43 1001 Wennberg, Paul California Institute of Technology Gas Phase Peroxynitric Acid from DC-8 TC4 1 1 2007 08 06 2011 09 07 0 start_UTC, s 3 1 1 1 999999 999999 999999 stop_UTC, s mid_UTC, s PNA, pptv 0 26 PI_CONTACT_INFO: Address: California Institute of Technology. MC 150-21. 1200 E. California Blvd, Pasadena, CA, 91125. Phone: (626) 395-2447. Fax: (626) 585-1917. email: wennberg@gps.caltech.edu PLATFORM: NASA DC-8 airborne laboratory. LOCATION: Aircraft location data in file TN_20070806.DC8. ASSOCIATED_DATA: N/A INSTRUMENT_INFO: Chemical Ionization Mass Spectrometer. Direct measurements in ambient air. DATA_INFO: Measurements are reported as 0.5 sec averages and in units of pptv. CAUTION: Do not extrapolate data outside of given time interval as these are discrete measurements. Calibration was conducted ~once per hour during the flight using H2O2 and HNO3 calibrants, and proxied to PNA using laboratory calibrations. Absolute calibration was obtained in the laboratory by thermal decomposition and NO2 measurement. Zeros were conducted ~3 times per hour by passing ambient air through a filter containing nylon wool coated with NaHCO3. UNCERTAINTY: +-(100% of measuremlent value + 20 pptv) ULOD_FLAG: 7777777 ULOD_VALUE: N/A LLOD_FLAG: 8888888 LLOD_VALUE: N/A; N/A; N/A; DM_CONTACT_INFO: John Crounse. California Institute of Technology. Department of Chemistry and Chemical Engineering. MC 150-21. 1200 E. California Blvd. Pasadena, CA 91125. Phone: (626) 395-6868. Fax: (626) 585-1917. email: crounjd@caltech.edu. PROJECT_INFO: TC4 study; 13 July-13 August 2007; Study of cloud processing and tropical convection processes STIPULATIONS_ON_USE: Use of these data requires PI notification and adherence to the TC4 data protocol. OTHER_COMMENTS: N/A REVISION: R1 R1: ULOD and LLOD flags changed to positive values, to conform to Ames format 2.1 specifications. R0: Preliminary Data Revision 0. Water correction has been applied using CIT-CIMS water. Reduction code 1.5 start_UTC stop_UTC mid_UTC PNA 42547.84 42548.34 42548.09 -5.3 42561.84 42562.34 42562.09 8.8 42575.91 42576.41 42576.16 -10.8 42589.84 42590.34 42590.09 15.3 42603.91 42604.41 42604.16 4.5 42617.84 42618.34 42618.09 4.6 42631.72 42632.22 42631.97 5.1 42645.72 42646.22 42645.97 -6.2 42659.72 42660.22 42659.97 -0.1 42673.78 42674.28 42674.03 3.1 42687.84 42688.34 42688.09 12.3 42701.91 42702.41 42702.16 -15.3 42715.91 42716.41 42716.16 -0.1 42729.84 42730.34 42730.09 11.2 42743.72 42744.22 42743.97 30.6 42757.72 42758.22 42757.97 32.7 42771.72 42772.22 42771.97 -12.6 42785.72 42786.22 42785.97 -13.1 42799.72 42800.22 42799.97 5.6 42813.72 42814.22 42813.97 78.3 42827.84 42828.34 42828.09 9.8 42841.72 42842.22 42841.97 -1.6 42855.72 42856.22 42855.97 5.0 42869.72 42870.22 42869.97 -1.0 42883.72 42884.22 42883.97 -10.7 42897.72 42898.22 42897.97 9.6 42911.72 42912.22 42911.97 -11.9 42925.72 42926.22 42925.97 -14.6 42939.78 42940.28 42940.03 22.1 42953.72 42954.22 42953.97 -2.7 42967.78 42968.28 42968.03 -10.9 42981.78 42982.28 42982.03 7.1 43009.72 43010.22 43009.97 5.3 43023.78 43024.28 43024.03 -10.4 43037.72 43038.22 43037.97 34.1 43051.78 43052.28 43052.03 1.7 43065.72 43066.22 43065.97 24.8 43079.72 43080.22 43079.97 19.0 43093.78 43094.28 43094.03 36.9 43107.72 43108.22 43107.97 6.2 43121.78 43122.28 43122.03 31.1 43135.72 43136.22 43135.97 0.7 43149.78 43150.28 43150.03 2.6 43163.72 43164.22 43163.97 7.0 43177.78 43178.28 43178.03 6.3 43191.72 43192.22 43191.97 35.1 43205.72 43206.22 43205.97 -10.6 43219.72 43220.22 43219.97 3.3 43233.72 43234.22 43233.97 7.7 43247.72 43248.22 43247.97 0.1 43261.72 43262.22 43261.97 10.4 43275.72 43276.22 43275.97 14.1 43289.72 43290.22 43289.97 -4.4 43303.72 43304.22 43303.97 -3.0 43317.72 43318.22 43317.97 8.9 43331.72 43332.22 43331.97 0.9 43345.72 43346.22 43345.97 2.2 43359.78 43360.28 43360.03 -5.9 43373.72 43374.22 43373.97 -2.7 43387.72 43388.22 43387.97 11.8 43401.72 43402.22 43401.97 27.4 43415.78 43416.28 43416.03 15.5 43429.72 43430.22 43429.97 28.1 43529.91 43530.41 43530.16 12.7 43543.84 43544.34 43544.09 70.2 43557.84 43558.34 43558.09 -3.7 43571.84 43572.34 43572.09 0.1 43585.84 43586.34 43586.09 60.6 43599.72 43600.22 43599.97 88.0 43613.72 43614.22 43613.97 25.2 43627.72 43628.22 43627.97 94.5 43641.72 43642.22 43641.97 14.7 43655.78 43656.28 43656.03 0.4 43669.72 43670.22 43669.97 0.5 43683.84 43684.34 43684.09 -10.9 43697.91 43698.41 43698.16 -0.2 43725.72 43726.22 43725.97 30.3 43739.72 43740.22 43739.97 -15.4 43753.72 43754.22 43753.97 6.8 43767.72 43768.22 43767.97 11.5 43781.72 43782.22 43781.97 18.6 43795.72 43796.22 43795.97 -8.9 43809.72 43810.22 43809.97 23.2 43823.72 43824.22 43823.97 -10.3 43837.72 43838.22 43837.97 20.8 43851.72 43852.22 43851.97 0.1 43865.72 43866.22 43865.97 -4.5 43879.72 43880.22 43879.97 -0.7 43893.78 43894.28 43894.03 0.4 43907.78 43908.28 43908.03 0.8 43921.72 43922.22 43921.97 -1.5 43935.72 43936.22 43935.97 -8.9 43949.72 43950.22 43949.97 4.3 43963.78 43964.28 43964.03 -9.1 43977.78 43978.28 43978.03 -6.5 43991.72 43992.22 43991.97 8.1 44005.72 44006.22 44005.97 1.9 44019.72 44020.22 44019.97 -3.0 44033.72 44034.22 44033.97 -1.3 44047.72 44048.22 44047.97 -1.7 44061.78 44062.28 44062.03 6.7 44075.72 44076.22 44075.97 7.7 44089.78 44090.28 44090.03 1.6 44103.72 44104.22 44103.97 23.3 44117.72 44118.22 44117.97 16.3 44131.72 44132.22 44131.97 -4.2 44145.78 44146.28 44146.03 8.7 44159.72 44160.22 44159.97 26.9 44173.72 44174.22 44173.97 18.2 44187.72 44188.22 44187.97 24.5 44201.72 44202.22 44201.97 -4.4 44215.72 44216.22 44215.97 1.5 44248.72 44249.22 44248.97 -12.1 44262.78 44263.28 44263.03 -1.1 44276.72 44277.22 44276.97 20.7 44290.72 44291.22 44290.97 25.0 44304.72 44305.22 44304.97 22.0 44318.78 44319.28 44319.03 -2.6 44332.72 44333.22 44332.97 21.3 44346.78 44347.28 44347.03 21.9 44360.72 44361.22 44360.97 7.8 44374.72 44375.22 44374.97 82.5 44388.72 44389.22 44388.97 45.0 44402.72 44403.22 44402.97 126.9 44416.72 44417.22 44416.97 137.9 44514.84 44515.34 44515.09 -18.5 44528.84 44529.34 44529.09 10.2 44542.84 44543.34 44543.09 127.8 44556.84 44557.34 44557.09 5.6 44570.91 44571.41 44571.16 155.0 44584.72 44585.22 44584.97 54.4 44598.72 44599.22 44598.97 76.4 44612.72 44613.22 44612.97 75.7 44626.72 44627.22 44626.97 55.0 44640.78 44641.28 44641.03 27.5 44654.72 44655.22 44654.97 1.3 44668.84 44669.34 44669.09 131.2 44682.72 44683.22 44682.97 55.3 44696.72 44697.22 44696.97 60.3 44710.72 44711.22 44710.97 22.7 44724.72 44725.22 44724.97 40.4 44738.72 44739.22 44738.97 -8.4 44752.78 44753.28 44753.03 -0.2 44766.72 44767.22 44766.97 29.2 44780.78 44781.28 44781.03 15.2 44794.78 44795.28 44795.03 1.8 44808.72 44809.22 44808.97 19.0 44822.72 44823.22 44822.97 11.1 44850.78 44851.28 44851.03 -5.3 44864.78 44865.28 44865.03 -8.9 44878.72 44879.22 44878.97 4.9 44892.72 44893.22 44892.97 32.0 44906.72 44907.22 44906.97 6.6 44920.72 44921.22 44920.97 20.3 44934.78 44935.28 44935.03 6.6 44948.72 44949.22 44948.97 -10.2 44962.72 44963.22 44962.97 4.0 44976.72 44977.22 44976.97 7.4 44990.72 44991.22 44990.97 -8.5 45004.72 45005.22 45004.97 2.5 45018.72 45019.22 45018.97 18.9 45032.72 45033.22 45032.97 -9.7 45046.78 45047.28 45047.03 50.1 45060.78 45061.28 45061.03 13.8 45074.72 45075.22 45074.97 46.7 45088.72 45089.22 45088.97 65.3 45102.72 45103.22 45102.97 30.7 45116.72 45117.22 45116.97 37.9 45130.78 45131.28 45131.03 99.5 45144.72 45145.22 45144.97 82.4 45158.72 45159.22 45158.97 30.5 45172.78 45173.28 45173.03 47.7 45186.72 45187.22 45186.97 48.5 45200.72 45201.22 45200.97 59.5 45214.72 45215.22 45214.97 70.6 45228.78 45229.28 45229.03 70.5 45242.72 45243.22 45242.97 41.3 45256.72 45257.22 45256.97 63.3 45270.72 45271.22 45270.97 48.3 45284.72 45285.22 45284.97 74.2 45313.16 45313.66 45313.41 9.9 45341.09 45341.59 45341.34 13.8 45355.09 45355.59 45355.34 41.5 45369.09 45369.59 45369.34 9.5 45383.09 45383.59 45383.34 30.5 45397.09 45397.59 45397.34 33.1 45411.09 45411.59 45411.34 23.3 45635.84 45636.34 45636.09 2.8 45649.84 45650.34 45650.09 5.2 45663.84 45664.34 45664.09 1.2 45677.84 45678.34 45678.09 11.3 45691.91 45692.41 45692.16 20.4 45705.84 45706.34 45706.09 3.6 45719.91 45720.41 45720.16 9.9 45733.84 45734.34 45734.09 6.1 45747.84 45748.34 45748.09 13.1 45761.72 45762.22 45761.97 11.6 45775.78 45776.28 45776.03 6.4 45789.91 45790.41 45790.16 16.9 45803.84 45804.34 45804.09 18.2 45817.84 45818.34 45818.09 19.5 45831.84 45832.34 45832.09 21.2 45845.84 45846.34 45846.09 5.2 45859.91 45860.41 45860.16 26.3 45873.78 45874.28 45874.03 31.5 45887.72 45888.22 45887.97 24.8 45901.72 45902.22 45901.97 33.1 45915.72 45916.22 45915.97 19.9 45929.84 45930.34 45930.09 17.1 45943.91 45944.41 45944.16 8.6 45957.84 45958.34 45958.09 22.0 45971.91 45972.41 45972.16 19.5 45985.72 45986.22 45985.97 7.9 45999.72 46000.22 45999.97 2.4 46013.72 46014.22 46013.97 -6.2 46027.72 46028.22 46027.97 3.2 46041.72 46042.22 46041.97 -3.8 46055.72 46056.22 46055.97 -0.3 46069.84 46070.34 46070.09 -2.9 46083.78 46084.28 46084.03 1.2 46111.78 46112.28 46112.03 -2.3 46125.72 46126.22 46125.97 -0.6 46139.72 46140.22 46139.97 -0.1 46153.78 46154.28 46154.03 15.4 46167.72 46168.22 46167.97 3.2 46181.72 46182.22 46181.97 12.0 46195.72 46196.22 46195.97 3.6 46209.78 46210.28 46210.03 12.4 46223.72 46224.22 46223.97 9.2 46237.78 46238.28 46238.03 -1.0 46251.72 46252.22 46251.97 0.4 46265.72 46266.22 46265.97 14.4 46279.78 46280.28 46280.03 29.4 46293.72 46294.22 46293.97 22.9 46307.72 46308.22 46307.97 40.2 46321.78 46322.28 46322.03 14.0 46335.72 46336.22 46335.97 28.8 46349.72 46350.22 46349.97 28.4 46363.72 46364.22 46363.97 31.3 46377.78 46378.28 46378.03 19.9 46391.72 46392.22 46391.97 20.8 46405.72 46406.22 46405.97 25.4 46419.72 46420.22 46419.97 20.1 46433.72 46434.22 46433.97 29.6 46447.78 46448.28 46448.03 8.3 46461.72 46462.22 46461.97 19.8 46475.72 46476.22 46475.97 22.9 46489.72 46490.22 46489.97 27.3 46503.72 46504.22 46503.97 26.5 46517.72 46518.22 46517.97 32.6 46531.72 46532.22 46531.97 38.7 46635.84 46636.34 46636.09 36.7 46649.84 46650.34 46650.09 38.7 46663.84 46664.34 46664.09 17.4 46677.84 46678.34 46678.09 29.9 46691.84 46692.34 46692.09 23.5 46705.84 46706.34 46706.09 11.9 46719.84 46720.34 46720.09 21.2 46733.72 46734.22 46733.97 8.3 46747.72 46748.22 46747.97 8.2 46761.72 46762.22 46761.97 10.6 46775.72 46776.22 46775.97 15.6 46789.84 46790.34 46790.09 11.6 46803.84 46804.34 46804.09 22.2 46817.84 46818.34 46818.09 27.0 46845.72 46846.22 46845.97 19.9 46859.72 46860.22 46859.97 21.7 46873.72 46874.22 46873.97 23.7 46887.78 46888.28 46888.03 16.0 46901.72 46902.22 46901.97 9.3 46915.72 46916.22 46915.97 11.3 46929.91 46930.41 46930.16 16.6 46943.84 46944.34 46944.09 7.7 46957.72 46958.22 46957.97 18.3 46971.72 46972.22 46971.97 16.5 46985.72 46986.22 46985.97 13.4 46999.72 47000.22 46999.97 13.0 47013.72 47014.22 47013.97 14.8 47027.72 47028.22 47027.97 12.8 47041.78 47042.28 47042.03 15.8 47055.78 47056.28 47056.03 38.2 47069.72 47070.22 47069.97 27.5 47083.72 47084.22 47083.97 26.1 47097.72 47098.22 47097.97 21.0 47111.72 47112.22 47111.97 8.9 47125.72 47126.22 47125.97 16.1 47139.72 47140.22 47139.97 17.3 47153.72 47154.22 47153.97 19.7 47167.72 47168.22 47167.97 13.7 47181.72 47182.22 47181.97 23.2 47195.72 47196.22 47195.97 7.7 47209.78 47210.28 47210.03 12.6 47223.72 47224.22 47223.97 13.3 47237.72 47238.22 47237.97 19.3 47251.72 47252.22 47251.97 12.9 47265.72 47266.22 47265.97 8.4 47279.72 47280.22 47279.97 16.9 47293.78 47294.28 47294.03 6.1 47307.72 47308.22 47307.97 10.3 47321.72 47322.22 47321.97 -0.6 47335.72 47336.22 47335.97 24.0 47349.78 47350.28 47350.03 6.5 47363.72 47364.22 47363.97 12.0 47377.72 47378.22 47377.97 12.8 47391.72 47392.22 47391.97 20.4 47405.72 47406.22 47405.97 15.7 47419.72 47420.22 47419.97 5.6 47433.72 47434.22 47433.97 6.9 47447.78 47448.28 47448.03 -0.1 47461.72 47462.22 47461.97 8.3 47475.72 47476.22 47475.97 4.8 47489.78 47490.28 47490.03 8.3 47503.72 47504.22 47503.97 -0.1 47517.72 47518.22 47517.97 11.6 47531.72 47532.22 47531.97 8.2 47635.84 47636.34 47636.09 -3.2 47649.84 47650.34 47650.09 2.0 47663.84 47664.34 47664.09 8.7 47677.84 47678.34 47678.09 6.7 47691.84 47692.34 47692.09 7.7 47705.72 47706.22 47705.97 6.0 47719.72 47720.22 47719.97 2.1 47733.72 47734.22 47733.97 7.6 47747.72 47748.22 47747.97 3.4 47761.72 47762.22 47761.97 8.6 47775.78 47776.28 47776.03 -5.1 47789.84 47790.34 47790.09 0.6 47803.84 47804.34 47804.09 5.3 47817.72 47818.22 47817.97 9.3 47831.72 47832.22 47831.97 -1.5 47845.78 47846.28 47846.03 5.8 47859.72 47860.22 47859.97 -1.2 47873.72 47874.22 47873.97 -2.1 47887.78 47888.28 47888.03 -0.9 47901.78 47902.28 47902.03 6.5 47915.72 47916.22 47915.97 6.1 47929.72 47930.22 47929.97 3.6 47943.72 47944.22 47943.97 -0.5 47957.72 47958.22 47957.97 -3.5 47971.72 47972.22 47971.97 9.0 47985.72 47986.22 47985.97 4.2 47999.78 48000.28 48000.03 9.8 48013.72 48014.22 48013.97 3.3 48027.72 48028.22 48027.97 12.3 48041.72 48042.22 48041.97 11.1 48055.72 48056.22 48055.97 3.4 48069.72 48070.22 48069.97 -2.8 48083.72 48084.22 48083.97 10.6 48097.72 48098.22 48097.97 5.8 48111.78 48112.28 48112.03 10.3 48125.78 48126.28 48126.03 -0.8 48139.72 48140.22 48139.97 -0.6 48153.72 48154.22 48153.97 3.9 48167.72 48168.22 48167.97 6.3 48181.72 48182.22 48181.97 7.2 48195.72 48196.22 48195.97 2.2 48209.72 48210.22 48209.97 10.4 48223.78 48224.28 48224.03 8.8 48237.72 48238.22 48237.97 8.1 48251.78 48252.28 48252.03 10.9 48265.72 48266.22 48265.97 3.0 48279.78 48280.28 48280.03 -1.6 48293.72 48294.22 48293.97 8.7 48307.72 48308.22 48307.97 -0.3 48321.72 48322.22 48321.97 7.4 48335.72 48336.22 48335.97 12.5 48349.72 48350.22 48349.97 5.0 48363.72 48364.22 48363.97 9.2 48377.72 48378.22 48377.97 10.7 48391.72 48392.22 48391.97 17.8 48405.78 48406.28 48406.03 3.2 48419.72 48420.22 48419.97 8.1 48433.72 48434.22 48433.97 1.8 48447.72 48448.22 48447.97 8.9 48461.78 48462.28 48462.03 0.6 48475.78 48476.28 48476.03 3.6 48489.72 48490.22 48489.97 3.6 48503.78 48504.28 48504.03 10.1 48517.72 48518.22 48517.97 10.8 48531.72 48532.22 48531.97 5.8 49105.91 49106.41 49106.16 13.6 49119.84 49120.34 49120.09 8.8 49133.84 49134.34 49134.09 9.6 49147.91 49148.41 49148.16 11.5 49161.91 49162.41 49162.16 0.9 49175.84 49176.34 49176.09 6.5 49189.91 49190.41 49190.16 5.0 49203.84 49204.34 49204.09 9.1 49217.78 49218.28 49218.03 14.4 49231.72 49232.22 49231.97 9.1 49245.72 49246.22 49245.97 11.0 49259.84 49260.34 49260.09 11.2 49273.84 49274.34 49274.09 15.9 49287.84 49288.34 49288.09 7.4 49301.84 49302.34 49302.09 11.6 49315.84 49316.34 49316.09 12.8 49329.78 49330.28 49330.03 12.1 49343.72 49344.22 49343.97 12.2 49357.78 49358.28 49358.03 2.0 49371.72 49372.22 49371.97 2.6 49385.72 49386.22 49385.97 6.9 49399.84 49400.34 49400.09 10.5 49413.84 49414.34 49414.09 7.6 49427.84 49428.34 49428.09 10.6 49441.72 49442.22 49441.97 15.9 49455.78 49456.28 49456.03 11.0 49469.72 49470.22 49469.97 0.7 49483.72 49484.22 49483.97 10.7 49497.78 49498.28 49498.03 17.7 49511.78 49512.28 49512.03 9.0 49525.72 49526.22 49525.97 9.1 49539.84 49540.34 49540.09 11.8 49553.72 49554.22 49553.97 14.4 49567.72 49568.22 49567.97 16.4 49581.72 49582.22 49581.97 8.5 49595.72 49596.22 49595.97 8.1 49609.72 49610.22 49609.97 12.4 49623.72 49624.22 49623.97 13.1 49637.72 49638.22 49637.97 9.9 49651.72 49652.22 49651.97 14.0 49665.78 49666.28 49666.03 5.4 49679.72 49680.22 49679.97 12.6 49693.72 49694.22 49693.97 4.6 49707.72 49708.22 49707.97 3.7 49721.72 49722.22 49721.97 12.2 49735.78 49736.28 49736.03 9.8 49749.78 49750.28 49750.03 14.9 49763.72 49764.22 49763.97 5.6 49777.78 49778.28 49778.03 21.6 49791.72 49792.22 49791.97 9.9 49805.72 49806.22 49805.97 8.5 49819.72 49820.22 49819.97 18.0 49833.78 49834.28 49834.03 13.0 49847.72 49848.22 49847.97 14.2 49861.72 49862.22 49861.97 11.3 49875.72 49876.22 49875.97 7.5 49889.72 49890.22 49889.97 0.9 49903.72 49904.22 49903.97 1.4 49917.72 49918.22 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