43 1001 Wennberg, Paul California Institute of Technology Gas Phase Peroxynitric Acid from DC-8 TC4 1 1 2007 08 03 2011 09 07 0 start_UTC, s 3 1 1 1 999999 999999 999999 stop_UTC, s mid_UTC, s PNA, pptv 0 26 PI_CONTACT_INFO: Address: California Institute of Technology. MC 150-21. 1200 E. California Blvd, Pasadena, CA, 91125. Phone: (626) 395-2447. Fax: (626) 585-1917. email: wennberg@gps.caltech.edu PLATFORM: NASA DC-8 airborne laboratory. LOCATION: Aircraft location data in file TN_20070803.DC8. ASSOCIATED_DATA: N/A INSTRUMENT_INFO: Chemical Ionization Mass Spectrometer. Direct measurements in ambient air. DATA_INFO: Measurements are reported as 0.5 sec averages and in units of pptv. CAUTION: Do not extrapolate data outside of given time interval as these are discrete measurements. Calibration was conducted ~once per hour during the flight using H2O2 and HNO3 calibrants, and proxied to PNA using laboratory calibrations. Absolute calibration was obtained in the laboratory by thermal decomposition and NO2 measurement. Zeros were conducted ~3 times per hour by passing ambient air through a filter containing nylon wool coated with NaHCO3. UNCERTAINTY: +-(100% of measuremlent value + 20 pptv) ULOD_FLAG: 7777777 ULOD_VALUE: N/A LLOD_FLAG: 8888888 LLOD_VALUE: N/A; N/A; N/A; DM_CONTACT_INFO: John Crounse. California Institute of Technology. Department of Chemistry and Chemical Engineering. MC 150-21. 1200 E. California Blvd. Pasadena, CA 91125. Phone: (626) 395-6868. Fax: (626) 585-1917. email: crounjd@caltech.edu. PROJECT_INFO: TC4 study; 13 July-13 August 2007; Study of cloud processing and tropical convection processes STIPULATIONS_ON_USE: Use of these data requires PI notification and adherence to the TC4 data protocol. OTHER_COMMENTS: N/A REVISION: R1 R1: ULOD and LLOD flags changed to positive values, to conform to Ames format 2.1 specifications. R0: Preliminary Data Revision 0. Water correction has been applied using CIT-CIMS water. Reduction code 1.5 start_UTC stop_UTC mid_UTC PNA 46387.91 46388.41 46388.16 27.7 46401.91 46402.41 46402.16 23.6 46415.91 46416.41 46416.16 23.2 46429.91 46430.41 46430.16 30.4 46443.84 46444.34 46444.09 10.3 46457.91 46458.41 46458.16 7.4 46471.84 46472.34 46472.09 26.4 46485.84 46486.34 46486.09 36.0 46499.84 46500.34 46500.09 10.2 46513.78 46514.28 46514.03 24.9 46527.84 46528.34 46528.09 15.0 46541.91 46542.41 46542.16 12.5 46555.84 46556.34 46556.09 23.2 46569.84 46570.34 46570.09 10.8 46583.84 46584.34 46584.09 1.5 46597.91 46598.41 46598.16 17.8 46611.72 46612.22 46611.97 9.2 46625.78 46626.28 46626.03 0.9 46639.78 46640.28 46640.03 -4.0 46653.72 46654.22 46653.97 10.4 46667.84 46668.34 46668.09 13.5 46681.84 46682.34 46682.09 5.8 46695.84 46696.34 46696.09 11.7 46709.91 46710.41 46710.16 1.6 46723.72 46724.22 46723.97 -11.2 46737.72 46738.22 46737.97 27.1 46751.78 46752.28 46752.03 -4.1 46765.78 46766.28 46766.03 6.0 46779.72 46780.22 46779.97 16.4 46793.72 46794.22 46793.97 9.2 46807.84 46808.34 46808.09 8.0 46821.91 46822.41 46822.16 -3.3 46835.72 46836.22 46835.97 -0.2 46849.72 46850.22 46849.97 20.5 46863.72 46864.22 46863.97 7.6 46877.72 46878.22 46877.97 0.3 46891.72 46892.22 46891.97 14.3 46905.72 46906.22 46905.97 6.2 46919.72 46920.22 46919.97 1.0 46933.72 46934.22 46933.97 18.0 46947.72 46948.22 46947.97 -5.2 46961.78 46962.28 46962.03 9.3 46975.72 46976.22 46975.97 1.7 46989.72 46990.22 46989.97 2.1 47003.72 47004.22 47003.97 13.2 47017.72 47018.22 47017.97 -2.9 47031.72 47032.22 47031.97 -1.5 47045.72 47046.22 47045.97 1.9 47059.72 47060.22 47059.97 6.0 47073.78 47074.28 47074.03 -5.8 47087.72 47088.22 47087.97 9.3 47101.78 47102.28 47102.03 -0.9 47115.72 47116.22 47115.97 11.0 47129.72 47130.22 47129.97 2.1 47143.72 47144.22 47143.97 2.0 47157.78 47158.28 47158.03 -12.3 47171.78 47172.28 47172.03 6.2 47185.78 47186.28 47186.03 -0.5 47199.72 47200.22 47199.97 9.7 47213.72 47214.22 47213.97 12.4 47227.78 47228.28 47228.03 1.8 47241.72 47242.22 47241.97 -1.3 47255.72 47256.22 47255.97 2.3 47269.72 47270.22 47269.97 13.9 47370.09 47370.59 47370.34 7.9 47384.09 47384.59 47384.34 2.5 47398.09 47398.59 47398.34 2.5 47412.09 47412.59 47412.34 4.3 47426.16 47426.66 47426.41 -11.1 47440.16 47440.66 47440.41 7.6 47454.09 47454.59 47454.34 -0.7 47468.09 47468.59 47468.34 9.3 47482.03 47482.53 47482.28 -1.4 47495.97 47496.47 47496.22 -3.0 47509.97 47510.47 47510.22 9.1 47524.09 47524.59 47524.34 17.4 47538.09 47538.59 47538.34 25.7 47552.09 47552.59 47552.34 13.2 47566.09 47566.59 47566.34 18.6 47580.09 47580.59 47580.34 -2.1 47594.03 47594.53 47594.28 29.7 47607.97 47608.47 47608.22 -3.3 47621.97 47622.47 47622.22 7.1 47635.97 47636.47 47636.22 6.3 47649.97 47650.47 47650.22 3.0 47664.09 47664.59 47664.34 11.3 47678.09 47678.59 47678.34 4.6 47692.16 47692.66 47692.41 14.7 47705.97 47706.47 47706.22 5.9 47720.03 47720.53 47720.28 -5.3 47734.03 47734.53 47734.28 0.5 47747.97 47748.47 47748.22 26.6 47761.97 47762.47 47762.22 9.5 47775.97 47776.47 47776.22 5.3 47789.97 47790.47 47790.22 16.7 47804.09 47804.59 47804.34 23.7 47818.03 47818.53 47818.28 0.5 47831.97 47832.47 47832.22 25.3 47845.97 47846.47 47846.22 1.0 47859.97 47860.47 47860.22 2.9 47906.91 47907.41 47907.16 6.8 47920.84 47921.34 47921.09 23.8 47934.84 47935.34 47935.09 1.3 47948.84 47949.34 47949.09 5.2 47962.84 47963.34 47963.09 8.9 47976.84 47977.34 47977.09 6.0 47990.91 47991.41 47991.16 -2.2 48004.84 48005.34 48005.09 11.6 48018.84 48019.34 48019.09 23.9 48032.91 48033.41 48033.16 -2.3 48046.91 48047.41 48047.16 2.7 48060.84 48061.34 48061.09 -4.1 48074.84 48075.34 48075.09 9.0 48088.84 48089.34 48089.09 7.1 48102.84 48103.34 48103.09 24.0 48116.84 48117.34 48117.09 1.1 48130.84 48131.34 48131.09 7.0 48144.84 48145.34 48145.09 8.9 48158.84 48159.34 48159.09 9.1 48172.84 48173.34 48173.09 7.5 48186.91 48187.41 48187.16 3.3 48200.91 48201.41 48201.16 14.1 48214.84 48215.34 48215.09 7.7 48228.84 48229.34 48229.09 12.0 48242.84 48243.34 48243.09 14.3 48256.84 48257.34 48257.09 16.8 48355.84 48356.34 48356.09 -5.5 48369.84 48370.34 48370.09 -6.5 48383.84 48384.34 48384.09 5.2 48397.84 48398.34 48398.09 14.6 48411.84 48412.34 48412.09 23.4 48425.84 48426.34 48426.09 -6.2 48439.84 48440.34 48440.09 6.0 48453.91 48454.41 48454.16 3.0 48467.72 48468.22 48467.97 16.3 48481.78 48482.28 48482.03 2.7 48495.72 48496.22 48495.97 -0.7 48509.84 48510.34 48510.09 20.3 48523.84 48524.34 48524.09 3.7 48537.84 48538.34 48538.09 -0.9 48551.84 48552.34 48552.09 13.9 48565.84 48566.34 48566.09 30.2 48579.72 48580.22 48579.97 14.3 48593.72 48594.22 48593.97 14.0 48607.78 48608.28 48608.03 0.9 48621.72 48622.22 48621.97 24.6 48635.78 48636.28 48636.03 3.7 48649.91 48650.41 48650.16 -2.2 48663.84 48664.34 48664.09 17.1 48677.84 48678.34 48678.09 4.3 48691.72 48692.22 48691.97 15.2 48705.78 48706.28 48706.03 25.9 48719.72 48720.22 48719.97 9.1 48733.72 48734.22 48733.97 14.0 48747.72 48748.22 48747.97 9.3 48761.72 48762.22 48761.97 13.4 48775.78 48776.28 48776.03 2.6 48789.84 48790.34 48790.09 13.7 48803.78 48804.28 48804.03 13.7 48817.78 48818.28 48818.03 -4.7 48831.72 48832.22 48831.97 4.0 48845.72 48846.22 48845.97 4.1 48859.72 48860.22 48859.97 7.2 48873.72 48874.22 48873.97 4.4 48887.78 48888.28 48888.03 -2.6 48901.72 48902.22 48901.97 9.0 48915.72 48916.22 48915.97 3.9 48929.72 48930.22 48929.97 2.7 48943.72 48944.22 48943.97 16.5 48957.72 48958.22 48957.97 1.6 48971.72 48972.22 48971.97 12.1 48985.72 48986.22 48985.97 -5.6 48999.72 49000.22 48999.97 4.2 49013.72 49014.22 49013.97 -0.0 49027.72 49028.22 49027.97 -1.6 49041.72 49042.22 49041.97 4.9 49055.72 49056.22 49055.97 0.6 49069.72 49070.22 49069.97 5.1 49083.72 49084.22 49083.97 21.1 49097.78 49098.28 49098.03 12.2 49111.78 49112.28 49112.03 -4.9 49125.72 49126.22 49125.97 -10.0 49139.78 49140.28 49140.03 14.2 49153.78 49154.28 49154.03 4.8 49167.72 49168.22 49167.97 3.7 49181.78 49182.28 49182.03 -6.8 49195.72 49196.22 49195.97 -4.2 49209.72 49210.22 49209.97 7.3 49223.72 49224.22 49223.97 -1.6 49237.72 49238.22 49237.97 1.5 49251.78 49252.28 49252.03 -14.1 49474.84 49475.34 49475.09 9.4 49488.84 49489.34 49489.09 2.3 49502.84 49503.34 49503.09 3.0 49516.91 49517.41 49517.16 -3.3 49530.84 49531.34 49531.09 -7.3 49544.84 49545.34 49545.09 -1.3 49558.72 49559.22 49558.97 -2.0 49572.72 49573.22 49572.97 7.9 49586.78 49587.28 49587.03 13.9 49600.72 49601.22 49600.97 1.9 49614.72 49615.22 49614.97 -3.0 49628.84 49629.34 49629.09 5.4 49642.84 49643.34 49643.09 5.0 49656.84 49657.34 49657.09 16.9 49670.72 49671.22 49670.97 14.9 49684.72 49685.22 49684.97 -11.8 49698.72 49699.22 49698.97 7.2 49712.72 49713.22 49712.97 -4.3 49726.72 49727.22 49726.97 16.4 49740.78 49741.28 49741.03 5.3 49754.72 49755.22 49754.97 6.9 49768.91 49769.41 49769.16 1.1 49782.78 49783.28 49783.03 -4.4 49796.78 49797.28 49797.03 2.8 49810.72 49811.22 49810.97 -0.7 49824.78 49825.28 49825.03 -4.0 49838.72 49839.22 49838.97 2.5 49852.78 49853.28 49853.03 12.3 49866.72 49867.22 49866.97 9.7 49880.72 49881.22 49880.97 1.5 49894.72 49895.22 49894.97 -4.9 49908.72 49909.22 49908.97 13.2 49922.72 49923.22 49922.97 6.9 49936.72 49937.22 49936.97 5.8 49950.72 49951.22 49950.97 1.3 49964.72 49965.22 49964.97 -0.2 49978.78 49979.28 49979.03 1.1 49992.78 49993.28 49993.03 -7.3 50006.78 50007.28 50007.03 11.4 50020.72 50021.22 50020.97 7.8 50034.72 50035.22 50034.97 -9.6 50048.78 50049.28 50049.03 1.3 50062.78 50063.28 50063.03 12.6 50076.78 50077.28 50077.03 3.8 50090.78 50091.28 50091.03 -5.6 50104.72 50105.22 50104.97 2.5 50118.72 50119.22 50118.97 6.1 50132.78 50133.28 50133.03 -4.7 50146.72 50147.22 50146.97 26.4 50160.78 50161.28 50161.03 10.9 50174.72 50175.22 50174.97 -0.8 50188.72 50189.22 50188.97 12.9 50202.72 50203.22 50202.97 0.6 50216.72 50217.22 50216.97 8.7 50230.72 50231.22 50230.97 -11.8 50244.72 50245.22 50244.97 4.9 50258.72 50259.22 50258.97 13.7 50272.78 50273.28 50273.03 -2.4 50286.72 50287.22 50286.97 0.6 50300.72 50301.22 50300.97 5.3 50314.72 50315.22 50314.97 -0.9 50328.72 50329.22 50328.97 5.3 50342.72 50343.22 50342.97 8.8 50356.72 50357.22 50356.97 0.5 50370.72 50371.22 50370.97 -6.4 50471.84 50472.34 50472.09 5.7 50485.84 50486.34 50486.09 9.2 50499.84 50500.34 50500.09 15.7 50513.84 50514.34 50514.09 14.0 50527.84 50528.34 50528.09 8.0 50541.72 50542.22 50541.97 -5.4 50555.72 50556.22 50555.97 2.0 50569.72 50570.22 50569.97 3.9 50583.72 50584.22 50583.97 12.5 50597.72 50598.22 50597.97 12.7 50611.78 50612.28 50612.03 0.0 50625.91 50626.41 50626.16 7.7 50639.84 50640.34 50640.09 6.2 50653.78 50654.28 50654.03 5.8 50667.72 50668.22 50667.97 2.4 50681.72 50682.22 50681.97 3.4 50695.72 50696.22 50695.97 5.6 50709.78 50710.28 50710.03 -5.7 50723.72 50724.22 50723.97 15.0 50737.72 50738.22 50737.97 2.5 50751.78 50752.28 50752.03 2.2 50765.72 50766.22 50765.97 7.4 50779.78 50780.28 50780.03 2.7 50793.72 50794.22 50793.97 11.7 50807.72 50808.22 50807.97 -1.6 50821.72 50822.22 50821.97 -2.6 50835.72 50836.22 50835.97 10.2 50849.72 50850.22 50849.97 6.2 50863.72 50864.22 50863.97 9.4 50877.78 50878.28 50878.03 6.4 50891.72 50892.22 50891.97 5.6 50905.72 50906.22 50905.97 3.3 50919.78 50920.28 50920.03 4.7 50933.72 50934.22 50933.97 10.8 50947.72 50948.22 50947.97 7.9 50961.72 50962.22 50961.97 1.9 50975.78 50976.28 50976.03 12.9 50989.72 50990.22 50989.97 -4.9 51003.72 51004.22 51003.97 3.8 51017.72 51018.22 51017.97 4.0 51031.72 51032.22 51031.97 3.4 51045.72 51046.22 51045.97 11.5 51059.72 51060.22 51059.97 2.9 51073.72 51074.22 51073.97 0.2 51087.72 51088.22 51087.97 -2.0 51101.72 51102.22 51101.97 10.9 51115.72 51116.22 51115.97 1.9 51129.78 51130.28 51130.03 19.2 51143.72 51144.22 51143.97 0.1 51157.72 51158.22 51157.97 -3.2 51171.72 51172.22 51171.97 7.7 51185.72 51186.22 51185.97 13.4 51199.72 51200.22 51199.97 8.8 51213.72 51214.22 51213.97 3.6 51227.72 51228.22 51227.97 8.5 51241.78 51242.28 51242.03 7.3 51255.72 51256.22 51255.97 -2.6 51269.72 51270.22 51269.97 8.4 51283.78 51284.28 51284.03 3.2 51297.72 51298.22 51297.97 1.5 51311.72 51312.22 51311.97 12.2 51325.72 51326.22 51325.97 2.3 51339.72 51340.22 51339.97 10.2 51353.72 51354.22 51353.97 7.5 51367.72 51368.22 51367.97 9.2 51468.91 51469.41 51469.16 9.9 51482.91 51483.41 51483.16 -10.7 51496.84 51497.34 51497.09 9.3 51510.84 51511.34 51511.09 0.5 51524.84 51525.34 51525.09 14.7 51538.84 51539.34 51539.09 4.0 51552.84 51553.34 51553.09 -5.2 51566.84 51567.34 51567.09 2.2 51580.84 51581.34 51581.09 8.8 51594.84 51595.34 51595.09 2.0 51608.91 51609.41 51609.16 3.4 51622.84 51623.34 51623.09 4.3 51636.84 51637.34 51637.09 7.8 51650.91 51651.41 51651.16 8.3 51664.91 51665.41 51665.16 11.6 51678.84 51679.34 51679.09 9.7 51692.84 51693.34 51693.09 8.2 51706.91 51707.41 51707.16 5.4 51720.84 51721.34 51721.09 10.7 51734.84 51735.34 51735.09 15.4 51748.78 51749.28 51749.03 13.1 51762.91 51763.41 51763.16 9.6 51776.84 51777.34 51777.09 11.9 51790.84 51791.34 51791.09 20.6 51804.84 51805.34 51805.09 14.4 51818.84 51819.34 51819.09 -1.4 51832.91 51833.41 51833.16 10.4 51846.84 51847.34 51847.09 23.0 51860.72 51861.22 51860.97 21.0 51874.72 51875.22 51874.97 11.9 51888.72 51889.22 51888.97 0.1 51902.84 51903.34 51903.09 15.4 51916.84 51917.34 51917.09 14.9 51930.84 51931.34 51931.09 12.0 51944.84 51945.34 51945.09 4.4 51958.78 51959.28 51959.03 4.1 51972.72 51973.22 51972.97 4.4 51986.78 51987.28 51987.03 9.2 52000.72 52001.22 52000.97 6.8 52014.72 52015.22 52014.97 8.3 52028.72 52029.22 52028.97 6.8 52042.72 52043.22 52042.97 5.4 52056.84 52057.34 52057.09 12.8 52070.78 52071.28 52071.03 11.5 52084.72 52085.22 52084.97 10.5 52098.78 52099.28 52099.03 10.1 52112.72 52113.22 52112.97 7.8 52126.78 52127.28 52127.03 8.0 52140.72 52141.22 52140.97 19.0 52154.72 52155.22 52154.97 17.9 52168.72 52169.22 52168.97 13.3 52182.72 52183.22 52182.97 14.6 52196.72 52197.22 52196.97 23.4 52210.72 52211.22 52210.97 21.5 52224.72 52225.22 52224.97 25.4 52238.78 52239.28 52239.03 28.7 52252.72 52253.22 52252.97 25.3 52266.72 52267.22 52266.97 38.0 52280.72 52281.22 52280.97 21.5 52294.72 52295.22 52294.97 23.1 52308.72 52309.22 52308.97 19.8 52322.78 52323.28 52323.03 26.5 52336.72 52337.22 52336.97 20.4 52350.78 52351.28 52351.03 29.5 52364.72 52365.22 52364.97 31.9 52927.84 52928.34 52928.09 37.3 52941.84 52942.34 52942.09 38.1 52955.84 52956.34 52956.09 30.0 52969.91 52970.41 52970.16 39.9 52983.91 52984.41 52984.16 24.3 52997.84 52998.34 52998.09 57.3 53011.84 53012.34 53012.09 40.4 53025.84 53026.34 53026.09 56.0 53039.84 53040.34 53040.09 54.6 53053.72 53054.22 53053.97 51.0 53067.72 53068.22 53067.97 52.6 53081.91 53082.41 53082.16 64.1 53095.84 53096.34 53096.09 54.2 53109.84 53110.34 53110.09 58.4 53123.91 53124.41 53124.16 43.5 53137.84 53138.34 53138.09 56.5 53151.91 53152.41 53152.16 49.0 53165.72 53166.22 53165.97 53.0 53179.78 53180.28 53180.03 55.5 53193.72 53194.22 53193.97 61.0 53207.72 53208.22 53207.97 50.0 53221.84 53222.34 53222.09 53.9 53235.91 53236.41 53236.16 50.5 53249.84 53250.34 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