43 1001 Wennberg, Paul California Institute of Technology Gas Phase Nitric Acid from DC-8 TC4 1 1 2007 07 24 2011 09 07 0 start_UTC, s 3 1 1 1 999999 999999 999999 stop_UTC, s mid_UTC, s HNO3, pptv 0 26 PI_CONTACT_INFO: Address: California Institute of Technology. MC 150-21. 1200 E. California Blvd, Pasadena, CA, 91125. Phone: (626) 395-2447. Fax: (626) 585-1917. email: wennberg@gps.caltech.edu PLATFORM: NASA DC-8 airborne laboratory. LOCATION: Aircraft location data in file TN_20070724.DC8. ASSOCIATED_DATA: N/A INSTRUMENT_INFO: Chemical Ionization Mass Spectrometer. Direct measurements in ambient air. DATA_INFO: Measurements are reported as 0.5 sec averages and in units of pptv. CAUTION: Do not extrapolate data outside of given time interval as these are discrete measurements. Calibration was conducted ~once per hour during the flight using isotopically labeled nitric acid evolved from a perm tube held at constant temperature. Absolute calibration was obtained by collection in water and subsequent ion chromatography. Zeros were conducted ~3 times per hour by passing ambient air through a filter containing nylon wool coated with NaHCO3. UNCERTAINTY: +-(50% of measuremlent value + 50 pptv) ULOD_FLAG: 7777777 ULOD_VALUE: N/A LLOD_FLAG: 8888888 LLOD_VALUE: N/A; N/A; N/A; DM_CONTACT_INFO: John Crounse. California Institute of Technology. Department of Chemistry and Chemical Engineering. MC 150-21. 1200 E. California Blvd. Pasadena, CA 91125. Phone: (626) 395-6868. Fax: (626) 585-1917. email: crounjd@caltech.edu. PROJECT_INFO: TC4 study; 13 July-13 August 2007; Study of cloud processing and tropical convection processes STIPULATIONS_ON_USE: Use of these data requires PI notification and adherence to the TC4 data protocol. OTHER_COMMENTS: N/A REVISION: R1 R1: ULOD and LLOD flags changed to positive values, to conform to Ames format 2.1 specifications. R0: Preliminary Data Revision 0. Water correction has been applied using CIT-CIMS water. Reduction code 1.5 start_UTC stop_UTC mid_UTC HNO3 46117.91 46118.41 46118.16 112.7 46132.41 46132.91 46132.66 89.9 46242.78 46243.28 46243.03 5.7 46257.28 46257.78 46257.53 28.3 46271.78 46272.28 46272.03 -1.1 46286.28 46286.78 46286.53 2.8 46315.28 46315.78 46315.53 163.0 46329.78 46330.28 46330.03 196.4 46344.28 46344.78 46344.53 179.4 46358.78 46359.28 46359.03 244.4 46373.16 46373.66 46373.41 163.6 46387.78 46388.28 46388.03 137.6 46402.28 46402.78 46402.53 163.7 46416.78 46417.28 46417.03 131.5 46431.28 46431.78 46431.53 120.4 46445.78 46446.28 46446.03 105.6 46460.28 46460.78 46460.53 129.2 46474.66 46475.16 46474.91 105.6 46489.16 46489.66 46489.41 129.5 46503.66 46504.16 46503.91 99.4 46518.16 46518.66 46518.41 106.8 46532.78 46533.28 46533.03 90.4 46547.28 46547.78 46547.53 105.1 46561.78 46562.28 46562.03 81.6 46576.28 46576.78 46576.53 74.2 46590.66 46591.16 46590.91 59.0 46605.16 46605.66 46605.41 54.1 46619.66 46620.16 46619.91 34.8 46634.16 46634.66 46634.41 80.3 46648.66 46649.16 46648.91 50.4 46663.16 46663.66 46663.41 34.7 46677.66 46678.16 46677.91 1.6 46692.16 46692.66 46692.41 8.1 46706.66 46707.16 46706.91 20.0 46721.16 46721.66 46721.41 4.6 46735.66 46736.16 46735.91 15.5 46750.16 46750.66 46750.41 39.6 46764.66 46765.16 46764.91 -3.4 46779.16 46779.66 46779.41 12.5 46793.66 46794.16 46793.91 1.6 46808.16 46808.66 46808.41 18.4 46822.66 46823.16 46822.91 -5.4 46837.16 46837.66 46837.41 5.7 46851.66 46852.16 46851.91 39.8 46866.16 46866.66 46866.41 16.1 46880.66 46881.16 46880.91 6.9 46895.16 46895.66 46895.41 24.9 46909.66 46910.16 46909.91 36.5 46924.16 46924.66 46924.41 15.8 46938.66 46939.16 46938.91 16.2 46953.16 46953.66 46953.41 30.8 46967.66 46968.16 46967.91 17.7 46982.16 46982.66 46982.41 -13.2 46996.66 46997.16 46996.91 8.0 47098.41 47098.91 47098.66 113.5 47112.91 47113.41 47113.16 63.0 47127.41 47127.91 47127.66 63.1 47141.91 47142.41 47142.16 42.9 47156.41 47156.91 47156.66 92.8 47170.91 47171.41 47171.16 57.4 47185.28 47185.78 47185.53 47.4 47199.78 47200.28 47200.03 44.4 47214.28 47214.78 47214.53 70.2 47228.78 47229.28 47229.03 39.9 47243.41 47243.91 47243.66 22.0 47257.91 47258.41 47258.16 0.7 47349.16 47349.66 47349.41 0.0 47363.66 47364.16 47363.91 11.5 47378.16 47378.66 47378.41 -25.0 47392.66 47393.16 47392.91 -0.2 47407.09 47407.59 47407.34 54.6 47421.66 47422.16 47421.91 21.9 47436.09 47436.59 47436.34 84.2 47450.66 47451.16 47450.91 16.4 47465.16 47465.66 47465.41 19.1 47479.66 47480.16 47479.91 15.5 47494.16 47494.66 47494.41 40.0 47508.66 47509.16 47508.91 28.8 47523.16 47523.66 47523.41 17.3 47537.66 47538.16 47537.91 -14.8 47583.03 47583.53 47583.28 22.9 47597.47 47597.97 47597.72 55.7 47612.03 47612.53 47612.28 9.0 47626.53 47627.03 47626.78 29.2 47641.03 47641.53 47641.28 42.3 47655.53 47656.03 47655.78 14.2 47669.97 47670.47 47670.22 18.5 47684.41 47684.91 47684.66 -2.0 47698.91 47699.41 47699.16 -15.9 47713.41 47713.91 47713.66 28.7 47727.97 47728.47 47728.22 31.4 47742.53 47743.03 47742.78 -2.0 47756.97 47757.47 47757.22 22.3 47771.53 47772.03 47771.78 16.1 47786.03 47786.53 47786.28 -0.3 47800.41 47800.91 47800.66 5.6 47814.84 47815.34 47815.09 12.8 47829.41 47829.91 47829.66 -3.7 47843.91 47844.41 47844.16 6.7 47858.34 47858.84 47858.59 6.7 47873.03 47873.53 47873.28 -9.0 47887.47 47887.97 47887.72 36.5 47901.91 47902.41 47902.16 -18.5 47916.41 47916.91 47916.66 -5.4 47930.91 47931.41 47931.16 -2.7 47945.41 47945.91 47945.66 -29.0 47959.91 47960.41 47960.16 13.0 47974.34 47974.84 47974.59 33.7 47988.91 47989.41 47989.16 -11.0 48088.47 48088.97 48088.72 42.6 48103.03 48103.53 48103.28 5.7 48117.34 48117.84 48117.59 32.6 48131.84 48132.34 48132.09 11.1 48146.34 48146.84 48146.59 37.8 48160.91 48161.41 48161.16 -2.0 48175.41 48175.91 48175.66 -0.3 48189.91 48190.41 48190.16 -0.9 48204.41 48204.91 48204.66 32.4 48218.91 48219.41 48219.16 19.5 48233.41 48233.91 48233.66 10.3 48247.91 48248.41 48248.16 -5.6 48262.41 48262.91 48262.66 9.3 48276.91 48277.41 48277.16 19.5 48291.41 48291.91 48291.66 -1.0 48305.91 48306.41 48306.16 31.5 48320.41 48320.91 48320.66 31.7 48334.91 48335.41 48335.16 12.0 48349.41 48349.91 48349.66 32.1 48363.84 48364.34 48364.09 25.6 48378.41 48378.91 48378.66 -2.3 48392.84 48393.34 48393.09 23.5 48407.34 48407.84 48407.59 15.5 48421.91 48422.41 48422.16 13.2 48436.41 48436.91 48436.66 5.5 48450.91 48451.41 48451.16 4.0 48465.41 48465.91 48465.66 4.5 48479.84 48480.34 48480.09 11.4 48494.34 48494.84 48494.59 27.9 48508.84 48509.34 48509.09 9.8 48523.34 48523.84 48523.59 34.4 48537.84 48538.34 48538.09 14.4 48552.34 48552.84 48552.59 10.1 48566.91 48567.41 48567.16 -5.2 48581.41 48581.91 48581.66 -3.9 48595.84 48596.34 48596.09 11.0 48610.34 48610.84 48610.59 30.6 48624.91 48625.41 48625.16 -23.4 48639.34 48639.84 48639.59 9.6 48653.84 48654.34 48654.09 55.6 48668.34 48668.84 48668.59 35.2 48682.84 48683.34 48683.09 38.1 48697.41 48697.91 48697.66 25.5 48711.84 48712.34 48712.09 9.6 48726.34 48726.84 48726.59 33.4 48740.84 48741.34 48741.09 24.0 48755.41 48755.91 48755.66 -2.9 48769.91 48770.41 48770.16 -18.9 48784.41 48784.91 48784.66 2.4 48798.91 48799.41 48799.16 -7.6 48813.34 48813.84 48813.59 -2.4 48827.84 48828.34 48828.09 -1.7 48842.34 48842.84 48842.59 21.7 48856.91 48857.41 48857.16 -19.5 48871.34 48871.84 48871.59 -5.1 48885.91 48886.41 48886.16 -8.0 48900.41 48900.91 48900.66 -3.6 48914.84 48915.34 48915.09 -2.7 48929.34 48929.84 48929.59 31.0 48943.91 48944.41 48944.16 7.5 48958.41 48958.91 48958.66 28.6 48972.84 48973.34 48973.09 44.3 48987.34 48987.84 48987.59 21.5 49213.41 49213.91 49213.66 89.4 49227.84 49228.34 49228.09 59.0 49242.34 49242.84 49242.59 35.7 49256.91 49257.41 49257.16 10.5 49271.28 49271.78 49271.53 -0.4 49285.78 49286.28 49286.03 -3.3 49300.28 49300.78 49300.53 6.7 49314.78 49315.28 49315.03 4.3 49329.22 49329.72 49329.47 21.3 49343.78 49344.28 49344.03 32.8 49358.34 49358.84 49358.59 22.2 49372.84 49373.34 49373.09 28.4 49387.28 49387.78 49387.53 -2.8 49401.72 49402.22 49401.97 -7.7 49416.28 49416.78 49416.53 -6.3 49430.72 49431.22 49430.97 10.4 49445.22 49445.72 49445.47 4.9 49459.72 49460.22 49459.97 -6.1 49474.22 49474.72 49474.47 8.3 49488.72 49489.22 49488.97 11.6 49503.22 49503.72 49503.47 -16.7 49517.72 49518.22 49517.97 1.5 49532.22 49532.72 49532.47 -6.0 49546.72 49547.22 49546.97 -14.4 49561.22 49561.72 49561.47 -18.4 49575.72 49576.22 49575.97 9.3 49590.28 49590.78 49590.53 -12.5 49604.78 49605.28 49605.03 -21.8 49619.22 49619.72 49619.47 -4.7 49633.72 49634.22 49633.97 22.2 49648.22 49648.72 49648.47 45.9 49662.72 49663.22 49662.97 55.6 49677.28 49677.78 49677.53 29.0 49691.72 49692.22 49691.97 32.3 49706.28 49706.78 49706.53 37.3 49720.72 49721.22 49720.97 33.4 49735.22 49735.72 49735.47 36.8 49749.72 49750.22 49749.97 10.1 49764.22 49764.72 49764.47 35.0 49778.78 49779.28 49779.03 26.1 49793.28 49793.78 49793.53 4.2 49807.72 49808.22 49807.97 -13.3 49822.22 49822.72 49822.47 13.8 49836.72 49837.22 49836.97 12.5 49851.22 49851.72 49851.47 -1.9 49865.78 49866.28 49866.03 -7.7 49880.22 49880.72 49880.47 -4.8 49894.72 49895.22 49894.97 9.8 49909.22 49909.72 49909.47 -10.1 49923.72 49924.22 49923.97 -15.7 49938.28 49938.78 49938.53 -32.5 49952.72 49953.22 49952.97 -3.3 49967.22 49967.72 49967.47 -11.1 49981.72 49982.22 49981.97 -16.4 49996.22 49996.72 49996.47 -26.6 50010.78 50011.28 50011.03 -27.3 50025.28 50025.78 50025.53 -21.9 50039.72 50040.22 50039.97 13.2 50054.22 50054.72 50054.47 -0.2 50068.72 50069.22 50068.97 11.9 50083.28 50083.78 50083.53 3.4 50097.72 50098.22 50097.97 5.8 50112.22 50112.72 50112.47 33.8 50213.41 50213.91 50213.66 -5.4 50227.84 50228.34 50228.09 18.6 50242.34 50242.84 50242.59 37.7 50256.84 50257.34 50257.09 40.8 50271.41 50271.91 50271.66 6.8 50285.84 50286.34 50286.09 24.7 50300.34 50300.84 50300.59 21.5 50314.84 50315.34 50315.09 30.9 50383.34 50383.84 50383.59 1.5 50397.84 50398.34 50398.09 4.9 50412.34 50412.84 50412.59 2.3 50426.84 50427.34 50427.09 13.1 50441.34 50441.84 50441.59 12.5 50455.84 50456.34 50456.09 -12.0 50470.34 50470.84 50470.59 11.4 50484.91 50485.41 50485.16 -12.0 50499.34 50499.84 50499.59 3.2 50513.84 50514.34 50514.09 9.0 50528.34 50528.84 50528.59 16.6 50542.84 50543.34 50543.09 9.7 50557.34 50557.84 50557.59 14.7 50571.84 50572.34 50572.09 0.6 50586.34 50586.84 50586.59 2.3 50600.84 50601.34 50601.09 -6.7 50615.41 50615.91 50615.66 10.7 50629.84 50630.34 50630.09 6.8 50644.34 50644.84 50644.59 -9.8 50658.84 50659.34 50659.09 -4.4 50673.34 50673.84 50673.59 -21.6 50687.84 50688.34 50688.09 -23.9 50702.41 50702.91 50702.66 -13.9 50716.91 50717.41 50717.16 -3.2 50731.34 50731.84 50731.59 -0.3 50745.84 50746.34 50746.09 -4.2 50760.34 50760.84 50760.59 1.5 50774.84 50775.34 50775.09 12.8 50789.34 50789.84 50789.59 2.5 50803.84 50804.34 50804.09 -11.6 50818.34 50818.84 50818.59 1.1 50832.84 50833.34 50833.09 -31.4 50847.34 50847.84 50847.59 -17.9 50861.84 50862.34 50862.09 -29.0 50876.34 50876.84 50876.59 8.0 50890.84 50891.34 50891.09 -3.0 50905.34 50905.84 50905.59 -7.8 50919.84 50920.34 50920.09 -18.3 50934.34 50934.84 50934.59 -6.7 50948.91 50949.41 50949.16 -34.3 50963.41 50963.91 50963.66 1.0 50977.84 50978.34 50978.09 -21.3 50992.34 50992.84 50992.59 -23.3 51006.84 51007.34 51007.09 -44.3 51021.34 51021.84 51021.59 -21.7 51035.84 51036.34 51036.09 -33.6 51050.34 51050.84 51050.59 -0.9 51064.84 51065.34 51065.09 -9.7 51079.34 51079.84 51079.59 -9.7 51093.84 51094.34 51094.09 -26.0 51108.34 51108.84 51108.59 -8.1 51208.34 51208.84 51208.59 27.4 51222.91 51223.41 51223.16 -12.7 51237.34 51237.84 51237.59 18.7 51251.84 51252.34 51252.09 9.8 51266.41 51266.91 51266.66 2.8 51280.91 51281.41 51281.16 8.6 51295.34 51295.84 51295.59 16.1 51309.84 51310.34 51310.09 -12.7 51324.41 51324.91 51324.66 -0.4 51338.91 51339.41 51339.16 11.0 51353.41 51353.91 51353.66 7.1 51367.91 51368.41 51368.16 5.9 51382.34 51382.84 51382.59 24.2 51396.84 51397.34 51397.09 17.0 51411.34 51411.84 51411.59 1.1 51425.84 51426.34 51426.09 12.7 51440.34 51440.84 51440.59 14.7 51454.78 51455.28 51455.03 24.6 51469.22 51469.72 51469.47 -3.1 51483.72 51484.22 51483.97 -11.7 51498.34 51498.84 51498.59 22.3 51512.84 51513.34 51513.09 4.5 51527.34 51527.84 51527.59 -9.6 51541.84 51542.34 51542.09 14.5 51556.34 51556.84 51556.59 9.9 51570.72 51571.22 51570.97 -4.9 51585.22 51585.72 51585.47 12.4 51599.72 51600.22 51599.97 -4.4 51614.22 51614.72 51614.47 7.4 51628.72 51629.22 51628.97 10.2 51643.22 51643.72 51643.47 35.0 51657.91 51658.41 51658.16 -23.8 51672.34 51672.84 51672.59 -2.7 51686.72 51687.22 51686.97 15.5 51701.22 51701.72 51701.47 13.4 51715.72 51716.22 51715.97 -27.8 51730.28 51730.78 51730.53 -0.2 51744.78 51745.28 51745.03 -10.4 51759.22 51759.72 51759.47 25.3 51773.72 51774.22 51773.97 -1.7 51788.28 51788.78 51788.53 -14.0 51802.72 51803.22 51802.97 27.1 51817.22 51817.72 51817.47 8.3 51831.72 51832.22 51831.97 19.5 51846.22 51846.72 51846.47 5.9 51860.72 51861.22 51860.97 1.7 51875.22 51875.72 51875.47 11.2 51889.72 51890.22 51889.97 -9.1 51904.22 51904.72 51904.47 31.4 51918.78 51919.28 51919.03 16.9 51933.22 51933.72 51933.47 25.1 51947.72 51948.22 51947.97 4.3 51962.22 51962.72 51962.47 53.6 51976.72 51977.22 51976.97 31.7 51991.22 51991.72 51991.47 5.8 52005.78 52006.28 52006.03 3.8 52020.22 52020.72 52020.47 24.2 52034.78 52035.28 52035.03 -0.0 52049.22 52049.72 52049.47 24.1 52063.72 52064.22 52063.97 7.8 52078.22 52078.72 52078.47 18.7 52092.78 52093.28 52093.03 -27.3 52107.22 52107.72 52107.47 13.6 52923.47 52923.97 52923.72 31.9 52937.97 52938.47 52938.22 39.3 52952.59 52953.09 52952.84 46.9 52967.09 52967.59 52967.34 16.7 52981.59 52982.09 52981.84 26.2 52995.97 52996.47 52996.22 33.3 53010.53 53011.03 53010.78 6.5 53024.97 53025.47 53025.22 26.8 53039.47 53039.97 53039.72 3.5 53054.03 53054.53 53054.28 48.6 53068.47 53068.97 53068.72 43.4 53082.97 53083.47 53083.22 36.0 53097.47 53097.97 53097.72 38.2 53112.03 53112.53 53112.28 48.3 53126.47 53126.97 53126.72 76.5 53140.97 53141.47 53141.22 48.2 53155.47 53155.97 53155.72 34.8 53169.97 53170.47 53170.22 59.0 53184.47 53184.97 53184.72 93.5 53360.47 53360.97 53360.72 23.8 53375.03 53375.53 53375.28 12.7 53389.47 53389.97 53389.72 23.2 53403.97 53404.47 53404.22 24.0 53418.53 53419.03 53418.78 -14.6 53432.97 53433.47 53433.22 27.9 53447.47 53447.97 53447.72 42.7 53461.97 53462.47 53462.22 63.5 53476.47 53476.97 53476.72 4.6 53490.97 53491.47 53491.22 -1.4 53505.53 53506.03 53505.78 6.9 53519.97 53520.47 53520.22 -8.5 53534.47 53534.97 53534.72 7.1 53548.97 53549.47 53549.22 14.8 53655.34 53655.84 53655.59 95.3 53669.91 53670.41 53670.16 122.5 53684.41 53684.91 53684.66 94.1 53698.84 53699.34 53699.09 67.8 53713.34 53713.84 53713.59 51.6 53727.91 53728.41 53728.16 46.6 53742.34 53742.84 53742.59 62.8 53756.72 53757.22 53756.97 66.2 53771.22 53771.72 53771.47 58.1 53785.72 53786.22 53785.97 50.5 53920.97 53921.47 53921.22 102.3 53935.53 53936.03 53935.78 78.0 53950.03 53950.53 53950.28 74.7 53964.47 53964.97 53964.72 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