41 1001 Wennberg, Paul California Institute of Technology Gas Phase Hydrogen Cyanide from DC-8 TC4 1 1 2007 07 24 2007 08 02 0 start_UTC, s 3 1 1 1 999999 999999 999999 stop_UTC, s mid_UTC, s HCN, pptv 0 24 PI_CONTACT_INFO: Address: California Institute of Technology. MC 150-21. 1200 E. California Blvd, Pasadena, CA, 91125. Phone: (626) 395-2447. Fax: (626) 585-1917. email: wennberg@gps.caltech.edu PLATFORM: NASA DC-8 airborne laboratory. LOCATION: Aircraft location data in file TN_20070724.DC8. ASSOCIATED_DATA: N/A INSTRUMENT_INFO: Chemical Ionization Mass Spectrometer. Direct measurements in ambient air. DATA_INFO: Measurements are reported as 0.5 sec averages and in units of pptv. CAUTION: Do not extrapolate data outside of given time interval as these are discrete measurements. Calibration was conducted ~once per hour during the flight using H2O2 and HNO3 calibrants, and proxied to HCN using laboratory calibrations. Absolute calibration was obtained in the laboratory by FTIR spectroscopy. Zeros were conducted ~3 times per hour by passing ambient air through a filter containing nylon wool coated with NaHCO3. UNCERTAINTY: +-(50% of measuremlent value + 50 pptv) ULOD_FLAG: -7777 ULOD_VALUE: N/A LLOD_FLAG: -8888 LLOD_VALUE: N/A; N/A; N/A; DM_CONTACT_INFO: John Crounse. California Institute of Technology. Department of Chemistry and Chemical Engineering. MC 150-21. 1200 E. California Blvd. Pasadena, CA 91125. Phone: (626) 395-6868. Fax: (626) 585-1917. email: crounjd@caltech.edu. PROJECT_INFO: TC4 study; 13 July-13 August 2007; Study of cloud processing and tropical convection processes STIPULATIONS_ON_USE: Use of these data requires PI notification and adherence to the TC4 data protocol. OTHER_COMMENTS: N/A REVISION: R0 R0: Preliminary Data Revision 0. Water correction has been applied using CIT-CIMS water. Reduction code 1.5 start_UTC(s) stop_UTC(s) mid_UTC(s) HCN(pptv) 46107.34 46107.84 46107.59 12.9 46121.91 46122.41 46122.16 21.8 46136.41 46136.91 46136.66 -9.6 46246.72 46247.22 46246.97 6.1 46261.22 46261.72 46261.47 -2.3 46275.72 46276.22 46275.97 -9.3 46290.22 46290.72 46290.47 -10.9 46304.72 46305.22 46304.97 124.6 46319.28 46319.78 46319.53 305.1 46333.72 46334.22 46333.97 352.6 46348.22 46348.72 46348.47 477.8 46362.66 46363.16 46362.91 225.9 46377.09 46377.59 46377.34 157.6 46391.72 46392.22 46391.97 150.9 46406.22 46406.72 46406.47 157.0 46420.72 46421.22 46420.97 171.4 46435.28 46435.78 46435.53 140.7 46449.78 46450.28 46450.03 160.5 46464.28 46464.78 46464.53 163.3 46493.09 46493.59 46493.34 178.3 46507.59 46508.09 46507.84 179.5 46522.09 46522.59 46522.34 179.6 46536.72 46537.22 46536.97 187.6 46551.28 46551.78 46551.53 161.1 46565.72 46566.22 46565.97 150.3 46580.22 46580.72 46580.47 176.8 46594.59 46595.09 46594.84 167.8 46609.09 46609.59 46609.34 151.5 46623.66 46624.16 46623.91 141.5 46638.09 46638.59 46638.34 159.4 46652.66 46653.16 46652.91 154.7 46667.09 46667.59 46667.34 181.9 46681.72 46682.22 46681.97 142.9 46696.09 46696.59 46696.34 142.0 46710.66 46711.16 46710.91 156.8 46725.09 46725.59 46725.34 152.7 46739.59 46740.09 46739.84 162.7 46754.09 46754.59 46754.34 154.7 46768.59 46769.09 46768.84 148.4 46783.09 46783.59 46783.34 144.3 46797.59 46798.09 46797.84 157.7 46812.16 46812.66 46812.41 147.0 46826.66 46827.16 46826.91 171.4 46841.16 46841.66 46841.41 135.7 46855.66 46856.16 46855.91 135.4 46870.09 46870.59 46870.34 151.3 46884.59 46885.09 46884.84 147.2 46899.09 46899.59 46899.34 173.5 46913.59 46914.09 46913.84 157.2 46928.09 46928.59 46928.34 160.1 46942.59 46943.09 46942.84 158.9 46957.16 46957.66 46957.41 141.6 46971.59 46972.09 46971.84 152.1 46986.09 46986.59 46986.34 165.0 47000.59 47001.09 47000.84 156.3 47102.34 47102.84 47102.59 153.3 47116.91 47117.41 47117.16 143.6 47131.41 47131.91 47131.66 154.2 47145.84 47146.34 47146.09 158.0 47160.41 47160.91 47160.66 148.5 47174.91 47175.41 47175.16 158.4 47189.22 47189.72 47189.47 156.6 47203.72 47204.22 47203.97 160.6 47218.22 47218.72 47218.47 136.3 47232.78 47233.28 47233.03 129.8 47247.34 47247.84 47247.59 142.6 47261.84 47262.34 47262.09 131.6 47353.09 47353.59 47353.34 123.5 47367.66 47368.16 47367.91 99.5 47382.09 47382.59 47382.34 116.7 47396.59 47397.09 47396.84 118.5 47411.16 47411.66 47411.41 141.8 47425.59 47426.09 47425.84 115.2 47440.09 47440.59 47440.34 119.8 47454.66 47455.16 47454.91 110.6 47469.09 47469.59 47469.34 127.6 47483.59 47484.09 47483.84 115.3 47498.09 47498.59 47498.34 103.5 47512.66 47513.16 47512.91 80.7 47527.16 47527.66 47527.41 101.1 47541.59 47542.09 47541.84 98.9 47587.03 47587.53 47587.28 68.1 47601.47 47601.97 47601.72 103.5 47615.97 47616.47 47616.22 106.3 47630.47 47630.97 47630.72 105.1 47644.97 47645.47 47645.22 69.2 47659.47 47659.97 47659.72 110.8 47673.97 47674.47 47674.22 88.6 47688.41 47688.91 47688.66 85.6 47702.84 47703.34 47703.09 71.7 47717.34 47717.84 47717.59 110.5 47731.97 47732.47 47732.22 93.9 47746.47 47746.97 47746.72 130.0 47760.97 47761.47 47761.22 91.5 47775.47 47775.97 47775.72 91.2 47789.84 47790.34 47790.09 83.8 47804.34 47804.84 47804.59 123.5 47818.84 47819.34 47819.09 107.4 47833.41 47833.91 47833.66 80.5 47847.91 47848.41 47848.16 60.9 47862.41 47862.91 47862.66 98.2 47876.97 47877.47 47877.22 101.1 47891.53 47892.03 47891.78 89.8 47905.91 47906.41 47906.16 80.3 47920.34 47920.84 47920.59 101.4 47934.84 47935.34 47935.09 99.4 47949.41 47949.91 47949.66 86.6 47963.84 47964.34 47964.09 76.7 47978.34 47978.84 47978.59 120.7 47992.84 47993.34 47993.09 81.5 48092.47 48092.97 48092.72 82.9 48107.03 48107.53 48107.28 79.4 48121.41 48121.91 48121.66 87.3 48135.84 48136.34 48136.09 80.1 48150.34 48150.84 48150.59 73.5 48164.84 48165.34 48165.09 71.7 48179.34 48179.84 48179.59 91.0 48193.84 48194.34 48194.09 84.5 48208.34 48208.84 48208.59 90.8 48222.84 48223.34 48223.09 82.6 48237.34 48237.84 48237.59 97.4 48251.84 48252.34 48252.09 81.3 48266.41 48266.91 48266.66 76.1 48280.84 48281.34 48281.09 87.8 48295.34 48295.84 48295.59 103.4 48309.84 48310.34 48310.09 104.5 48324.41 48324.91 48324.66 70.3 48338.84 48339.34 48339.09 91.7 48353.34 48353.84 48353.59 79.6 48367.91 48368.41 48368.16 78.0 48382.34 48382.84 48382.59 99.7 48396.84 48397.34 48397.09 111.9 48411.34 48411.84 48411.59 113.2 48425.84 48426.34 48426.09 100.4 48440.34 48440.84 48440.59 90.6 48454.84 48455.34 48455.09 89.0 48469.34 48469.84 48469.59 80.8 48483.84 48484.34 48484.09 94.7 48498.41 48498.91 48498.66 89.0 48512.84 48513.34 48513.09 73.7 48527.34 48527.84 48527.59 94.3 48541.84 48542.34 48542.09 100.8 48556.41 48556.91 48556.66 89.4 48570.91 48571.41 48571.16 80.6 48585.34 48585.84 48585.59 108.4 48599.91 48600.41 48600.16 88.4 48614.34 48614.84 48614.59 86.5 48628.84 48629.34 48629.09 88.1 48643.41 48643.91 48643.66 119.7 48657.84 48658.34 48658.09 98.5 48672.34 48672.84 48672.59 98.3 48686.91 48687.41 48687.16 97.4 48701.34 48701.84 48701.59 111.6 48715.84 48716.34 48716.09 95.1 48730.41 48730.91 48730.66 103.9 48744.91 48745.41 48745.16 96.7 48759.41 48759.91 48759.66 119.3 48773.84 48774.34 48774.09 98.2 48788.34 48788.84 48788.59 112.0 48802.84 48803.34 48803.09 100.5 48817.34 48817.84 48817.59 99.7 48831.84 48832.34 48832.09 98.5 48846.41 48846.91 48846.66 103.4 48860.84 48861.34 48861.09 100.1 48875.34 48875.84 48875.59 92.6 48889.84 48890.34 48890.09 97.8 48904.34 48904.84 48904.59 101.5 48918.84 48919.34 48919.09 98.0 48933.34 48933.84 48933.59 88.6 48947.84 48948.34 48948.09 113.0 48962.34 48962.84 48962.59 104.4 48976.84 48977.34 48977.09 96.7 48991.34 48991.84 48991.59 106.4 49217.34 49217.84 49217.59 108.8 49231.84 49232.34 49232.09 122.9 49246.41 49246.91 49246.66 100.8 49260.84 49261.34 49261.09 104.6 49275.22 49275.72 49275.47 101.1 49289.72 49290.22 49289.97 105.0 49304.22 49304.72 49304.47 121.7 49318.72 49319.22 49318.97 113.7 49333.22 49333.72 49333.47 115.3 49347.72 49348.22 49347.97 122.7 49362.34 49362.84 49362.59 117.4 49376.72 49377.22 49376.97 124.3 49391.22 49391.72 49391.47 128.2 49405.72 49406.22 49405.97 119.4 49420.22 49420.72 49420.47 96.2 49434.72 49435.22 49434.97 120.2 49449.28 49449.78 49449.53 109.0 49463.78 49464.28 49464.03 105.3 49478.22 49478.72 49478.47 119.4 49492.72 49493.22 49492.97 81.0 49507.28 49507.78 49507.53 97.8 49521.72 49522.22 49521.97 89.8 49536.22 49536.72 49536.47 105.9 49550.72 49551.22 49550.97 112.3 49565.28 49565.78 49565.53 94.6 49579.72 49580.22 49579.97 77.9 49594.22 49594.72 49594.47 133.5 49608.72 49609.22 49608.97 112.1 49623.22 49623.72 49623.47 116.5 49637.72 49638.22 49637.97 119.2 49652.22 49652.72 49652.47 125.9 49666.72 49667.22 49666.97 126.7 49681.22 49681.72 49681.47 121.9 49695.72 49696.22 49695.97 124.6 49710.22 49710.72 49710.47 120.1 49724.72 49725.22 49724.97 105.6 49739.28 49739.78 49739.53 111.8 49753.78 49754.28 49754.03 131.8 49768.22 49768.72 49768.47 116.8 49782.78 49783.28 49783.03 87.6 49797.22 49797.72 49797.47 119.9 49811.72 49812.22 49811.97 101.4 49826.22 49826.72 49826.47 107.0 49840.72 49841.22 49840.97 117.8 49855.22 49855.72 49855.47 117.6 49869.72 49870.22 49869.97 112.0 49884.22 49884.72 49884.47 99.3 49898.72 49899.22 49898.97 79.1 49913.22 49913.72 49913.47 94.0 49927.72 49928.22 49927.97 95.9 49942.22 49942.72 49942.47 73.3 49956.72 49957.22 49956.97 96.0 49971.22 49971.72 49971.47 104.7 49985.72 49986.22 49985.97 91.0 50000.22 50000.72 50000.47 76.3 50014.78 50015.28 50015.03 69.5 50029.22 50029.72 50029.47 61.3 50043.78 50044.28 50044.03 76.3 50058.22 50058.72 50058.47 58.1 50072.78 50073.28 50073.03 67.9 50087.22 50087.72 50087.47 72.2 50101.72 50102.22 50101.97 74.8 50116.22 50116.72 50116.47 59.6 50217.41 50217.91 50217.66 61.3 50231.84 50232.34 50232.09 72.7 50246.41 50246.91 50246.66 61.6 50260.84 50261.34 50261.09 79.1 50275.34 50275.84 50275.59 76.8 50289.84 50290.34 50290.09 73.6 50304.34 50304.84 50304.59 81.5 50318.84 50319.34 50319.09 69.2 50387.41 50387.91 50387.66 63.8 50401.84 50402.34 50402.09 65.1 50416.34 50416.84 50416.59 55.0 50430.84 50431.34 50431.09 46.3 50445.34 50445.84 50445.59 54.5 50459.84 50460.34 50460.09 51.1 50474.34 50474.84 50474.59 39.4 50488.84 50489.34 50489.09 29.9 50503.34 50503.84 50503.59 35.1 50517.91 50518.41 50518.16 41.0 50532.34 50532.84 50532.59 55.1 50546.84 50547.34 50547.09 61.3 50561.34 50561.84 50561.59 47.6 50575.84 50576.34 50576.09 32.2 50590.34 50590.84 50590.59 51.2 50604.84 50605.34 50605.09 46.3 50619.34 50619.84 50619.59 34.1 50633.84 50634.34 50634.09 50.7 50648.34 50648.84 50648.59 56.8 50662.91 50663.41 50663.16 58.6 50677.34 50677.84 50677.59 54.7 50691.84 50692.34 50692.09 58.8 50706.34 50706.84 50706.59 43.5 50720.84 50721.34 50721.09 53.0 50735.34 50735.84 50735.59 48.4 50749.91 50750.41 50750.16 67.4 50764.34 50764.84 50764.59 42.5 50778.91 50779.41 50779.16 35.5 50793.34 50793.84 50793.59 36.7 50807.84 50808.34 50808.09 39.0 50822.34 50822.84 50822.59 38.2 50836.84 50837.34 50837.09 17.5 50851.34 50851.84 50851.59 49.1 50865.91 50866.41 50866.16 34.9 50880.34 50880.84 50880.59 49.7 50894.84 50895.34 50895.09 32.5 50909.34 50909.84 50909.59 43.7 50923.84 50924.34 50924.09 32.4 50938.41 50938.91 50938.66 42.0 50952.84 50953.34 50953.09 38.9 50967.34 50967.84 50967.59 39.5 50981.91 50982.41 50982.16 34.3 50996.34 50996.84 50996.59 46.3 51010.84 51011.34 51011.09 50.5 51025.34 51025.84 51025.59 45.6 51039.84 51040.34 51040.09 32.0 51054.34 51054.84 51054.59 53.2 51068.84 51069.34 51069.09 59.5 51083.34 51083.84 51083.59 51.1 51097.91 51098.41 51098.16 52.8 51112.34 51112.84 51112.59 39.1 51212.41 51212.91 51212.66 34.5 51226.84 51227.34 51227.09 52.8 51241.34 51241.84 51241.59 47.0 51255.84 51256.34 51256.09 55.0 51270.41 51270.91 51270.66 31.7 51284.84 51285.34 51285.09 59.9 51299.34 51299.84 51299.59 55.1 51313.91 51314.41 51314.16 50.4 51328.34 51328.84 51328.59 53.0 51342.84 51343.34 51343.09 49.6 51357.41 51357.91 51357.66 57.3 51371.84 51372.34 51372.09 61.3 51386.34 51386.84 51386.59 63.9 51400.84 51401.34 51401.09 61.8 51415.41 51415.91 51415.66 51.4 51429.84 51430.34 51430.09 55.9 51444.41 51444.91 51444.66 56.4 51458.72 51459.22 51458.97 65.3 51473.22 51473.72 51473.47 56.6 51487.72 51488.22 51487.97 68.9 51502.34 51502.84 51502.59 67.8 51516.84 51517.34 51517.09 63.5 51531.34 51531.84 51531.59 56.7 51545.84 51546.34 51546.09 57.6 51560.34 51560.84 51560.59 71.3 51574.72 51575.22 51574.97 61.6 51589.22 51589.72 51589.47 72.0 51603.78 51604.28 51604.03 43.2 51618.22 51618.72 51618.47 59.6 51632.78 51633.28 51633.03 36.0 51647.34 51647.84 51647.59 54.7 51661.84 51662.34 51662.09 44.5 51676.22 51676.72 51676.47 52.1 51690.72 51691.22 51690.97 55.0 51705.22 51705.72 51705.47 35.7 51719.72 51720.22 51719.97 47.2 51734.22 51734.72 51734.47 52.2 51748.72 51749.22 51748.97 47.5 51763.28 51763.78 51763.53 74.0 51777.72 51778.22 51777.97 58.2 51792.28 51792.78 51792.53 72.5 51806.78 51807.28 51807.03 54.1 51821.28 51821.78 51821.53 69.9 51835.72 51836.22 51835.97 58.3 51850.22 51850.72 51850.47 48.2 51864.72 51865.22 51864.97 49.7 51879.22 51879.72 51879.47 65.6 51893.72 51894.22 51893.97 48.6 51908.22 51908.72 51908.47 54.6 51922.72 51923.22 51922.97 42.0 51937.28 51937.78 51937.53 55.7 51951.72 51952.22 51951.97 64.8 51966.22 51966.72 51966.47 49.3 51980.78 51981.28 51981.03 56.3 51995.22 51995.72 51995.47 43.3 52009.72 52010.22 52009.97 49.3 52024.28 52024.78 52024.53 40.7 52038.72 52039.22 52038.97 41.2 52053.22 52053.72 52053.47 53.1 52067.72 52068.22 52067.97 40.1 52082.22 52082.72 52082.47 46.6 52096.72 52097.22 52096.97 42.7 52111.28 52111.78 52111.53 49.3 52666.59 52667.09 52666.84 109.4 52681.09 52681.59 52681.34 119.9 52695.59 52696.09 52695.84 117.0 52710.16 52710.66 52710.41 105.2 52724.59 52725.09 52724.84 98.2 52739.09 52739.59 52739.34 118.8 52753.59 52754.09 52753.84 110.6 52767.97 52768.47 52768.22 104.7 52782.47 52782.97 52782.72 113.4 52796.97 52797.47 52797.22 107.1 52811.59 52812.09 52811.84 110.9 52826.09 52826.59 52826.34 98.5 52840.59 52841.09 52840.84 90.4 52855.09 52855.59 52855.34 111.6 52869.59 52870.09 52869.84 107.9 52883.97 52884.47 52884.22 115.9 52898.53 52899.03 52898.78 92.6 52913.03 52913.53 52913.28 109.7 52927.47 52927.97 52927.72 123.3 52941.97 52942.47 52942.22 117.5 52956.59 52957.09 52956.84 108.7 52971.09 52971.59 52971.34 118.9 52985.53 52986.03 52985.78 101.9 52999.97 53000.47 53000.22 104.6 53014.47 53014.97 53014.72 103.0 53028.97 53029.47 53029.22 150.7 53043.47 53043.97 53043.72 142.5 53058.03 53058.53 53058.28 129.6 53072.47 53072.97 53072.72 160.0 53086.97 53087.47 53087.22 167.6 53101.47 53101.97 53101.72 147.7 53115.97 53116.47 53116.22 147.3 53130.47 53130.97 53130.72 147.7 53144.97 53145.47 53145.22 147.3 53159.53 53160.03 53159.78 172.0 53173.97 53174.47 53174.22 174.9 53188.53 53189.03 53188.78 152.1 53364.47 53364.97 53364.72 191.1 53378.97 53379.47 53379.22 153.5 53393.53 53394.03 53393.78 212.4 53407.97 53408.47 53408.22 166.9 53422.47 53422.97 53422.72 172.9 53436.97 53437.47 53437.22 162.4 53451.47 53451.97 53451.72 153.5 53465.97 53466.47 53466.22 174.5 53480.47 53480.97 53480.72 172.0 53494.97 53495.47 53495.22 148.7 53509.47 53509.97 53509.72 182.3 53523.97 53524.47 53524.22 164.8 53538.47 53538.97 53538.72 182.8 53552.97 53553.47 53553.22 185.9 53659.34 53659.84 53659.59 149.2 53673.84 53674.34 53674.09 112.3 53688.41 53688.91 53688.66 147.8 53702.84 53703.34 53703.09 128.1 53717.34 53717.84 53717.59 174.8 53731.84 53732.34 53732.09 156.9 53746.28 53746.78 53746.53 161.4 53760.78 53761.28 53761.03 359.6 53775.22 53775.72 53775.47 167.1 53789.78 53790.28 53790.03 137.1 53924.97 53925.47 53925.22 173.6 53939.47 53939.97 53939.72 183.2 53953.97 53954.47 53954.22 186.3 53968.47 53968.97 53968.72 207.5 53982.97 53983.47 53983.22 172.1 53997.47 53997.97 53997.72 193.3 54012.03 54012.53 54012.28 155.9 54026.47 54026.97 54026.72 188.2 54040.97 54041.47 54041.22 147.8 54055.53 54056.03 54055.78 153.7 54070.03 54070.53 54070.28 128.7 54084.47 54084.97 54084.72 154.3 54098.97 54099.47 54099.22 129.6 54113.53 54114.03 54113.78 133.2 54127.97 54128.47 54128.22 149.9 54142.53 54143.03 54142.78 159.7 54156.97 54157.47 54157.22 163.0 54171.47 54171.97 54171.72 164.4 54186.03 54186.53 54186.28 185.4 54200.47 54200.97 54200.72 165.3 54215.03 54215.53 54215.28 156.8 54229.47 54229.97 54229.72 208.4 54243.97 54244.47 54244.22 182.6 54258.47 54258.97 54258.72 197.7 54272.97 54273.47 54273.22 226.6 54287.47 54287.97 54287.72 214.8 54302.03 54302.53 54302.28 244.4 54316.47 54316.97 54316.72 227.1 54330.97 54331.47 54331.22 232.6 54345.47 54345.97 54345.72 268.7 54359.97 54360.47 54360.22 235.9 54374.47 54374.97 54374.72 217.2 54388.97 54389.47 54389.22 223.4 54403.47 54403.97 54403.72 212.9 54417.97 54418.47 54418.22 232.1 54432.47 54432.97 54432.72 242.7 54446.97 54447.47 54447.22 259.6 54461.53 54462.03 54461.78 187.5 54475.97 54476.47 54476.22 164.9 54490.47 54490.97 54490.72 190.5 54504.97 54505.47 54505.22 205.2 54519.47 54519.97 54519.72 202.2 54533.97 54534.47 54534.22 209.3 54548.47 54548.97 54548.72 194.3 54655.34 54655.84 54655.59 175.2 54669.84 54670.34 54670.09 169.4 54684.34 54684.84 54684.59 212.2 54698.84 54699.34 54699.09 198.0 54713.34 54713.84 54713.59 197.4 54727.91 54728.41 54728.16 204.8 54742.22 54742.72 54742.47 286.9 54756.72 54757.22 54756.97 254.9 54771.22 54771.72 54771.47 232.2 54785.78 54786.28 54786.03 223.6 54800.41 54800.91 54800.66 230.2 54814.84 54815.34 54815.09 254.1 54829.41 54829.91 54829.66 224.8 54843.72 54844.22 54843.97 238.6 54858.28 54858.78 54858.53 261.8 54872.72 54873.22 54872.97 257.1 54887.28 54887.78 54887.53 277.4 54901.72 54902.22 54901.97 259.3 54916.22 54916.72 54916.47 220.2 54930.72 54931.22 54930.97 303.1 54945.34 54945.84 54945.59 218.6 54959.78 54960.28 54960.03 281.3 54974.22 54974.72 54974.47 273.6 54988.72 54989.22 54988.97 243.1 55159.16 55159.66 55159.41 231.2 55173.59 55174.09 55173.84 263.4 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