43 1001 Wennberg, Paul California Institute of Technology Gas Phase Hydrogen Peroxide from DC-8 TC4 1 1 2007 08 06 2011 09 07 0 start_UTC, s 3 1 1 1 999999 999999 999999 stop_UTC, s mid_UTC, s H2O2, pptv 0 26 PI_CONTACT_INFO: Address: California Institute of Technology. MC 150-21. 1200 E. California Blvd, Pasadena, CA, 91125. Phone: (626) 395-2447. Fax: (626) 585-1917. email: wennberg@gps.caltech.edu PLATFORM: NASA DC-8 airborne laboratory. LOCATION: Aircraft location data in file TN_20070806.DC8. ASSOCIATED_DATA: N/A INSTRUMENT_INFO: Chemical Ionization Mass Spectrometer. Direct measurements in ambient air. DATA_INFO: Measurements are reported as 0.5 sec averages and in units of pptv. CAUTION: Do not extrapolate data outside of given time interval as these are discrete measurements. Calibration was conducted ~once per hour during the flight using H2O2 obtained from vapor pressure over urea hydrogen peroxide held at constant temperature. Absolute calibration was obtained by collection in water and subsequent wet chemistry. Zeros were conducted ~3 times per hour by passing ambient air through a filter containing nylon wool coated with NaHCO3. UNCERTAINTY: +-(50% of measuremlent value + 150 pptv) ULOD_FLAG: 7777777 ULOD_VALUE: N/A LLOD_FLAG: 8888888 LLOD_VALUE: N/A; N/A; N/A; DM_CONTACT_INFO: John Crounse. California Institute of Technology. Department of Chemistry and Chemical Engineering. MC 150-21. 1200 E. California Blvd. Pasadena, CA 91125. Phone: (626) 395-6868. Fax: (626) 585-1917. email: crounjd@caltech.edu. PROJECT_INFO: TC4 study; 13 July-13 August 2007; Study of cloud processing and tropical convection processes STIPULATIONS_ON_USE: Use of these data requires PI notification and adherence to the TC4 data protocol. OTHER_COMMENTS: N/A REVISION: R1 R1: ULOD and LLOD flags changed to positive values, to conform to Ames format 2.1 specifications. R0: Preliminary Data Revision 0. Water correction has been applied using CIT-CIMS water. Reduction code 1.5 start_UTC stop_UTC mid_UTC H2O2 42535.84 42536.34 42536.09 438.9 42549.84 42550.34 42550.09 457.1 42563.84 42564.34 42564.09 332.1 42577.84 42578.34 42578.09 337.1 42591.84 42592.34 42592.09 150.5 42605.91 42606.41 42606.16 174.2 42619.91 42620.41 42620.16 111.4 42633.72 42634.22 42633.97 413.0 42647.72 42648.22 42647.97 309.5 42661.72 42662.22 42661.97 534.7 42675.84 42676.34 42676.09 232.5 42689.84 42690.34 42690.09 359.0 42703.84 42704.34 42704.09 349.1 42717.84 42718.34 42718.09 323.6 42731.78 42732.28 42732.03 308.7 42745.72 42746.22 42745.97 320.5 42759.78 42760.28 42760.03 299.3 42773.72 42774.22 42773.97 305.9 42787.72 42788.22 42787.97 352.5 42801.72 42802.22 42801.97 368.9 42815.72 42816.22 42815.97 382.2 42829.84 42830.34 42830.09 471.4 42843.72 42844.22 42843.97 415.4 42857.72 42858.22 42857.97 390.4 42871.72 42872.22 42871.97 465.1 42885.72 42886.22 42885.97 562.2 42899.72 42900.22 42899.97 502.5 42913.72 42914.22 42913.97 463.1 42927.72 42928.22 42927.97 460.3 42941.78 42942.28 42942.03 463.8 42955.72 42956.22 42955.97 524.7 42969.72 42970.22 42969.97 549.1 42983.78 42984.28 42984.03 422.7 42997.78 42998.28 42998.03 468.3 43011.72 43012.22 43011.97 468.1 43025.78 43026.28 43026.03 430.6 43039.72 43040.22 43039.97 359.1 43053.78 43054.28 43054.03 441.4 43067.78 43068.28 43068.03 351.5 43081.72 43082.22 43081.97 327.3 43095.72 43096.22 43095.97 329.9 43109.78 43110.28 43110.03 261.9 43123.72 43124.22 43123.97 311.0 43137.72 43138.22 43137.97 359.4 43151.72 43152.22 43151.97 371.2 43165.72 43166.22 43165.97 413.7 43179.78 43180.28 43180.03 411.1 43193.72 43194.22 43193.97 347.2 43207.72 43208.22 43207.97 348.0 43221.72 43222.22 43221.97 335.9 43235.72 43236.22 43235.97 272.0 43249.78 43250.28 43250.03 274.3 43263.78 43264.28 43264.03 261.2 43277.72 43278.22 43277.97 265.6 43291.72 43292.22 43291.97 252.9 43305.72 43306.22 43305.97 234.9 43319.78 43320.28 43320.03 196.6 43333.72 43334.22 43333.97 307.8 43347.72 43348.22 43347.97 152.3 43361.72 43362.22 43361.97 210.5 43375.72 43376.22 43375.97 249.7 43389.72 43390.22 43389.97 234.1 43403.72 43404.22 43403.97 230.3 43417.78 43418.28 43418.03 234.7 43431.78 43432.28 43432.03 248.7 43531.84 43532.34 43532.09 253.2 43545.84 43546.34 43546.09 303.9 43559.84 43560.34 43560.09 255.3 43573.84 43574.34 43574.09 258.5 43587.84 43588.34 43588.09 252.2 43601.72 43602.22 43601.97 263.7 43615.72 43616.22 43615.97 238.1 43629.72 43630.22 43629.97 268.3 43643.72 43644.22 43643.97 231.0 43657.72 43658.22 43657.97 285.0 43671.91 43672.41 43672.16 306.0 43685.84 43686.34 43686.09 238.1 43699.84 43700.34 43700.09 229.7 43713.72 43714.22 43713.97 230.7 43727.72 43728.22 43727.97 270.9 43741.72 43742.22 43741.97 345.2 43755.72 43756.22 43755.97 389.0 43769.78 43770.28 43770.03 349.6 43783.72 43784.22 43783.97 298.4 43797.72 43798.22 43797.97 317.1 43811.72 43812.22 43811.97 323.2 43825.72 43826.22 43825.97 344.5 43839.72 43840.22 43839.97 349.1 43853.78 43854.28 43854.03 371.5 43867.72 43868.22 43867.97 375.7 43881.78 43882.28 43882.03 249.9 43895.72 43896.22 43895.97 236.3 43909.72 43910.22 43909.97 205.3 43923.78 43924.28 43924.03 188.5 43937.78 43938.28 43938.03 262.1 43951.72 43952.22 43951.97 279.6 43965.78 43966.28 43966.03 140.0 43979.78 43980.28 43980.03 341.3 43993.72 43994.22 43993.97 316.3 44007.72 44008.22 44007.97 357.6 44021.72 44022.22 44021.97 265.2 44035.72 44036.22 44035.97 361.4 44049.72 44050.22 44049.97 337.9 44063.72 44064.22 44063.97 459.5 44077.72 44078.22 44077.97 323.5 44091.72 44092.22 44091.97 552.2 44105.78 44106.28 44106.03 680.3 44119.78 44120.28 44120.03 514.7 44133.78 44134.28 44134.03 649.4 44147.78 44148.28 44148.03 539.0 44161.72 44162.22 44161.97 453.5 44175.72 44176.22 44175.97 470.6 44189.78 44190.28 44190.03 398.9 44203.72 44204.22 44203.97 430.5 44217.72 44218.22 44217.97 347.8 44250.72 44251.22 44250.97 307.1 44264.72 44265.22 44264.97 324.8 44278.78 44279.28 44279.03 314.4 44292.72 44293.22 44292.97 302.7 44306.78 44307.28 44307.03 257.9 44320.78 44321.28 44321.03 308.6 44334.72 44335.22 44334.97 369.6 44348.72 44349.22 44348.97 352.6 44362.72 44363.22 44362.97 280.1 44376.72 44377.22 44376.97 249.7 44390.72 44391.22 44390.97 283.8 44404.72 44405.22 44404.97 335.2 44418.78 44419.28 44419.03 347.4 44516.91 44517.41 44517.16 209.8 44530.91 44531.41 44531.16 159.3 44544.84 44545.34 44545.09 268.8 44558.84 44559.34 44559.09 155.5 44572.72 44573.22 44572.97 292.2 44586.72 44587.22 44586.97 277.9 44600.72 44601.22 44600.97 276.6 44614.72 44615.22 44614.97 221.0 44628.72 44629.22 44628.97 187.2 44642.78 44643.28 44643.03 207.4 44656.91 44657.41 44657.16 178.9 44670.84 44671.34 44671.09 246.6 44684.72 44685.22 44684.97 189.5 44698.72 44699.22 44698.97 126.5 44712.72 44713.22 44712.97 191.6 44726.72 44727.22 44726.97 261.8 44740.72 44741.22 44740.97 318.3 44754.72 44755.22 44754.97 315.4 44768.72 44769.22 44768.97 389.3 44782.78 44783.28 44783.03 375.9 44796.78 44797.28 44797.03 202.2 44810.72 44811.22 44810.97 426.6 44824.72 44825.22 44824.97 321.0 44838.72 44839.22 44838.97 217.9 44852.72 44853.22 44852.97 329.7 44866.72 44867.22 44866.97 530.0 44880.72 44881.22 44880.97 520.3 44894.72 44895.22 44894.97 511.9 44908.72 44909.22 44908.97 538.5 44922.78 44923.28 44923.03 479.0 44936.72 44937.22 44936.97 447.0 44950.78 44951.28 44951.03 542.1 44964.72 44965.22 44964.97 628.1 44978.72 44979.22 44978.97 562.9 44992.78 44993.28 44993.03 762.6 45006.72 45007.22 45006.97 599.0 45020.72 45021.22 45020.97 137.7 45034.72 45035.22 45034.97 199.2 45048.72 45049.22 45048.97 265.0 45062.72 45063.22 45062.97 222.4 45076.72 45077.22 45076.97 351.0 45090.72 45091.22 45090.97 353.4 45104.72 45105.22 45104.97 276.5 45118.72 45119.22 45118.97 297.1 45132.78 45133.28 45133.03 389.6 45146.72 45147.22 45146.97 424.6 45160.72 45161.22 45160.97 583.3 45174.78 45175.28 45175.03 437.9 45188.78 45189.28 45189.03 421.0 45202.72 45203.22 45202.97 523.5 45216.72 45217.22 45216.97 506.2 45230.78 45231.28 45231.03 362.8 45244.72 45245.22 45244.97 508.7 45258.78 45259.28 45259.03 125.9 45272.72 45273.22 45272.97 276.2 45286.78 45287.28 45287.03 399.2 45308.22 45308.72 45308.47 580.1 45315.09 45315.59 45315.34 410.7 45329.09 45329.59 45329.34 484.9 45343.09 45343.59 45343.34 554.9 45357.09 45357.59 45357.34 501.6 45371.16 45371.66 45371.41 513.1 45385.16 45385.66 45385.41 528.2 45399.16 45399.66 45399.41 603.8 45413.09 45413.59 45413.34 509.9 45637.84 45638.34 45638.09 270.9 45651.84 45652.34 45652.09 222.1 45665.84 45666.34 45666.09 112.4 45679.84 45680.34 45680.09 111.1 45693.84 45694.34 45694.09 96.3 45707.84 45708.34 45708.09 98.5 45721.84 45722.34 45722.09 144.2 45735.84 45736.34 45736.09 126.3 45749.84 45750.34 45750.09 102.4 45763.72 45764.22 45763.97 92.3 45777.84 45778.34 45778.09 135.6 45791.91 45792.41 45792.16 121.5 45805.84 45806.34 45806.09 128.1 45819.91 45820.41 45820.16 148.4 45833.84 45834.34 45834.09 138.9 45847.91 45848.41 45848.16 115.9 45861.84 45862.34 45862.09 93.4 45875.72 45876.22 45875.97 121.1 45889.78 45890.28 45890.03 77.1 45903.72 45904.22 45903.97 96.6 45917.72 45918.22 45917.97 57.4 45931.91 45932.41 45932.16 83.3 45945.84 45946.34 45946.09 85.9 45959.91 45960.41 45960.16 102.9 45973.91 45974.41 45974.16 79.3 45987.72 45988.22 45987.97 82.9 46001.78 46002.28 46002.03 54.5 46015.72 46016.22 46015.97 72.6 46029.72 46030.22 46029.97 67.2 46043.72 46044.22 46043.97 39.5 46057.72 46058.22 46057.97 52.8 46071.84 46072.34 46072.09 38.9 46085.72 46086.22 46085.97 90.6 46113.72 46114.22 46113.97 83.7 46127.72 46128.22 46127.97 61.2 46141.72 46142.22 46141.97 94.3 46155.78 46156.28 46156.03 82.3 46169.78 46170.28 46170.03 51.6 46183.78 46184.28 46184.03 42.0 46197.72 46198.22 46197.97 60.4 46211.72 46212.22 46211.97 59.0 46225.72 46226.22 46225.97 27.1 46239.72 46240.22 46239.97 41.8 46253.72 46254.22 46253.97 67.2 46267.72 46268.22 46267.97 27.7 46281.72 46282.22 46281.97 44.3 46295.72 46296.22 46295.97 37.6 46309.72 46310.22 46309.97 87.2 46323.72 46324.22 46323.97 47.4 46337.72 46338.22 46337.97 49.2 46351.72 46352.22 46351.97 70.1 46365.72 46366.22 46365.97 109.2 46379.72 46380.22 46379.97 45.2 46393.72 46394.22 46393.97 41.3 46407.78 46408.28 46408.03 48.8 46421.72 46422.22 46421.97 45.7 46435.72 46436.22 46435.97 55.9 46449.72 46450.22 46449.97 33.8 46463.72 46464.22 46463.97 57.8 46477.72 46478.22 46477.97 55.3 46491.72 46492.22 46491.97 54.5 46505.78 46506.28 46506.03 50.9 46519.78 46520.28 46520.03 51.4 46533.72 46534.22 46533.97 31.3 46637.91 46638.41 46638.16 38.7 46651.91 46652.41 46652.16 54.4 46665.84 46666.34 46666.09 89.9 46679.84 46680.34 46680.09 86.0 46693.84 46694.34 46694.09 72.3 46707.84 46708.34 46708.09 67.2 46721.84 46722.34 46722.09 85.0 46735.78 46736.28 46736.03 90.2 46749.72 46750.22 46749.97 71.6 46763.72 46764.22 46763.97 57.9 46777.84 46778.34 46778.09 62.6 46791.84 46792.34 46792.09 14.3 46805.84 46806.34 46806.09 137.4 46819.84 46820.34 46820.09 123.1 46847.72 46848.22 46847.97 121.4 46861.72 46862.22 46861.97 112.9 46875.72 46876.22 46875.97 161.9 46889.78 46890.28 46890.03 137.0 46903.72 46904.22 46903.97 138.6 46917.72 46918.22 46917.97 86.4 46931.91 46932.41 46932.16 131.8 46945.84 46946.34 46946.09 123.8 46959.72 46960.22 46959.97 88.1 46973.72 46974.22 46973.97 116.9 46987.78 46988.28 46988.03 124.4 47001.72 47002.22 47001.97 94.4 47015.72 47016.22 47015.97 99.7 47029.78 47030.28 47030.03 95.8 47043.72 47044.22 47043.97 111.3 47057.78 47058.28 47058.03 141.6 47071.72 47072.22 47071.97 114.1 47085.72 47086.22 47085.97 149.3 47099.72 47100.22 47099.97 114.6 47113.72 47114.22 47113.97 116.8 47127.72 47128.22 47127.97 120.7 47141.72 47142.22 47141.97 122.5 47155.72 47156.22 47155.97 124.2 47169.78 47170.28 47170.03 125.4 47183.72 47184.22 47183.97 96.9 47197.72 47198.22 47197.97 99.4 47211.72 47212.22 47211.97 86.9 47225.72 47226.22 47225.97 101.5 47239.78 47240.28 47240.03 155.7 47253.72 47254.22 47253.97 64.9 47267.72 47268.22 47267.97 71.9 47281.72 47282.22 47281.97 84.4 47295.78 47296.28 47296.03 72.4 47309.78 47310.28 47310.03 69.6 47323.72 47324.22 47323.97 77.3 47337.72 47338.22 47337.97 77.5 47351.78 47352.28 47352.03 71.3 47365.72 47366.22 47365.97 49.1 47379.78 47380.28 47380.03 90.5 47393.72 47394.22 47393.97 54.4 47407.72 47408.22 47407.97 17.4 47421.72 47422.22 47421.97 60.7 47435.72 47436.22 47435.97 61.7 47449.78 47450.28 47450.03 69.7 47463.72 47464.22 47463.97 71.0 47477.72 47478.22 47477.97 77.8 47491.78 47492.28 47492.03 57.7 47505.72 47506.22 47505.97 66.5 47519.72 47520.22 47519.97 83.3 47533.72 47534.22 47533.97 66.0 47637.84 47638.34 47638.09 29.7 47651.84 47652.34 47652.09 9.8 47665.84 47666.34 47666.09 27.0 47679.84 47680.34 47680.09 40.0 47693.84 47694.34 47694.09 12.8 47707.72 47708.22 47707.97 4.8 47721.72 47722.22 47721.97 65.1 47735.72 47736.22 47735.97 22.0 47749.78 47750.28 47750.03 -3.5 47763.72 47764.22 47763.97 15.6 47777.91 47778.41 47778.16 -11.2 47791.84 47792.34 47792.09 19.4 47805.84 47806.34 47806.09 43.6 47819.72 47820.22 47819.97 19.1 47833.72 47834.22 47833.97 14.5 47847.78 47848.28 47848.03 -1.6 47861.72 47862.22 47861.97 13.5 47875.78 47876.28 47876.03 13.8 47889.72 47890.22 47889.97 30.9 47903.72 47904.22 47903.97 14.8 47917.78 47918.28 47918.03 21.9 47931.72 47932.22 47931.97 -0.2 47945.72 47946.22 47945.97 5.7 47959.72 47960.22 47959.97 17.8 47973.72 47974.22 47973.97 17.9 47987.72 47988.22 47987.97 16.3 48001.78 48002.28 48002.03 18.7 48015.72 48016.22 48015.97 32.6 48029.72 48030.22 48029.97 47.3 48043.72 48044.22 48043.97 -2.2 48057.72 48058.22 48057.97 48.7 48071.78 48072.28 48072.03 34.6 48085.72 48086.22 48085.97 35.1 48099.72 48100.22 48099.97 41.8 48113.78 48114.28 48114.03 -5.3 48127.72 48128.22 48127.97 25.0 48141.72 48142.22 48141.97 44.2 48155.72 48156.22 48155.97 22.1 48169.72 48170.22 48169.97 47.7 48183.72 48184.22 48183.97 20.3 48197.72 48198.22 48197.97 29.0 48211.72 48212.22 48211.97 70.8 48225.72 48226.22 48225.97 59.2 48239.72 48240.22 48239.97 40.8 48253.72 48254.22 48253.97 55.2 48267.72 48268.22 48267.97 49.2 48281.78 48282.28 48282.03 48.2 48295.72 48296.22 48295.97 80.4 48309.72 48310.22 48309.97 123.6 48323.72 48324.22 48323.97 87.9 48337.72 48338.22 48337.97 73.1 48351.78 48352.28 48352.03 79.7 48365.72 48366.22 48365.97 81.7 48379.72 48380.22 48379.97 53.2 48393.72 48394.22 48393.97 71.4 48407.72 48408.22 48407.97 75.3 48421.72 48422.22 48421.97 99.3 48435.72 48436.22 48435.97 47.7 48449.72 48450.22 48449.97 74.4 48463.72 48464.22 48463.97 60.8 48477.72 48478.22 48477.97 79.0 48491.78 48492.28 48492.03 66.5 48505.72 48506.22 48505.97 42.7 48519.72 48520.22 48519.97 75.6 48533.78 48534.28 48534.03 62.5 49205.91 49206.41 49206.16 247.3 49219.78 49220.28 49220.03 247.1 49233.72 49234.22 49233.97 218.1 49247.84 49248.34 49248.09 257.6 49261.84 49262.34 49262.09 240.7 49275.84 49276.34 49276.09 219.2 49289.84 49290.34 49290.09 270.7 49303.84 49304.34 49304.09 234.6 49317.84 49318.34 49318.09 250.1 49331.72 49332.22 49331.97 220.7 49345.72 49346.22 49345.97 207.0 49359.72 49360.22 49359.97 208.1 49373.72 49374.22 49373.97 241.1 49387.78 49388.28 49388.03 263.1 49401.84 49402.34 49402.09 270.3 49415.84 49416.34 49416.09 219.0 49429.84 49430.34 49430.09 252.3 49443.72 49444.22 49443.97 230.7 49457.72 49458.22 49457.97 273.1 49471.72 49472.22 49471.97 288.2 49485.78 49486.28 49486.03 248.1 49499.72 49500.22 49499.97 206.0 49513.72 49514.22 49513.97 243.4 49527.72 49528.22 49527.97 256.1 49541.84 49542.34 49542.09 210.9 49555.78 49556.28 49556.03 227.4 49569.78 49570.28 49570.03 199.5 49583.78 49584.28 49584.03 202.7 49597.78 49598.28 49598.03 196.9 49611.72 49612.22 49611.97 198.3 49625.72 49626.22 49625.97 203.4 49639.78 49640.28 49640.03 179.8 49653.78 49654.28 49654.03 197.6 49667.78 49668.28 49668.03 169.8 49681.72 49682.22 49681.97 200.2 49695.72 49696.22 49695.97 207.3 49709.78 49710.28 49710.03 188.2 49723.72 49724.22 49723.97 221.4 49737.72 49738.22 49737.97 185.1 49751.78 49752.28 49752.03 175.4 49765.78 49766.28 49766.03 156.9 49779.72 49780.22 49779.97 217.9 49793.72 49794.22 49793.97 172.9 49807.72 49808.22 49807.97 190.1 49821.72 49822.22 49821.97 208.8 49835.72 49836.22 49835.97 204.6 49849.72 49850.22 49849.97 211.6 49863.72 49864.22 49863.97 231.1 49877.72 49878.22 49877.97 207.8 49891.72 49892.22 49891.97 230.0 49905.72 49906.22 49905.97 230.5 49919.72 49920.22 49919.97 249.1 49933.78 49934.28 49934.03 302.9 49947.72 49948.22 49947.97 239.5 49961.72 49962.22 49961.97 250.3 49975.72 49976.22 49975.97 230.3 49989.72 49990.22 49989.97 239.3 50003.72 50004.22 50003.97 224.3 50108.84 50109.34 50109.09 75.2 50122.84 50123.34 50123.09 11.6 50136.84 50137.34 50137.09 4.6 50150.91 50151.41 50151.16 188.7 50164.91 50165.41 50165.16 151.7 50178.84 50179.34 50179.09 195.5 50192.72 50193.22 50192.97 157.0 50206.72 50207.22 50206.97 197.5 50220.72 50221.22 50220.97 145.1 50234.72 50235.22 50234.97 172.0 50248.91 50249.41 50249.16 154.9 50262.84 50263.34 50263.09 137.4 50276.84 50277.34 50277.09 130.4 50318.72 50319.22 50318.97 131.8 50332.72 50333.22 50332.97 127.4 50346.72 50347.22 50346.97 152.3 50360.72 50361.22 50360.97 136.9 50374.72 50375.22 50374.97 131.1 50388.72 50389.22 50388.97 153.1 50402.91 50403.41 50403.16 122.6 50416.72 50417.22 50416.97 127.6 50430.78 50431.28 50431.03 103.4 50444.72 50445.22 50444.97 121.9 50458.72 50459.22 50458.97 101.7 50472.72 50473.22 50472.97 127.1 50486.72 50487.22 50486.97 93.4 50500.72 50501.22 50500.97 132.8 50514.72 50515.22 50514.97 89.1 50528.78 50529.28 50529.03 94.2 50542.72 50543.22 50542.97 108.3 50556.72 50557.22 50556.97 141.1 50570.72 50571.22 50570.97 126.3 50584.72 50585.22 50584.97 83.5 50598.72 50599.22 50598.97 132.7 50612.72 50613.22 50612.97 112.3 50626.78 50627.28 50627.03 89.5 50640.78 50641.28 50641.03 118.8 50654.72 50655.22 50654.97 115.4 50668.78 50669.28 50669.03 107.0 50682.78 50683.28 50683.03 138.0 50696.72 50697.22 50696.97 99.6 50710.78 50711.28 50711.03 111.4 50724.72 50725.22 50724.97 77.8 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