41 1001 Wennberg, Paul California Institute of Technology Gas Phase Peroxynitric Acid from DC-8 TC4 1 1 2007 07 21 2007 07 21 0 start_UTC, s 3 1 1 1 999999 999999 999999 stop_UTC, s mid_UTC, s PNA, pptv 0 24 PI_CONTACT_INFO: Address: California Institute of Technology. MC 150-21. 1200 E. California Blvd, Pasadena, CA, 91125. Phone: (626) 395-2447. Fax: (626) 585-1917. email: wennberg@gps.caltech.edu PLATFORM: NASA DC-8 airborne laboratory. LOCATION: Aircraft location data in file TN_20070721.DC8. ASSOCIATED_DATA: N/A INSTRUMENT_INFO: Chemical Ionization Mass Spectrometer. Direct measurements in ambient air. DATA_INFO: Measurements are reported as 0.5 sec averages and in units of pptv. CAUTION: Do not extrapolate data outside of given time interval as these are discrete measurements. Calibration was conducted ~once per hour during the flight using H2O2 and HNO3 calibrants, and proxied to PNA using laboratory calibrations. Absolute calibration was obtained in the laboratory by thermal decomposition and NO2 measurement. Zeros were conducted ~3 times per hour by passing ambient air through a filter containing nylon wool coated with NaHCO3. UNCERTAINTY: +-(100% of measuremlent value + 20 pptv) ULOD_FLAG: -7777 ULOD_VALUE: N/A LLOD_FLAG: -8888 LLOD_VALUE: N/A; N/A; N/A; DM_CONTACT_INFO: John Crounse. California Institute of Technology. Department of Chemistry and Chemical Engineering. MC 150-21. 1200 E. California Blvd. Pasadena, CA 91125. Phone: (626) 395-6868. Fax: (626) 585-1917. email: crounjd@caltech.edu. PROJECT_INFO: TC4 study; 13 July-13 August 2007; Study of cloud processing and tropical convection processes STIPULATIONS_ON_USE: Use of these data requires PI notification and adherence to the TC4 data protocol. OTHER_COMMENTS: N/A REVISION: R0 R0: Preliminary Data Revision 0. Water correction has been applied using CIT-CIMS water. Reduction code 1.5 start_UTC(s) stop_UTC(s) mid_UTC(s) PNA(pptv) 48479.84 48480.34 48480.09 10.1 48493.84 48494.34 48494.09 10.0 48507.84 48508.34 48508.09 12.5 48521.84 48522.34 48522.09 20.4 48535.84 48536.34 48536.09 31.6 48549.84 48550.34 48550.09 39.8 48563.84 48564.34 48564.09 33.0 48577.72 48578.22 48577.97 25.3 48591.72 48592.22 48591.97 25.6 48605.72 48606.22 48605.97 17.9 48619.72 48620.22 48619.97 31.5 48633.84 48634.34 48634.09 20.3 48647.84 48648.34 48648.09 21.9 48661.91 48662.41 48662.16 18.3 48675.72 48676.22 48675.97 26.1 48689.72 48690.22 48689.97 38.8 48703.72 48704.22 48703.97 24.6 48717.78 48718.28 48718.03 24.9 48731.72 48732.22 48731.97 31.8 48745.72 48746.22 48745.97 26.9 48759.78 48760.28 48760.03 11.2 48773.84 48774.34 48774.09 22.0 48787.72 48788.22 48787.97 27.4 48801.72 48802.22 48801.97 34.3 48815.78 48816.28 48816.03 34.3 48829.72 48830.22 48829.97 21.4 48843.78 48844.28 48844.03 28.5 48857.72 48858.22 48857.97 27.0 48871.72 48872.22 48871.97 20.2 48885.72 48886.22 48885.97 19.3 48899.72 48900.22 48899.97 15.6 48913.72 48914.22 48913.97 19.5 48927.72 48928.22 48927.97 7.1 48941.72 48942.22 48941.97 33.6 48955.72 48956.22 48955.97 23.3 48969.72 48970.22 48969.97 33.3 48983.72 48984.22 48983.97 33.6 48997.72 48998.22 48997.97 24.3 49011.78 49012.28 49012.03 29.9 49025.78 49026.28 49026.03 25.4 49039.72 49040.22 49039.97 20.6 49053.72 49054.22 49053.97 19.7 49067.72 49068.22 49067.97 15.7 49081.72 49082.22 49081.97 20.2 49095.72 49096.22 49095.97 25.0 49109.72 49110.22 49109.97 17.1 49123.72 49124.22 49123.97 31.9 49137.72 49138.22 49137.97 20.9 49151.72 49152.22 49151.97 8.2 49165.72 49166.22 49165.97 22.5 49179.72 49180.22 49179.97 19.9 49193.72 49194.22 49193.97 21.2 49207.72 49208.22 49207.97 20.9 49221.72 49222.22 49221.97 24.2 49235.78 49236.28 49236.03 29.8 49249.72 49250.22 49249.97 51.7 49263.72 49264.22 49263.97 55.3 49277.72 49278.22 49277.97 34.2 49291.78 49292.28 49292.03 40.2 49305.78 49306.28 49306.03 28.6 49319.72 49320.22 49319.97 25.3 49333.72 49334.22 49333.97 42.1 49347.72 49348.22 49347.97 39.6 49361.78 49362.28 49362.03 22.0 49375.72 49376.22 49375.97 31.0 49477.84 49478.34 49478.09 7.5 49491.84 49492.34 49492.09 18.3 49505.84 49506.34 49506.09 25.4 49519.84 49520.34 49520.09 25.2 49533.84 49534.34 49534.09 24.3 49547.84 49548.34 49548.09 15.3 49561.72 49562.22 49561.97 29.9 49575.72 49576.22 49575.97 14.8 49589.78 49590.28 49590.03 7.7 49603.78 49604.28 49604.03 29.2 49617.72 49618.22 49617.97 37.7 49631.84 49632.34 49632.09 36.5 49645.84 49646.34 49646.09 33.8 49659.84 49660.34 49660.09 45.7 49673.72 49674.22 49673.97 37.5 49687.78 49688.28 49688.03 25.1 49701.72 49702.22 49701.97 31.3 49715.72 49716.22 49715.97 39.7 49729.78 49730.28 49730.03 31.5 49743.78 49744.28 49744.03 43.9 49757.72 49758.22 49757.97 61.0 49771.91 49772.41 49772.16 67.1 49785.72 49786.22 49785.97 62.3 49799.72 49800.22 49799.97 59.0 49813.72 49814.22 49813.97 51.4 49827.72 49828.22 49827.97 39.2 49841.72 49842.22 49841.97 58.0 49855.72 49856.22 49855.97 42.6 49869.72 49870.22 49869.97 50.3 49883.72 49884.22 49883.97 54.4 49897.78 49898.28 49898.03 80.1 49911.72 49912.22 49911.97 32.7 49925.72 49926.22 49925.97 47.1 49939.78 49940.28 49940.03 39.5 49953.78 49954.28 49954.03 51.5 49967.72 49968.22 49967.97 50.5 49981.72 49982.22 49981.97 61.9 49995.72 49996.22 49995.97 53.5 50009.72 50010.22 50009.97 28.4 50023.72 50024.22 50023.97 47.3 50037.72 50038.22 50037.97 44.0 50051.78 50052.28 50052.03 26.7 50065.78 50066.28 50066.03 32.1 50079.78 50080.28 50080.03 28.4 50093.72 50094.22 50093.97 21.3 50107.78 50108.28 50108.03 27.9 50121.72 50122.22 50121.97 28.7 50135.78 50136.28 50136.03 31.9 50149.72 50150.22 50149.97 24.2 50163.78 50164.28 50164.03 41.5 50177.72 50178.22 50177.97 69.1 50191.78 50192.28 50192.03 47.5 50205.72 50206.22 50205.97 59.6 50219.72 50220.22 50219.97 78.6 50233.72 50234.22 50233.97 64.2 50247.72 50248.22 50247.97 54.8 50261.72 50262.22 50261.97 39.7 50275.72 50276.22 50275.97 46.0 50289.72 50290.22 50289.97 51.8 50303.72 50304.22 50303.97 59.8 50317.72 50318.22 50317.97 60.8 50331.78 50332.28 50332.03 48.0 50345.72 50346.22 50345.97 39.9 50359.72 50360.22 50359.97 28.0 50373.72 50374.22 50373.97 43.9 50476.84 50477.34 50477.09 32.9 50490.84 50491.34 50491.09 29.3 50504.91 50505.41 50505.16 39.4 50518.91 50519.41 50519.16 31.5 50532.84 50533.34 50533.09 20.4 50546.72 50547.22 50546.97 30.7 50560.72 50561.22 50560.97 31.8 50574.78 50575.28 50575.03 40.7 50588.72 50589.22 50588.97 30.3 50602.78 50603.28 50603.03 42.8 50616.78 50617.28 50617.03 30.9 50630.84 50631.34 50631.09 32.8 50644.84 50645.34 50645.09 44.0 50658.72 50659.22 50658.97 30.7 50672.72 50673.22 50672.97 30.6 50686.72 50687.22 50686.97 36.1 50700.72 50701.22 50700.97 30.7 50714.72 50715.22 50714.97 29.0 50728.72 50729.22 50728.97 36.6 50742.72 50743.22 50742.97 32.4 50756.72 50757.22 50756.97 23.1 50770.78 50771.28 50771.03 27.5 50784.72 50785.22 50784.97 44.4 50798.78 50799.28 50799.03 30.2 50812.78 50813.28 50813.03 33.5 50826.78 50827.28 50827.03 33.2 50840.78 50841.28 50841.03 23.4 50854.72 50855.22 50854.97 24.8 50868.72 50869.22 50868.97 26.8 50882.72 50883.22 50882.97 35.6 50896.72 50897.22 50896.97 51.0 50910.72 50911.22 50910.97 49.3 50924.72 50925.22 50924.97 34.8 50938.72 50939.22 50938.97 39.9 50952.72 50953.22 50952.97 33.4 50966.78 50967.28 50967.03 28.6 50980.72 50981.22 50980.97 31.6 50994.78 50995.28 50995.03 35.1 51008.72 51009.22 51008.97 40.7 51022.78 51023.28 51023.03 24.0 51036.72 51037.22 51036.97 31.5 51050.72 51051.22 51050.97 43.6 51064.72 51065.22 51064.97 34.2 51078.78 51079.28 51079.03 59.4 51092.72 51093.22 51092.97 40.6 51106.72 51107.22 51106.97 35.2 51120.72 51121.22 51120.97 38.2 51134.72 51135.22 51134.97 24.1 51148.72 51149.22 51148.97 27.2 51162.72 51163.22 51162.97 31.6 51176.72 51177.22 51176.97 30.5 51190.72 51191.22 51190.97 21.7 51204.72 51205.22 51204.97 22.2 51218.72 51219.22 51218.97 29.5 51232.78 51233.28 51233.03 33.5 51246.72 51247.22 51246.97 43.4 51260.72 51261.22 51260.97 30.1 51274.72 51275.22 51274.97 17.7 51288.72 51289.22 51288.97 25.8 51302.72 51303.22 51302.97 20.2 51316.72 51317.22 51316.97 27.4 51330.72 51331.22 51330.97 21.7 51344.78 51345.28 51345.03 12.2 51358.72 51359.22 51358.97 24.3 51372.78 51373.28 51373.03 25.8 51569.84 51570.34 51570.09 30.0 51583.84 51584.34 51584.09 29.5 51597.84 51598.34 51598.09 42.6 51611.84 51612.34 51612.09 45.2 51625.84 51626.34 51626.09 46.8 51639.84 51640.34 51640.09 62.4 51653.72 51654.22 51653.97 49.6 51667.72 51668.22 51667.97 54.9 51681.72 51682.22 51681.97 44.9 51695.72 51696.22 51695.97 43.8 51709.72 51710.22 51709.97 39.7 51723.84 51724.34 51724.09 42.2 51737.84 51738.34 51738.09 44.8 51751.84 51752.34 51752.09 45.2 51765.72 51766.22 51765.97 41.8 51779.72 51780.22 51779.97 46.2 51793.72 51794.22 51793.97 41.2 51807.78 51808.28 51808.03 61.1 51821.72 51822.22 51821.97 42.9 51835.72 51836.22 51835.97 49.8 51849.72 51850.22 51849.97 51.4 51863.84 51864.34 51864.09 53.6 51877.72 51878.22 51877.97 54.8 51891.72 51892.22 51891.97 67.1 51905.72 51906.22 51905.97 50.8 51919.72 51920.22 51919.97 45.2 51933.78 51934.28 51934.03 43.6 51947.72 51948.22 51947.97 53.5 51961.72 51962.22 51961.97 54.4 51975.72 51976.22 51975.97 62.2 51989.72 51990.22 51989.97 65.1 52003.72 52004.22 52003.97 48.3 52017.72 52018.22 52017.97 52.4 52031.72 52032.22 52031.97 43.7 52045.72 52046.22 52045.97 64.7 52059.78 52060.28 52060.03 70.5 52073.78 52074.28 52074.03 50.8 52087.72 52088.22 52087.97 59.4 52101.78 52102.28 52102.03 42.2 52115.72 52116.22 52115.97 51.9 52129.78 52130.28 52130.03 39.4 52143.78 52144.28 52144.03 56.6 52157.72 52158.22 52157.97 48.4 52171.72 52172.22 52171.97 61.3 52185.72 52186.22 52185.97 60.0 52199.72 52200.22 52199.97 50.8 52213.78 52214.28 52214.03 53.9 52227.78 52228.28 52228.03 47.6 52241.72 52242.22 52241.97 49.7 52255.72 52256.22 52255.97 50.8 52269.72 52270.22 52269.97 54.6 52283.72 52284.22 52283.97 56.7 52297.72 52298.22 52297.97 51.5 52311.72 52312.22 52311.97 38.8 52325.72 52326.22 52325.97 49.4 52339.72 52340.22 52339.97 53.0 52353.78 52354.28 52354.03 49.5 52367.72 52368.22 52367.97 44.8 52381.72 52382.22 52381.97 51.3 52395.72 52396.22 52395.97 45.9 52409.72 52410.22 52409.97 35.0 52423.72 52424.22 52423.97 49.6 52437.72 52438.22 52437.97 45.1 52451.72 52452.22 52451.97 48.6 52465.72 52466.22 52465.97 50.3 52568.84 52569.34 52569.09 52.1 52582.91 52583.41 52583.16 36.2 52596.91 52597.41 52597.16 39.2 52610.84 52611.34 52611.09 55.6 52624.84 52625.34 52625.09 42.8 52638.78 52639.28 52639.03 46.8 52652.78 52653.28 52653.03 45.3 52666.72 52667.22 52666.97 53.3 52680.72 52681.22 52680.97 43.2 52694.72 52695.22 52694.97 48.0 52708.78 52709.28 52709.03 46.5 52722.91 52723.41 52723.16 47.8 52736.84 52737.34 52737.09 46.0 52750.72 52751.22 52750.97 46.0 52764.72 52765.22 52764.97 46.0 52778.72 52779.22 52778.97 44.6 52792.72 52793.22 52792.97 44.0 52806.78 52807.28 52807.03 30.5 52820.72 52821.22 52820.97 51.4 52834.72 52835.22 52834.97 34.0 52848.72 52849.22 52848.97 42.4 52862.72 52863.22 52862.97 43.8 52876.72 52877.22 52876.97 45.2 52890.72 52891.22 52890.97 38.6 52904.72 52905.22 52904.97 35.3 52918.72 52919.22 52918.97 43.5 52932.72 52933.22 52932.97 39.3 52946.78 52947.28 52947.03 39.3 52960.72 52961.22 52960.97 30.3 52974.78 52975.28 52975.03 27.0 52988.78 52989.28 52989.03 42.3 53002.72 53003.22 53002.97 42.3 53016.72 53017.22 53016.97 42.6 53030.72 53031.22 53030.97 43.8 53044.78 53045.28 53045.03 33.8 53058.72 53059.22 53058.97 28.8 53072.78 53073.28 53073.03 16.8 53086.78 53087.28 53087.03 16.5 53100.72 53101.22 53100.97 5.0 53114.78 53115.28 53115.03 3.0 53128.72 53129.22 53128.97 19.2 53142.72 53143.22 53142.97 11.7 53156.72 53157.22 53156.97 27.7 53170.72 53171.22 53170.97 12.4 53184.72 53185.22 53184.97 20.5 53198.78 53199.28 53199.03 1.5 53212.72 53213.22 53212.97 14.1 53226.78 53227.28 53227.03 5.9 53240.72 53241.22 53240.97 9.1 53254.78 53255.28 53255.03 -0.2 53268.72 53269.22 53268.97 12.3 53282.78 53283.28 53283.03 -2.6 53296.78 53297.28 53297.03 6.4 53310.72 53311.22 53310.97 10.4 53324.72 53325.22 53324.97 4.2 53338.78 53339.28 53339.03 1.5 53352.78 53353.28 53353.03 16.3 53366.78 53367.28 53367.03 -3.8 53380.72 53381.22 53380.97 10.4 53394.72 53395.22 53394.97 7.7 53408.78 53409.28 53409.03 11.2 53422.78 53423.28 53423.03 0.5 53436.72 53437.22 53436.97 10.4 53450.72 53451.22 53450.97 -1.1 53464.72 53465.22 53464.97 -8.9 53564.03 53564.53 53564.28 3.8 53577.91 53578.41 53578.16 5.2 53591.84 53592.34 53592.09 8.0 53605.91 53606.41 53606.16 -0.2 53619.91 53620.41 53620.16 -0.2 53633.84 53634.34 53634.09 11.9 53647.91 53648.41 53648.16 2.8 53661.91 53662.41 53662.16 -4.5 53675.84 53676.34 53676.09 -0.2 53689.84 53690.34 53690.09 5.9 53703.91 53704.41 53704.16 -4.0 53717.91 53718.41 53718.16 8.9 53731.91 53732.41 53732.16 -9.0 53745.84 53746.34 53746.09 36.0 53759.91 53760.41 53760.16 12.1 53773.91 53774.41 53774.16 -1.9 53787.84 53788.34 53788.09 16.9 53801.91 53802.41 53802.16 -10.5 53815.91 53816.41 53816.16 -5.3 53829.84 53830.34 53830.09 -0.5 53843.91 53844.41 53844.16 -2.3 53857.91 53858.41 53858.16 -4.1 53871.84 53872.34 53872.09 12.0 53885.91 53886.41 53886.16 -4.7 53899.91 53900.41 53900.16 -2.1 53913.84 53914.34 53914.09 3.2 53927.91 53928.41 53928.16 1.3 53941.84 53942.34 53942.09 9.2 53955.91 53956.41 53956.16 -12.4 53969.84 53970.34 53970.09 24.8 53983.91 53984.41 53984.16 -6.8 53997.84 53998.34 53998.09 11.4 54011.84 54012.34 54012.09 4.1 54025.84 54026.34 54026.09 7.9 54039.84 54040.34 54040.09 27.8 54053.91 54054.41 54054.16 7.6 54067.91 54068.41 54068.16 10.8 54081.84 54082.34 54082.09 1.7 54095.91 54096.41 54096.16 13.9 54109.91 54110.41 54110.16 -2.6 54123.91 54124.41 54124.16 -4.8 54137.84 54138.34 54138.09 6.9 54151.84 54152.34 54152.09 33.0 54165.84 54166.34 54166.09 34.9 54179.84 54180.34 54180.09 27.4 54193.91 54194.41 54194.16 4.4 54207.84 54208.34 54208.09 2.5 54221.84 54222.34 54222.09 0.1 54235.84 54236.34 54236.09 13.9 54249.84 54250.34 54250.09 0.1 54263.84 54264.34 54264.09 17.5 54277.91 54278.41 54278.16 16.0 54291.91 54292.41 54292.16 0.9 54305.91 54306.41 54306.16 -14.7 54319.84 54320.34 54320.09 9.9 54333.84 54334.34 54334.09 4.4 54347.91 54348.41 54348.16 -3.4 54361.84 54362.34 54362.09 17.6 54375.84 54376.34 54376.09 11.6 54389.91 54390.41 54390.16 17.6 54403.84 54404.34 54404.09 18.5 54417.91 54418.41 54418.16 -11.4 54431.84 54432.34 54432.09 -4.8 54445.91 54446.41 54446.16 -5.0 54459.91 54460.41 54460.16 1.3 54989.91 54990.41 54990.16 -5.4 55003.84 55004.34 55004.09 12.2 55017.91 55018.41 55018.16 9.0 55031.91 55032.41 55032.16 -5.3 55045.84 55046.34 55046.09 14.4 55059.84 55060.34 55060.09 4.3 55073.91 55074.41 55074.16 10.1 55087.84 55088.34 55088.09 6.7 55101.84 55102.34 55102.09 12.9 55115.91 55116.41 55116.16 -5.8 55129.84 55130.34 55130.09 21.6 55143.84 55144.34 55144.09 20.0 55157.84 55158.34 55158.09 19.6 55171.91 55172.41 55172.16 9.9 55185.91 55186.41 55186.16 -7.1 55199.91 55200.41 55200.16 17.3 55213.84 55214.34 55214.09 -1.6 55227.91 55228.41 55228.16 30.6 55241.84 55242.34 55242.09 20.4 55255.84 55256.34 55256.09 25.2 55269.84 55270.34 55270.09 22.2 55283.84 55284.34 55284.09 40.8 55297.84 55298.34 55298.09 15.4 55311.84 55312.34 55312.09 4.0 55325.84 55326.34 55326.09 18.7 55339.84 55340.34 55340.09 0.9 55353.84 55354.34 55354.09 17.8 55367.84 55368.34 55368.09 14.1 55381.84 55382.34 55382.09 18.3 55395.72 55396.22 55395.97 6.2 55409.72 55410.22 55409.97 28.5 55423.91 55424.41 55424.16 36.0 55437.84 55438.34 55438.09 23.1 55451.91 55452.41 55452.16 20.1 55465.84 55466.34 55466.09 30.5 55479.84 55480.34 55480.09 20.0 55493.78 55494.28 55494.03 18.1 55507.72 55508.22 55507.97 29.0 55521.78 55522.28 55522.03 28.0 55535.72 55536.22 55535.97 19.8 55549.72 55550.22 55549.97 25.9 55563.72 55564.22 55563.97 11.9 55577.84 55578.34 55578.09 15.3 55591.84 55592.34 55592.09 10.3 55605.72 55606.22 55605.97 23.9 55619.72 55620.22 55619.97 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