 44167.22 44167.72 44167.47 120.0 44181.28 44181.78 44181.53 119.8 44195.28 44195.78 44195.53 175.9 44209.22 44209.72 44209.47 136.1 44223.22 44223.72 44223.47 137.5 44237.22 44237.72 44237.47 121.3 44251.28 44251.78 44251.53 120.1 44265.22 44265.72 44265.47 126.3 44279.22 44279.72 44279.47 85.2 44293.22 44293.72 44293.47 80.8 44307.28 44307.78 44307.53 34.2 44321.28 44321.78 44321.53 55.3 44335.22 44335.72 44335.47 58.2 44349.22 44349.72 44349.47 12.3 44363.28 44363.78 44363.53 13.1 44377.22 44377.72 44377.47 42.9 44391.28 44391.78 44391.53 58.6 44405.22 44405.72 44405.47 56.2 44419.22 44419.72 44419.47 69.0 44433.22 44433.72 44433.47 62.0 44447.22 44447.72 44447.47 58.2 44461.22 44461.72 44461.47 46.6 44475.22 44475.72 44475.47 30.8 44489.22 44489.72 44489.47 40.4 44503.22 44503.72 44503.47 34.4 44605.34 44605.84 44605.59 34.9 44619.41 44619.91 44619.66 46.4 44633.41 44633.91 44633.66 42.5 44647.34 44647.84 44647.59 39.9 44661.34 44661.84 44661.59 42.3 44675.34 44675.84 44675.59 78.4 44689.41 44689.91 44689.66 77.0 44703.34 44703.84 44703.59 51.6 44717.41 44717.91 44717.66 19.1 44731.22 44731.72 44731.47 4.1 44745.22 44745.72 44745.47 4.5 44759.34 44759.84 44759.59 3.2 44773.41 44773.91 44773.66 6.4 44787.34 44787.84 44787.59 6.4 44801.34 44801.84 44801.59 13.7 44815.34 44815.84 44815.59 21.3 44829.34 44829.84 44829.59 2.4 44843.22 44843.72 44843.47 7.1 44857.22 44857.72 44857.47 17.2 44871.22 44871.72 44871.47 12.4 44885.22 44885.72 44885.47 -1.5 44899.34 44899.84 44899.59 14.9 44913.41 44913.91 44913.66 11.4 44927.34 44927.84 44927.59 -0.9 44941.28 44941.78 44941.53 44.7 44955.22 44955.72 44955.47 65.3 44969.28 44969.78 44969.53 81.1 44983.22 44983.72 44983.47 64.6 44997.22 44997.72 44997.47 74.8 45011.22 45011.72 45011.47 76.5 45025.22 45025.72 45025.47 68.8 45039.28 45039.78 45039.53 56.4 45053.28 45053.78 45053.53 64.7 45067.28 45067.78 45067.53 63.6 45081.28 45081.78 45081.53 74.3 45095.22 45095.72 45095.47 57.4 45109.22 45109.72 45109.47 62.5 45123.22 45123.72 45123.47 64.6 45137.22 45137.72 45137.47 85.6 45151.22 45151.72 45151.47 56.0 45165.22 45165.72 45165.47 82.4 45179.22 45179.72 45179.47 77.0 45193.22 45193.72 45193.47 38.1 45207.22 45207.72 45207.47 39.5 45221.22 45221.72 45221.47 30.3 45235.22 45235.72 45235.47 13.6 45249.28 45249.78 45249.53 4.4 45263.22 45263.72 45263.47 26.6 45277.28 45277.78 45277.53 5.1 45291.22 45291.72 45291.47 23.7 45305.28 45305.78 45305.53 22.6 45319.22 45319.72 45319.47 34.3 45333.22 45333.72 45333.47 20.3 45347.22 45347.72 45347.47 15.0 45361.22 45361.72 45361.47 2.8 45375.22 45375.72 45375.47 10.3 45389.28 45389.78 45389.53 -3.4 45403.22 45403.72 45403.47 3.0 45417.22 45417.72 45417.47 3.1 45431.22 45431.72 45431.47 13.6 45445.28 45445.78 45445.53 19.8 45459.22 45459.72 45459.47 18.0 45473.22 45473.72 45473.47 12.2 45487.28 45487.78 45487.53 14.6 45501.22 45501.72 45501.47 15.1 45604.41 45604.91 45604.66 14.9 45618.34 45618.84 45618.59 14.2 45632.34 45632.84 45632.59 12.1 45646.34 45646.84 45646.59 14.5 45660.34 45660.84 45660.59 12.1 45674.34 45674.84 45674.59 22.7 45688.34 45688.84 45688.59 23.2 45702.22 45702.72 45702.47 14.3 45716.22 45716.72 45716.47 26.5 45730.22 45730.72 45730.47 16.4 45744.22 45744.72 45744.47 21.6 45758.34 45758.84 45758.59 41.7 45772.34 45772.84 45772.59 28.1 45786.34 45786.84 45786.59 25.4 45800.34 45800.84 45800.59 28.0 45814.28 45814.78 45814.53 24.6 45828.22 45828.72 45828.47 8.3 45842.22 45842.72 45842.47 5.3 45856.22 45856.72 45856.47 13.2 45870.22 45870.72 45870.47 9.9 45884.22 45884.72 45884.47 6.7 45898.34 45898.84 45898.59 22.4 45912.34 45912.84 45912.59 8.8 45926.22 45926.72 45926.47 11.5 45940.22 45940.72 45940.47 19.9 45954.28 45954.78 45954.53 30.8 45968.22 45968.72 45968.47 16.6 45982.22 45982.72 45982.47 23.6 45996.22 45996.72 45996.47 19.7 46024.22 46024.72 46024.47 12.8 46038.22 46038.72 46038.47 18.6 46052.22 46052.72 46052.47 10.7 46066.22 46066.72 46066.47 14.5 46080.22 46080.72 46080.47 17.4 46094.22 46094.72 46094.47 13.1 46108.22 46108.72 46108.47 23.7 46122.22 46122.72 46122.47 15.4 46136.22 46136.72 46136.47 14.0 46150.22 46150.72 46150.47 8.3 46164.22 46164.72 46164.47 13.2 46178.22 46178.72 46178.47 9.2 46192.22 46192.72 46192.47 19.1 46206.22 46206.72 46206.47 5.1 46220.22 46220.72 46220.47 8.9 46234.22 46234.72 46234.47 0.8 46248.22 46248.72 46248.47 -3.9 46262.28 46262.78 46262.53 9.5 46276.22 46276.72 46276.47 11.7 46290.28 46290.78 46290.53 8.7 46304.22 46304.72 46304.47 6.2 46318.22 46318.72 46318.47 13.9 46332.22 46332.72 46332.47 13.3 46346.22 46346.72 46346.47 10.6 46360.22 46360.72 46360.47 17.9 46374.22 46374.72 46374.47 17.4 46388.22 46388.72 46388.47 18.5 46402.28 46402.78 46402.53 4.6 46416.28 46416.78 46416.53 11.3 46430.22 46430.72 46430.47 12.1 46444.28 46444.78 46444.53 5.6 46458.22 46458.72 46458.47 6.7 46472.28 46472.78 46472.53 4.4 46486.28 46486.78 46486.53 11.6 46500.22 46500.72 46500.47 19.1 46726.59 46727.09 46726.84 -11.0 46740.66 46741.16 46740.91 4.2 46754.59 46755.09 46754.84 -0.6 46768.66 46769.16 46768.91 -0.7 46782.59 46783.09 46782.84 -0.5 46796.66 46797.16 46796.91 -1.7 46810.59 46811.09 46810.84 4.1 46824.66 46825.16 46824.91 -6.1 46838.59 46839.09 46838.84 6.4 46852.59 46853.09 46852.84 4.1 46866.59 46867.09 46866.84 2.5 46880.59 46881.09 46880.84 3.3 46894.59 46895.09 46894.84 32.3 46908.59 46909.09 46908.84 3.3 46950.59 46951.09 46950.84 -2.3 46964.59 46965.09 46964.84 12.8 46978.59 46979.09 46978.84 19.6 46992.59 46993.09 46992.84 18.2 47006.47 47006.97 47006.72 33.0 47020.59 47021.09 47020.84 10.2 47034.66 47035.16 47034.91 -2.6 47048.59 47049.09 47048.84 10.4 47062.59 47063.09 47062.84 2.3 47076.59 47077.09 47076.84 6.2 47090.59 47091.09 47090.84 2.0 47104.59 47105.09 47104.84 8.5 47118.47 47118.97 47118.72 14.5 47132.47 47132.97 47132.72 14.8 47146.47 47146.97 47146.72 -1.2 47160.47 47160.97 47160.72 4.8 47174.59 47175.09 47174.84 7.9 47216.47 47216.97 47216.72 3.5 47230.47 47230.97 47230.72 7.4 47244.53 47245.03 47244.78 -2.4 47258.53 47259.03 47258.78 -2.5 47272.47 47272.97 47272.72 2.7 47286.47 47286.97 47286.72 9.9 47300.47 47300.97 47300.72 7.2 47314.59 47315.09 47314.84 4.5 47328.53 47329.03 47328.78 4.4 47342.47 47342.97 47342.72 9.5 47356.47 47356.97 47356.72 14.2 47370.53 47371.03 47370.78 11.8 47384.53 47385.03 47384.78 8.9 47398.47 47398.97 47398.72 16.0 47412.47 47412.97 47412.72 20.9 47426.47 47426.97 47426.72 17.9 47440.47 47440.97 47440.72 18.5 47454.47 47454.97 47454.72 23.8 47468.53 47469.03 47468.78 5.9 47482.47 47482.97 47482.72 11.0 47496.47 47496.97 47496.72 13.3 47510.47 47510.97 47510.72 11.7 47524.47 47524.97 47524.72 -0.7 47538.47 47538.97 47538.72 5.2 47552.47 47552.97 47552.72 9.6 47566.47 47566.97 47566.72 8.5 47580.53 47581.03 47580.78 8.3 47594.53 47595.03 47594.78 0.6 47608.47 47608.97 47608.72 -2.8 47622.47 47622.97 47622.72 -4.3 47726.59 47727.09 47726.84 -0.4 47740.59 47741.09 47740.84 3.9 47754.59 47755.09 47754.84 5.1 47768.59 47769.09 47768.84 10.2 47782.59 47783.09 47782.84 8.4 47796.66 47797.16 47796.91 14.9 47810.59 47811.09 47810.84 12.6 47824.66 47825.16 47824.91 12.0 47838.66 47839.16 47838.91 -2.7 47852.59 47853.09 47852.84 14.8 47866.47 47866.97 47866.72 6.7 47880.66 47881.16 47880.91 2.6 47894.66 47895.16 47894.91 5.6 47908.59 47909.09 47908.84 6.8 47922.59 47923.09 47922.84 2.3 47936.59 47937.09 47936.84 4.0 47950.59 47951.09 47950.84 2.5 47964.59 47965.09 47964.84 7.8 47978.47 47978.97 47978.72 10.2 47992.47 47992.97 47992.72 5.8 48006.47 48006.97 48006.72 -3.1 48020.59 48021.09 48020.84 -3.0 48034.59 48035.09 48034.84 -3.7 48048.59 48049.09 48048.84 1.1 48062.66 48063.16 48062.91 2.2 48076.59 48077.09 48076.84 2.0 48090.53 48091.03 48090.78 4.8 48104.47 48104.97 48104.72 4.5 48118.47 48118.97 48118.72 1.8 48132.47 48132.97 48132.72 4.5 48146.47 48146.97 48146.72 2.3 48160.47 48160.97 48160.72 15.1 48174.59 48175.09 48174.84 -12.7 48188.59 48189.09 48188.84 -4.3 48202.47 48202.97 48202.72 -4.3 48216.53 48217.03 48216.78 -5.9 48230.53 48231.03 48230.78 -4.7 48244.53 48245.03 48244.78 11.0 48258.53 48259.03 48258.78 10.9 48272.47 48272.97 48272.72 -2.9 48286.47 48286.97 48286.72 -5.0 48300.47 48300.97 48300.72 7.9 48314.47 48314.97 48314.72 -0.2 48328.47 48328.97 48328.72 -5.2 48342.47 48342.97 48342.72 6.8 48356.47 48356.97 48356.72 -1.7 48370.47 48370.97 48370.72 -4.3 48384.47 48384.97 48384.72 -4.1 48398.47 48398.97 48398.72 -7.3 48412.47 48412.97 48412.72 7.5 48426.47 48426.97 48426.72 5.1 48440.47 48440.97 48440.72 -5.8 48454.47 48454.97 48454.72 7.6 48468.47 48468.97 48468.72 1.3 48482.47 48482.97 48482.72 -0.7 48496.47 48496.97 48496.72 4.4 48510.47 48510.97 48510.72 3.7 48524.47 48524.97 48524.72 -1.7 48538.47 48538.97 48538.72 7.0 48552.47 48552.97 48552.72 16.0 48566.47 48566.97 48566.72 1.2 48580.47 48580.97 48580.72 14.9 48594.53 48595.03 48594.78 10.5 48608.53 48609.03 48608.78 0.2 48622.53 48623.03 48622.78 15.8 48726.66 48727.16 48726.91 -4.9 48740.59 48741.09 48740.84 -7.4 48754.59 48755.09 48754.84 -1.6 48768.66 48769.16 48768.91 2.0 48782.66 48783.16 48782.91 -11.4 48796.59 48797.09 48796.84 9.2 48810.59 48811.09 48810.84 34.4 48824.59 48825.09 48824.84 16.4 48838.59 48839.09 48838.84 22.4 48852.47 48852.97 48852.72 28.7 48866.53 48867.03 48866.78 15.0 48880.66 48881.16 48880.91 25.9 48894.59 48895.09 48894.84 16.3 48908.66 48909.16 48908.91 13.0 48922.59 48923.09 48922.84 -2.7 48936.59 48937.09 48936.84 9.7 48950.53 48951.03 48950.78 -3.8 48964.47 48964.97 48964.72 7.6 48978.47 48978.97 48978.72 4.9 48992.47 48992.97 48992.72 -1.1 49006.47 49006.97 49006.72 12.8 49020.66 49021.16 49020.91 5.0 49034.66 49035.16 49034.91 5.6 49048.59 49049.09 49048.84 13.3 49062.47 49062.97 49062.72 22.3 49076.47 49076.97 49076.72 10.7 49090.47 49090.97 49090.72 12.3 49104.47 49104.97 49104.72 12.0 49118.53 49119.03 49118.78 7.7 49132.53 49133.03 49132.78 -6.2 49146.47 49146.97 49146.72 6.9 49160.47 49160.97 49160.72 4.1 49174.53 49175.03 49174.78 6.6 49188.47 49188.97 49188.72 14.1 49202.47 49202.97 49202.72 1.8 49216.47 49216.97 49216.72 10.8 49230.53 49231.03 49230.78 11.2 49244.47 49244.97 49244.72 12.3 49258.47 49258.97 49258.72 4.3 49272.53 49273.03 49272.78 20.3 49286.47 49286.97 49286.72 20.2 49300.53 49301.03 49300.78 0.4 49314.47 49314.97 49314.72 12.7 49328.47 49328.97 49328.72 10.3 49342.53 49343.03 49342.78 15.2 49356.47 49356.97 49356.72 5.7 49370.53 49371.03 49370.78 12.4 49384.47 49384.97 49384.72 9.4 49398.47 49398.97 49398.72 10.8 49412.47 49412.97 49412.72 13.9 49426.47 49426.97 49426.72 15.5 49440.47 49440.97 49440.72 10.4 49454.47 49454.97 49454.72 2.2 49468.47 49468.97 49468.72 9.1 49482.47 49482.97 49482.72 17.5 49496.47 49496.97 49496.72 20.8 49510.47 49510.97 49510.72 10.7 49524.47 49524.97 49524.72 16.0 49538.47 49538.97 49538.72 12.8 49552.47 49552.97 49552.72 3.7 49566.47 49566.97 49566.72 18.7 49580.47 49580.97 49580.72 19.5 49594.47 49594.97 49594.72 17.9 49608.47 49608.97 49608.72 18.6 49622.47 49622.97 49622.72 16.8 50195.41 50195.91 50195.66 14.3 50209.34 50209.84 50209.59 10.1 50223.41 50223.91 50223.66 6.6 50237.34 50237.84 50237.59 0.3 50251.22 50251.72 50251.47 -15.0 50265.28 50265.78 50265.53 1.9 50279.28 50279.78 50279.53 17.7 50293.28 50293.78 50293.53 13.4 50307.22 50307.72 50307.47 12.6 50321.22 50321.72 50321.47 14.3 50335.22 50335.72 50335.47 18.2 50349.34 50349.84 50349.59 2.3 50363.22 50363.72 50363.47 -3.4 50377.28 50377.78 50377.53 -4.1 50391.22 50391.72 50391.47 1.5 50405.22 50405.72 50405.47 -11.4 50419.28 50419.78 50419.53 -7.1 50433.22 50433.72 50433.47 2.3 50447.28 50447.78 50447.53 -0.2 50461.28 50461.78 50461.53 -3.1 50475.22 50475.72 50475.47 -18.0 50489.22 50489.72 50489.47 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50937.28 50937.78 50937.53 4.1 50951.22 50951.72 50951.47 -1.8 50965.28 50965.78 50965.53 2.6 50979.22 50979.72 50979.47 1.2 50993.22 50993.72 50993.47 -0.1 51007.22 51007.72 51007.47 0.7 51021.22 51021.72 51021.47 12.9 51035.28 51035.78 51035.53 -2.5 51049.22 51049.72 51049.47 7.4 51063.22 51063.72 51063.47 3.9 51077.22 51077.72 51077.47 5.0 51091.28 51091.78 51091.53 11.3 51195.34 51195.84 51195.59 -12.1 51209.34 51209.84 51209.59 9.0 51223.34 51223.84 51223.59 14.3 51237.34 51237.84 51237.59 -0.6 51251.41 51251.91 51251.66 8.3 51265.41 51265.91 51265.66 -7.0 51279.34 51279.84 51279.59 15.7 51293.41 51293.91 51293.66 -7.7 51307.34 51307.84 51307.59 7.1 51321.41 51321.91 51321.66 -1.9 51335.22 51335.72 51335.47 3.6 51349.34 51349.84 51349.59 -5.1 51363.34 51363.84 51363.59 2.5 51377.34 51377.84 51377.59 3.0 51391.34 51391.84 51391.59 1.1 51405.34 51405.84 51405.59 4.6 51419.34 51419.84 51419.59 0.9 51433.34 51433.84 51433.59 -3.2 51447.22 51447.72 51447.47 1.4 51461.22 51461.72 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