41 1001 Wennberg, Paul California Institute of Technology Gas Phase Hydrogen Peroxide from DC-8 TC4 1 1 2007 07 24 2007 08 02 0 start_UTC, s 3 1 1 1 999999 999999 999999 stop_UTC, s mid_UTC, s H2O2, pptv 0 24 PI_CONTACT_INFO: Address: California Institute of Technology. MC 150-21. 1200 E. California Blvd, Pasadena, CA, 91125. Phone: (626) 395-2447. Fax: (626) 585-1917. email: wennberg@gps.caltech.edu PLATFORM: NASA DC-8 airborne laboratory. LOCATION: Aircraft location data in file TN_20070724.DC8. ASSOCIATED_DATA: N/A INSTRUMENT_INFO: Chemical Ionization Mass Spectrometer. Direct measurements in ambient air. DATA_INFO: Measurements are reported as 0.5 sec averages and in units of pptv. CAUTION: Do not extrapolate data outside of given time interval as these are discrete measurements. Calibration was conducted ~once per hour during the flight using H2O2 obtained from vapor pressure over urea hydrogen peroxide held at constant temperature. Absolute calibration was obtained by collection in water and subsequent wet chemistry. Zeros were conducted ~3 times per hour by passing ambient air through a filter containing nylon wool coated with NaHCO3. UNCERTAINTY: +-(50% of measuremlent value + 150 pptv) ULOD_FLAG: -7777 ULOD_VALUE: N/A LLOD_FLAG: -8888 LLOD_VALUE: N/A; N/A; N/A; DM_CONTACT_INFO: John Crounse. California Institute of Technology. Department of Chemistry and Chemical Engineering. MC 150-21. 1200 E. California Blvd. Pasadena, CA 91125. Phone: (626) 395-6868. Fax: (626) 585-1917. email: crounjd@caltech.edu. PROJECT_INFO: TC4 study; 13 July-13 August 2007; Study of cloud processing and tropical convection processes STIPULATIONS_ON_USE: Use of these data requires PI notification and adherence to the TC4 data protocol. OTHER_COMMENTS: N/A REVISION: R0 R0: Preliminary Data Revision 0. Water correction has been applied using CIT-CIMS water. Reduction code 1.5 start_UTC(s) stop_UTC(s) mid_UTC(s) H2O2(pptv) 46107.84 46108.34 46108.09 14.6 46122.34 46122.84 46122.59 9.6 46136.91 46137.41 46137.16 -16.3 46247.22 46247.72 46247.47 9.2 46261.72 46262.22 46261.97 3.1 46276.22 46276.72 46276.47 -4.1 46290.72 46291.22 46290.97 -1.3 46305.22 46305.72 46305.47 169.6 46319.72 46320.22 46319.97 428.8 46334.22 46334.72 46334.47 436.5 46348.72 46349.22 46348.97 620.0 46363.09 46363.59 46363.34 451.5 46377.59 46378.09 46377.84 938.1 46392.28 46392.78 46392.53 680.0 46406.72 46407.22 46406.97 779.8 46421.22 46421.72 46421.47 1047.0 46435.72 46436.22 46435.97 1043.7 46450.22 46450.72 46450.47 1055.5 46464.72 46465.22 46464.97 1032.6 46479.09 46479.59 46479.34 849.6 46493.59 46494.09 46493.84 1026.8 46508.09 46508.59 46508.34 1128.2 46522.59 46523.09 46522.84 1082.7 46537.22 46537.72 46537.47 1192.5 46551.72 46552.22 46551.97 873.5 46566.22 46566.72 46566.47 841.6 46580.78 46581.28 46581.03 445.8 46595.09 46595.59 46595.34 296.6 46609.59 46610.09 46609.84 269.4 46624.09 46624.59 46624.34 123.3 46638.59 46639.09 46638.84 114.1 46653.09 46653.59 46653.34 330.5 46667.66 46668.16 46667.91 613.2 46682.22 46682.72 46682.47 655.1 46696.66 46697.16 46696.91 852.4 46711.16 46711.66 46711.41 742.6 46725.59 46726.09 46725.84 754.3 46740.09 46740.59 46740.34 901.0 46754.59 46755.09 46754.84 831.8 46769.09 46769.59 46769.34 887.7 46783.59 46784.09 46783.84 932.2 46798.09 46798.59 46798.34 813.8 46812.59 46813.09 46812.84 915.2 46827.16 46827.66 46827.41 843.0 46841.66 46842.16 46841.91 951.2 46856.09 46856.59 46856.34 972.8 46870.66 46871.16 46870.91 870.0 46885.09 46885.59 46885.34 988.8 46899.66 46900.16 46899.91 1034.8 46914.09 46914.59 46914.34 868.9 46928.59 46929.09 46928.84 1102.2 46943.09 46943.59 46943.34 1070.3 46957.59 46958.09 46957.84 1143.2 46972.09 46972.59 46972.34 1063.2 46986.59 46987.09 46986.84 1069.6 47001.09 47001.59 47001.34 1002.8 47102.84 47103.34 47103.09 1323.3 47117.34 47117.84 47117.59 1365.6 47131.84 47132.34 47132.09 872.8 47146.41 47146.91 47146.66 872.4 47160.91 47161.41 47161.16 1497.7 47175.41 47175.91 47175.66 1533.2 47189.72 47190.22 47189.97 826.1 47204.22 47204.72 47204.47 678.7 47218.72 47219.22 47218.97 829.7 47233.22 47233.72 47233.47 923.5 47247.84 47248.34 47248.09 129.6 47262.34 47262.84 47262.59 265.3 47346.78 47347.28 47347.03 49.3 47353.59 47354.09 47353.84 12.7 47368.09 47368.59 47368.34 8.1 47382.59 47383.09 47382.84 190.0 47397.09 47397.59 47397.34 470.6 47411.59 47412.09 47411.84 1073.4 47426.16 47426.66 47426.41 1028.0 47440.59 47441.09 47440.84 1262.5 47455.09 47455.59 47455.34 930.7 47469.59 47470.09 47469.84 996.8 47484.16 47484.66 47484.41 812.8 47498.66 47499.16 47498.91 690.2 47513.16 47513.66 47513.41 590.4 47527.59 47528.09 47527.84 504.2 47542.09 47542.59 47542.34 413.5 47587.47 47587.97 47587.72 574.6 47602.03 47602.53 47602.28 496.0 47616.47 47616.97 47616.72 459.9 47630.97 47631.47 47631.22 437.1 47645.47 47645.97 47645.72 470.9 47660.03 47660.53 47660.28 469.8 47674.41 47674.91 47674.66 364.2 47688.84 47689.34 47689.09 368.9 47703.34 47703.84 47703.59 368.6 47717.84 47718.34 47718.09 416.9 47732.47 47732.97 47732.72 424.7 47747.03 47747.53 47747.28 475.4 47761.53 47762.03 47761.78 401.1 47775.97 47776.47 47776.22 393.7 47790.34 47790.84 47790.59 405.9 47804.84 47805.34 47805.09 348.6 47819.34 47819.84 47819.59 481.8 47833.84 47834.34 47834.09 401.8 47848.41 47848.91 47848.66 364.6 47862.84 47863.34 47863.09 357.2 47877.47 47877.97 47877.72 362.8 47891.97 47892.47 47892.22 365.3 47906.41 47906.91 47906.66 325.7 47920.91 47921.41 47921.16 427.3 47935.34 47935.84 47935.59 453.4 47949.84 47950.34 47950.09 423.3 47964.34 47964.84 47964.59 361.3 47978.84 47979.34 47979.09 349.9 47993.34 47993.84 47993.59 367.9 48092.97 48093.47 48093.22 348.1 48107.47 48107.97 48107.72 344.9 48121.84 48122.34 48122.09 408.3 48136.34 48136.84 48136.59 430.7 48150.84 48151.34 48151.09 409.6 48165.34 48165.84 48165.59 458.5 48179.84 48180.34 48180.09 469.3 48194.41 48194.91 48194.66 450.1 48208.91 48209.41 48209.16 357.9 48223.34 48223.84 48223.59 423.5 48237.84 48238.34 48238.09 414.3 48252.34 48252.84 48252.59 448.2 48266.84 48267.34 48267.09 380.1 48281.34 48281.84 48281.59 380.4 48295.84 48296.34 48296.09 472.5 48310.34 48310.84 48310.59 504.0 48324.84 48325.34 48325.09 491.7 48339.34 48339.84 48339.59 447.3 48353.84 48354.34 48354.09 428.5 48368.34 48368.84 48368.59 591.6 48382.91 48383.41 48383.16 593.1 48397.41 48397.91 48397.66 497.3 48411.84 48412.34 48412.09 646.6 48426.34 48426.84 48426.59 476.3 48440.84 48441.34 48441.09 571.6 48455.34 48455.84 48455.59 519.9 48469.84 48470.34 48470.09 536.3 48484.34 48484.84 48484.59 371.2 48498.84 48499.34 48499.09 581.3 48513.34 48513.84 48513.59 490.1 48527.91 48528.41 48528.16 230.3 48542.34 48542.84 48542.59 219.8 48556.84 48557.34 48557.09 627.2 48571.41 48571.91 48571.66 257.7 48585.84 48586.34 48586.09 299.9 48600.41 48600.91 48600.66 377.7 48614.91 48615.41 48615.16 347.2 48629.34 48629.84 48629.59 311.3 48643.84 48644.34 48644.09 483.6 48658.34 48658.84 48658.59 281.9 48672.84 48673.34 48673.09 287.1 48687.34 48687.84 48687.59 207.5 48701.84 48702.34 48702.09 169.3 48716.41 48716.91 48716.66 115.1 48730.84 48731.34 48731.09 158.9 48745.34 48745.84 48745.59 231.5 48759.91 48760.41 48760.16 296.9 48774.34 48774.84 48774.59 325.9 48788.84 48789.34 48789.09 378.1 48803.34 48803.84 48803.59 352.4 48817.84 48818.34 48818.09 252.4 48832.41 48832.91 48832.66 358.1 48846.84 48847.34 48847.09 213.1 48861.41 48861.91 48861.66 425.0 48875.84 48876.34 48876.09 200.8 48890.41 48890.91 48890.66 170.9 48904.84 48905.34 48905.09 278.7 48919.34 48919.84 48919.59 327.2 48933.84 48934.34 48934.09 364.6 48948.41 48948.91 48948.66 519.9 48962.91 48963.41 48963.16 509.9 48977.34 48977.84 48977.59 470.1 48991.91 48992.41 48992.16 547.4 49217.84 49218.34 49218.09 504.0 49232.34 49232.84 49232.59 503.6 49246.84 49247.34 49247.09 410.0 49261.34 49261.84 49261.59 409.7 49275.72 49276.22 49275.97 39.7 49290.28 49290.78 49290.53 136.4 49304.78 49305.28 49305.03 249.8 49319.28 49319.78 49319.53 254.7 49333.78 49334.28 49334.03 265.2 49348.22 49348.72 49348.47 289.1 49362.84 49363.34 49363.09 342.6 49377.22 49377.72 49377.47 401.4 49391.72 49392.22 49391.97 396.8 49406.22 49406.72 49406.47 164.9 49420.72 49421.22 49420.97 51.4 49435.22 49435.72 49435.47 158.9 49449.78 49450.28 49450.03 116.7 49464.22 49464.72 49464.47 136.2 49478.72 49479.22 49478.97 51.5 49493.22 49493.72 49493.47 -6.0 49507.72 49508.22 49507.97 2.6 49522.28 49522.78 49522.53 20.1 49536.72 49537.22 49536.97 145.2 49551.22 49551.72 49551.47 165.4 49565.72 49566.22 49565.97 153.1 49580.22 49580.72 49580.47 89.8 49594.72 49595.22 49594.97 407.0 49609.22 49609.72 49609.47 403.5 49623.72 49624.22 49623.97 455.2 49638.22 49638.72 49638.47 600.1 49652.72 49653.22 49652.97 674.9 49667.22 49667.72 49667.47 709.2 49681.78 49682.28 49682.03 670.1 49696.22 49696.72 49696.47 658.7 49710.72 49711.22 49710.97 661.4 49725.22 49725.72 49725.47 668.7 49739.72 49740.22 49739.97 692.6 49754.22 49754.72 49754.47 754.6 49768.72 49769.22 49768.97 705.0 49783.22 49783.72 49783.47 744.9 49797.78 49798.28 49798.03 698.6 49812.28 49812.78 49812.53 725.9 49826.72 49827.22 49826.97 644.3 49841.22 49841.72 49841.47 674.4 49855.78 49856.28 49856.03 508.8 49870.22 49870.72 49870.47 605.3 49884.78 49885.28 49885.03 771.4 49899.28 49899.78 49899.53 438.1 49913.72 49914.22 49913.97 200.9 49928.22 49928.72 49928.47 263.7 49942.72 49943.22 49942.97 265.9 49957.28 49957.78 49957.53 272.2 49971.78 49972.28 49972.03 239.2 49986.22 49986.72 49986.47 161.5 50000.72 50001.22 50000.97 116.8 50015.22 50015.72 50015.47 125.0 50029.72 50030.22 50029.97 43.9 50044.22 50044.72 50044.47 19.5 50058.72 50059.22 50058.97 22.2 50073.22 50073.72 50073.47 -6.1 50087.78 50088.28 50088.03 8.2 50102.28 50102.78 50102.53 110.1 50116.78 50117.28 50117.03 -7.2 50217.84 50218.34 50218.09 162.2 50232.34 50232.84 50232.59 251.1 50246.84 50247.34 50247.09 226.8 50261.34 50261.84 50261.59 243.7 50275.84 50276.34 50276.09 216.0 50290.41 50290.91 50290.66 269.9 50304.84 50305.34 50305.09 224.5 50319.41 50319.91 50319.66 357.1 50387.91 50388.41 50388.16 140.6 50402.34 50402.84 50402.59 337.3 50416.84 50417.34 50417.09 399.6 50431.41 50431.91 50431.66 204.8 50445.84 50446.34 50446.09 218.6 50460.34 50460.84 50460.59 164.3 50474.84 50475.34 50475.09 140.0 50489.34 50489.84 50489.59 219.5 50503.84 50504.34 50504.09 287.3 50518.41 50518.91 50518.66 226.5 50532.84 50533.34 50533.09 207.4 50547.34 50547.84 50547.59 344.5 50561.84 50562.34 50562.09 244.8 50576.34 50576.84 50576.59 159.2 50590.84 50591.34 50591.09 274.5 50605.41 50605.91 50605.66 201.0 50619.84 50620.34 50620.09 186.7 50634.34 50634.84 50634.59 174.6 50648.91 50649.41 50649.16 299.3 50663.34 50663.84 50663.59 219.2 50677.84 50678.34 50678.09 220.7 50692.34 50692.84 50692.59 134.1 50706.91 50707.41 50707.16 175.5 50721.34 50721.84 50721.59 266.2 50735.84 50736.34 50736.09 209.7 50750.34 50750.84 50750.59 204.8 50764.84 50765.34 50765.09 263.3 50779.34 50779.84 50779.59 272.3 50793.84 50794.34 50794.09 192.9 50808.41 50808.91 50808.66 158.1 50822.84 50823.34 50823.09 200.1 50837.34 50837.84 50837.59 163.3 50851.84 50852.34 50852.09 213.0 50866.34 50866.84 50866.59 232.8 50880.91 50881.41 50881.16 240.2 50895.34 50895.84 50895.59 216.5 50909.84 50910.34 50910.09 217.4 50924.34 50924.84 50924.59 238.9 50938.84 50939.34 50939.09 186.1 50953.34 50953.84 50953.59 256.0 50967.91 50968.41 50968.16 311.2 50982.34 50982.84 50982.59 241.4 50996.84 50997.34 50997.09 222.8 51011.34 51011.84 51011.59 181.7 51025.84 51026.34 51026.09 246.8 51040.34 51040.84 51040.59 265.5 51054.84 51055.34 51055.09 201.5 51069.34 51069.84 51069.59 353.5 51083.91 51084.41 51084.16 209.8 51098.34 51098.84 51098.59 152.1 51112.91 51113.41 51113.16 193.7 51212.84 51213.34 51213.09 160.5 51227.41 51227.91 51227.66 157.4 51241.91 51242.41 51242.16 225.7 51256.41 51256.91 51256.66 182.7 51270.84 51271.34 51271.09 157.9 51285.34 51285.84 51285.59 118.7 51299.84 51300.34 51300.09 144.8 51314.34 51314.84 51314.59 145.7 51328.84 51329.34 51329.09 238.2 51343.34 51343.84 51343.59 264.4 51357.84 51358.34 51358.09 276.1 51372.34 51372.84 51372.59 279.7 51386.84 51387.34 51387.09 107.5 51401.34 51401.84 51401.59 110.3 51415.84 51416.34 51416.09 165.5 51430.34 51430.84 51430.59 160.9 51444.91 51445.41 51445.16 133.2 51459.22 51459.72 51459.47 214.2 51473.72 51474.22 51473.97 225.3 51488.22 51488.72 51488.47 208.0 51502.91 51503.41 51503.16 189.8 51517.34 51517.84 51517.59 142.1 51531.84 51532.34 51532.09 108.9 51546.34 51546.84 51546.59 72.0 51560.91 51561.41 51561.16 260.6 51575.28 51575.78 51575.53 262.4 51589.72 51590.22 51589.97 374.3 51604.28 51604.78 51604.53 97.4 51618.72 51619.22 51618.97 194.1 51633.22 51633.72 51633.47 105.2 51647.84 51648.34 51648.09 91.9 51662.34 51662.84 51662.59 25.4 51676.72 51677.22 51676.97 14.0 51691.28 51691.78 51691.53 76.2 51705.72 51706.22 51705.97 144.0 51720.22 51720.72 51720.47 27.5 51734.72 51735.22 51734.97 108.0 51749.22 51749.72 51749.47 82.8 51763.78 51764.28 51764.03 56.9 51778.22 51778.72 51778.47 103.6 51792.72 51793.22 51792.97 67.6 51807.22 51807.72 51807.47 24.0 51821.78 51822.28 51822.03 32.1 51836.28 51836.78 51836.53 17.2 51850.72 51851.22 51850.97 91.7 51865.22 51865.72 51865.47 77.1 51879.78 51880.28 51880.03 54.1 51894.22 51894.72 51894.47 38.8 51908.72 51909.22 51908.97 24.0 51923.22 51923.72 51923.47 185.9 51937.72 51938.22 51937.97 168.3 51952.22 51952.72 51952.47 185.7 51966.72 51967.22 51966.97 194.5 51981.22 51981.72 51981.47 125.6 51995.78 51996.28 51996.03 84.4 52010.22 52010.72 52010.47 118.5 52024.78 52025.28 52025.03 107.5 52039.22 52039.72 52039.47 160.9 52053.72 52054.22 52053.97 166.3 52068.22 52068.72 52068.47 194.5 52082.72 52083.22 52082.97 153.5 52097.22 52097.72 52097.47 159.5 52111.72 52112.22 52111.97 64.7 52667.09 52667.59 52667.34 596.4 52681.59 52682.09 52681.84 695.1 52696.16 52696.66 52696.41 623.5 52710.59 52711.09 52710.84 649.6 52725.09 52725.59 52725.34 589.7 52739.59 52740.09 52739.84 668.0 52754.09 52754.59 52754.34 612.8 52768.47 52768.97 52768.72 653.6 52782.97 52783.47 52783.22 634.8 52797.47 52797.97 52797.72 654.6 52812.09 52812.59 52812.34 611.6 52826.66 52827.16 52826.91 597.7 52841.09 52841.59 52841.34 483.2 52855.59 52856.09 52855.84 498.6 52870.09 52870.59 52870.34 513.5 52884.47 52884.97 52884.72 588.3 52898.97 52899.47 52899.22 538.3 52913.47 52913.97 52913.72 539.2 52928.03 52928.53 52928.28 449.4 52942.47 52942.97 52942.72 480.5 52957.09 52957.59 52957.34 454.5 52971.66 52972.16 52971.91 394.3 52985.97 52986.47 52986.22 392.7 53000.53 53001.03 53000.78 379.6 53015.03 53015.53 53015.28 328.8 53029.47 53029.97 53029.72 484.6 53043.97 53044.47 53044.22 342.4 53058.47 53058.97 53058.72 275.3 53072.97 53073.47 53073.22 250.5 53087.47 53087.97 53087.72 331.4 53102.03 53102.53 53102.28 312.5 53116.47 53116.97 53116.72 377.0 53130.97 53131.47 53131.22 370.3 53145.53 53146.03 53145.78 387.8 53159.97 53160.47 53160.22 346.9 53174.47 53174.97 53174.72 280.9 53188.97 53189.47 53189.22 302.5 53364.97 53365.47 53365.22 114.3 53379.47 53379.97 53379.72 112.5 53393.97 53394.47 53394.22 76.1 53408.47 53408.97 53408.72 116.2 53422.97 53423.47 53423.22 47.4 53437.47 53437.97 53437.72 15.3 53451.97 53452.47 53452.22 24.2 53466.47 53466.97 53466.72 -19.5 53481.03 53481.53 53481.28 51.7 53495.47 53495.97 53495.72 48.9 53510.03 53510.53 53510.28 5.3 53524.47 53524.97 53524.72 4.6 53539.03 53539.53 53539.28 41.1 53553.47 53553.97 53553.72 47.1 53659.84 53660.34 53660.09 -3.4 53674.34 53674.84 53674.59 2.2 53688.91 53689.41 53689.16 2.8 53703.41 53703.91 53703.66 -29.7 53717.84 53718.34 53718.09 -17.3 53732.34 53732.84 53732.59 11.7 53746.72 53747.22 53746.97 -2.5 53761.28 53761.78 53761.53 -2.7 53775.78 53776.28 53776.03 -12.0 53790.22 53790.72 53790.47 -7.4 53925.47 53925.97 53925.72 -28.4 53939.97 53940.47 53940.22 -14.6 53954.47 53954.97 53954.72 -1.0 53968.97 53969.47 53969.22 -23.8 53983.47 53983.97 53983.72 13.2 53998.03 53998.53 53998.28 -6.8 54012.47 54012.97 54012.72 17.6 54026.97 54027.47 54027.22 28.9 54041.47 54041.97 54041.72 -3.6 54055.97 54056.47 54056.22 4.3 54070.47 54070.97 54070.72 23.9 54084.97 54085.47 54085.22 11.7 54099.47 54099.97 54099.72 22.7 54113.97 54114.47 54114.22 -10.0 54128.47 54128.97 54128.72 21.2 54143.03 54143.53 54143.28 46.6 54157.47 54157.97 54157.72 35.0 54171.97 54172.47 54172.22 2.6 54186.47 54186.97 54186.72 14.0 54201.03 54201.53 54201.28 0.4 54215.53 54216.03 54215.78 3.9 54229.97 54230.47 54230.22 20.7 54244.47 54244.97 54244.72 41.1 54259.03 54259.53 54259.28 15.0 54273.53 54274.03 54273.78 6.6 54288.03 54288.53 54288.28 52.7 54302.47 54302.97 54302.72 -6.6 54316.97 54317.47 54317.22 -22.2 54331.47 54331.97 54331.72 17.8 54345.97 54346.47 54346.22 -6.4 54360.47 54360.97 54360.72 -3.4 54374.97 54375.47 54375.22 39.4 54389.47 54389.97 54389.72 -25.2 54403.97 54404.47 54404.22 25.5 54418.53 54419.03 54418.78 -44.6 54432.97 54433.47 54433.22 -24.2 54447.47 54447.97 54447.72 3.8 54461.97 54462.47 54462.22 25.3 54476.53 54477.03 54476.78 29.3 54490.97 54491.47 54491.22 -1.7 54505.47 54505.97 54505.72 23.8 54520.03 54520.53 54520.28 22.3 54534.47 54534.97 54534.72 35.0 54549.03 54549.53 54549.28 21.9 54655.84 54656.34 54656.09 -7.9 54670.41 54670.91 54670.66 5.1 54684.84 54685.34 54685.09 32.5 54699.34 54699.84 54699.59 -14.5 54713.84 54714.34 54714.09 38.3 54728.34 54728.84 54728.59 30.7 54742.78 54743.28 54743.03 -42.0 54757.22 54757.72 54757.47 -28.4 54771.78 54772.28 54772.03 -11.2 54786.28 54786.78 54786.53 3.6 54800.84 54801.34 54801.09 12.9 54815.34 54815.84 54815.59 10.4 54829.84 54830.34 54830.09 21.2 54844.22 54844.72 54844.47 -12.0 54858.72 54859.22 54858.97 -7.4 54873.22 54873.72 54873.47 11.5 54887.72 54888.22 54887.97 -9.8 54902.22 54902.72 54902.47 -10.3 54916.72 54917.22 54916.97 5.5 54931.22 54931.72 54931.47 6.2 54945.84 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