43 1001 Wennberg, Paul California Institute of Technology Gas Phase Nitric Acid from DC-8 TC4 1 1 2007 07 22 2011 09 07 0 start_UTC, s 3 1 1 1 999999 999999 999999 stop_UTC, s mid_UTC, s HNO3, pptv 0 26 PI_CONTACT_INFO: Address: California Institute of Technology. MC 150-21. 1200 E. California Blvd, Pasadena, CA, 91125. Phone: (626) 395-2447. Fax: (626) 585-1917. email: wennberg@gps.caltech.edu PLATFORM: NASA DC-8 airborne laboratory. LOCATION: Aircraft location data in file TN_20070722.DC8. ASSOCIATED_DATA: N/A INSTRUMENT_INFO: Chemical Ionization Mass Spectrometer. Direct measurements in ambient air. DATA_INFO: Measurements are reported as 0.5 sec averages and in units of pptv. CAUTION: Do not extrapolate data outside of given time interval as these are discrete measurements. Calibration was conducted ~once per hour during the flight using isotopically labeled nitric acid evolved from a perm tube held at constant temperature. Absolute calibration was obtained by collection in water and subsequent ion chromatography. Zeros were conducted ~3 times per hour by passing ambient air through a filter containing nylon wool coated with NaHCO3. UNCERTAINTY: +-(50% of measuremlent value + 50 pptv) ULOD_FLAG: 7777777 ULOD_VALUE: N/A LLOD_FLAG: 8888888 LLOD_VALUE: N/A; N/A; N/A; DM_CONTACT_INFO: John Crounse. California Institute of Technology. Department of Chemistry and Chemical Engineering. MC 150-21. 1200 E. California Blvd. Pasadena, CA 91125. Phone: (626) 395-6868. Fax: (626) 585-1917. email: crounjd@caltech.edu. PROJECT_INFO: TC4 study; 13 July-13 August 2007; Study of cloud processing and tropical convection processes STIPULATIONS_ON_USE: Use of these data requires PI notification and adherence to the TC4 data protocol. OTHER_COMMENTS: N/A REVISION: R1 R1: ULOD and LLOD flags changed to positive values, to conform to Ames format 2.1 specifications. R0: Preliminary Data Revision 0. Water correction has been applied using CIT-CIMS water. Reduction code 1.5 start_UTC stop_UTC mid_UTC HNO3 46528.41 46528.91 46528.66 112.4 46542.41 46542.91 46542.66 101.6 46556.34 46556.84 46556.59 131.0 46570.41 46570.91 46570.66 76.5 46584.41 46584.91 46584.66 33.8 46598.41 46598.91 46598.66 33.9 46612.28 46612.78 46612.53 39.1 46626.28 46626.78 46626.53 30.2 46640.28 46640.78 46640.53 49.9 46654.28 46654.78 46654.53 38.5 46668.41 46668.91 46668.66 48.3 46682.41 46682.91 46682.66 0.6 46696.41 46696.91 46696.66 33.7 46710.28 46710.78 46710.53 30.8 46724.28 46724.78 46724.53 25.4 46738.28 46738.78 46738.53 -7.8 46752.28 46752.78 46752.53 5.3 46766.28 46766.78 46766.53 22.9 46780.28 46780.78 46780.53 367.7 46794.22 46794.72 46794.47 246.8 46808.41 46808.91 46808.66 235.6 46822.28 46822.78 46822.53 298.2 46836.28 46836.78 46836.53 263.1 46850.28 46850.78 46850.53 210.7 46864.28 46864.78 46864.53 192.0 46878.28 46878.78 46878.53 181.3 46892.28 46892.78 46892.53 155.0 46906.28 46906.78 46906.53 152.4 46920.28 46920.78 46920.53 160.2 46934.28 46934.78 46934.53 159.5 46948.28 46948.78 46948.53 130.8 46962.28 46962.78 46962.53 135.8 46976.28 46976.78 46976.53 91.9 46990.28 46990.78 46990.53 134.3 47004.28 47004.78 47004.53 116.3 47018.28 47018.78 47018.53 104.3 47032.28 47032.78 47032.53 114.8 47046.28 47046.78 47046.53 80.0 47060.22 47060.72 47060.47 107.0 47074.28 47074.78 47074.53 71.1 47088.22 47088.72 47088.47 95.8 47102.28 47102.78 47102.53 73.1 47116.28 47116.78 47116.53 121.9 47130.28 47130.78 47130.53 124.4 47144.28 47144.78 47144.53 108.7 47158.28 47158.78 47158.53 99.4 47172.28 47172.78 47172.53 116.0 47186.28 47186.78 47186.53 95.9 47200.28 47200.78 47200.53 89.6 47214.28 47214.78 47214.53 58.5 47228.28 47228.78 47228.53 77.0 47242.28 47242.78 47242.53 58.8 47256.28 47256.78 47256.53 31.8 47270.28 47270.78 47270.53 41.4 47284.28 47284.78 47284.53 2.4 47298.28 47298.78 47298.53 11.9 47312.28 47312.78 47312.53 13.7 47326.28 47326.78 47326.53 11.3 47340.28 47340.78 47340.53 16.2 47354.28 47354.78 47354.53 -5.4 47368.28 47368.78 47368.53 39.4 47382.22 47382.72 47382.47 27.4 47396.22 47396.72 47396.47 40.5 47410.22 47410.72 47410.47 41.7 47508.34 47508.84 47508.59 74.4 47522.41 47522.91 47522.66 34.0 47536.34 47536.84 47536.59 43.8 47550.41 47550.91 47550.66 41.8 47564.41 47564.91 47564.66 24.7 47578.41 47578.91 47578.66 -7.6 47592.28 47592.78 47592.53 33.6 47606.28 47606.78 47606.53 17.2 47620.28 47620.78 47620.53 35.8 47634.28 47634.78 47634.53 29.3 47648.28 47648.78 47648.53 68.9 47662.41 47662.91 47662.66 28.8 47676.41 47676.91 47676.66 47.6 47690.41 47690.91 47690.66 26.1 47704.28 47704.78 47704.53 55.2 47718.28 47718.78 47718.53 28.0 47732.28 47732.78 47732.53 54.0 47746.28 47746.78 47746.53 23.4 47760.28 47760.78 47760.53 36.2 47774.28 47774.78 47774.53 37.2 47788.28 47788.78 47788.53 30.8 47802.41 47802.91 47802.66 33.7 47816.28 47816.78 47816.53 5.6 47830.28 47830.78 47830.53 42.9 47844.28 47844.78 47844.53 55.6 47858.28 47858.78 47858.53 27.9 47872.28 47872.78 47872.53 7.0 47886.22 47886.72 47886.47 48.4 47900.28 47900.78 47900.53 31.6 47914.22 47914.72 47914.47 61.6 47928.28 47928.78 47928.53 52.2 47942.22 47942.72 47942.47 77.6 47956.22 47956.72 47956.47 31.1 47970.28 47970.78 47970.53 43.2 47984.22 47984.72 47984.47 27.4 47998.28 47998.78 47998.53 15.6 48012.22 48012.72 48012.47 75.7 48026.28 48026.78 48026.53 7.2 48040.28 48040.78 48040.53 -4.8 48054.28 48054.78 48054.53 27.0 48068.22 48068.72 48068.47 39.5 48082.28 48082.78 48082.53 45.8 48096.22 48096.72 48096.47 27.4 48110.22 48110.72 48110.47 59.8 48124.28 48124.78 48124.53 33.4 48138.22 48138.72 48138.47 48.5 48152.22 48152.72 48152.47 51.5 48166.22 48166.72 48166.47 30.4 48180.22 48180.72 48180.47 49.1 48194.22 48194.72 48194.47 15.0 48208.22 48208.72 48208.47 33.4 48222.22 48222.72 48222.47 20.7 48236.22 48236.72 48236.47 39.6 48250.22 48250.72 48250.47 37.4 48264.22 48264.72 48264.47 29.0 48278.22 48278.72 48278.47 5.4 48292.28 48292.78 48292.53 1.8 48306.28 48306.78 48306.53 -4.5 48320.22 48320.72 48320.47 38.6 48334.22 48334.72 48334.47 8.2 48348.22 48348.72 48348.47 -4.7 48362.22 48362.72 48362.47 21.1 48376.28 48376.78 48376.53 9.6 48390.22 48390.72 48390.47 35.0 48404.28 48404.78 48404.53 27.7 48501.34 48501.84 48501.59 24.1 48515.41 48515.91 48515.66 5.7 48529.34 48529.84 48529.59 30.5 48543.41 48543.91 48543.66 26.4 48557.34 48557.84 48557.59 37.1 48571.28 48571.78 48571.53 2.0 48585.22 48585.72 48585.47 30.0 48599.22 48599.72 48599.47 19.9 48613.22 48613.72 48613.47 33.2 48627.22 48627.72 48627.47 19.8 48641.28 48641.78 48641.53 10.9 48655.41 48655.91 48655.66 -6.5 48669.41 48669.91 48669.66 22.8 48683.22 48683.72 48683.47 30.2 48697.28 48697.78 48697.53 17.7 48711.22 48711.72 48711.47 38.8 48725.22 48725.72 48725.47 23.8 48739.22 48739.72 48739.47 52.7 48753.22 48753.72 48753.47 49.5 48767.28 48767.78 48767.53 48.8 48781.22 48781.72 48781.47 32.1 48795.28 48795.78 48795.53 63.5 48809.22 48809.72 48809.47 77.1 48823.28 48823.78 48823.53 67.6 48837.22 48837.72 48837.47 131.5 48851.22 48851.72 48851.47 90.1 48865.22 48865.72 48865.47 88.2 48879.28 48879.78 48879.53 101.5 48893.22 48893.72 48893.47 103.6 48907.22 48907.72 48907.47 93.8 48921.22 48921.72 48921.47 107.0 48935.22 48935.72 48935.47 47.5 48949.28 48949.78 48949.53 34.7 48963.22 48963.72 48963.47 33.5 48977.22 48977.72 48977.47 49.5 48991.22 48991.72 48991.47 41.1 49005.22 49005.72 49005.47 39.1 49019.28 49019.78 49019.53 40.5 49033.22 49033.72 49033.47 23.3 49047.22 49047.72 49047.47 56.6 49061.22 49061.72 49061.47 58.3 49075.28 49075.78 49075.53 17.5 49089.28 49089.78 49089.53 20.0 49103.22 49103.72 49103.47 32.5 49117.22 49117.72 49117.47 8.5 49131.28 49131.78 49131.53 2.5 49145.28 49145.78 49145.53 15.1 49159.22 49159.72 49159.47 19.6 49173.22 49173.72 49173.47 27.3 49187.28 49187.78 49187.53 10.4 49201.28 49201.78 49201.53 33.6 49215.22 49215.72 49215.47 8.4 49229.22 49229.72 49229.47 26.2 49243.22 49243.72 49243.47 44.4 49257.22 49257.72 49257.47 9.5 49271.22 49271.72 49271.47 17.6 49285.22 49285.72 49285.47 18.9 49299.28 49299.78 49299.53 -5.6 49313.22 49313.72 49313.47 15.7 49327.22 49327.72 49327.47 16.9 49341.28 49341.78 49341.53 8.6 49355.22 49355.72 49355.47 12.7 49369.22 49369.72 49369.47 5.0 49383.28 49383.78 49383.53 -8.7 49397.22 49397.72 49397.47 8.3 49588.41 49588.91 49588.66 10.8 49602.41 49602.91 49602.66 24.6 49616.34 49616.84 49616.59 7.2 49630.41 49630.91 49630.66 0.5 49644.34 49644.84 49644.59 19.1 49658.41 49658.91 49658.66 15.0 49672.28 49672.78 49672.53 0.5 49686.22 49686.72 49686.47 19.4 49700.22 49700.72 49700.47 15.8 49714.28 49714.78 49714.53 3.4 49728.22 49728.72 49728.47 12.9 49742.41 49742.91 49742.66 7.6 49756.41 49756.91 49756.66 -24.6 49770.41 49770.91 49770.66 -13.4 49784.28 49784.78 49784.53 2.8 49798.28 49798.78 49798.53 -12.0 49812.22 49812.72 49812.47 2.5 49826.28 49826.78 49826.53 10.6 49840.22 49840.72 49840.47 5.1 49854.22 49854.72 49854.47 9.7 49868.22 49868.72 49868.47 34.6 49882.28 49882.78 49882.53 3.3 49896.28 49896.78 49896.53 -19.7 49910.22 49910.72 49910.47 9.0 49924.22 49924.72 49924.47 3.6 49938.22 49938.72 49938.47 9.4 49952.22 49952.72 49952.47 11.4 49966.22 49966.72 49966.47 5.6 49980.28 49980.78 49980.53 -0.4 49994.22 49994.72 49994.47 11.8 50008.22 50008.72 50008.47 10.4 50022.28 50022.78 50022.53 16.4 50036.22 50036.72 50036.47 34.1 50050.22 50050.72 50050.47 16.6 50064.22 50064.72 50064.47 16.4 50078.22 50078.72 50078.47 15.1 50092.28 50092.78 50092.53 11.8 50106.22 50106.72 50106.47 14.7 50120.22 50120.72 50120.47 -0.3 50134.22 50134.72 50134.47 17.0 50148.28 50148.78 50148.53 20.7 50162.28 50162.78 50162.53 31.1 50176.28 50176.78 50176.53 13.5 50190.22 50190.72 50190.47 31.4 50204.22 50204.72 50204.47 40.2 50218.28 50218.78 50218.53 12.7 50232.28 50232.78 50232.53 20.6 50246.28 50246.78 50246.53 25.5 50260.22 50260.72 50260.47 37.0 50274.22 50274.72 50274.47 39.0 50288.22 50288.72 50288.47 37.3 50302.22 50302.72 50302.47 40.0 50316.28 50316.78 50316.53 33.5 50330.22 50330.72 50330.47 4.5 50344.22 50344.72 50344.47 34.0 50358.28 50358.78 50358.53 6.8 50372.22 50372.72 50372.47 18.8 50386.28 50386.78 50386.53 10.2 50400.28 50400.78 50400.53 19.2 50414.22 50414.72 50414.47 30.1 50428.28 50428.78 50428.53 12.6 50442.28 50442.78 50442.53 5.1 50456.28 50456.78 50456.53 19.1 50470.28 50470.78 50470.53 25.6 50484.22 50484.72 50484.47 30.9 50588.34 50588.84 50588.59 25.2 50602.41 50602.91 50602.66 16.9 50616.41 50616.91 50616.66 15.4 50630.41 50630.91 50630.66 2.7 50644.41 50644.91 50644.66 21.4 50658.41 50658.91 50658.66 25.0 50672.28 50672.78 50672.53 6.3 50686.28 50686.78 50686.53 10.4 50700.28 50700.78 50700.53 3.2 50714.28 50714.78 50714.53 11.9 50728.28 50728.78 50728.53 14.1 50742.41 50742.91 50742.66 11.3 50756.41 50756.91 50756.66 17.8 50770.41 50770.91 50770.66 29.9 50784.28 50784.78 50784.53 25.7 50798.22 50798.72 50798.47 20.7 50812.28 50812.78 50812.53 6.5 50826.28 50826.78 50826.53 20.9 50840.28 50840.78 50840.53 8.2 50854.28 50854.78 50854.53 13.2 50868.28 50868.78 50868.53 16.1 50882.28 50882.78 50882.53 -10.9 50896.28 50896.78 50896.53 9.4 50910.28 50910.78 50910.53 -2.3 50924.22 50924.72 50924.47 15.2 50938.28 50938.78 50938.53 2.9 50952.28 50952.78 50952.53 12.1 50966.22 50966.72 50966.47 18.7 50980.22 50980.72 50980.47 22.1 50994.22 50994.72 50994.47 14.0 51008.22 51008.72 51008.47 28.2 51022.28 51022.78 51022.53 18.9 51036.28 51036.78 51036.53 8.5 51050.28 51050.78 51050.53 18.7 51064.28 51064.78 51064.53 7.5 51078.28 51078.78 51078.53 11.3 51092.28 51092.78 51092.53 18.2 51106.22 51106.72 51106.47 20.3 51120.22 51120.72 51120.47 22.9 51134.28 51134.78 51134.53 20.9 51148.28 51148.78 51148.53 17.4 51162.28 51162.78 51162.53 22.9 51176.28 51176.78 51176.53 -5.0 51190.22 51190.72 51190.47 8.6 51204.28 51204.78 51204.53 22.4 51218.28 51218.78 51218.53 3.5 51232.28 51232.78 51232.53 -3.6 51246.28 51246.78 51246.53 12.4 51260.28 51260.78 51260.53 1.3 51274.28 51274.78 51274.53 4.6 51288.28 51288.78 51288.53 7.1 51302.28 51302.78 51302.53 3.8 51316.28 51316.78 51316.53 7.7 51330.28 51330.78 51330.53 2.9 51344.28 51344.78 51344.53 9.2 51358.28 51358.78 51358.53 14.4 51372.28 51372.78 51372.53 0.6 51386.22 51386.72 51386.47 27.7 51400.28 51400.78 51400.53 3.6 51414.22 51414.72 51414.47 21.2 51428.28 51428.78 51428.53 28.6 51442.28 51442.78 51442.53 21.0 51456.22 51456.72 51456.47 20.8 51470.28 51470.78 51470.53 14.0 51484.28 51484.78 51484.53 13.3 51587.41 51587.91 51587.66 4.2 51601.41 51601.91 51601.66 -9.4 51615.41 51615.91 51615.66 -9.7 51629.41 51629.91 51629.66 6.9 51643.41 51643.91 51643.66 8.1 51657.28 51657.78 51657.53 16.5 51671.28 51671.78 51671.53 21.1 51685.28 51685.78 51685.53 16.5 51699.28 51699.78 51699.53 7.1 51713.28 51713.78 51713.53 7.0 51727.22 51727.72 51727.47 18.6 51741.41 51741.91 51741.66 4.0 51755.41 51755.91 51755.66 7.5 51769.22 51769.72 51769.47 33.7 51783.22 51783.72 51783.47 7.8 51797.28 51797.78 51797.53 1.5 51811.22 51811.72 51811.47 26.8 51825.28 51825.78 51825.53 27.8 51839.28 51839.78 51839.53 7.6 51853.28 51853.78 51853.53 9.0 51867.28 51867.78 51867.53 4.0 51881.28 51881.78 51881.53 14.9 51895.28 51895.78 51895.53 11.7 51909.22 51909.72 51909.47 20.8 51923.22 51923.72 51923.47 20.0 51937.22 51937.72 51937.47 17.4 51951.22 51951.72 51951.47 13.0 51965.22 51965.72 51965.47 19.1 51979.28 51979.78 51979.53 4.0 51993.28 51993.78 51993.53 13.9 52007.22 52007.72 52007.47 16.2 52021.22 52021.72 52021.47 14.4 52035.22 52035.72 52035.47 19.3 52049.22 52049.72 52049.47 10.3 52063.28 52063.78 52063.53 13.3 52077.28 52077.78 52077.53 21.0 52091.28 52091.78 52091.53 18.8 52105.22 52105.72 52105.47 22.7 52119.22 52119.72 52119.47 6.9 52133.22 52133.72 52133.47 10.9 52147.22 52147.72 52147.47 25.6 52161.28 52161.78 52161.53 12.6 52175.28 52175.78 52175.53 12.5 52189.22 52189.72 52189.47 8.3 52203.28 52203.78 52203.53 -5.2 52217.28 52217.78 52217.53 6.4 52231.22 52231.72 52231.47 16.0 52245.28 52245.78 52245.53 28.8 52259.22 52259.72 52259.47 33.5 52273.28 52273.78 52273.53 5.4 52287.22 52287.72 52287.47 16.7 52301.28 52301.78 52301.53 10.4 52315.28 52315.78 52315.53 17.4 52329.28 52329.78 52329.53 2.8 52343.28 52343.78 52343.53 3.5 52357.28 52357.78 52357.53 5.6 52371.28 52371.78 52371.53 10.2 52385.28 52385.78 52385.53 13.6 52399.28 52399.78 52399.53 10.7 52413.28 52413.78 52413.53 16.2 52427.22 52427.72 52427.47 22.3 52441.22 52441.72 52441.47 21.2 52455.28 52455.78 52455.53 4.0 52469.28 52469.78 52469.53 8.6 52483.28 52483.78 52483.53 8.9 53015.41 53015.91 53015.66 0.9 53029.34 53029.84 53029.59 4.5 53043.34 53043.84 53043.59 9.5 53057.41 53057.91 53057.66 -13.4 53071.34 53071.84 53071.59 1.8 53085.22 53085.72 53085.47 8.7 53099.22 53099.72 53099.47 3.2 53113.22 53113.72 53113.47 9.0 53127.22 53127.72 53127.47 16.2 53141.22 53141.72 53141.47 4.9 53155.28 53155.78 53155.53 8.0 53169.41 53169.91 53169.66 -0.7 53183.41 53183.91 53183.66 -3.8 53197.22 53197.72 53197.47 15.5 53211.28 53211.78 53211.53 -2.5 53225.22 53225.72 53225.47 12.2 53239.28 53239.78 53239.53 8.7 53253.22 53253.72 53253.47 -1.5 53267.22 53267.72 53267.47 6.6 53281.22 53281.72 53281.47 1.0 53295.28 53295.78 53295.53 -16.0 53309.22 53309.72 53309.47 3.2 53323.28 53323.78 53323.53 2.9 53337.28 53337.78 53337.53 -4.2 53351.28 53351.78 53351.53 1.2 53365.22 53365.72 53365.47 7.2 53379.22 53379.72 53379.47 14.3 53393.28 53393.78 53393.53 7.1 53407.28 53407.78 53407.53 -9.1 53421.28 53421.78 53421.53 2.1 53435.22 53435.72 53435.47 6.8 53449.28 53449.78 53449.53 9.8 53463.28 53463.78 53463.53 0.6 53477.28 53477.78 53477.53 18.5 53491.22 53491.72 53491.47 13.2 53505.28 53505.78 53505.53 -13.3 53519.28 53519.78 53519.53 -0.4 53533.22 53533.72 53533.47 5.6 53547.28 53547.78 53547.53 0.1 53561.28 53561.78 53561.53 6.7 53575.22 53575.72 53575.47 -0.5 53589.28 53589.78 53589.53 8.3 53603.28 53603.78 53603.53 3.4 53617.28 53617.78 53617.53 -1.2 53631.28 53631.78 53631.53 3.6 53645.28 53645.78 53645.53 8.5 53659.28 53659.78 53659.53 -2.7 53673.28 53673.78 53673.53 2.1 53687.28 53687.78 53687.53 -2.2 53701.28 53701.78 53701.53 17.6 53715.28 53715.78 53715.53 3.3 53729.28 53729.78 53729.53 11.7 53743.28 53743.78 53743.53 16.1 53757.28 53757.78 53757.53 7.5 53771.28 53771.78 53771.53 -1.2 53785.28 53785.78 53785.53 0.4 53799.28 53799.78 53799.53 2.9 53813.28 53813.78 53813.53 8.2 53827.28 53827.78 53827.53 22.4 53841.28 53841.78 53841.53 20.0 53855.28 53855.78 53855.53 11.9 53869.22 53869.72 53869.47 12.6 53883.28 53883.78 53883.53 7.4 53897.22 53897.72 53897.47 20.2 53911.28 53911.78 53911.53 9.4 54014.41 54014.91 54014.66 20.5 54028.41 54028.91 54028.66 8.4 54042.41 54042.91 54042.66 13.4 54056.41 54056.91 54056.66 16.8 54070.28 54070.78 54070.53 14.7 54084.22 54084.72 54084.47 27.6 54098.28 54098.78 54098.53 8.8 54112.28 54112.78 54112.53 11.1 54126.28 54126.78 54126.53 15.3 55168.53 55169.03 55168.78 3.7 55182.53 55183.03 55182.78 -0.6 55196.47 55196.97 55196.72 22.1 55210.47 55210.97 55210.72 24.1 55224.53 55225.03 55224.78 4.9 55238.47 55238.97 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