43 1001 Wennberg, Paul California Institute of Technology Gas Phase Nitric Acid from DC-8 TC4 1 1 2007 08 05 2011 09 07 0 start_UTC, s 3 1 1 1 999999 999999 999999 stop_UTC, s mid_UTC, s HNO3, pptv 0 26 PI_CONTACT_INFO: Address: California Institute of Technology. MC 150-21. 1200 E. California Blvd, Pasadena, CA, 91125. Phone: (626) 395-2447. Fax: (626) 585-1917. email: wennberg@gps.caltech.edu PLATFORM: NASA DC-8 airborne laboratory. LOCATION: Aircraft location data in file TN_20070805.DC8. ASSOCIATED_DATA: N/A INSTRUMENT_INFO: Chemical Ionization Mass Spectrometer. Direct measurements in ambient air. DATA_INFO: Measurements are reported as 0.5 sec averages and in units of pptv. CAUTION: Do not extrapolate data outside of given time interval as these are discrete measurements. Calibration was conducted ~once per hour during the flight using isotopically labeled nitric acid evolved from a perm tube held at constant temperature. Absolute calibration was obtained by collection in water and subsequent ion chromatography. Zeros were conducted ~3 times per hour by passing ambient air through a filter containing nylon wool coated with NaHCO3. UNCERTAINTY: +-(50% of measuremlent value + 50 pptv) ULOD_FLAG: 7777777 ULOD_VALUE: N/A LLOD_FLAG: 8888888 LLOD_VALUE: N/A; N/A; N/A; DM_CONTACT_INFO: John Crounse. California Institute of Technology. Department of Chemistry and Chemical Engineering. MC 150-21. 1200 E. California Blvd. Pasadena, CA 91125. Phone: (626) 395-6868. Fax: (626) 585-1917. email: crounjd@caltech.edu. PROJECT_INFO: TC4 study; 13 July-13 August 2007; Study of cloud processing and tropical convection processes STIPULATIONS_ON_USE: Use of these data requires PI notification and adherence to the TC4 data protocol. OTHER_COMMENTS: N/A REVISION: R1 R1: ULOD and LLOD flags changed to positive values, to conform to Ames format 2.1 specifications. R0: Preliminary Data Revision 0. Water correction has been applied using CIT-CIMS water. Reduction code 1.5 start_UTC stop_UTC mid_UTC HNO3 46313.59 46314.09 46313.84 -15.7 46327.66 46328.16 46327.91 14.9 46341.66 46342.16 46341.91 59.3 46355.53 46356.03 46355.78 54.4 46369.53 46370.03 46369.78 31.2 46383.47 46383.97 46383.72 27.0 46397.47 46397.97 46397.72 -14.2 46411.47 46411.97 46411.72 24.5 46425.53 46426.03 46425.78 8.2 46439.47 46439.97 46439.72 16.5 46453.47 46453.97 46453.72 36.3 46467.47 46467.97 46467.72 -21.3 46495.47 46495.97 46495.72 3.4 46509.47 46509.97 46509.72 12.1 46523.47 46523.97 46523.72 -24.0 46537.47 46537.97 46537.72 8.9 46551.47 46551.97 46551.72 -32.6 46565.53 46566.03 46565.78 92.2 46579.53 46580.03 46579.78 199.5 46593.53 46594.03 46593.78 81.6 46695.34 46695.84 46695.59 318.3 46709.34 46709.84 46709.59 312.3 46723.34 46723.84 46723.59 297.2 46737.34 46737.84 46737.59 326.1 46751.34 46751.84 46751.59 333.2 46765.34 46765.84 46765.59 303.0 46779.34 46779.84 46779.59 411.2 46793.22 46793.72 46793.47 306.8 46807.28 46807.78 46807.53 215.9 46821.22 46821.72 46821.47 386.8 46835.22 46835.72 46835.47 292.4 46849.41 46849.91 46849.66 172.2 46863.34 46863.84 46863.59 120.7 46877.41 46877.91 46877.66 23.3 46891.34 46891.84 46891.59 6.4 46905.22 46905.72 46905.47 36.1 46919.22 46919.72 46919.47 -0.5 46933.22 46933.72 46933.47 20.9 46947.22 46947.72 46947.47 6.0 46961.28 46961.78 46961.53 82.2 46975.28 46975.78 46975.53 35.4 46989.34 46989.84 46989.59 81.0 47003.34 47003.84 47003.59 52.8 47017.28 47017.78 47017.53 47.7 47031.22 47031.72 47031.47 -12.9 47045.22 47045.72 47045.47 26.9 47059.22 47059.72 47059.47 35.8 47073.22 47073.72 47073.47 -18.6 47087.22 47087.72 47087.47 4.0 47101.22 47101.72 47101.47 62.2 47115.22 47115.72 47115.47 42.3 47143.22 47143.72 47143.47 23.8 47157.22 47157.72 47157.47 13.0 47171.22 47171.72 47171.47 12.3 47185.22 47185.72 47185.47 32.1 47199.28 47199.78 47199.53 24.3 47213.22 47213.72 47213.47 15.5 47227.22 47227.72 47227.47 26.1 47241.22 47241.72 47241.47 24.5 47255.22 47255.72 47255.47 17.6 47269.22 47269.72 47269.47 3.8 47283.22 47283.72 47283.47 -3.0 47297.22 47297.72 47297.47 -30.3 47311.22 47311.72 47311.47 15.4 47325.22 47325.72 47325.47 19.0 47339.22 47339.72 47339.47 -2.2 47353.22 47353.72 47353.47 -12.2 47367.22 47367.72 47367.47 8.7 47381.22 47381.72 47381.47 19.7 47395.22 47395.72 47395.47 12.1 47409.22 47409.72 47409.47 55.9 47423.28 47423.78 47423.53 73.7 47437.22 47437.72 47437.47 73.8 47451.28 47451.78 47451.53 146.0 47465.22 47465.72 47465.47 158.6 47479.28 47479.78 47479.53 49.7 47493.28 47493.78 47493.53 -17.3 47507.22 47507.72 47507.47 9.0 47521.22 47521.72 47521.47 -36.3 47535.22 47535.72 47535.47 7.8 47549.22 47549.72 47549.47 -11.4 47563.28 47563.78 47563.53 50.4 47577.22 47577.72 47577.47 31.8 47591.22 47591.72 47591.47 15.5 47816.59 47817.09 47816.84 -12.1 47858.59 47859.09 47858.84 -9.6 47872.47 47872.97 47872.72 -18.2 47886.47 47886.97 47886.72 -7.1 47900.47 47900.97 47900.72 3.5 47914.47 47914.97 47914.72 -19.1 47928.47 47928.97 47928.72 -26.6 47942.53 47943.03 47942.78 6.0 47956.47 47956.97 47956.72 -27.5 47970.66 47971.16 47970.91 -12.6 47984.47 47984.97 47984.72 -16.9 47998.47 47998.97 47998.72 -14.0 48012.53 48013.03 48012.78 -21.4 48026.47 48026.97 48026.72 -13.0 48040.47 48040.97 48040.72 -6.5 48054.47 48054.97 48054.72 -6.5 48068.47 48068.97 48068.72 -16.3 48082.47 48082.97 48082.72 14.2 48096.47 48096.97 48096.72 -12.5 48110.53 48111.03 48110.78 3.0 48124.47 48124.97 48124.72 -17.1 48138.47 48138.97 48138.72 14.5 48152.47 48152.97 48152.72 -9.5 48166.47 48166.97 48166.72 -9.5 48180.47 48180.97 48180.72 -12.5 48194.47 48194.97 48194.72 -27.8 48208.47 48208.97 48208.72 21.5 48222.47 48222.97 48222.72 -3.9 48236.47 48236.97 48236.72 -20.0 48250.47 48250.97 48250.72 -13.0 48264.47 48264.97 48264.72 -16.2 48278.47 48278.97 48278.72 2.3 48292.53 48293.03 48292.78 -6.2 48306.47 48306.97 48306.72 -23.0 48320.47 48320.97 48320.72 -35.1 48334.53 48335.03 48334.78 4.3 48348.47 48348.97 48348.72 -11.4 48362.53 48363.03 48362.78 26.9 48376.53 48377.03 48376.78 -14.1 48390.47 48390.97 48390.72 -29.6 48404.53 48405.03 48404.78 -11.6 48418.53 48419.03 48418.78 -31.9 48432.53 48433.03 48432.78 19.1 48446.47 48446.97 48446.72 -11.3 48460.47 48460.97 48460.72 -9.4 48474.47 48474.97 48474.72 5.9 48488.47 48488.97 48488.72 -3.2 48502.53 48503.03 48502.78 -27.5 48516.47 48516.97 48516.72 -22.7 48530.47 48530.97 48530.72 -0.0 48544.47 48544.97 48544.72 -4.6 48558.47 48558.97 48558.72 -9.3 48572.53 48573.03 48572.78 -15.4 48586.47 48586.97 48586.72 -3.5 48600.47 48600.97 48600.72 -3.2 48614.53 48615.03 48614.78 -12.5 48628.47 48628.97 48628.72 15.6 48642.47 48642.97 48642.72 29.6 48656.47 48656.97 48656.72 -16.7 48670.53 48671.03 48670.78 -13.8 48684.47 48684.97 48684.72 -18.8 48698.47 48698.97 48698.72 -6.6 48712.53 48713.03 48712.78 -24.0 48815.41 48815.91 48815.66 7.8 48829.34 48829.84 48829.59 16.6 48843.34 48843.84 48843.59 5.6 48857.34 48857.84 48857.59 -3.6 48871.34 48871.84 48871.59 14.1 48885.41 48885.91 48885.66 -5.4 48899.34 48899.84 48899.59 27.3 48913.34 48913.84 48913.59 33.7 48927.34 48927.84 48927.59 14.2 48941.41 48941.91 48941.66 -10.7 48955.22 48955.72 48955.47 10.1 48969.34 48969.84 48969.59 17.4 49011.34 49011.84 49011.59 43.6 49025.41 49025.91 49025.66 23.1 49039.41 49039.91 49039.66 30.2 49053.34 49053.84 49053.59 19.2 49067.22 49067.72 49067.47 3.1 49081.22 49081.72 49081.47 8.3 49095.22 49095.72 49095.47 57.1 49109.34 49109.84 49109.59 -18.0 49123.34 49123.84 49123.59 20.2 49137.34 49137.84 49137.59 27.4 49151.34 49151.84 49151.59 22.1 49165.34 49165.84 49165.59 24.3 49179.22 49179.72 49179.47 16.6 49193.22 49193.72 49193.47 25.8 49207.28 49207.78 49207.53 24.5 49221.22 49221.72 49221.47 16.8 49235.28 49235.78 49235.53 0.1 49249.22 49249.72 49249.47 39.4 49263.34 49263.84 49263.59 32.3 49277.28 49277.78 49277.53 35.3 49291.28 49291.78 49291.53 36.0 49305.28 49305.78 49305.53 23.1 49319.28 49319.78 49319.53 34.5 49333.22 49333.72 49333.47 36.3 49347.22 49347.72 49347.47 -2.6 49361.22 49361.72 49361.47 39.6 49375.22 49375.72 49375.47 32.3 49389.22 49389.72 49389.47 6.1 49403.28 49403.78 49403.53 31.4 49417.22 49417.72 49417.47 26.9 49431.22 49431.72 49431.47 28.6 49445.22 49445.72 49445.47 0.4 49459.22 49459.72 49459.47 36.8 49473.22 49473.72 49473.47 42.7 49487.28 49487.78 49487.53 34.7 49501.22 49501.72 49501.47 36.2 49515.22 49515.72 49515.47 26.3 49529.22 49529.72 49529.47 18.9 49543.28 49543.78 49543.53 31.4 49557.22 49557.72 49557.47 31.5 49571.28 49571.78 49571.53 74.5 49585.22 49585.72 49585.47 21.1 49599.22 49599.72 49599.47 51.4 49613.28 49613.78 49613.53 24.9 49627.22 49627.72 49627.47 38.6 49641.22 49641.72 49641.47 37.5 49655.22 49655.72 49655.47 45.7 49669.28 49669.78 49669.53 66.1 49683.22 49683.72 49683.47 20.3 49697.28 49697.78 49697.53 20.2 49711.22 49711.72 49711.47 39.1 49814.47 49814.97 49814.72 29.6 49828.47 49828.97 49828.72 45.9 49842.47 49842.97 49842.72 35.2 49856.53 49857.03 49856.78 14.2 49870.53 49871.03 49870.78 24.6 49884.47 49884.97 49884.72 18.0 49898.53 49899.03 49898.78 51.0 49912.53 49913.03 49912.78 36.8 49926.47 49926.97 49926.72 18.5 49940.47 49940.97 49940.72 29.7 49954.47 49954.97 49954.72 43.8 49968.53 49969.03 49968.78 19.7 49982.47 49982.97 49982.72 51.5 49996.53 49997.03 49996.78 21.2 50010.47 50010.97 50010.72 17.6 50024.47 50024.97 50024.72 18.6 50038.53 50039.03 50038.78 28.0 50052.47 50052.97 50052.72 25.5 50066.53 50067.03 50066.78 11.4 50080.53 50081.03 50080.78 48.6 50094.53 50095.03 50094.78 31.5 50108.47 50108.97 50108.72 40.8 50122.47 50122.97 50122.72 41.8 50136.47 50136.97 50136.72 17.9 50150.47 50150.97 50150.72 49.1 50164.47 50164.97 50164.72 28.2 50178.47 50178.97 50178.72 20.2 50192.53 50193.03 50192.78 11.4 50206.47 50206.97 50206.72 30.9 50220.47 50220.97 50220.72 14.7 50234.47 50234.97 50234.72 24.8 50248.53 50249.03 50248.78 12.0 50262.47 50262.97 50262.72 30.1 50276.47 50276.97 50276.72 9.2 50290.47 50290.97 50290.72 12.5 50304.47 50304.97 50304.72 42.0 50318.47 50318.97 50318.72 37.9 50332.47 50332.97 50332.72 24.9 50346.47 50346.97 50346.72 31.5 50360.53 50361.03 50360.78 -4.6 50374.47 50374.97 50374.72 13.2 50388.47 50388.97 50388.72 22.1 50402.47 50402.97 50402.72 13.9 50416.47 50416.97 50416.72 47.6 50430.47 50430.97 50430.72 16.1 50444.47 50444.97 50444.72 9.0 50458.47 50458.97 50458.72 20.1 50472.53 50473.03 50472.78 38.5 50486.47 50486.97 50486.72 18.8 50500.53 50501.03 50500.78 29.6 50514.53 50515.03 50514.78 23.8 50528.47 50528.97 50528.72 36.5 50542.47 50542.97 50542.72 23.7 50556.47 50556.97 50556.72 22.8 50570.47 50570.97 50570.72 22.8 50584.47 50584.97 50584.72 44.7 50598.53 50599.03 50598.78 7.4 50612.53 50613.03 50612.78 24.2 50626.47 50626.97 50626.72 26.0 50640.47 50640.97 50640.72 13.7 50654.47 50654.97 50654.72 35.0 50668.47 50668.97 50668.72 34.3 50682.47 50682.97 50682.72 37.4 50696.53 50697.03 50696.78 34.5 50710.47 50710.97 50710.72 37.9 51298.34 51298.84 51298.59 2.4 51312.34 51312.84 51312.59 12.2 51326.34 51326.84 51326.59 -6.9 51340.34 51340.84 51340.59 16.4 51354.34 51354.84 51354.59 10.9 51368.41 51368.91 51368.66 27.4 51382.41 51382.91 51382.66 32.5 51396.41 51396.91 51396.66 18.4 51410.34 51410.84 51410.59 9.3 51424.34 51424.84 51424.59 -10.3 51438.34 51438.84 51438.59 2.4 51452.34 51452.84 51452.59 24.5 51466.41 51466.91 51466.66 4.9 51480.34 51480.84 51480.59 17.2 51494.34 51494.84 51494.59 34.3 51508.34 51508.84 51508.59 35.5 51522.41 51522.91 51522.66 26.4 51536.34 51536.84 51536.59 21.2 51550.28 51550.78 51550.53 0.7 51564.22 51564.72 51564.47 4.1 51578.41 51578.91 51578.66 22.2 51592.34 51592.84 51592.59 16.3 51606.34 51606.84 51606.59 36.9 51620.34 51620.84 51620.59 8.9 51634.34 51634.84 51634.59 -5.5 51648.34 51648.84 51648.59 1.0 51662.28 51662.78 51662.53 12.8 51676.28 51676.78 51676.53 10.3 51690.22 51690.72 51690.47 2.3 51704.22 51704.72 51704.47 17.1 51718.28 51718.78 51718.53 11.2 51732.34 51732.84 51732.59 38.3 51746.34 51746.84 51746.59 17.1 51760.41 51760.91 51760.66 7.9 51774.22 51774.72 51774.47 36.9 51788.22 51788.72 51788.47 47.8 51802.22 51802.72 51802.47 35.4 51816.22 51816.72 51816.47 33.7 51830.22 51830.72 51830.47 5.7 51844.22 51844.72 51844.47 12.1 51858.28 51858.78 51858.53 12.2 51872.34 51872.84 51872.59 17.8 51886.22 51886.72 51886.47 21.7 51900.28 51900.78 51900.53 48.1 51914.22 51914.72 51914.47 40.3 51928.22 51928.72 51928.47 40.7 51942.28 51942.78 51942.53 44.1 51956.22 51956.72 51956.47 28.8 51970.22 51970.72 51970.47 12.7 51984.28 51984.78 51984.53 13.7 51998.22 51998.72 51998.47 32.7 52012.22 52012.72 52012.47 38.5 52026.28 52026.78 52026.53 4.2 52040.22 52040.72 52040.47 19.7 52054.22 52054.72 52054.47 3.2 52068.28 52068.78 52068.53 25.2 52082.22 52082.72 52082.47 24.4 52096.22 52096.72 52096.47 38.5 52110.28 52110.78 52110.53 46.6 52124.28 52124.78 52124.53 -0.8 52138.22 52138.72 52138.47 24.6 52152.22 52152.72 52152.47 15.5 52166.22 52166.72 52166.47 -9.7 52180.28 52180.78 52180.53 36.3 52285.34 52285.84 52285.59 15.0 52299.34 52299.84 52299.59 10.3 52313.34 52313.84 52313.59 26.0 52327.34 52327.84 52327.59 17.8 52341.41 52341.91 52341.66 22.3 52355.34 52355.84 52355.59 32.1 52369.34 52369.84 52369.59 10.6 52383.41 52383.91 52383.66 7.3 52397.34 52397.84 52397.59 56.6 52411.34 52411.84 52411.59 28.6 52425.22 52425.72 52425.47 20.6 52439.34 52439.84 52439.59 25.9 52453.34 52453.84 52453.59 32.9 52467.34 52467.84 52467.59 25.6 52481.34 52481.84 52481.59 25.4 52495.41 52495.91 52495.66 16.3 52509.34 52509.84 52509.59 3.3 52523.34 52523.84 52523.59 36.2 52537.28 52537.78 52537.53 25.1 52551.22 52551.72 52551.47 15.0 52565.22 52565.72 52565.47 34.0 52579.34 52579.84 52579.59 28.7 52593.34 52593.84 52593.59 29.8 52607.34 52607.84 52607.59 4.9 52621.34 52621.84 52621.59 26.1 52635.22 52635.72 52635.47 1.7 52649.28 52649.78 52649.53 -7.0 52663.22 52663.72 52663.47 -6.7 52677.28 52677.78 52677.53 37.7 52691.28 52691.78 52691.53 24.5 52705.22 52705.72 52705.47 25.9 52719.28 52719.78 52719.53 29.6 52733.41 52733.91 52733.66 -0.5 52747.22 52747.72 52747.47 41.1 52761.22 52761.72 52761.47 2.7 52775.22 52775.72 52775.47 8.3 52789.28 52789.78 52789.53 29.9 52803.22 52803.72 52803.47 18.2 52817.28 52817.78 52817.53 -0.7 52831.22 52831.72 52831.47 16.5 52845.28 52845.78 52845.53 30.6 52859.22 52859.72 52859.47 15.3 52873.28 52873.78 52873.53 14.6 52887.22 52887.72 52887.47 21.5 52901.22 52901.72 52901.47 39.0 52915.28 52915.78 52915.53 41.3 52929.22 52929.72 52929.47 40.0 52943.28 52943.78 52943.53 42.6 52957.22 52957.72 52957.47 47.3 52971.34 52971.84 52971.59 38.8 52985.41 52985.91 52985.66 31.9 52999.41 52999.91 52999.66 33.8 53013.34 53013.84 53013.59 35.4 53027.34 53027.84 53027.59 28.6 53041.34 53041.84 53041.59 53.2 53055.34 53055.84 53055.59 17.8 53069.34 53069.84 53069.59 33.2 53083.34 53083.84 53083.59 32.2 53097.41 53097.91 53097.66 11.7 53111.34 53111.84 53111.59 8.9 53125.34 53125.84 53125.59 39.1 53139.34 53139.84 53139.59 19.3 53153.34 53153.84 53153.59 29.0 53167.34 53167.84 53167.59 64.4 53181.34 53181.84 53181.59 48.8 53300.34 53300.84 53300.59 13.5 53314.41 53314.91 53314.66 -2.0 53328.34 53328.84 53328.59 -3.3 53342.34 53342.84 53342.59 15.3 53356.34 53356.84 53356.59 18.4 53370.41 53370.91 53370.66 0.2 53384.41 53384.91 53384.66 7.2 53398.34 53398.84 53398.59 12.1 53412.22 53412.72 53412.47 17.6 53426.22 53426.72 53426.47 2.8 53440.34 53440.84 53440.59 2.7 53454.34 53454.84 53454.59 7.9 53468.34 53468.84 53468.59 5.0 53482.34 53482.84 53482.59 20.8 53496.34 53496.84 53496.59 14.1 53510.34 53510.84 53510.59 10.9 53524.22 53524.72 53524.47 10.0 53538.22 53538.72 53538.47 1.4 53552.28 53552.78 53552.53 30.7 53566.22 53566.72 53566.47 -1.0 53580.34 53580.84 53580.59 5.0 53594.34 53594.84 53594.59 14.5 53608.34 53608.84 53608.59 -35.5 53622.28 53622.78 53622.53 18.2 53636.28 53636.78 53636.53 -23.7 53650.22 53650.72 53650.47 22.7 53664.28 53664.78 53664.53 -2.5 53678.34 53678.84 53678.59 25.5 53692.34 53692.84 53692.59 24.4 53706.41 53706.91 53706.66 45.5 53720.34 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