43 1001 Wennberg, Paul California Institute of Technology Gas Phase Peroxynitric Acid from DC-8 TC4 1 1 2007 07 29 2011 09 07 0 start_UTC, s 3 1 1 1 999999 999999 999999 stop_UTC, s mid_UTC, s PNA, pptv 0 26 PI_CONTACT_INFO: Address: California Institute of Technology. MC 150-21. 1200 E. California Blvd, Pasadena, CA, 91125. Phone: (626) 395-2447. Fax: (626) 585-1917. email: wennberg@gps.caltech.edu PLATFORM: NASA DC-8 airborne laboratory. LOCATION: Aircraft location data in file TN_20070729.DC8. ASSOCIATED_DATA: N/A INSTRUMENT_INFO: Chemical Ionization Mass Spectrometer. Direct measurements in ambient air. DATA_INFO: Measurements are reported as 0.5 sec averages and in units of pptv. CAUTION: Do not extrapolate data outside of given time interval as these are discrete measurements. Calibration was conducted ~once per hour during the flight using H2O2 and HNO3 calibrants, and proxied to PNA using laboratory calibrations. Absolute calibration was obtained in the laboratory by thermal decomposition and NO2 measurement. Zeros were conducted ~3 times per hour by passing ambient air through a filter containing nylon wool coated with NaHCO3. UNCERTAINTY: +-(100% of measuremlent value + 20 pptv) ULOD_FLAG: 7777777 ULOD_VALUE: N/A LLOD_FLAG: 8888888 LLOD_VALUE: N/A; N/A; N/A; DM_CONTACT_INFO: John Crounse. California Institute of Technology. Department of Chemistry and Chemical Engineering. MC 150-21. 1200 E. California Blvd. Pasadena, CA 91125. Phone: (626) 395-6868. Fax: (626) 585-1917. email: crounjd@caltech.edu. PROJECT_INFO: TC4 study; 13 July-13 August 2007; Study of cloud processing and tropical convection processes STIPULATIONS_ON_USE: Use of these data requires PI notification and adherence to the TC4 data protocol. OTHER_COMMENTS: N/A REVISION: R1 R1: ULOD and LLOD flags changed to positive values, to conform to Ames format 2.1 specifications. R0: Preliminary Data Revision 0. Water correction has been applied using CIT-CIMS water. Reduction code 1.5 start_UTC stop_UTC mid_UTC PNA 45510.84 45511.34 45511.09 2.6 45546.84 45547.34 45547.09 5.9 45582.84 45583.34 45583.09 -2.2 45618.84 45619.34 45619.09 -1.8 45654.91 45655.41 45655.16 -0.1 45690.91 45691.41 45691.16 -0.5 45726.78 45727.28 45727.03 46.0 45762.91 45763.41 45763.16 38.0 45798.84 45799.34 45799.09 47.7 45834.78 45835.28 45835.03 28.7 45870.72 45871.22 45870.97 25.1 45906.72 45907.22 45906.97 51.9 45942.78 45943.28 45943.03 5.0 45978.78 45979.28 45979.03 19.8 46014.78 46015.28 46015.03 -3.7 46050.72 46051.22 46050.97 27.5 46086.78 46087.28 46087.03 -4.9 46122.78 46123.28 46123.03 -3.0 46158.72 46159.22 46158.97 20.8 46194.78 46195.28 46195.03 7.2 46230.72 46231.22 46230.97 21.4 46266.72 46267.22 46266.97 16.6 46302.78 46303.28 46303.03 -8.1 46338.78 46339.28 46339.03 13.7 46374.72 46375.22 46374.97 0.4 46514.91 46515.41 46515.16 10.3 46550.84 46551.34 46551.09 6.9 46586.91 46587.41 46587.16 9.8 46622.72 46623.22 46622.97 23.4 46658.84 46659.34 46659.09 16.2 46694.91 46695.41 46695.16 -9.2 46730.72 46731.22 46730.97 15.9 46935.47 46935.97 46935.72 20.5 46971.47 46971.97 46971.72 25.8 47007.47 47007.97 47007.72 13.2 47043.47 47043.97 47043.72 20.7 47079.53 47080.03 47079.78 14.4 47115.53 47116.03 47115.78 47.3 47309.03 47309.53 47309.28 53.8 47344.97 47345.47 47345.22 32.0 47380.97 47381.47 47381.22 30.0 47522.84 47523.34 47523.09 18.1 47558.91 47559.41 47559.16 26.2 47594.72 47595.22 47594.97 23.8 47630.72 47631.22 47630.97 30.2 47666.84 47667.34 47667.09 27.8 47702.72 47703.22 47702.97 34.4 47738.72 47739.22 47738.97 24.2 47774.72 47775.22 47774.97 27.7 47810.72 47811.22 47810.97 25.9 47846.72 47847.22 47846.97 34.9 47882.72 47883.22 47882.97 28.4 47918.78 47919.28 47919.03 40.3 47954.72 47955.22 47954.97 40.1 47990.72 47991.22 47990.97 17.6 48026.78 48027.28 48027.03 22.2 48062.72 48063.22 48062.97 25.0 48098.72 48099.22 48098.97 26.6 48134.72 48135.22 48134.97 23.0 48170.72 48171.22 48170.97 26.7 48206.72 48207.22 48206.97 23.2 48242.72 48243.22 48242.97 21.1 48278.78 48279.28 48279.03 25.1 48314.72 48315.22 48314.97 24.3 48350.72 48351.22 48350.97 21.8 48386.72 48387.22 48386.97 18.6 48422.78 48423.28 48423.03 20.3 48688.84 48689.34 48689.09 17.9 48724.84 48725.34 48725.09 21.6 48760.84 48761.34 48761.09 22.4 48796.84 48797.34 48797.09 17.1 48832.84 48833.34 48833.09 18.2 48868.84 48869.34 48869.09 21.9 48904.84 48905.34 48905.09 39.7 48940.84 48941.34 48941.09 29.5 48976.84 48977.34 48977.09 30.4 49012.84 49013.34 49013.09 35.9 49048.84 49049.34 49049.09 40.7 49084.91 49085.41 49085.16 32.8 49120.84 49121.34 49121.09 38.7 49156.91 49157.41 49157.16 42.8 49192.84 49193.34 49193.09 38.0 49228.84 49229.34 49229.09 41.0 49264.91 49265.41 49265.16 35.4 49300.84 49301.34 49301.09 32.6 49336.84 49337.34 49337.09 38.6 49372.91 49373.41 49373.16 36.9 49408.84 49409.34 49409.09 30.3 49444.84 49445.34 49445.09 30.7 49480.91 49481.41 49481.16 27.9 49516.91 49517.41 49517.16 27.4 49552.91 49553.41 49553.16 20.8 49695.84 49696.34 49696.09 34.7 49731.84 49732.34 49732.09 26.1 49767.84 49768.34 49768.09 19.8 49803.72 49804.22 49803.97 42.4 49839.91 49840.41 49840.16 31.9 49875.91 49876.41 49876.16 24.8 49911.78 49912.28 49912.03 22.5 49947.72 49948.22 49947.97 28.3 49983.84 49984.34 49984.09 19.9 50019.72 50020.22 50019.97 30.5 50055.72 50056.22 50055.97 21.9 50091.72 50092.22 50091.97 19.0 50127.72 50128.22 50127.97 28.5 50163.72 50164.22 50163.97 25.8 50199.72 50200.22 50199.97 24.4 50235.72 50236.22 50235.97 26.4 50271.72 50272.22 50271.97 26.1 50307.72 50308.22 50307.97 19.9 50343.72 50344.22 50343.97 19.4 50379.78 50380.28 50380.03 25.4 50415.78 50416.28 50416.03 30.9 50451.72 50452.22 50451.97 29.2 50487.72 50488.22 50487.97 22.8 50523.78 50524.28 50524.03 36.8 50559.72 50560.22 50559.97 28.3 50595.78 50596.28 50596.03 28.5 50738.84 50739.34 50739.09 22.2 50774.84 50775.34 50775.09 23.5 50810.91 50811.41 50811.16 32.8 50846.84 50847.34 50847.09 29.1 50882.84 50883.34 50883.09 27.1 50918.84 50919.34 50919.09 25.2 50954.84 50955.34 50955.09 25.9 50990.84 50991.34 50991.09 28.7 51026.84 51027.34 51027.09 23.2 51062.84 51063.34 51063.09 25.2 51098.84 51099.34 51099.09 22.4 51134.72 51135.22 51134.97 24.8 51170.72 51171.22 51170.97 28.9 51206.84 51207.34 51207.09 25.7 51242.72 51243.22 51242.97 24.9 51278.78 51279.28 51279.03 28.3 51314.72 51315.22 51314.97 25.6 51350.72 51351.22 51350.97 21.0 51386.72 51387.22 51386.97 25.2 51422.72 51423.22 51422.97 16.6 51458.72 51459.22 51458.97 20.0 51494.72 51495.22 51494.97 16.9 51530.72 51531.22 51530.97 16.4 51566.72 51567.22 51566.97 13.6 51602.72 51603.22 51602.97 20.5 51638.78 51639.28 51639.03 22.7 52202.84 52203.34 52203.09 5.4 52238.84 52239.34 52239.09 9.0 52274.84 52275.34 52275.09 8.8 52310.84 52311.34 52311.09 13.6 52346.84 52347.34 52347.09 6.4 52382.84 52383.34 52383.09 6.4 52418.84 52419.34 52419.09 12.0 52454.84 52455.34 52455.09 4.9 52490.84 52491.34 52491.09 8.3 52526.91 52527.41 52527.16 3.2 52562.91 52563.41 52563.16 9.5 52598.84 52599.34 52599.09 9.5 52634.84 52635.34 52635.09 11.6 52670.91 52671.41 52671.16 10.1 52706.84 52707.34 52707.09 8.8 52742.84 52743.34 52743.09 11.9 52778.84 52779.34 52779.09 5.8 52814.84 52815.34 52815.09 17.9 52850.84 52851.34 52851.09 16.5 52886.84 52887.34 52887.09 10.5 52922.84 52923.34 52923.09 10.2 52963.66 52964.16 52963.91 10.6 52999.59 53000.09 52999.84 6.7 53035.59 53036.09 53035.84 8.8 53071.59 53072.09 53071.84 16.5 53211.91 53212.41 53212.16 9.4 53247.84 53248.34 53248.09 15.2 53283.84 53284.34 53284.09 17.4 53319.84 53320.34 53320.09 21.4 53355.84 53356.34 53356.09 12.1 53391.84 53392.34 53392.09 6.4 53427.91 53428.41 53428.16 10.7 53463.72 53464.22 53463.97 9.5 53499.84 53500.34 53500.09 1.3 53535.84 53536.34 53536.09 4.4 54218.84 54219.34 54219.09 10.4 54254.84 54255.34 54255.09 15.8 54290.84 54291.34 54291.09 14.6 54326.72 54327.22 54326.97 12.7 54362.91 54363.41 54363.16 8.9 54398.91 54399.41 54399.16 -2.4 54434.72 54435.22 54434.97 17.9 54470.78 54471.28 54471.03 14.9 54506.84 54507.34 54507.09 11.5 54542.72 54543.22 54542.97 15.7 54578.72 54579.22 54578.97 -6.0 54614.72 54615.22 54614.97 -8.5 54650.72 54651.22 54650.97 -5.0 54686.78 54687.28 54687.03 12.0 54722.72 54723.22 54722.97 -0.4 54758.72 54759.22 54758.97 8.0 54794.72 54795.22 54794.97 -13.8 54830.72 54831.22 54830.97 18.7 54866.78 54867.28 54867.03 -1.4 54902.72 54903.22 54902.97 25.5 54938.72 54939.22 54938.97 2.3 54974.72 54975.22 54974.97 13.6 55010.72 55011.22 55010.97 18.9 55046.72 55047.22 55046.97 7.0 55082.78 55083.28 55083.03 -18.9 55118.78 55119.28 55119.03 -0.3 55378.91 55379.41 55379.16 -1.8 55414.91 55415.41 55415.16 6.9 55450.84 55451.34 55451.09 -3.9 55486.84 55487.34 55487.09 8.7 55522.84 55523.34 55523.09 16.6 55558.84 55559.34 55559.09 3.3 55594.84 55595.34 55595.09 25.4 55630.84 55631.34 55631.09 27.2 55666.84 55667.34 55667.09 17.7 55702.84 55703.34 55703.09 23.6 55738.91 55739.41 55739.16 5.7 55774.78 55775.28 55775.03 -0.5 55810.72 55811.22 55810.97 0.9 55846.91 55847.41 55847.16 -2.2 55882.78 55883.28 55883.03 -2.5 55918.72 55919.22 55918.97 9.4 55954.72 55955.22 55954.97 9.3 55990.78 55991.28 55991.03 9.3 56026.72 56027.22 56026.97 3.9 56062.72 56063.22 56062.97 16.4 56098.72 56099.22 56098.97 -9.0 56134.72 56135.22 56134.97 -0.5 56170.72 56171.22 56170.97 -4.8 56206.78 56207.28 56207.03 -2.6 56242.78 56243.28 56243.03 11.2 56278.78 56279.28 56279.03 8.7 56415.84 56416.34 56416.09 5.7 56451.84 56452.34 56452.09 0.7 56487.84 56488.34 56488.09 12.3 56523.72 56524.22 56523.97 12.7 56559.84 56560.34 56560.09 8.0 56595.91 56596.41 56596.16 1.0 56631.78 56632.28 56632.03 3.7 56667.72 56668.22 56667.97 -6.7 56703.84 56704.34 56704.09 18.1 56739.72 56740.22 56739.97 -4.3 56775.78 56776.28 56776.03 13.8 56811.78 56812.28 56812.03 6.4 56847.72 56848.22 56847.97 5.9 56883.78 56884.28 56884.03 -6.5 56919.72 56920.22 56919.97 7.7 56955.72 56956.22 56955.97 0.7 56991.72 56992.22 56991.97 6.0 57027.72 57028.22 57027.97 -7.1 57063.72 57064.22 57063.97 6.0 57099.72 57100.22 57099.97 12.9 57135.78 57136.28 57136.03 -2.2 57171.72 57172.22 57171.97 5.6 57207.78 57208.28 57208.03 10.8 57243.72 57244.22 57243.97 5.1 57279.72 57280.22 57279.97 0.1 57315.72 57316.22 57315.97 11.1 57452.84 57453.34 57453.09 7.3 57488.84 57489.34 57489.09 2.7 57524.72 57525.22 57524.97 -4.3 57560.78 57561.28 57561.03 1.9 57596.84 57597.34 57597.09 5.8 57632.72 57633.22 57632.97 17.2 57668.72 57669.22 57668.97 9.9 57704.72 57705.22 57704.97 1.7 57740.72 57741.22 57740.97 1.6 57776.78 57777.28 57777.03 9.2 57812.72 57813.22 57812.97 15.6 57848.72 57849.22 57848.97 11.7 57884.78 57885.28 57885.03 12.1 57920.72 57921.22 57920.97 2.0 57956.78 57957.28 57957.03 7.1 57992.72 57993.22 57992.97 14.5 58028.72 58029.22 58028.97 8.9 58064.72 58065.22 58064.97 7.0 58100.72 58101.22 58100.97 2.5 58136.72 58137.22 58136.97 21.5 58172.72 58173.22 58172.97 3.8 58208.72 58209.22 58208.97 14.0 58244.78 58245.28 58245.03 9.7 58280.72 58281.22 58280.97 15.5 58316.72 58317.22 58316.97 20.7 58352.72 58353.22 58352.97 9.1 58912.84 58913.34 58913.09 29.8 58948.84 58949.34 58949.09 10.9 59074.03 59074.53 59074.28 1.5 59109.97 59110.47 59110.22 16.2 59145.97 59146.47 59146.22 11.5 59182.03 59182.53 59182.28 2.7 59217.97 59218.47 59218.22 11.6 59253.97 59254.47 59254.22 21.2 59290.03 59290.53 59290.28 28.2 59326.03 59326.53 59326.28 2.2 59361.97 59362.47 59362.22 24.1 59397.97 59398.47 59398.22 18.8 59433.97 59434.47 59434.22 11.8 59469.97 59470.47 59470.22 4.2 59506.03 59506.53 59506.28 5.9 59542.03 59542.53 59542.28 17.7 59578.03 59578.53 59578.28 13.6 59613.97 59614.47 59614.22 11.6 59649.97 59650.47 59650.22 -2.5 59685.97 59686.47 59686.22 6.0 59721.97 59722.47 59722.22 20.5 59757.97 59758.47 59758.22 16.0 59794.03 59794.53 59794.28 2.1 59931.84 59932.34 59932.09 5.8 59967.84 59968.34 59968.09 5.9 60003.91 60004.41 60004.16 -6.0 60039.72 60040.22 60039.97 7.1 60075.84 60076.34 60076.09 3.6 60111.84 60112.34 60112.09 3.3 60147.72 60148.22 60147.97 -2.2 60183.78 60184.28 60184.03 1.0 60309.97 60310.47 60310.22 10.3 60345.97 60346.47 60346.22 6.4 60620.09 60620.59 60620.34 -0.6 60656.09 60656.59 60656.34 -1.3 60692.09 60692.59 60692.34 1.6 60728.09 60728.59 60728.34 -3.1 60764.09 60764.59 60764.34 -2.4 60800.09 60800.59 60800.34 2.7 60910.97 60911.47 60911.22 10.0 61445.34 61445.84 61445.59 2.6 61481.34 61481.84 61481.59 -1.1 61517.34 61517.84 61517.59 -0.3 61553.34 61553.84 61553.59 4.2 61589.41 61589.91 61589.66 9.3 61625.34 61625.84 61625.59 7.0 61661.41 61661.91 61661.66 1.9 61697.34 61697.84 61697.59 -1.4 61733.41 61733.91 61733.66 11.6 61769.41 61769.91 61769.66 -2.4 61805.34 61805.84 61805.59 8.6 62067.84 62068.34 62068.09 1.3 62103.84 62104.34 62104.09 8.7 62139.78 62140.28 62140.03 3.9 62175.72 62176.22 62175.97 1.3 62211.84 62212.34 62212.09 0.8 62247.72 62248.22 62247.97 5.3 62283.78 62284.28 62284.03 6.7 62319.72 62320.22 62319.97 6.7 62355.72 62356.22 62355.97 4.7 62391.72 62392.22 62391.97 2.2 62427.72 62428.22 62427.97 8.8 62463.72 62464.22 62463.97 4.3 62499.78 62500.28 62500.03 4.2 62535.78 62536.28 62536.03 5.4 62571.72 62572.22 62571.97 4.7 62607.72 62608.22 62607.97 4.4 62643.84 62644.34 62644.09 3.5 62679.84 62680.34 62680.09 7.3 63077.84 63078.34 63078.09 13.0 63113.84 63114.34 63114.09 10.4 63149.84 63150.34 63150.09 6.8 63185.84 63186.34 63186.09 8.4 63221.84 63222.34 63222.09 11.1 63257.84 63258.34 63258.09 15.9 63293.84 63294.34 63294.09 12.2 63329.72 63330.22 63329.97 15.0 63365.91 63366.41 63366.16 10.3 63401.84 63402.34 63402.09 17.2 63437.72 63438.22 63437.97 23.2 63473.72 63474.22 63473.97 35.4 63509.72 63510.22 63509.97 32.8 63545.91 63546.41 63546.16 20.8 63581.72 63582.22 63581.97 21.2 63617.72 63618.22 63617.97 20.6 63653.78 63654.28 63654.03 27.4 63689.72 63690.22 63689.97 20.5 63725.72 63726.22 63725.97 13.5 63761.72 63762.22 63761.97 12.7 63797.78 63798.28 63798.03 16.0 63833.72 63834.22 63833.97 11.7 63869.78 63870.28 63870.03 12.5 63905.72 63906.22 63905.97 17.2 63941.72 63942.22 63941.97 17.5 63977.72 63978.22 63977.97 17.6 64120.84 64121.34 64121.09 16.4 64156.84 64157.34 64157.09 14.7 64192.84 64193.34 64193.09 13.8 64228.84 64229.34 64229.09 9.2 64264.84 64265.34 64265.09 14.7 64300.84 64301.34 64301.09 18.7 64336.84 64337.34 64337.09 15.9 64372.91 64373.41 64373.16 15.6 64408.84 64409.34 64409.09 15.1 64444.84 64445.34 64445.09 13.7 64480.91 64481.41 64481.16 13.4 64516.84 64517.34 64517.09 13.8 64552.78 64553.28 64553.03 10.2 64588.84 64589.34 64589.09 11.8 64624.91 64625.41 64625.16 13.3 64660.72 64661.22 64660.97 14.6 64696.72 64697.22 64696.97 13.1 64732.78 64733.28 64733.03 11.7 64768.78 64769.28 64769.03 16.5 64804.78 64805.28 64805.03 16.9 64840.78 64841.28 64841.03 11.0 64876.72 64877.22 64876.97 13.7 64912.72 64913.22 64912.97 10.2 64948.78 64949.28 64949.03 14.9 64984.72 64985.22 64984.97 14.1 65020.78 65021.28 65021.03 15.1 65587.84 65588.34 65588.09 16.7 65623.91 65624.41 65624.16 23.9 65659.78 65660.28 65660.03 18.7 65695.72 65696.22 65695.97 25.1 65731.84 65732.34 65732.09 25.8 65767.78 65768.28 65768.03 31.9 65803.72 65804.22 65803.97 31.2 65839.72 65840.22 65839.97 37.4 65875.72 65876.22 65875.97 27.1 65911.78 65912.28 65912.03 24.8 65947.72 65948.22 65947.97 28.5 65983.78 65984.28 65984.03 24.2 66019.72 66020.22 66019.97 29.4 66055.72 66056.22 66055.97 27.5 66091.72 66092.22 66091.97 28.1 66127.72 66128.22 66127.97 33.5 66163.72 66164.22 66163.97 36.5 66199.78 66200.28 66200.03 30.8 66235.72 66236.22 66235.97 32.3 66271.72 66272.22 66271.97 23.9 66307.72 66308.22 66307.97 25.0 66343.72 66344.22 66343.97 28.4 66379.72 66380.22 66379.97 30.8 66415.72 66416.22 66415.97 16.4 66451.72 66452.22 66451.97 19.6 66487.72 66488.22 66487.97 21.1 66631.84 66632.34 66632.09 30.3 66667.91 66668.41 66668.16 32.1 66703.84 66704.34 66704.09 31.9 66739.72 66740.22 66739.97 26.7 66775.84 66776.34 66776.09 28.8 66811.84 66812.34 66812.09 17.9 66847.91 66848.41 66848.16 20.1 66883.72 66884.22 66883.97 23.2 66919.84 66920.34 66920.09 26.3 66955.91 66956.41 66956.16 22.1 66991.78 66992.28 66992.03 24.8 67027.72 67028.22 67027.97 17.3 67063.72 67064.22 67063.97 15.1 67099.72 67100.22 67099.97 17.4 67135.72 67136.22 67135.97 24.0 67171.72 67172.22 67171.97 17.8 67207.72 67208.22 67207.97 33.7 67243.72 67244.22 67243.97 26.6 67279.78 67280.28 67280.03 39.2 67315.72 67316.22 67315.97 27.0 67351.72 67352.22 67351.97 25.3 67387.72 67388.22 67387.97 34.4 67423.72 67424.22 67423.97 35.3 67459.72 67460.22 67459.97 27.2 67495.72 67496.22 67495.97 20.7 67531.72 67532.22 67531.97 16.3 67675.84 67676.34 67676.09 20.6 67711.84 67712.34 67712.09 22.1 67747.72 67748.22 67747.97 28.2 67783.72 67784.22 67783.97 46.1 67819.84 67820.34 67820.09 22.7 67855.72 67856.22 67855.97 26.4 67891.72 67892.22 67891.97 23.2 67927.72 67928.22 67927.97 16.0 67963.72 67964.22 67963.97 15.5 67999.72 68000.22 67999.97 24.9 68035.72 68036.22 68035.97 25.0 68071.72 68072.22 68071.97 23.7 68107.72 68108.22 68107.97 24.1 68143.72 68144.22 68143.97 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