41 1001 Wennberg, Paul California Institute of Technology Gas Phase Hydrogen Cyanide from DC-8 TC4 1 1 2007 07 29 2007 08 02 0 start_UTC, s 3 1 1 1 999999 999999 999999 stop_UTC, s mid_UTC, s HCN, pptv 0 24 PI_CONTACT_INFO: Address: California Institute of Technology. MC 150-21. 1200 E. California Blvd, Pasadena, CA, 91125. Phone: (626) 395-2447. Fax: (626) 585-1917. email: wennberg@gps.caltech.edu PLATFORM: NASA DC-8 airborne laboratory. LOCATION: Aircraft location data in file TN_20070729.DC8. ASSOCIATED_DATA: N/A INSTRUMENT_INFO: Chemical Ionization Mass Spectrometer. Direct measurements in ambient air. DATA_INFO: Measurements are reported as 0.5 sec averages and in units of pptv. CAUTION: Do not extrapolate data outside of given time interval as these are discrete measurements. Calibration was conducted ~once per hour during the flight using H2O2 and HNO3 calibrants, and proxied to HCN using laboratory calibrations. Absolute calibration was obtained in the laboratory by FTIR spectroscopy. Zeros were conducted ~3 times per hour by passing ambient air through a filter containing nylon wool coated with NaHCO3. UNCERTAINTY: +-(50% of measuremlent value + 50 pptv) ULOD_FLAG: -7777 ULOD_VALUE: N/A LLOD_FLAG: -8888 LLOD_VALUE: N/A; N/A; N/A; DM_CONTACT_INFO: John Crounse. California Institute of Technology. Department of Chemistry and Chemical Engineering. MC 150-21. 1200 E. California Blvd. Pasadena, CA 91125. Phone: (626) 395-6868. Fax: (626) 585-1917. email: crounjd@caltech.edu. PROJECT_INFO: TC4 study; 13 July-13 August 2007; Study of cloud processing and tropical convection processes STIPULATIONS_ON_USE: Use of these data requires PI notification and adherence to the TC4 data protocol. OTHER_COMMENTS: N/A REVISION: R0 R0: Preliminary Data Revision 0. Water correction has been applied using CIT-CIMS water. Reduction code 1.5 start_UTC(s) stop_UTC(s) mid_UTC(s) HCN(pptv) 45476.34 45476.84 45476.59 7.9 45493.09 45493.59 45493.34 0.7 45512.41 45512.91 45512.66 1.8 45529.09 45529.59 45529.34 -3.6 45548.34 45548.84 45548.59 3.7 45565.09 45565.59 45565.34 -5.1 45584.34 45584.84 45584.59 7.0 45598.91 45599.41 45599.16 -11.0 45620.34 45620.84 45620.59 -4.6 45637.09 45637.59 45637.34 1.6 45656.34 45656.84 45656.59 -10.6 45673.09 45673.59 45673.34 -5.1 45692.34 45692.84 45692.59 6.2 45709.09 45709.59 45709.34 95.7 45728.22 45728.72 45728.47 124.5 45742.78 45743.28 45743.03 147.7 45764.34 45764.84 45764.59 111.7 45781.09 45781.59 45781.34 86.1 45800.41 45800.91 45800.66 78.3 45817.09 45817.59 45817.34 86.1 45836.28 45836.78 45836.53 86.7 45852.97 45853.47 45853.22 90.9 45872.22 45872.72 45872.47 94.1 45888.97 45889.47 45889.22 83.9 45908.34 45908.84 45908.59 91.9 45925.09 45925.59 45925.34 88.1 45944.22 45944.72 45944.47 83.2 45958.78 45959.28 45959.03 90.4 45980.22 45980.72 45980.47 90.2 45996.97 45997.47 45997.22 82.1 46016.22 46016.72 46016.47 75.1 46032.97 46033.47 46033.22 79.8 46052.22 46052.72 46052.47 102.0 46068.97 46069.47 46069.22 91.8 46088.22 46088.72 46088.47 95.5 46104.97 46105.47 46105.22 97.2 46124.28 46124.78 46124.53 95.9 46140.97 46141.47 46141.22 92.0 46160.22 46160.72 46160.47 92.1 46176.97 46177.47 46177.22 89.5 46196.22 46196.72 46196.47 107.1 46212.97 46213.47 46213.22 88.8 46232.22 46232.72 46232.47 94.7 46248.97 46249.47 46249.22 91.6 46268.22 46268.72 46268.47 90.3 46284.97 46285.47 46285.22 89.7 46304.28 46304.78 46304.53 81.9 46320.97 46321.47 46321.22 83.5 46340.22 46340.72 46340.47 80.3 46356.97 46357.47 46357.22 85.0 46376.22 46376.72 46376.47 79.9 46390.78 46391.28 46391.03 80.6 46516.41 46516.91 46516.66 105.9 46530.91 46531.41 46531.16 80.9 46552.34 46552.84 46552.59 78.0 46569.09 46569.59 46569.34 84.6 46588.28 46588.78 46588.53 106.6 46602.78 46603.28 46603.03 87.1 46624.22 46624.72 46624.47 86.1 46640.97 46641.47 46641.22 91.4 46660.34 46660.84 46660.59 103.0 46677.09 46677.59 46677.34 95.3 46696.41 46696.91 46696.66 100.0 46710.78 46711.28 46711.03 94.3 46732.22 46732.72 46732.47 128.1 46746.78 46747.28 46747.03 55.7 46936.97 46937.47 46937.22 105.6 46951.53 46952.03 46951.78 121.9 46972.97 46973.47 46973.22 99.4 46989.72 46990.22 46989.97 104.8 47009.03 47009.53 47009.28 120.0 47025.72 47026.22 47025.97 120.3 47044.97 47045.47 47045.22 150.7 47061.72 47062.22 47061.97 132.2 47081.03 47081.53 47081.28 126.9 47097.72 47098.22 47097.97 146.5 47116.97 47117.47 47117.22 119.8 47131.53 47132.03 47131.78 191.0 47310.47 47310.97 47310.72 144.8 47327.22 47327.72 47327.47 146.4 47346.47 47346.97 47346.72 141.7 47363.22 47363.72 47363.47 165.0 47382.53 47383.03 47382.78 149.6 47397.03 47397.53 47397.28 210.2 47524.34 47524.84 47524.59 141.9 47541.09 47541.59 47541.34 158.4 47560.34 47560.84 47560.59 136.8 47576.97 47577.47 47577.22 171.3 47596.28 47596.78 47596.53 170.0 47610.78 47611.28 47611.03 187.5 47632.28 47632.78 47632.53 179.7 47648.97 47649.47 47649.22 179.6 47668.34 47668.84 47668.59 172.7 47684.97 47685.47 47685.22 164.7 47704.22 47704.72 47704.47 153.9 47718.78 47719.28 47719.03 161.1 47740.22 47740.72 47740.47 162.8 47756.97 47757.47 47757.22 153.5 47776.22 47776.72 47776.47 170.0 47792.97 47793.47 47793.22 172.5 47812.22 47812.72 47812.47 175.8 47828.97 47829.47 47829.22 170.0 47848.28 47848.78 47848.53 169.6 47864.97 47865.47 47865.22 175.6 47884.22 47884.72 47884.47 169.9 47900.97 47901.47 47901.22 173.1 47920.28 47920.78 47920.53 167.6 47936.97 47937.47 47937.22 172.4 47956.28 47956.78 47956.53 190.0 47972.97 47973.47 47973.22 177.1 47992.22 47992.72 47992.47 153.6 48008.97 48009.47 48009.22 162.7 48028.22 48028.72 48028.47 163.7 48044.97 48045.47 48045.22 183.9 48064.22 48064.72 48064.47 189.2 48078.78 48079.28 48079.03 175.8 48100.22 48100.72 48100.47 181.5 48116.97 48117.47 48117.22 176.0 48136.22 48136.72 48136.47 182.8 48150.78 48151.28 48151.03 163.2 48172.22 48172.72 48172.47 173.5 48186.78 48187.28 48187.03 162.3 48208.22 48208.72 48208.47 190.2 48222.78 48223.28 48223.03 204.5 48244.22 48244.72 48244.47 183.3 48260.97 48261.47 48261.22 171.6 48280.22 48280.72 48280.47 178.4 48296.97 48297.47 48297.22 177.7 48316.22 48316.72 48316.47 182.9 48332.97 48333.47 48333.22 172.9 48352.22 48352.72 48352.47 180.8 48368.97 48369.47 48369.22 165.7 48388.22 48388.72 48388.47 171.3 48404.97 48405.47 48405.22 155.8 48424.28 48424.78 48424.53 154.1 48440.97 48441.47 48441.22 164.6 48690.34 48690.84 48690.59 158.9 48707.09 48707.59 48707.34 165.7 48726.34 48726.84 48726.59 184.3 48743.09 48743.59 48743.34 160.1 48762.41 48762.91 48762.66 160.4 48779.09 48779.59 48779.34 168.4 48798.34 48798.84 48798.59 140.8 48815.09 48815.59 48815.34 167.6 48834.34 48834.84 48834.59 178.7 48851.09 48851.59 48851.34 172.0 48870.41 48870.91 48870.66 195.6 48884.91 48885.41 48885.16 133.1 48906.34 48906.84 48906.59 151.4 48923.09 48923.59 48923.34 163.8 48942.34 48942.84 48942.59 156.8 48959.09 48959.59 48959.34 163.4 48978.41 48978.91 48978.66 177.3 48992.91 48993.41 48993.16 161.4 49014.34 49014.84 49014.59 161.4 49031.09 49031.59 49031.34 167.9 49050.34 49050.84 49050.59 190.6 49067.09 49067.59 49067.34 163.4 49086.34 49086.84 49086.59 172.3 49100.91 49101.41 49101.16 165.4 49122.34 49122.84 49122.59 185.2 49136.91 49137.41 49137.16 169.7 49158.34 49158.84 49158.59 186.6 49175.09 49175.59 49175.34 174.5 49194.41 49194.91 49194.66 153.1 49211.09 49211.59 49211.34 173.7 49230.41 49230.91 49230.66 164.0 49247.09 49247.59 49247.34 173.2 49266.34 49266.84 49266.59 150.7 49283.09 49283.59 49283.34 177.9 49302.34 49302.84 49302.59 166.6 49316.91 49317.41 49317.16 168.8 49338.34 49338.84 49338.59 176.7 49352.91 49353.41 49353.16 196.4 49374.34 49374.84 49374.59 167.6 49391.09 49391.59 49391.34 173.0 49410.34 49410.84 49410.59 166.5 49427.09 49427.59 49427.34 162.0 49446.34 49446.84 49446.59 145.6 49463.09 49463.59 49463.34 164.9 49482.34 49482.84 49482.59 174.9 49496.91 49497.41 49497.16 138.3 49518.34 49518.84 49518.59 175.0 49532.91 49533.41 49533.16 150.1 49554.41 49554.91 49554.66 146.0 49571.09 49571.59 49571.34 154.8 49697.41 49697.91 49697.66 166.7 49714.09 49714.59 49714.34 156.6 49733.34 49733.84 49733.59 164.6 49750.09 49750.59 49750.34 149.5 49769.34 49769.84 49769.59 160.6 49785.97 49786.47 49786.22 159.0 49805.22 49805.72 49805.47 148.2 49819.78 49820.28 49820.03 169.5 49841.34 49841.84 49841.59 171.1 49858.09 49858.59 49858.34 163.2 49877.34 49877.84 49877.59 157.4 49893.97 49894.47 49894.22 159.1 49913.22 49913.72 49913.47 160.3 49929.97 49930.47 49930.22 160.9 49985.41 49985.91 49985.66 155.9 50001.97 50002.47 50002.22 156.3 50021.22 50021.72 50021.47 166.2 50037.97 50038.47 50038.22 159.8 50057.22 50057.72 50057.47 158.6 50073.97 50074.47 50074.22 148.5 50093.22 50093.72 50093.47 169.9 50109.97 50110.47 50110.22 159.2 50129.22 50129.72 50129.47 141.9 50143.78 50144.28 50144.03 128.7 50165.22 50165.72 50165.47 138.0 50181.97 50182.47 50182.22 158.5 50201.22 50201.72 50201.47 150.0 50217.97 50218.47 50218.22 152.7 50237.22 50237.72 50237.47 151.3 50253.97 50254.47 50254.22 156.7 50273.28 50273.78 50273.53 142.8 50287.78 50288.28 50288.03 134.3 50309.22 50309.72 50309.47 128.3 50323.78 50324.28 50324.03 147.2 50345.22 50345.72 50345.47 145.4 50361.97 50362.47 50362.22 158.0 50381.28 50381.78 50381.53 174.3 50397.97 50398.47 50398.22 156.1 50417.22 50417.72 50417.47 141.7 50433.97 50434.47 50434.22 152.4 50453.22 50453.72 50453.47 161.8 50469.97 50470.47 50470.22 158.0 50489.22 50489.72 50489.47 170.0 50505.97 50506.47 50506.22 162.1 50525.22 50525.72 50525.47 154.2 50541.97 50542.47 50542.22 153.6 50561.22 50561.72 50561.47 150.7 50577.97 50578.47 50578.22 161.7 50597.22 50597.72 50597.47 149.9 50613.97 50614.47 50614.22 157.5 50740.34 50740.84 50740.59 142.8 50757.09 50757.59 50757.34 158.5 50776.41 50776.91 50776.66 187.6 50790.91 50791.41 50791.16 157.7 50812.41 50812.91 50812.66 157.4 50829.09 50829.59 50829.34 155.9 50848.34 50848.84 50848.59 156.7 50862.91 50863.41 50863.16 150.3 50884.34 50884.84 50884.59 156.0 50901.09 50901.59 50901.34 155.0 50920.41 50920.91 50920.66 155.1 50937.09 50937.59 50937.34 160.1 50956.34 50956.84 50956.59 146.7 50973.09 50973.59 50973.34 157.3 50992.28 50992.78 50992.53 159.8 51008.97 51009.47 51009.22 154.6 51028.41 51028.91 51028.66 148.2 51045.09 51045.59 51045.34 160.1 51064.34 51064.84 51064.59 161.1 51081.09 51081.59 51081.34 150.9 51100.34 51100.84 51100.59 154.6 51116.97 51117.47 51117.22 149.1 51136.22 51136.72 51136.47 151.7 51152.97 51153.47 51153.22 165.7 51172.34 51172.84 51172.59 163.9 51189.09 51189.59 51189.34 153.7 51208.41 51208.91 51208.66 154.9 51224.97 51225.47 51225.22 155.1 51244.28 51244.78 51244.53 152.0 51260.97 51261.47 51261.22 143.8 51280.22 51280.72 51280.47 159.4 51294.78 51295.28 51295.03 179.3 51316.22 51316.72 51316.47 146.9 51330.78 51331.28 51331.03 129.0 51352.22 51352.72 51352.47 143.6 51368.97 51369.47 51369.22 148.1 51388.22 51388.72 51388.47 132.3 51402.78 51403.28 51403.03 164.5 51424.22 51424.72 51424.47 152.7 51440.97 51441.47 51441.22 140.5 51460.22 51460.72 51460.47 146.8 51476.97 51477.47 51477.22 144.6 51496.22 51496.72 51496.47 144.0 51512.97 51513.47 51513.22 142.4 51532.22 51532.72 51532.47 140.0 51546.78 51547.28 51547.03 117.4 51568.22 51568.72 51568.47 146.3 51584.97 51585.47 51585.22 144.4 51604.28 51604.78 51604.53 143.8 51620.97 51621.47 51621.22 152.3 51640.28 51640.78 51640.53 150.8 51656.97 51657.47 51657.22 148.9 52204.41 52204.91 52204.66 147.6 52221.09 52221.59 52221.34 146.8 52240.34 52240.84 52240.59 145.4 52254.91 52255.41 52255.16 139.8 52276.34 52276.84 52276.59 146.8 52293.09 52293.59 52293.34 141.8 52312.41 52312.91 52312.66 129.5 52326.91 52327.41 52327.16 144.7 52348.34 52348.84 52348.59 137.2 52365.09 52365.59 52365.34 133.8 52384.41 52384.91 52384.66 147.7 52401.09 52401.59 52401.34 135.8 52420.34 52420.84 52420.59 155.2 52437.09 52437.59 52437.34 141.1 52456.34 52456.84 52456.59 142.2 52470.91 52471.41 52471.16 154.6 52492.34 52492.84 52492.59 151.0 52509.09 52509.59 52509.34 146.9 52528.41 52528.91 52528.66 150.7 52542.91 52543.41 52543.16 136.6 52564.34 52564.84 52564.59 137.9 52581.09 52581.59 52581.34 147.4 52600.34 52600.84 52600.59 161.3 52614.91 52615.41 52615.16 143.3 52636.34 52636.84 52636.59 130.9 52653.09 52653.59 52653.34 152.1 52672.41 52672.91 52672.66 159.2 52689.09 52689.59 52689.34 145.2 52708.34 52708.84 52708.59 153.9 52725.09 52725.59 52725.34 143.9 52744.34 52744.84 52744.59 150.6 52761.09 52761.59 52761.34 160.6 52780.34 52780.84 52780.59 145.5 52797.09 52797.59 52797.34 151.5 52816.34 52816.84 52816.59 137.7 52830.91 52831.41 52831.16 140.1 52852.41 52852.91 52852.66 163.0 52869.09 52869.59 52869.34 162.6 52888.34 52888.84 52888.59 152.6 52905.09 52905.59 52905.34 159.9 52924.34 52924.84 52924.59 138.7 52941.09 52941.59 52941.34 148.2 52965.09 52965.59 52965.34 168.5 52981.84 52982.34 52982.09 148.7 53001.09 53001.59 53001.34 142.3 53017.84 53018.34 53018.09 157.1 53037.09 53037.59 53037.34 142.7 53053.84 53054.34 53054.09 151.6 53073.09 53073.59 53073.34 159.6 53089.84 53090.34 53090.09 151.2 53213.34 53213.84 53213.59 155.5 53230.09 53230.59 53230.34 163.7 53249.41 53249.91 53249.66 183.7 53266.09 53266.59 53266.34 166.4 53285.34 53285.84 53285.59 156.8 53302.09 53302.59 53302.34 161.2 53321.41 53321.91 53321.66 154.6 53337.97 53338.47 53338.22 159.4 53357.41 53357.91 53357.66 145.9 53374.09 53374.59 53374.34 138.9 53393.34 53393.84 53393.59 136.6 53410.09 53410.59 53410.34 124.0 53429.34 53429.84 53429.59 132.0 53445.97 53446.47 53446.22 138.0 53465.22 53465.72 53465.47 158.4 53481.97 53482.47 53482.22 145.0 53501.34 53501.84 53501.59 165.8 53518.09 53518.59 53518.34 152.2 53537.41 53537.91 53537.66 131.9 53553.97 53554.47 53554.22 146.4 54220.41 54220.91 54220.66 78.0 54234.91 54235.41 54235.16 83.6 54256.41 54256.91 54256.66 63.7 54273.09 54273.59 54273.34 63.1 54292.41 54292.91 54292.66 65.6 54309.09 54309.59 54309.34 66.1 54328.22 54328.72 54328.47 64.5 54344.97 54345.47 54345.22 59.8 54364.34 54364.84 54364.59 62.1 54381.09 54381.59 54381.34 58.8 54400.34 54400.84 54400.59 62.1 54417.09 54417.59 54417.34 62.1 54436.22 54436.72 54436.47 70.5 54452.97 54453.47 54453.22 56.2 54472.22 54472.72 54472.47 66.0 54488.97 54489.47 54489.22 57.7 54508.41 54508.91 54508.66 61.6 54525.09 54525.59 54525.34 56.7 54544.28 54544.78 54544.53 51.6 54560.97 54561.47 54561.22 60.7 54580.22 54580.72 54580.47 60.1 54594.78 54595.28 54595.03 43.7 54616.28 54616.78 54616.53 46.1 54632.97 54633.47 54633.22 49.1 54652.22 54652.72 54652.47 54.2 54668.97 54669.47 54669.22 47.7 54688.22 54688.72 54688.47 49.0 54702.78 54703.28 54703.03 42.9 54724.28 54724.78 54724.53 36.2 54740.97 54741.47 54741.22 49.0 54760.22 54760.72 54760.47 62.3 54776.97 54777.47 54777.22 44.8 54796.22 54796.72 54796.47 48.6 54812.97 54813.47 54813.22 43.9 54832.22 54832.72 54832.47 39.2 54846.78 54847.28 54847.03 42.9 54868.22 54868.72 54868.47 42.0 54882.78 54883.28 54883.03 44.4 54904.22 54904.72 54904.47 46.8 54920.97 54921.47 54921.22 52.1 54940.22 54940.72 54940.47 66.1 54956.97 54957.47 54957.22 76.9 54976.22 54976.72 54976.47 79.4 54990.78 54991.28 54991.03 90.3 55012.22 55012.72 55012.47 101.8 55028.97 55029.47 55029.22 100.4 55048.22 55048.72 55048.47 106.7 55062.78 55063.28 55063.03 104.8 55084.22 55084.72 55084.47 87.1 55098.78 55099.28 55099.03 98.8 55120.28 55120.78 55120.53 38.2 55136.97 55137.47 55137.22 62.6 55380.34 55380.84 55380.59 64.6 55397.09 55397.59 55397.34 73.2 55416.41 55416.91 55416.66 79.0 55433.09 55433.59 55433.34 70.4 55452.41 55452.91 55452.66 68.7 55469.09 55469.59 55469.34 67.4 55488.34 55488.84 55488.59 69.5 55505.09 55505.59 55505.34 62.3 55524.41 55524.91 55524.66 69.4 55541.09 55541.59 55541.34 69.4 55560.34 55560.84 55560.59 79.9 55577.09 55577.59 55577.34 100.3 55596.34 55596.84 55596.59 119.5 55613.09 55613.59 55613.34 107.5 55632.22 55632.72 55632.47 111.5 55646.78 55647.28 55647.03 115.3 55668.34 55668.84 55668.59 101.9 55682.91 55683.41 55683.16 108.1 55704.34 55704.84 55704.59 108.1 55721.09 55721.59 55721.34 97.5 55740.34 55740.84 55740.59 96.7 55754.78 55755.28 55755.03 132.4 55776.22 55776.72 55776.47 55.4 55790.78 55791.28 55791.03 64.3 55812.41 55812.91 55812.66 45.2 55829.09 55829.59 55829.34 49.3 55848.34 55848.84 55848.59 48.2 55864.97 55865.47 55865.22 43.9 55884.22 55884.72 55884.47 50.2 55900.97 55901.47 55901.22 47.2 55920.22 55920.72 55920.47 53.9 55934.78 55935.28 55935.03 37.1 55956.28 55956.78 55956.53 56.3 55972.97 55973.47 55973.22 46.0 55992.28 55992.78 55992.53 50.9 56008.97 56009.47 56009.22 45.8 56028.22 56028.72 56028.47 44.9 56044.97 56045.47 56045.22 47.6 56064.22 56064.72 56064.47 47.1 56078.78 56079.28 56079.03 54.3 56100.22 56100.72 56100.47 46.0 56116.97 56117.47 56117.22 43.7 56136.22 56136.72 56136.47 44.4 56152.97 56153.47 56153.22 43.4 56172.22 56172.72 56172.47 38.5 56188.97 56189.47 56189.22 45.3 56208.28 56208.78 56208.53 62.5 56224.97 56225.47 56225.22 49.1 56244.22 56244.72 56244.47 52.0 56260.97 56261.47 56261.22 43.6 56280.22 56280.72 56280.47 48.2 56296.97 56297.47 56297.22 45.1 56417.34 56417.84 56417.59 43.6 56434.09 56434.59 56434.34 47.0 56453.34 56453.84 56453.59 47.3 56470.09 56470.59 56470.34 49.3 56489.41 56489.91 56489.66 54.1 56506.09 56506.59 56506.34 49.8 56525.28 56525.78 56525.53 60.4 56541.97 56542.47 56542.22 41.3 56561.34 56561.84 56561.59 55.2 56575.91 56576.41 56576.16 58.7 56597.41 56597.91 56597.66 42.9 56614.09 56614.59 56614.34 43.8 56633.22 56633.72 56633.47 42.8 56649.97 56650.47 56650.22 42.0 56669.28 56669.78 56669.53 44.0 56685.97 56686.47 56686.22 36.4 56705.34 56705.84 56705.59 48.4 56722.09 56722.59 56722.34 52.9 56741.22 56741.72 56741.47 48.3 56757.97 56758.47 56758.22 55.9 56777.28 56777.78 56777.53 53.3 56791.78 56792.28 56792.03 53.4 56813.22 56813.72 56813.47 66.0 56829.97 56830.47 56830.22 59.8 56849.22 56849.72 56849.47 60.0 56865.97 56866.47 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