43 1001 Wennberg, Paul California Institute of Technology Gas Phase Peroxynitric Acid from DC-8 TC4 1 1 2007 07 22 2011 09 07 0 start_UTC, s 3 1 1 1 999999 999999 999999 stop_UTC, s mid_UTC, s PNA, pptv 0 26 PI_CONTACT_INFO: Address: California Institute of Technology. MC 150-21. 1200 E. California Blvd, Pasadena, CA, 91125. Phone: (626) 395-2447. Fax: (626) 585-1917. email: wennberg@gps.caltech.edu PLATFORM: NASA DC-8 airborne laboratory. LOCATION: Aircraft location data in file TN_20070722.DC8. ASSOCIATED_DATA: N/A INSTRUMENT_INFO: Chemical Ionization Mass Spectrometer. Direct measurements in ambient air. DATA_INFO: Measurements are reported as 0.5 sec averages and in units of pptv. CAUTION: Do not extrapolate data outside of given time interval as these are discrete measurements. Calibration was conducted ~once per hour during the flight using H2O2 and HNO3 calibrants, and proxied to PNA using laboratory calibrations. Absolute calibration was obtained in the laboratory by thermal decomposition and NO2 measurement. Zeros were conducted ~3 times per hour by passing ambient air through a filter containing nylon wool coated with NaHCO3. UNCERTAINTY: +-(100% of measuremlent value + 20 pptv) ULOD_FLAG: 7777777 ULOD_VALUE: N/A LLOD_FLAG: 8888888 LLOD_VALUE: N/A; N/A; N/A; DM_CONTACT_INFO: John Crounse. California Institute of Technology. Department of Chemistry and Chemical Engineering. MC 150-21. 1200 E. California Blvd. Pasadena, CA 91125. Phone: (626) 395-6868. Fax: (626) 585-1917. email: crounjd@caltech.edu. PROJECT_INFO: TC4 study; 13 July-13 August 2007; Study of cloud processing and tropical convection processes STIPULATIONS_ON_USE: Use of these data requires PI notification and adherence to the TC4 data protocol. OTHER_COMMENTS: N/A REVISION: R1 R1: ULOD and LLOD flags changed to positive values, to conform to Ames format 2.1 specifications. R0: Preliminary Data Revision 0. Water correction has been applied using CIT-CIMS water. Reduction code 1.5 start_UTC stop_UTC mid_UTC PNA 46530.84 46531.34 46531.09 -3.2 46544.84 46545.34 46545.09 -1.6 46558.91 46559.41 46559.16 -2.4 46572.84 46573.34 46573.09 -4.0 46586.84 46587.34 46587.09 -2.0 46600.84 46601.34 46601.09 -4.2 46614.78 46615.28 46615.03 -2.5 46628.72 46629.22 46628.97 7.3 46642.72 46643.22 46642.97 -2.0 46656.72 46657.22 46656.97 0.5 46670.84 46671.34 46671.09 2.0 46684.84 46685.34 46685.09 -3.2 46698.91 46699.41 46699.16 2.1 46712.72 46713.22 46712.97 -2.5 46726.72 46727.22 46726.97 2.6 46740.72 46741.22 46740.97 -6.3 46754.78 46755.28 46755.03 -0.9 46768.72 46769.22 46768.97 -8.5 46782.78 46783.28 46783.03 98.0 46796.78 46797.28 46797.03 85.3 46810.91 46811.41 46811.16 26.0 46824.78 46825.28 46825.03 49.8 46838.78 46839.28 46839.03 61.3 46852.78 46853.28 46853.03 21.1 46866.78 46867.28 46867.03 67.8 46880.72 46881.22 46880.97 68.5 46894.78 46895.28 46895.03 0.6 46908.78 46909.28 46909.03 60.2 46922.78 46923.28 46923.03 56.3 46936.72 46937.22 46936.97 59.4 46950.78 46951.28 46951.03 16.9 46964.78 46965.28 46965.03 16.4 46978.78 46979.28 46979.03 25.9 46992.78 46993.28 46993.03 12.1 47006.78 47007.28 47007.03 26.1 47020.78 47021.28 47021.03 -1.2 47034.78 47035.28 47035.03 21.7 47048.78 47049.28 47049.03 11.6 47062.78 47063.28 47063.03 11.7 47076.78 47077.28 47077.03 26.5 47090.78 47091.28 47091.03 -6.9 47104.72 47105.22 47104.97 31.3 47118.78 47119.28 47119.03 3.0 47132.78 47133.28 47133.03 -16.0 47146.72 47147.22 47146.97 6.4 47160.78 47161.28 47161.03 -5.5 47174.78 47175.28 47175.03 9.8 47188.78 47189.28 47189.03 -19.6 47202.78 47203.28 47203.03 9.1 47216.72 47217.22 47216.97 -1.6 47230.72 47231.22 47230.97 -4.8 47244.78 47245.28 47245.03 -13.7 47258.78 47259.28 47259.03 -19.6 47272.78 47273.28 47273.03 -0.9 47286.72 47287.22 47286.97 20.7 47300.78 47301.28 47301.03 -8.5 47314.78 47315.28 47315.03 -14.1 47328.72 47329.22 47328.97 13.0 47342.78 47343.28 47343.03 -0.4 47356.78 47357.28 47357.03 -8.1 47370.78 47371.28 47371.03 -8.5 47384.78 47385.28 47385.03 2.2 47398.78 47399.28 47399.03 21.9 47412.78 47413.28 47413.03 -0.3 47510.91 47511.41 47511.16 4.1 47524.84 47525.34 47525.09 7.6 47538.91 47539.41 47539.16 -16.2 47552.84 47553.34 47553.09 15.5 47566.91 47567.41 47567.16 -14.6 47580.91 47581.41 47581.16 -5.8 47594.78 47595.28 47595.03 11.3 47608.78 47609.28 47609.03 14.4 47622.78 47623.28 47623.03 38.1 47636.72 47637.22 47636.97 26.9 47650.72 47651.22 47650.97 13.0 47664.91 47665.41 47665.16 2.8 47678.91 47679.41 47679.16 11.6 47692.84 47693.34 47693.09 19.4 47706.78 47707.28 47707.03 16.9 47720.78 47721.28 47721.03 44.2 47734.72 47735.22 47734.97 45.4 47748.72 47749.22 47748.97 63.8 47762.72 47763.22 47762.97 40.4 47776.72 47777.22 47776.97 35.0 47790.72 47791.22 47790.97 38.4 47804.78 47805.28 47805.03 27.0 47818.78 47819.28 47819.03 4.0 47832.78 47833.28 47833.03 2.4 47846.72 47847.22 47846.97 13.1 47860.78 47861.28 47861.03 36.9 47874.78 47875.28 47875.03 24.9 47888.72 47889.22 47888.97 10.7 47902.72 47903.22 47902.97 18.1 47916.72 47917.22 47916.97 44.0 47930.78 47931.28 47931.03 32.0 47944.72 47945.22 47944.97 28.1 47958.72 47959.22 47958.97 16.4 47972.78 47973.28 47973.03 35.2 47986.72 47987.22 47986.97 35.2 48000.78 48001.28 48001.03 33.8 48014.72 48015.22 48014.97 43.7 48028.78 48029.28 48029.03 7.8 48042.72 48043.22 48042.97 12.6 48056.72 48057.22 48056.97 44.7 48070.72 48071.22 48070.97 41.4 48084.72 48085.22 48084.97 28.0 48098.78 48099.28 48099.03 21.0 48112.72 48113.22 48112.97 37.2 48126.78 48127.28 48127.03 8.5 48140.72 48141.22 48140.97 33.5 48154.72 48155.22 48154.97 38.1 48168.72 48169.22 48168.97 33.6 48182.78 48183.28 48183.03 -4.5 48196.78 48197.28 48197.03 24.8 48210.72 48211.22 48210.97 27.6 48224.78 48225.28 48225.03 26.7 48238.72 48239.22 48238.97 17.4 48252.78 48253.28 48253.03 -3.4 48266.78 48267.28 48267.03 29.6 48280.78 48281.28 48281.03 16.3 48294.78 48295.28 48295.03 -8.8 48308.78 48309.28 48309.03 7.9 48322.78 48323.28 48323.03 25.6 48336.78 48337.28 48337.03 18.8 48350.78 48351.28 48351.03 -1.9 48364.78 48365.28 48365.03 18.1 48378.72 48379.22 48378.97 0.0 48392.78 48393.28 48393.03 3.0 48406.78 48407.28 48407.03 -18.4 48503.84 48504.34 48504.09 2.4 48517.84 48518.34 48518.09 28.7 48531.91 48532.41 48532.16 -13.0 48545.84 48546.34 48546.09 2.4 48559.84 48560.34 48560.09 18.1 48573.78 48574.28 48574.03 4.6 48587.78 48588.28 48588.03 -18.6 48601.72 48602.22 48601.97 -3.1 48615.72 48616.22 48615.97 14.3 48629.72 48630.22 48629.97 34.4 48643.72 48644.22 48643.97 35.9 48657.91 48658.41 48658.16 8.1 48671.84 48672.34 48672.09 36.9 48685.72 48686.22 48685.97 34.8 48699.78 48700.28 48700.03 31.7 48713.72 48714.22 48713.97 22.1 48727.72 48728.22 48727.97 20.8 48741.72 48742.22 48741.97 14.2 48755.72 48756.22 48755.97 10.1 48769.78 48770.28 48770.03 24.9 48783.72 48784.22 48783.97 10.5 48797.78 48798.28 48798.03 13.7 48811.72 48812.22 48811.97 11.9 48825.78 48826.28 48826.03 -2.9 48839.72 48840.22 48839.97 27.1 48853.78 48854.28 48854.03 19.7 48867.78 48868.28 48868.03 -8.7 48881.72 48882.22 48881.97 18.1 48895.72 48896.22 48895.97 8.1 48909.78 48910.28 48910.03 16.7 48923.72 48924.22 48923.97 2.4 48937.72 48938.22 48937.97 33.0 48951.72 48952.22 48951.97 11.1 48965.72 48966.22 48965.97 -12.0 48979.78 48980.28 48980.03 -7.8 48993.72 48994.22 48993.97 -0.8 49007.72 49008.22 49007.97 16.0 49021.72 49022.22 49021.97 8.3 49035.78 49036.28 49036.03 3.3 49049.78 49050.28 49050.03 3.4 49063.78 49064.28 49064.03 8.6 49077.78 49078.28 49078.03 -6.8 49091.72 49092.22 49091.97 21.3 49105.72 49106.22 49105.97 -2.6 49119.72 49120.22 49119.97 12.8 49133.78 49134.28 49134.03 3.2 49147.72 49148.22 49147.97 4.2 49161.78 49162.28 49162.03 -1.4 49175.72 49176.22 49175.97 -2.4 49189.78 49190.28 49190.03 7.0 49203.78 49204.28 49204.03 -10.5 49217.72 49218.22 49217.97 3.7 49231.78 49232.28 49232.03 -3.0 49245.78 49246.28 49246.03 9.6 49259.72 49260.22 49259.97 8.6 49273.72 49274.22 49273.97 4.1 49287.72 49288.22 49287.97 7.2 49301.72 49302.22 49301.97 2.1 49315.78 49316.28 49316.03 2.7 49329.72 49330.22 49329.97 7.6 49343.78 49344.28 49344.03 0.4 49357.78 49358.28 49358.03 5.0 49371.78 49372.28 49372.03 -12.1 49385.72 49386.22 49385.97 2.6 49399.72 49400.22 49399.97 -1.2 49590.84 49591.34 49591.09 11.0 49604.84 49605.34 49605.09 14.9 49618.84 49619.34 49619.09 8.0 49632.84 49633.34 49633.09 4.7 49646.91 49647.41 49647.16 -3.5 49660.91 49661.41 49661.16 3.6 49674.72 49675.22 49674.97 15.4 49688.72 49689.22 49688.97 9.4 49702.78 49703.28 49703.03 15.5 49716.78 49717.28 49717.03 8.3 49730.78 49731.28 49731.03 9.2 49744.91 49745.41 49745.16 1.4 49758.91 49759.41 49759.16 -1.4 49772.78 49773.28 49773.03 11.4 49786.72 49787.22 49786.97 14.0 49800.72 49801.22 49800.97 16.7 49814.72 49815.22 49814.97 8.1 49828.78 49829.28 49829.03 6.1 49842.78 49843.28 49843.03 5.8 49856.72 49857.22 49856.97 21.1 49870.78 49871.28 49871.03 13.0 49884.72 49885.22 49884.97 12.6 49898.72 49899.22 49898.97 12.3 49912.72 49913.22 49912.97 15.9 49926.72 49927.22 49926.97 9.2 49940.78 49941.28 49941.03 3.9 49954.72 49955.22 49954.97 6.1 49968.78 49969.28 49969.03 10.7 49982.78 49983.28 49983.03 6.8 49996.72 49997.22 49996.97 13.5 50010.78 50011.28 50011.03 6.5 50024.72 50025.22 50024.97 18.1 50038.72 50039.22 50038.97 10.0 50052.78 50053.28 50053.03 11.4 50066.72 50067.22 50066.97 10.6 50080.72 50081.22 50080.97 10.3 50094.78 50095.28 50095.03 23.3 50108.78 50109.28 50109.03 13.5 50122.72 50123.22 50122.97 23.1 50136.72 50137.22 50136.97 14.4 50150.78 50151.28 50151.03 12.3 50164.72 50165.22 50164.97 15.6 50178.72 50179.22 50178.97 26.1 50192.72 50193.22 50192.97 10.8 50206.72 50207.22 50206.97 10.0 50220.72 50221.22 50220.97 11.0 50234.72 50235.22 50234.97 19.2 50248.72 50249.22 50248.97 13.7 50262.72 50263.22 50262.97 17.3 50276.72 50277.22 50276.97 14.7 50290.78 50291.28 50291.03 13.2 50304.72 50305.22 50304.97 20.0 50318.72 50319.22 50318.97 15.1 50332.78 50333.28 50333.03 12.1 50346.72 50347.22 50346.97 15.0 50360.78 50361.28 50361.03 5.7 50374.78 50375.28 50375.03 20.4 50388.78 50389.28 50389.03 11.7 50402.72 50403.22 50402.97 12.9 50416.72 50417.22 50416.97 16.2 50430.72 50431.22 50430.97 10.8 50444.72 50445.22 50444.97 12.9 50458.72 50459.22 50458.97 8.7 50472.72 50473.22 50472.97 9.1 50486.72 50487.22 50486.97 15.8 50590.91 50591.41 50591.16 2.7 50604.91 50605.41 50605.16 18.6 50618.84 50619.34 50619.09 16.2 50632.84 50633.34 50633.09 6.8 50646.84 50647.34 50647.09 11.7 50660.91 50661.41 50661.16 14.9 50674.72 50675.22 50674.97 15.7 50688.72 50689.22 50688.97 23.0 50702.72 50703.22 50702.97 21.9 50716.72 50717.22 50716.97 5.2 50730.72 50731.22 50730.97 7.6 50744.84 50745.34 50745.09 6.2 50758.91 50759.41 50759.16 7.2 50772.72 50773.22 50772.97 9.5 50786.78 50787.28 50787.03 6.4 50800.72 50801.22 50800.97 12.1 50814.78 50815.28 50815.03 21.3 50828.72 50829.22 50828.97 11.1 50842.72 50843.22 50842.97 13.3 50856.72 50857.22 50856.97 14.3 50870.78 50871.28 50871.03 14.3 50884.72 50885.22 50884.97 7.9 50898.72 50899.22 50898.97 7.2 50912.72 50913.22 50912.97 4.0 50926.78 50927.28 50927.03 7.8 50940.72 50941.22 50940.97 6.4 50954.72 50955.22 50954.97 11.2 50968.72 50969.22 50968.97 11.5 50982.72 50983.22 50982.97 15.1 50996.78 50997.28 50997.03 18.7 51010.72 51011.22 51010.97 10.7 51024.72 51025.22 51024.97 12.1 51038.72 51039.22 51038.97 16.3 51052.72 51053.22 51052.97 16.4 51066.72 51067.22 51066.97 16.1 51080.72 51081.22 51080.97 16.7 51094.72 51095.22 51094.97 18.2 51108.78 51109.28 51109.03 20.2 51122.78 51123.28 51123.03 20.5 51136.72 51137.22 51136.97 17.7 51150.72 51151.22 51150.97 14.1 51164.72 51165.22 51164.97 14.6 51178.72 51179.22 51178.97 17.4 51192.78 51193.28 51193.03 19.1 51206.78 51207.28 51207.03 16.2 51220.78 51221.28 51221.03 16.1 51234.78 51235.28 51235.03 5.6 51248.72 51249.22 51248.97 13.2 51262.72 51263.22 51262.97 10.5 51276.72 51277.22 51276.97 16.0 51290.72 51291.22 51290.97 12.1 51304.72 51305.22 51304.97 11.3 51318.78 51319.28 51319.03 18.0 51332.72 51333.22 51332.97 9.7 51346.78 51347.28 51347.03 12.3 51360.72 51361.22 51360.97 8.6 51374.72 51375.22 51374.97 15.1 51388.78 51389.28 51389.03 11.0 51402.72 51403.22 51402.97 12.8 51416.78 51417.28 51417.03 18.6 51430.72 51431.22 51430.97 21.5 51444.72 51445.22 51444.97 17.2 51458.72 51459.22 51458.97 16.5 51472.72 51473.22 51472.97 16.4 51486.72 51487.22 51486.97 19.2 51589.84 51590.34 51590.09 19.2 51603.84 51604.34 51604.09 11.2 51617.84 51618.34 51618.09 11.1 51631.84 51632.34 51632.09 14.1 51645.84 51646.34 51646.09 8.9 51659.72 51660.22 51659.97 6.4 51673.78 51674.28 51674.03 8.2 51687.78 51688.28 51688.03 6.9 51701.72 51702.22 51701.97 14.2 51715.78 51716.28 51716.03 7.6 51729.72 51730.22 51729.97 10.2 51743.84 51744.34 51744.09 5.6 51757.84 51758.34 51758.09 -1.5 51771.72 51772.22 51771.97 2.6 51785.72 51786.22 51785.97 8.4 51799.78 51800.28 51800.03 -1.3 51813.78 51814.28 51814.03 3.8 51827.72 51828.22 51827.97 8.8 51841.72 51842.22 51841.97 12.6 51855.72 51856.22 51855.97 9.9 51869.72 51870.22 51869.97 10.0 51883.78 51884.28 51884.03 1.0 51897.72 51898.22 51897.97 15.6 51911.72 51912.22 51911.97 6.0 51925.72 51926.22 51925.97 11.2 51939.72 51940.22 51939.97 8.9 51953.72 51954.22 51953.97 16.2 51967.72 51968.22 51967.97 6.5 51981.72 51982.22 51981.97 -0.2 51995.72 51996.22 51995.97 5.7 52009.72 52010.22 52009.97 5.6 52023.78 52024.28 52024.03 -1.9 52037.72 52038.22 52037.97 2.6 52051.78 52052.28 52052.03 6.2 52065.78 52066.28 52066.03 1.4 52079.72 52080.22 52079.97 4.2 52093.72 52094.22 52093.97 -2.8 52107.72 52108.22 52107.97 13.3 52121.78 52122.28 52122.03 3.0 52135.72 52136.22 52135.97 17.5 52149.72 52150.22 52149.97 15.7 52163.72 52164.22 52163.97 10.6 52177.78 52178.28 52178.03 1.5 52191.72 52192.22 52191.97 14.4 52205.72 52206.22 52205.97 8.5 52219.72 52220.22 52219.97 8.1 52233.72 52234.22 52233.97 8.0 52247.78 52248.28 52248.03 23.2 52261.72 52262.22 52261.97 13.5 52275.72 52276.22 52275.97 20.1 52289.78 52290.28 52290.03 18.0 52303.72 52304.22 52303.97 13.4 52317.72 52318.22 52317.97 14.9 52331.78 52332.28 52332.03 6.8 52345.72 52346.22 52345.97 13.6 52359.72 52360.22 52359.97 9.6 52373.72 52374.22 52373.97 12.7 52387.72 52388.22 52387.97 14.1 52401.72 52402.22 52401.97 10.3 52415.72 52416.22 52415.97 10.2 52429.72 52430.22 52429.97 9.6 52443.72 52444.22 52443.97 12.2 52457.78 52458.28 52458.03 18.3 52471.72 52472.22 52471.97 11.9 52485.72 52486.22 52485.97 7.2 53017.84 53018.34 53018.09 26.1 53031.84 53032.34 53032.09 24.0 53045.91 53046.41 53046.16 10.3 53059.84 53060.34 53060.09 12.6 53073.91 53074.41 53074.16 -1.8 53087.72 53088.22 53087.97 35.3 53101.78 53102.28 53102.03 14.1 53115.78 53116.28 53116.03 12.9 53129.72 53130.22 53129.97 21.4 53143.72 53144.22 53143.97 18.5 53157.72 53158.22 53157.97 21.6 53171.84 53172.34 53172.09 16.7 53185.91 53186.41 53186.16 6.7 53199.72 53200.22 53199.97 25.8 53213.78 53214.28 53214.03 10.6 53227.72 53228.22 53227.97 19.4 53241.72 53242.22 53241.97 14.3 53255.78 53256.28 53256.03 11.6 53269.78 53270.28 53270.03 7.9 53283.78 53284.28 53284.03 14.8 53297.72 53298.22 53297.97 18.1 53311.78 53312.28 53312.03 15.5 53325.78 53326.28 53326.03 5.7 53339.78 53340.28 53340.03 11.8 53353.72 53354.22 53353.97 13.4 53367.72 53368.22 53367.97 28.5 53381.72 53382.22 53381.97 24.5 53395.72 53396.22 53395.97 24.0 53409.72 53410.22 53409.97 19.7 53423.72 53424.22 53423.97 14.8 53437.72 53438.22 53437.97 25.8 53451.72 53452.22 53451.97 20.7 53465.78 53466.28 53466.03 8.1 53479.72 53480.22 53479.97 12.0 53493.72 53494.22 53493.97 13.3 53507.72 53508.22 53507.97 15.4 53521.72 53522.22 53521.97 14.1 53535.72 53536.22 53535.97 18.0 53549.78 53550.28 53550.03 20.8 53563.72 53564.22 53563.97 16.4 53577.72 53578.22 53577.97 20.0 53591.72 53592.22 53591.97 14.4 53605.78 53606.28 53606.03 29.3 53619.72 53620.22 53619.97 15.3 53633.72 53634.22 53633.97 26.5 53647.72 53648.22 53647.97 19.9 53661.72 53662.22 53661.97 24.5 53675.72 53676.22 53675.97 27.2 53689.72 53690.22 53689.97 19.9 53703.72 53704.22 53703.97 23.6 53717.72 53718.22 53717.97 26.6 53731.72 53732.22 53731.97 17.6 53745.72 53746.22 53745.97 21.1 53759.72 53760.22 53759.97 24.6 53773.78 53774.28 53774.03 17.6 53787.72 53788.22 53787.97 18.0 53801.78 53802.28 53802.03 21.0 53815.72 53816.22 53815.97 23.1 53829.72 53830.22 53829.97 16.5 53843.72 53844.22 53843.97 19.0 53857.72 53858.22 53857.97 18.6 53871.78 53872.28 53872.03 13.3 53885.72 53886.22 53885.97 22.4 53899.72 53900.22 53899.97 17.6 53913.72 53914.22 53913.97 27.9 54016.84 54017.34 54017.09 24.4 54030.91 54031.41 54031.16 12.5 54044.84 54045.34 54045.09 21.5 54058.84 54059.34 54059.09 8.8 54072.72 54073.22 54072.97 25.5 54086.72 54087.22 54086.97 20.9 54100.72 54101.22 54100.97 22.2 54114.72 54115.22 54114.97 15.3 54128.72 54129.22 54128.97 20.3 54142.91 54143.41 54143.16 -1.1 55170.97 55171.47 55171.22 16.8 55184.97 55185.47 55185.22 8.1 55199.03 55199.53 55199.28 12.4 55212.97 55213.47 55213.22 15.3 55226.97 55227.47 55227.22 10.0 55240.97 55241.47 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