41 1001 Wennberg, Paul California Institute of Technology Gas Phase Hydrogen Cyanide from DC-8 TC4 1 1 2007 07 22 2007 07 23 0 start_UTC, s 3 1 1 1 999999 999999 999999 stop_UTC, s mid_UTC, s HCN, pptv 0 24 PI_CONTACT_INFO: Address: California Institute of Technology. MC 150-21. 1200 E. California Blvd, Pasadena, CA, 91125. Phone: (626) 395-2447. Fax: (626) 585-1917. email: wennberg@gps.caltech.edu PLATFORM: NASA DC-8 airborne laboratory. LOCATION: Aircraft location data in file TN_20070722.DC8. ASSOCIATED_DATA: N/A INSTRUMENT_INFO: Chemical Ionization Mass Spectrometer. Direct measurements in ambient air. DATA_INFO: Measurements are reported as 0.5 sec averages and in units of pptv. CAUTION: Do not extrapolate data outside of given time interval as these are discrete measurements. Calibration was conducted ~once per hour during the flight using H2O2 and HNO3 calibrants, and proxied to HCN using laboratory calibrations. Absolute calibration was obtained in the laboratory by FTIR spectroscopy. Zeros were conducted ~3 times per hour by passing ambient air through a filter containing nylon wool coated with NaHCO3. UNCERTAINTY: +-(50% of measuremlent value + 50 pptv) ULOD_FLAG: -7777 ULOD_VALUE: N/A LLOD_FLAG: -8888 LLOD_VALUE: N/A; N/A; N/A; DM_CONTACT_INFO: John Crounse. California Institute of Technology. Department of Chemistry and Chemical Engineering. MC 150-21. 1200 E. California Blvd. Pasadena, CA 91125. Phone: (626) 395-6868. Fax: (626) 585-1917. email: crounjd@caltech.edu. PROJECT_INFO: TC4 study; 13 July-13 August 2007; Study of cloud processing and tropical convection processes STIPULATIONS_ON_USE: Use of these data requires PI notification and adherence to the TC4 data protocol. OTHER_COMMENTS: N/A REVISION: R0 R0: Preliminary Data Revision 0. Water correction has been applied using CIT-CIMS water. Reduction code 1.5 start_UTC(s) stop_UTC(s) mid_UTC(s) HCN(pptv) 46784.28 46784.78 46784.53 533.4 46798.22 46798.72 46798.47 336.0 46812.34 46812.84 46812.59 385.8 46826.22 46826.72 46826.47 266.7 46840.22 46840.72 46840.47 286.0 46854.22 46854.72 46854.47 186.6 46868.22 46868.72 46868.47 187.9 46882.22 46882.72 46882.47 195.1 46896.28 46896.78 46896.53 178.9 46910.22 46910.72 46910.47 178.1 46924.22 46924.72 46924.47 206.1 46938.22 46938.72 46938.47 169.9 46952.22 46952.72 46952.47 150.4 46966.28 46966.78 46966.53 141.8 46980.22 46980.72 46980.47 162.2 46994.22 46994.72 46994.47 151.8 47008.22 47008.72 47008.47 157.7 47022.22 47022.72 47022.47 161.9 47036.22 47036.72 47036.47 144.9 47050.22 47050.72 47050.47 153.4 47064.28 47064.78 47064.53 142.8 47078.22 47078.72 47078.47 142.6 47092.28 47092.78 47092.53 142.2 47106.28 47106.78 47106.53 133.4 47120.22 47120.72 47120.47 138.0 47134.22 47134.72 47134.47 136.9 47148.22 47148.72 47148.47 149.3 47162.22 47162.72 47162.47 138.1 47176.22 47176.72 47176.47 140.9 47190.22 47190.72 47190.47 158.9 47204.22 47204.72 47204.47 150.3 47218.28 47218.78 47218.53 115.8 47232.28 47232.78 47232.53 132.8 47246.28 47246.78 47246.53 144.8 47260.22 47260.72 47260.47 139.5 47274.28 47274.78 47274.53 155.0 47288.22 47288.72 47288.47 130.9 47302.22 47302.72 47302.47 129.7 47316.22 47316.72 47316.47 127.6 47330.22 47330.72 47330.47 121.9 47344.22 47344.72 47344.47 135.2 47358.22 47358.72 47358.47 133.0 47372.28 47372.78 47372.53 142.1 47386.22 47386.72 47386.47 129.8 47400.22 47400.72 47400.47 138.9 47414.28 47414.78 47414.53 129.4 47512.34 47512.84 47512.59 142.9 47526.41 47526.91 47526.66 138.4 47540.34 47540.84 47540.59 160.0 47554.41 47554.91 47554.66 141.9 47568.34 47568.84 47568.59 151.8 47582.34 47582.84 47582.59 138.1 47596.22 47596.72 47596.47 135.7 47610.22 47610.72 47610.47 144.3 47624.22 47624.72 47624.47 152.3 47638.22 47638.72 47638.47 132.2 47652.34 47652.84 47652.59 148.2 47666.34 47666.84 47666.59 128.2 47680.41 47680.91 47680.66 112.7 47694.22 47694.72 47694.47 126.7 47708.22 47708.72 47708.47 132.6 47722.28 47722.78 47722.53 115.6 47736.22 47736.72 47736.47 115.9 47750.22 47750.72 47750.47 109.2 47764.28 47764.78 47764.53 106.9 47778.22 47778.72 47778.47 98.5 47792.28 47792.78 47792.53 99.2 47806.22 47806.72 47806.47 95.3 47820.22 47820.72 47820.47 112.7 47834.28 47834.78 47834.53 101.5 47848.22 47848.72 47848.47 116.9 47862.22 47862.72 47862.47 118.9 47876.22 47876.72 47876.47 114.5 47890.22 47890.72 47890.47 139.5 47904.22 47904.72 47904.47 125.8 47918.22 47918.72 47918.47 126.9 47932.28 47932.78 47932.53 100.2 47946.22 47946.72 47946.47 116.1 47960.28 47960.78 47960.53 114.6 47974.22 47974.72 47974.47 102.4 47988.22 47988.72 47988.47 90.1 48002.22 48002.72 48002.47 91.5 48016.28 48016.78 48016.53 112.0 48030.22 48030.72 48030.47 106.8 48044.22 48044.72 48044.47 94.4 48058.22 48058.72 48058.47 93.3 48072.22 48072.72 48072.47 96.5 48086.22 48086.72 48086.47 93.8 48100.22 48100.72 48100.47 108.5 48114.28 48114.78 48114.53 78.9 48128.22 48128.72 48128.47 95.3 48142.22 48142.72 48142.47 108.5 48156.28 48156.78 48156.53 99.9 48170.28 48170.78 48170.53 95.1 48184.22 48184.72 48184.47 81.8 48198.28 48198.78 48198.53 113.0 48212.22 48212.72 48212.47 115.3 48226.22 48226.72 48226.47 87.7 48240.22 48240.72 48240.47 70.7 48254.22 48254.72 48254.47 72.4 48268.22 48268.72 48268.47 96.6 48282.22 48282.72 48282.47 69.1 48296.28 48296.78 48296.53 71.1 48310.22 48310.72 48310.47 90.7 48324.22 48324.72 48324.47 106.3 48338.22 48338.72 48338.47 87.0 48352.22 48352.72 48352.47 83.4 48366.28 48366.78 48366.53 84.9 48380.22 48380.72 48380.47 118.7 48394.22 48394.72 48394.47 90.9 48408.22 48408.72 48408.47 89.8 48505.34 48505.84 48505.59 86.8 48519.34 48519.84 48519.59 82.0 48533.34 48533.84 48533.59 75.8 48547.34 48547.84 48547.59 71.5 48561.41 48561.91 48561.66 84.5 48575.22 48575.72 48575.47 89.0 48589.28 48589.78 48589.53 101.0 48603.22 48603.72 48603.47 100.0 48617.28 48617.78 48617.53 116.1 48631.22 48631.72 48631.47 97.8 48645.34 48645.84 48645.59 97.2 48659.34 48659.84 48659.59 95.8 48673.34 48673.84 48673.59 86.1 48687.22 48687.72 48687.47 83.6 48701.22 48701.72 48701.47 100.0 48715.22 48715.72 48715.47 106.7 48729.22 48729.72 48729.47 105.5 48743.28 48743.78 48743.53 82.8 48757.22 48757.72 48757.47 90.5 48771.28 48771.78 48771.53 118.5 48785.22 48785.72 48785.47 113.1 48799.22 48799.72 48799.47 109.5 48813.22 48813.72 48813.47 105.0 48827.22 48827.72 48827.47 101.5 48841.22 48841.72 48841.47 90.5 48855.22 48855.72 48855.47 68.9 48869.22 48869.72 48869.47 109.6 48883.22 48883.72 48883.47 127.8 48897.22 48897.72 48897.47 130.0 48911.28 48911.78 48911.53 128.1 48925.22 48925.72 48925.47 125.1 48939.22 48939.72 48939.47 97.4 48953.22 48953.72 48953.47 108.1 48967.22 48967.72 48967.47 112.4 48981.22 48981.72 48981.47 97.2 48995.22 48995.72 48995.47 96.5 49009.22 49009.72 49009.47 99.4 49023.22 49023.72 49023.47 106.7 49037.22 49037.72 49037.47 117.3 49051.22 49051.72 49051.47 105.7 49065.28 49065.78 49065.53 109.9 49079.22 49079.72 49079.47 97.4 49093.22 49093.72 49093.47 110.0 49107.22 49107.72 49107.47 102.4 49121.28 49121.78 49121.53 87.7 49135.22 49135.72 49135.47 102.1 49149.28 49149.78 49149.53 82.5 49163.22 49163.72 49163.47 88.7 49177.28 49177.78 49177.53 92.3 49191.22 49191.72 49191.47 95.5 49205.22 49205.72 49205.47 97.0 49219.22 49219.72 49219.47 87.6 49233.22 49233.72 49233.47 95.9 49247.22 49247.72 49247.47 103.2 49261.28 49261.78 49261.53 92.6 49275.22 49275.72 49275.47 98.1 49289.22 49289.72 49289.47 87.1 49303.22 49303.72 49303.47 96.3 49317.22 49317.72 49317.47 100.4 49331.22 49331.72 49331.47 99.9 49345.22 49345.72 49345.47 107.0 49359.22 49359.72 49359.47 91.6 49373.22 49373.72 49373.47 100.6 49387.28 49387.78 49387.53 105.3 49401.22 49401.72 49401.47 98.9 49592.34 49592.84 49592.59 118.4 49606.34 49606.84 49606.59 109.4 49620.34 49620.84 49620.59 107.7 49634.34 49634.84 49634.59 103.5 49648.34 49648.84 49648.59 107.2 49662.41 49662.91 49662.66 119.5 49676.22 49676.72 49676.47 112.7 49690.22 49690.72 49690.47 117.6 49704.22 49704.72 49704.47 116.9 49718.22 49718.72 49718.47 110.5 49732.41 49732.91 49732.66 94.9 49746.34 49746.84 49746.59 109.7 49760.41 49760.91 49760.66 109.5 49774.22 49774.72 49774.47 110.5 49788.22 49788.72 49788.47 112.1 49802.22 49802.72 49802.47 122.0 49816.22 49816.72 49816.47 106.9 49830.22 49830.72 49830.47 112.4 49844.22 49844.72 49844.47 124.0 49858.28 49858.78 49858.53 123.9 49872.28 49872.78 49872.53 118.6 49886.28 49886.78 49886.53 142.3 49900.22 49900.72 49900.47 124.3 49914.22 49914.72 49914.47 110.3 49928.22 49928.72 49928.47 162.3 49942.22 49942.72 49942.47 121.3 49956.22 49956.72 49956.47 121.8 49970.28 49970.78 49970.53 122.7 49984.22 49984.72 49984.47 126.9 49998.22 49998.72 49998.47 120.3 50012.28 50012.78 50012.53 124.1 50026.22 50026.72 50026.47 151.9 50040.22 50040.72 50040.47 137.6 50054.22 50054.72 50054.47 130.1 50068.22 50068.72 50068.47 122.6 50082.28 50082.78 50082.53 142.0 50096.28 50096.78 50096.53 148.5 50110.22 50110.72 50110.47 159.4 50124.22 50124.72 50124.47 152.6 50138.22 50138.72 50138.47 175.4 50152.22 50152.72 50152.47 170.3 50166.22 50166.72 50166.47 165.5 50180.22 50180.72 50180.47 169.8 50194.22 50194.72 50194.47 152.6 50208.22 50208.72 50208.47 146.7 50222.22 50222.72 50222.47 150.7 50236.22 50236.72 50236.47 173.9 50250.22 50250.72 50250.47 182.4 50264.28 50264.78 50264.53 162.9 50278.28 50278.78 50278.53 183.0 50292.22 50292.72 50292.47 188.2 50306.22 50306.72 50306.47 193.3 50320.22 50320.72 50320.47 198.8 50334.28 50334.78 50334.53 170.3 50348.22 50348.72 50348.47 178.1 50362.22 50362.72 50362.47 164.3 50376.22 50376.72 50376.47 175.3 50390.22 50390.72 50390.47 182.7 50404.22 50404.72 50404.47 183.3 50418.22 50418.72 50418.47 164.8 50432.22 50432.72 50432.47 175.7 50446.28 50446.78 50446.53 189.7 50460.22 50460.72 50460.47 193.8 50474.22 50474.72 50474.47 167.4 50488.22 50488.72 50488.47 174.6 50592.34 50592.84 50592.59 180.2 50606.34 50606.84 50606.59 185.1 50620.34 50620.84 50620.59 169.8 50634.34 50634.84 50634.59 153.3 50648.34 50648.84 50648.59 193.7 50662.34 50662.84 50662.59 201.7 50676.22 50676.72 50676.47 183.9 50690.22 50690.72 50690.47 184.2 50704.22 50704.72 50704.47 228.3 50718.22 50718.72 50718.47 174.9 50732.34 50732.84 50732.59 209.3 50746.34 50746.84 50746.59 183.7 50760.34 50760.84 50760.59 187.2 50774.22 50774.72 50774.47 178.4 50788.28 50788.78 50788.53 195.5 50802.22 50802.72 50802.47 182.3 50816.22 50816.72 50816.47 169.6 50830.22 50830.72 50830.47 205.9 50844.28 50844.78 50844.53 196.7 50858.22 50858.72 50858.47 195.1 50872.28 50872.78 50872.53 198.9 50886.22 50886.72 50886.47 200.9 50900.22 50900.72 50900.47 174.7 50914.28 50914.78 50914.53 171.8 50928.28 50928.78 50928.53 184.1 50942.22 50942.72 50942.47 207.0 50956.22 50956.72 50956.47 185.3 50970.28 50970.78 50970.53 156.9 50984.22 50984.72 50984.47 205.8 50998.28 50998.78 50998.53 221.3 51012.22 51012.72 51012.47 209.6 51026.22 51026.72 51026.47 199.4 51040.22 51040.72 51040.47 200.7 51054.22 51054.72 51054.47 217.7 51068.28 51068.78 51068.53 222.4 51082.22 51082.72 51082.47 229.2 51096.22 51096.72 51096.47 217.1 51110.22 51110.72 51110.47 202.4 51124.28 51124.78 51124.53 207.1 51138.22 51138.72 51138.47 207.3 51152.22 51152.72 51152.47 196.2 51166.22 51166.72 51166.47 206.4 51180.28 51180.78 51180.53 205.9 51194.28 51194.78 51194.53 236.8 51208.22 51208.72 51208.47 193.9 51222.22 51222.72 51222.47 200.7 51236.22 51236.72 51236.47 198.2 51250.22 51250.72 51250.47 210.7 51264.22 51264.72 51264.47 204.6 51278.28 51278.78 51278.53 186.0 51292.22 51292.72 51292.47 184.3 51306.22 51306.72 51306.47 212.4 51320.28 51320.78 51320.53 205.5 51334.22 51334.72 51334.47 192.3 51348.28 51348.78 51348.53 197.2 51362.22 51362.72 51362.47 189.6 51376.28 51376.78 51376.53 215.1 51390.22 51390.72 51390.47 202.1 51404.22 51404.72 51404.47 216.1 51418.22 51418.72 51418.47 219.7 51432.22 51432.72 51432.47 218.7 51446.22 51446.72 51446.47 218.4 51460.22 51460.72 51460.47 212.2 51474.28 51474.78 51474.53 224.6 51488.28 51488.78 51488.53 238.3 51591.34 51591.84 51591.59 203.4 51605.34 51605.84 51605.59 198.9 51619.34 51619.84 51619.59 179.7 51633.34 51633.84 51633.59 177.1 51647.41 51647.91 51647.66 175.5 51661.22 51661.72 51661.47 158.9 51675.22 51675.72 51675.47 185.2 51689.22 51689.72 51689.47 166.3 51703.22 51703.72 51703.47 178.2 51717.22 51717.72 51717.47 144.2 51731.41 51731.91 51731.66 160.4 51745.34 51745.84 51745.59 149.1 51759.41 51759.91 51759.66 138.9 51773.28 51773.78 51773.53 151.5 51787.28 51787.78 51787.53 139.6 51801.22 51801.72 51801.47 147.3 51815.22 51815.72 51815.47 144.6 51829.22 51829.72 51829.47 150.6 51843.22 51843.72 51843.47 136.9 51857.22 51857.72 51857.47 149.9 51871.22 51871.72 51871.47 155.2 51885.28 51885.78 51885.53 152.6 51899.22 51899.72 51899.47 156.4 51913.22 51913.72 51913.47 144.0 51927.22 51927.72 51927.47 157.1 51941.22 51941.72 51941.47 152.2 51955.22 51955.72 51955.47 139.9 51969.22 51969.72 51969.47 141.9 51983.28 51983.78 51983.53 147.5 51997.28 51997.78 51997.53 127.9 52011.28 52011.78 52011.53 138.8 52025.28 52025.78 52025.53 132.3 52039.28 52039.78 52039.53 137.1 52053.22 52053.72 52053.47 147.4 52067.22 52067.72 52067.47 150.3 52081.22 52081.72 52081.47 142.5 52095.22 52095.72 52095.47 131.4 52109.22 52109.72 52109.47 159.9 52123.22 52123.72 52123.47 173.1 52137.22 52137.72 52137.47 153.5 52151.22 52151.72 52151.47 170.7 52165.22 52165.72 52165.47 180.4 52179.28 52179.78 52179.53 145.1 52193.22 52193.72 52193.47 176.5 52207.22 52207.72 52207.47 148.9 52221.22 52221.72 52221.47 173.0 52235.22 52235.72 52235.47 179.6 52249.22 52249.72 52249.47 208.1 52263.22 52263.72 52263.47 220.8 52277.22 52277.72 52277.47 244.6 52291.28 52291.78 52291.53 243.3 52305.22 52305.72 52305.47 241.7 52319.22 52319.72 52319.47 249.4 52333.22 52333.72 52333.47 213.2 52347.22 52347.72 52347.47 228.9 52361.22 52361.72 52361.47 203.0 52375.22 52375.72 52375.47 204.0 52389.22 52389.72 52389.47 208.4 52403.22 52403.72 52403.47 207.6 52417.28 52417.78 52417.53 211.0 52431.22 52431.72 52431.47 212.3 52445.22 52445.72 52445.47 201.6 52459.22 52459.72 52459.47 203.5 52473.22 52473.72 52473.47 234.0 52487.28 52487.78 52487.53 251.2 53019.34 53019.84 53019.59 190.7 53033.34 53033.84 53033.59 179.7 53047.34 53047.84 53047.59 178.7 53061.41 53061.91 53061.66 180.1 53075.34 53075.84 53075.59 180.2 53089.22 53089.72 53089.47 198.1 53103.22 53103.72 53103.47 208.2 53117.28 53117.78 53117.53 193.0 53131.22 53131.72 53131.47 183.3 53145.22 53145.72 53145.47 194.4 53159.34 53159.84 53159.59 189.3 53173.34 53173.84 53173.59 197.0 53187.22 53187.72 53187.47 187.1 53201.22 53201.72 53201.47 186.1 53215.22 53215.72 53215.47 169.0 53229.22 53229.72 53229.47 165.8 53243.22 53243.72 53243.47 177.7 53257.22 53257.72 53257.47 170.1 53271.22 53271.72 53271.47 164.4 53285.22 53285.72 53285.47 173.0 53299.22 53299.72 53299.47 163.4 53313.28 53313.78 53313.53 179.1 53327.22 53327.72 53327.47 163.6 53341.22 53341.72 53341.47 180.6 53355.22 53355.72 53355.47 179.4 53369.22 53369.72 53369.47 179.9 53383.22 53383.72 53383.47 180.2 53397.22 53397.72 53397.47 179.5 53411.28 53411.78 53411.53 188.9 53425.22 53425.72 53425.47 193.5 53439.22 53439.72 53439.47 179.7 53453.28 53453.78 53453.53 181.4 53467.22 53467.72 53467.47 175.5 53481.22 53481.72 53481.47 168.4 53495.22 53495.72 53495.47 176.0 53509.28 53509.78 53509.53 165.3 53523.28 53523.78 53523.53 169.2 53537.22 53537.72 53537.47 179.8 53551.28 53551.78 53551.53 214.4 53565.22 53565.72 53565.47 218.8 53579.22 53579.72 53579.47 220.1 53593.22 53593.72 53593.47 214.1 53607.22 53607.72 53607.47 209.2 53621.28 53621.78 53621.53 221.1 53635.22 53635.72 53635.47 227.2 53649.28 53649.78 53649.53 233.5 53663.22 53663.72 53663.47 222.3 53677.28 53677.78 53677.53 241.6 53691.22 53691.72 53691.47 202.3 53705.22 53705.72 53705.47 214.5 53719.22 53719.72 53719.47 212.3 53733.28 53733.78 53733.53 208.0 53747.22 53747.72 53747.47 211.4 53761.28 53761.78 53761.53 235.4 53775.22 53775.72 53775.47 224.9 53789.22 53789.72 53789.47 228.1 53803.22 53803.72 53803.47 247.2 53817.28 53817.78 53817.53 230.9 53831.22 53831.72 53831.47 233.9 53845.28 53845.78 53845.53 245.8 53859.28 53859.78 53859.53 233.6 53873.28 53873.78 53873.53 226.3 53887.22 53887.72 53887.47 196.0 53901.22 53901.72 53901.47 181.0 53915.22 53915.72 53915.47 226.3 54018.34 54018.84 54018.59 251.4 54032.34 54032.84 54032.59 244.9 54046.41 54046.91 54046.66 247.7 54074.22 54074.72 54074.47 261.8 54088.22 54088.72 54088.47 281.9 54102.28 54102.78 54102.53 245.2 54116.22 54116.72 54116.47 267.8 54130.22 54130.72 54130.47 294.1 55172.47 55172.97 55172.72 204.4 55186.47 55186.97 55186.72 225.2 55200.47 55200.97 55200.72 208.3 55214.47 55214.97 55214.72 206.6 55228.53 55229.03 55228.78 193.3 55242.53 55243.03 55242.78 184.5 55256.47 55256.97 55256.72 205.9 55270.47 55270.97 55270.72 227.7 55284.47 55284.97 55284.72 218.9 55298.47 55298.97 55298.72 228.7 55312.47 55312.97 55312.72 218.3 55326.47 55326.97 55326.72 192.1 55340.47 55340.97 55340.72 176.5 55354.47 55354.97 55354.72 175.9 55368.53 55369.03 55368.78 176.1 55382.47 55382.97 55382.72 216.6 55396.47 55396.97 55396.72 192.1 55410.47 55410.97 55410.72 219.0 55424.47 55424.97 55424.72 148.4 55438.47 55438.97 55438.72 200.0 55452.47 55452.97 55452.72 214.0 55466.53 55467.03 55466.78 210.1 55480.47 55480.97 55480.72 220.0 55494.53 55495.03 55494.78 206.0 55508.47 55508.97 55508.72 216.2 55522.47 55522.97 55522.72 222.7 55536.47 55536.97 55536.72 177.8 55550.47 55550.97 55550.72 189.3 55564.47 55564.97 55564.72 190.5 55578.47 55578.97 55578.72 185.5 55592.47 55592.97 55592.72 185.5 55606.47 55606.97 55606.72 190.4 55620.47 55620.97 55620.72 183.9 55634.47 55634.97 55634.72 186.4 55648.47 55648.97 55648.72 205.8 55662.47 55662.97 55662.72 216.6 55676.47 55676.97 55676.72 208.5 55690.47 55690.97 55690.72 192.9 55704.47 55704.97 55704.72 223.7 55718.53 55719.03 55718.78 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