43 1001 Wennberg, Paul California Institute of Technology Gas Phase Peroxynitric Acid from DC-8 TC4 1 1 2007 07 24 2011 09 07 0 start_UTC, s 3 1 1 1 999999 999999 999999 stop_UTC, s mid_UTC, s PNA, pptv 0 26 PI_CONTACT_INFO: Address: California Institute of Technology. MC 150-21. 1200 E. California Blvd, Pasadena, CA, 91125. Phone: (626) 395-2447. Fax: (626) 585-1917. email: wennberg@gps.caltech.edu PLATFORM: NASA DC-8 airborne laboratory. LOCATION: Aircraft location data in file TN_20070724.DC8. ASSOCIATED_DATA: N/A INSTRUMENT_INFO: Chemical Ionization Mass Spectrometer. Direct measurements in ambient air. DATA_INFO: Measurements are reported as 0.5 sec averages and in units of pptv. CAUTION: Do not extrapolate data outside of given time interval as these are discrete measurements. Calibration was conducted ~once per hour during the flight using H2O2 and HNO3 calibrants, and proxied to PNA using laboratory calibrations. Absolute calibration was obtained in the laboratory by thermal decomposition and NO2 measurement. Zeros were conducted ~3 times per hour by passing ambient air through a filter containing nylon wool coated with NaHCO3. UNCERTAINTY: +-(100% of measuremlent value + 20 pptv) ULOD_FLAG: 7777777 ULOD_VALUE: N/A LLOD_FLAG: 8888888 LLOD_VALUE: N/A; N/A; N/A; DM_CONTACT_INFO: John Crounse. California Institute of Technology. Department of Chemistry and Chemical Engineering. MC 150-21. 1200 E. California Blvd. Pasadena, CA 91125. Phone: (626) 395-6868. Fax: (626) 585-1917. email: crounjd@caltech.edu. PROJECT_INFO: TC4 study; 13 July-13 August 2007; Study of cloud processing and tropical convection processes STIPULATIONS_ON_USE: Use of these data requires PI notification and adherence to the TC4 data protocol. OTHER_COMMENTS: N/A REVISION: R1 R1: ULOD and LLOD flags changed to positive values, to conform to Ames format 2.1 specifications. R0: Preliminary Data Revision 0. Water correction has been applied using CIT-CIMS water. Reduction code 1.5 start_UTC stop_UTC mid_UTC PNA 46120.34 46120.84 46120.59 2.7 46134.84 46135.34 46135.09 0.0 46245.28 46245.78 46245.53 -2.1 46259.72 46260.22 46259.97 0.8 46274.22 46274.72 46274.47 5.3 46288.78 46289.28 46289.03 -2.3 46303.22 46303.72 46303.47 -26.2 46317.72 46318.22 46317.97 75.2 46332.28 46332.78 46332.53 34.5 46346.78 46347.28 46347.03 45.0 46361.28 46361.78 46361.53 21.7 46375.66 46376.16 46375.91 18.3 46390.22 46390.72 46390.47 86.9 46404.78 46405.28 46405.03 47.0 46419.28 46419.78 46419.53 -3.9 46433.78 46434.28 46434.03 13.8 46448.28 46448.78 46448.53 35.7 46462.78 46463.28 46463.03 29.5 46491.66 46492.16 46491.91 16.6 46506.09 46506.59 46506.34 59.8 46520.66 46521.16 46520.91 18.9 46535.22 46535.72 46535.47 42.5 46549.72 46550.22 46549.97 49.6 46564.28 46564.78 46564.53 -14.3 46578.78 46579.28 46579.03 -2.2 46593.16 46593.66 46593.41 -23.4 46607.66 46608.16 46607.91 4.8 46622.16 46622.66 46622.41 16.8 46636.59 46637.09 46636.84 12.6 46651.16 46651.66 46651.41 3.9 46665.66 46666.16 46665.91 7.1 46680.22 46680.72 46680.47 14.3 46694.59 46695.09 46694.84 23.5 46709.09 46709.59 46709.34 -11.0 46723.66 46724.16 46723.91 16.0 46738.16 46738.66 46738.41 -2.0 46752.59 46753.09 46752.84 13.5 46767.16 46767.66 46767.41 0.8 46781.66 46782.16 46781.91 1.0 46796.09 46796.59 46796.34 -0.8 46810.59 46811.09 46810.84 -1.3 46825.16 46825.66 46825.41 3.7 46839.59 46840.09 46839.84 8.8 46854.16 46854.66 46854.41 -14.6 46868.59 46869.09 46868.84 19.9 46883.09 46883.59 46883.34 -0.5 46897.59 46898.09 46897.84 -4.0 46912.16 46912.66 46912.41 -14.5 46926.66 46927.16 46926.91 16.8 46941.16 46941.66 46941.41 -12.0 46955.59 46956.09 46955.84 8.6 46970.16 46970.66 46970.41 -2.1 46984.59 46985.09 46984.84 13.2 46999.09 46999.59 46999.34 1.3 47100.84 47101.34 47101.09 5.6 47115.41 47115.91 47115.66 -0.2 47129.84 47130.34 47130.09 -10.4 47144.34 47144.84 47144.59 7.0 47158.91 47159.41 47159.16 11.0 47173.34 47173.84 47173.59 12.2 47187.72 47188.22 47187.97 9.3 47202.22 47202.72 47202.47 -2.0 47216.72 47217.22 47216.97 3.8 47231.22 47231.72 47231.47 -8.1 47245.84 47246.34 47246.09 0.8 47260.34 47260.84 47260.59 2.6 47351.66 47352.16 47351.91 5.8 47366.16 47366.66 47366.41 9.1 47380.66 47381.16 47380.91 7.0 47395.09 47395.59 47395.34 6.7 47409.66 47410.16 47409.91 2.2 47424.16 47424.66 47424.41 6.6 47438.59 47439.09 47438.84 11.9 47453.16 47453.66 47453.41 12.9 47467.59 47468.09 47467.84 19.8 47482.16 47482.66 47482.41 5.7 47496.59 47497.09 47496.84 8.7 47511.09 47511.59 47511.34 35.7 47525.66 47526.16 47525.91 -2.8 47540.22 47540.72 47540.47 10.9 47585.53 47586.03 47585.78 8.8 47600.03 47600.53 47600.28 9.9 47614.53 47615.03 47614.78 -4.2 47628.97 47629.47 47629.22 19.0 47643.53 47644.03 47643.78 2.7 47658.03 47658.53 47658.28 9.1 47672.47 47672.97 47672.72 23.0 47686.84 47687.34 47687.09 7.0 47701.41 47701.91 47701.66 7.3 47715.91 47716.41 47716.16 -7.9 47730.47 47730.97 47730.72 16.1 47744.97 47745.47 47745.22 22.1 47759.53 47760.03 47759.78 -8.8 47773.97 47774.47 47774.22 10.3 47788.41 47788.91 47788.66 -6.8 47802.84 47803.34 47803.09 10.8 47817.34 47817.84 47817.59 6.1 47831.84 47832.34 47832.09 -10.5 47846.41 47846.91 47846.66 -3.4 47860.84 47861.34 47861.09 20.9 47875.53 47876.03 47875.78 -16.8 47889.97 47890.47 47890.22 14.8 47904.34 47904.84 47904.59 29.5 47918.91 47919.41 47919.16 -26.7 47933.41 47933.91 47933.66 -15.9 47947.84 47948.34 47948.09 -1.1 47962.41 47962.91 47962.66 26.7 47976.84 47977.34 47977.09 -3.4 47991.41 47991.91 47991.66 7.1 48090.97 48091.47 48091.22 17.9 48105.47 48105.97 48105.72 4.1 48119.91 48120.41 48120.16 -15.6 48134.34 48134.84 48134.59 6.9 48148.84 48149.34 48149.09 16.2 48163.41 48163.91 48163.66 -22.0 48177.91 48178.41 48178.16 -0.5 48192.34 48192.84 48192.59 19.2 48206.84 48207.34 48207.09 -0.4 48221.34 48221.84 48221.59 18.8 48235.84 48236.34 48236.09 -8.6 48250.34 48250.84 48250.59 -9.6 48264.84 48265.34 48265.09 13.1 48279.41 48279.91 48279.66 5.4 48293.91 48294.41 48294.16 -21.2 48308.34 48308.84 48308.59 30.1 48322.84 48323.34 48323.09 27.3 48337.41 48337.91 48337.66 0.6 48351.91 48352.41 48352.16 -1.5 48366.34 48366.84 48366.59 15.4 48380.84 48381.34 48381.09 2.9 48395.34 48395.84 48395.59 4.8 48409.84 48410.34 48410.09 -9.7 48424.34 48424.84 48424.59 28.7 48438.84 48439.34 48439.09 11.4 48453.34 48453.84 48453.59 13.3 48467.84 48468.34 48468.09 32.4 48482.34 48482.84 48482.59 2.8 48496.84 48497.34 48497.09 -9.1 48511.41 48511.91 48511.66 6.2 48525.84 48526.34 48526.09 13.9 48540.34 48540.84 48540.59 3.7 48554.91 48555.41 48555.16 -19.4 48569.34 48569.84 48569.59 13.3 48583.91 48584.41 48584.16 13.0 48598.34 48598.84 48598.59 9.2 48612.91 48613.41 48613.16 -21.0 48627.34 48627.84 48627.59 3.1 48641.84 48642.34 48642.09 28.0 48656.41 48656.91 48656.66 3.2 48670.91 48671.41 48671.16 -3.4 48685.34 48685.84 48685.59 -2.5 48699.84 48700.34 48700.09 6.3 48714.34 48714.84 48714.59 21.7 48728.84 48729.34 48729.09 12.2 48743.34 48743.84 48743.59 0.0 48757.84 48758.34 48758.09 12.2 48772.34 48772.84 48772.59 10.5 48786.84 48787.34 48787.09 -7.2 48801.34 48801.84 48801.59 1.9 48815.91 48816.41 48816.16 8.9 48830.34 48830.84 48830.59 14.9 48844.84 48845.34 48845.09 8.0 48859.34 48859.84 48859.59 8.8 48873.84 48874.34 48874.09 12.0 48888.34 48888.84 48888.59 11.9 48902.84 48903.34 48903.09 -3.3 48917.34 48917.84 48917.59 13.7 48931.84 48932.34 48932.09 2.2 48946.34 48946.84 48946.59 12.1 48960.84 48961.34 48961.09 23.8 48975.34 48975.84 48975.59 15.2 48989.84 48990.34 48990.09 9.8 49215.91 49216.41 49216.16 5.0 49230.41 49230.91 49230.66 -0.5 49244.91 49245.41 49245.16 1.1 49259.41 49259.91 49259.66 -10.3 49273.78 49274.28 49274.03 -4.1 49288.22 49288.72 49288.47 18.0 49302.72 49303.22 49302.97 9.2 49317.22 49317.72 49317.47 15.0 49331.72 49332.22 49331.97 6.7 49346.28 49346.78 49346.53 -0.8 49360.91 49361.41 49361.16 6.3 49375.28 49375.78 49375.53 18.4 49389.72 49390.22 49389.97 10.1 49404.28 49404.78 49404.53 -1.2 49418.72 49419.22 49418.97 6.4 49433.28 49433.78 49433.53 -2.4 49447.72 49448.22 49447.97 9.1 49462.28 49462.78 49462.53 -6.6 49476.72 49477.22 49476.97 5.6 49491.22 49491.72 49491.47 0.9 49505.72 49506.22 49505.97 10.6 49520.22 49520.72 49520.47 1.3 49534.72 49535.22 49534.97 5.7 49549.22 49549.72 49549.47 8.4 49563.72 49564.22 49563.97 6.1 49578.28 49578.78 49578.53 7.3 49592.72 49593.22 49592.97 -0.9 49607.28 49607.78 49607.53 18.8 49621.78 49622.28 49622.03 -15.9 49636.22 49636.72 49636.47 10.5 49650.78 49651.28 49651.03 3.5 49665.22 49665.72 49665.47 6.9 49679.72 49680.22 49679.97 8.9 49694.22 49694.72 49694.47 5.0 49708.72 49709.22 49708.97 -1.0 49723.22 49723.72 49723.47 2.0 49737.78 49738.28 49738.03 8.4 49752.22 49752.72 49752.47 9.8 49766.72 49767.22 49766.97 1.5 49781.22 49781.72 49781.47 -5.0 49795.72 49796.22 49795.97 11.1 49810.22 49810.72 49810.47 14.3 49824.72 49825.22 49824.97 0.7 49839.28 49839.78 49839.53 14.5 49853.78 49854.28 49854.03 10.6 49868.22 49868.72 49868.47 1.0 49882.78 49883.28 49883.03 2.6 49897.22 49897.72 49897.47 -6.6 49911.72 49912.22 49911.97 7.1 49926.22 49926.72 49926.47 8.4 49940.72 49941.22 49940.97 11.5 49955.22 49955.72 49955.47 8.2 49969.72 49970.22 49969.97 -1.6 49984.22 49984.72 49984.47 -7.0 49998.72 49999.22 49998.97 -8.4 50013.28 50013.78 50013.53 -6.1 50027.72 50028.22 50027.97 24.3 50042.22 50042.72 50042.47 -4.0 50056.78 50057.28 50057.03 -5.6 50071.22 50071.72 50071.47 6.2 50085.72 50086.22 50085.97 21.3 50100.22 50100.72 50100.47 -9.6 50114.72 50115.22 50114.97 -9.4 50215.84 50216.34 50216.09 4.2 50230.34 50230.84 50230.59 -1.8 50244.84 50245.34 50245.09 10.3 50259.34 50259.84 50259.59 1.8 50273.91 50274.41 50274.16 -1.7 50288.41 50288.91 50288.66 3.6 50302.91 50303.41 50303.16 17.1 50317.34 50317.84 50317.59 18.1 50385.84 50386.34 50386.09 -7.6 50400.34 50400.84 50400.59 -17.2 50414.84 50415.34 50415.09 8.5 50429.34 50429.84 50429.59 6.0 50443.84 50444.34 50444.09 13.0 50458.34 50458.84 50458.59 3.8 50472.84 50473.34 50473.09 12.3 50487.41 50487.91 50487.66 -11.7 50501.84 50502.34 50502.09 25.1 50516.41 50516.91 50516.66 18.9 50530.91 50531.41 50531.16 0.2 50545.34 50545.84 50545.59 -0.5 50559.91 50560.41 50560.16 -10.2 50574.34 50574.84 50574.59 27.9 50588.84 50589.34 50589.09 -8.4 50603.34 50603.84 50603.59 5.5 50617.84 50618.34 50618.09 4.9 50632.34 50632.84 50632.59 -1.2 50646.84 50647.34 50647.09 6.8 50661.34 50661.84 50661.59 1.4 50675.84 50676.34 50676.09 -4.6 50690.34 50690.84 50690.59 -1.8 50704.84 50705.34 50705.09 -3.8 50719.34 50719.84 50719.59 -3.1 50733.84 50734.34 50734.09 9.0 50748.41 50748.91 50748.66 8.7 50762.91 50763.41 50763.16 -1.8 50777.34 50777.84 50777.59 5.8 50791.84 50792.34 50792.09 -21.2 50806.34 50806.84 50806.59 -9.0 50820.91 50821.41 50821.16 6.9 50835.34 50835.84 50835.59 11.2 50849.84 50850.34 50850.09 1.8 50864.34 50864.84 50864.59 22.1 50878.84 50879.34 50879.09 -1.1 50893.34 50893.84 50893.59 12.3 50907.84 50908.34 50908.09 -17.8 50922.34 50922.84 50922.59 -19.2 50936.84 50937.34 50937.09 -12.6 50951.34 50951.84 50951.59 -17.1 50965.84 50966.34 50966.09 -1.3 50980.34 50980.84 50980.59 3.4 50994.84 50995.34 50995.09 -5.9 51009.34 51009.84 51009.59 -21.4 51023.84 51024.34 51024.09 -6.5 51038.34 51038.84 51038.59 -4.1 51052.84 51053.34 51053.09 3.6 51067.34 51067.84 51067.59 3.5 51081.84 51082.34 51082.09 11.1 51096.34 51096.84 51096.59 11.6 51110.91 51111.41 51111.16 1.9 51210.91 51211.41 51211.16 30.2 51225.34 51225.84 51225.59 -6.7 51239.84 51240.34 51240.09 14.3 51254.34 51254.84 51254.59 -0.4 51268.84 51269.34 51269.09 -5.1 51283.41 51283.91 51283.66 -0.3 51297.84 51298.34 51298.09 -17.5 51312.41 51312.91 51312.66 -5.3 51326.84 51327.34 51327.09 -2.1 51341.41 51341.91 51341.66 -8.4 51355.91 51356.41 51356.16 -3.7 51370.34 51370.84 51370.59 3.9 51384.84 51385.34 51385.09 11.8 51399.34 51399.84 51399.59 12.0 51413.84 51414.34 51414.09 2.4 51428.34 51428.84 51428.59 11.4 51442.84 51443.34 51443.09 19.9 51457.22 51457.72 51457.47 11.3 51471.72 51472.22 51471.97 -1.5 51486.22 51486.72 51486.47 9.7 51500.84 51501.34 51501.09 -5.9 51515.34 51515.84 51515.59 5.6 51529.84 51530.34 51530.09 -12.1 51544.34 51544.84 51544.59 3.5 51558.84 51559.34 51559.09 0.0 51573.22 51573.72 51573.47 24.9 51587.72 51588.22 51587.97 7.2 51602.22 51602.72 51602.47 -1.7 51616.72 51617.22 51616.97 -11.9 51631.22 51631.72 51631.47 7.5 51645.84 51646.34 51646.09 -17.2 51660.34 51660.84 51660.59 -1.7 51674.72 51675.22 51674.97 -1.0 51689.28 51689.78 51689.53 -9.9 51703.72 51704.22 51703.97 -7.3 51718.22 51718.72 51718.47 13.5 51732.72 51733.22 51732.97 12.4 51747.22 51747.72 51747.47 -17.0 51761.72 51762.22 51761.97 -5.5 51776.22 51776.72 51776.47 -8.7 51790.72 51791.22 51790.97 -13.8 51805.22 51805.72 51805.47 -4.1 51819.78 51820.28 51820.03 -18.2 51834.22 51834.72 51834.47 -6.9 51848.72 51849.22 51848.97 4.8 51863.22 51863.72 51863.47 -2.0 51877.72 51878.22 51877.97 7.2 51892.22 51892.72 51892.47 -4.6 51906.78 51907.28 51907.03 0.2 51921.28 51921.78 51921.53 3.9 51935.72 51936.22 51935.97 2.3 51950.28 51950.78 51950.53 0.2 51964.72 51965.22 51964.97 -6.0 51979.22 51979.72 51979.47 25.3 51993.72 51994.22 51993.97 -12.8 52008.28 52008.78 52008.53 -5.5 52022.72 52023.22 52022.97 12.7 52037.22 52037.72 52037.47 -19.5 52051.72 52052.22 52051.97 2.9 52066.22 52066.72 52066.47 21.6 52080.72 52081.22 52080.97 11.6 52095.22 52095.72 52095.47 -3.5 52109.72 52110.22 52109.97 -13.1 52665.09 52665.59 52665.34 0.3 52679.59 52680.09 52679.84 14.7 52694.09 52694.59 52694.34 -20.1 52708.66 52709.16 52708.91 -5.3 52723.16 52723.66 52723.41 6.4 52737.59 52738.09 52737.84 -5.6 52752.09 52752.59 52752.34 5.3 52766.47 52766.97 52766.72 12.1 52781.03 52781.53 52781.28 7.7 52795.47 52795.97 52795.72 11.8 52810.09 52810.59 52810.34 7.1 52824.66 52825.16 52824.91 6.1 52839.09 52839.59 52839.34 -2.1 52853.59 52854.09 52853.84 7.8 52868.09 52868.59 52868.34 -8.9 52882.47 52882.97 52882.72 15.7 52896.97 52897.47 52897.22 11.3 52911.47 52911.97 52911.72 -4.4 52925.97 52926.47 52926.22 10.6 52940.47 52940.97 52940.72 4.4 52955.16 52955.66 52955.41 -6.3 52969.66 52970.16 52969.91 9.7 52983.97 52984.47 52984.22 -7.1 52998.47 52998.97 52998.72 1.7 53012.97 53013.47 53013.22 -1.1 53041.97 53042.47 53042.22 0.8 53056.47 53056.97 53056.72 5.1 53070.97 53071.47 53071.22 4.8 53085.53 53086.03 53085.78 5.1 53099.97 53100.47 53100.22 3.8 53114.53 53115.03 53114.78 -2.0 53129.03 53129.53 53129.28 5.3 53143.47 53143.97 53143.72 7.1 53157.97 53158.47 53158.22 9.4 53172.47 53172.97 53172.72 22.6 53187.03 53187.53 53187.28 6.9 53363.03 53363.53 53363.28 28.2 53377.47 53377.97 53377.72 28.3 53391.97 53392.47 53392.22 34.0 53406.47 53406.97 53406.72 17.2 53421.03 53421.53 53421.28 19.6 53435.47 53435.97 53435.72 22.0 53449.97 53450.47 53450.22 24.6 53464.47 53464.97 53464.72 31.1 53478.97 53479.47 53479.22 16.0 53493.47 53493.97 53493.72 13.6 53508.03 53508.53 53508.28 19.3 53522.47 53522.97 53522.72 13.5 53536.97 53537.47 53537.22 8.6 53551.47 53551.97 53551.72 4.7 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