41 1001 Wennberg, Paul California Institute of Technology Gas Phase Peroxyacetic Acid from DC-8 TC4 1 1 2007 07 21 2007 07 21 0 start_UTC, s 3 1 1 1 999999 999999 999999 stop_UTC, s mid_UTC, s PAA, pptv 0 24 PI_CONTACT_INFO: Address: California Institute of Technology. MC 150-21. 1200 E. California Blvd, Pasadena, CA, 91125. Phone: (626) 395-2447. Fax: (626) 585-1917. email: wennberg@gps.caltech.edu PLATFORM: NASA DC-8 airborne laboratory. LOCATION: Aircraft location data in file TN_20070721.DC8. ASSOCIATED_DATA: N/A INSTRUMENT_INFO: Chemical Ionization Mass Spectrometer. Direct measurements in ambient air. DATA_INFO: Measurements are reported as 0.5 sec averages and in units of pptv. CAUTION: Do not extrapolate data outside of given time interval as these are discrete measurements. Calibration was conducted ~once per hour during the flight using H2O2 and HNO3 calibrants, and proxied to PAA using laboratory calibrations. Absolute calibration was obtained in the laboratory by collection in water and subsequent wet chemistry. Zeros were conducted ~3 times per hour by passing ambient air through a filter containing nylon wool coated with NaHCO3. UNCERTAINTY: +-(50% of measuremlent value + 30 pptv) ULOD_FLAG: -7777 ULOD_VALUE: N/A LLOD_FLAG: -8888 LLOD_VALUE: N/A; N/A; N/A; DM_CONTACT_INFO: John Crounse. California Institute of Technology. Department of Chemistry and Chemical Engineering. MC 150-21. 1200 E. California Blvd. Pasadena, CA 91125. Phone: (626) 395-6868. Fax: (626) 585-1917. email: crounjd@caltech.edu. PROJECT_INFO: TC4 study; 13 July-13 August 2007; Study of cloud processing and tropical convection processes STIPULATIONS_ON_USE: Use of these data requires PI notification and adherence to the TC4 data protocol. OTHER_COMMENTS: N/A REVISION: R0 R0: Preliminary Data Revision 0. Water correction has been applied using CIT-CIMS water. Reduction code 1.5 start_UTC(s) stop_UTC(s) mid_UTC(s) PAA(pptv) 48486.84 48487.34 48487.09 63.1 48500.84 48501.34 48501.09 80.8 48514.84 48515.34 48515.09 70.3 48528.84 48529.34 48529.09 110.7 48542.84 48543.34 48543.09 103.1 48556.91 48557.41 48557.16 113.0 48570.72 48571.22 48570.97 94.0 48584.72 48585.22 48584.97 104.5 48598.72 48599.22 48598.97 79.5 48612.78 48613.28 48613.03 93.2 48626.84 48627.34 48627.09 86.0 48640.84 48641.34 48641.09 89.5 48654.84 48655.34 48655.09 91.3 48668.84 48669.34 48669.09 99.4 48682.72 48683.22 48682.97 99.5 48696.78 48697.28 48697.03 95.2 48710.72 48711.22 48710.97 103.3 48724.78 48725.28 48725.03 83.9 48738.72 48739.22 48738.97 105.7 48752.78 48753.28 48753.03 83.4 48766.78 48767.28 48767.03 103.2 48780.84 48781.34 48781.09 101.6 48794.72 48795.22 48794.97 92.3 48808.72 48809.22 48808.97 98.9 48822.78 48823.28 48823.03 75.8 48836.72 48837.22 48836.97 84.3 48850.72 48851.22 48850.97 97.7 48864.72 48865.22 48864.97 89.6 48878.72 48879.22 48878.97 73.5 48892.72 48893.22 48892.97 118.7 48906.72 48907.22 48906.97 83.8 48920.72 48921.22 48920.97 94.8 48934.72 48935.22 48934.97 110.1 48948.72 48949.22 48948.97 89.6 48962.72 48963.22 48962.97 119.7 48976.72 48977.22 48976.97 105.6 48990.72 48991.22 48990.97 124.4 49004.78 49005.28 49005.03 104.2 49018.72 49019.22 49018.97 65.4 49032.72 49033.22 49032.97 110.1 49046.78 49047.28 49047.03 137.4 49060.72 49061.22 49060.97 98.1 49074.72 49075.22 49074.97 119.4 49088.72 49089.22 49088.97 106.0 49102.72 49103.22 49102.97 99.6 49116.72 49117.22 49116.97 74.5 49130.72 49131.22 49130.97 96.5 49144.78 49145.28 49145.03 71.0 49158.78 49159.28 49159.03 65.0 49172.78 49173.28 49173.03 111.4 49186.72 49187.22 49186.97 79.8 49200.72 49201.22 49200.97 88.1 49214.72 49215.22 49214.97 90.0 49228.72 49229.22 49228.97 115.9 49242.78 49243.28 49243.03 108.6 49256.72 49257.22 49256.97 124.9 49270.72 49271.22 49270.97 115.1 49284.78 49285.28 49285.03 106.1 49298.78 49299.28 49299.03 108.1 49312.78 49313.28 49313.03 92.8 49326.72 49327.22 49326.97 95.4 49340.72 49341.22 49340.97 117.9 49354.72 49355.22 49354.97 130.9 49368.72 49369.22 49368.97 99.2 49382.72 49383.22 49382.97 112.2 49484.84 49485.34 49485.09 95.1 49498.91 49499.41 49499.16 107.5 49512.91 49513.41 49513.16 72.9 49526.84 49527.34 49527.09 100.4 49540.84 49541.34 49541.09 87.4 49554.78 49555.28 49555.03 114.7 49568.72 49569.22 49568.97 86.7 49582.78 49583.28 49583.03 96.1 49596.78 49597.28 49597.03 100.2 49610.72 49611.22 49610.97 100.5 49624.84 49625.34 49625.09 95.9 49638.84 49639.34 49639.09 106.4 49652.84 49653.34 49653.09 107.5 49666.72 49667.22 49666.97 121.5 49680.72 49681.22 49680.97 123.6 49694.72 49695.22 49694.97 113.3 49708.78 49709.28 49709.03 93.5 49722.72 49723.22 49722.97 99.9 49736.72 49737.22 49736.97 98.4 49750.72 49751.22 49750.97 83.6 49764.78 49765.28 49765.03 113.6 49778.78 49779.28 49779.03 92.7 49792.72 49793.22 49792.97 86.2 49806.78 49807.28 49807.03 120.9 49820.72 49821.22 49820.97 107.9 49834.78 49835.28 49835.03 71.2 49848.72 49849.22 49848.97 93.3 49862.72 49863.22 49862.97 112.8 49876.72 49877.22 49876.97 97.4 49890.72 49891.22 49890.97 116.0 49904.72 49905.22 49904.97 158.5 49918.78 49919.28 49919.03 137.6 49932.72 49933.22 49932.97 107.1 49946.72 49947.22 49946.97 112.3 49960.72 49961.22 49960.97 136.2 49974.72 49975.22 49974.97 135.4 49988.72 49989.22 49988.97 125.4 50002.72 50003.22 50002.97 106.6 50016.78 50017.28 50017.03 105.8 50030.72 50031.22 50030.97 133.4 50044.72 50045.22 50044.97 125.0 50058.72 50059.22 50058.97 101.8 50072.78 50073.28 50073.03 108.2 50086.72 50087.22 50086.97 115.0 50100.72 50101.22 50100.97 103.0 50114.72 50115.22 50114.97 118.3 50128.72 50129.22 50128.97 115.7 50142.72 50143.22 50142.97 110.3 50156.72 50157.22 50156.97 138.9 50170.72 50171.22 50170.97 133.0 50184.72 50185.22 50184.97 106.2 50198.78 50199.28 50199.03 105.3 50212.72 50213.22 50212.97 127.0 50226.78 50227.28 50227.03 130.1 50240.72 50241.22 50240.97 141.0 50254.72 50255.22 50254.97 130.4 50268.72 50269.22 50268.97 136.8 50282.72 50283.22 50282.97 97.8 50296.72 50297.22 50296.97 103.9 50310.72 50311.22 50310.97 97.9 50324.72 50325.22 50324.97 80.0 50338.72 50339.22 50338.97 89.6 50352.72 50353.22 50352.97 110.3 50366.72 50367.22 50366.97 86.4 50380.78 50381.28 50381.03 125.8 50483.91 50484.41 50484.16 106.1 50497.84 50498.34 50498.09 104.2 50511.84 50512.34 50512.09 98.7 50525.84 50526.34 50526.09 98.4 50539.84 50540.34 50540.09 99.9 50553.72 50554.22 50553.97 97.6 50567.72 50568.22 50567.97 106.3 50581.72 50582.22 50581.97 98.7 50595.72 50596.22 50595.97 109.4 50609.72 50610.22 50609.97 102.2 50623.91 50624.41 50624.16 100.9 50637.91 50638.41 50638.16 109.1 50651.84 50652.34 50652.09 88.2 50665.72 50666.22 50665.97 107.3 50679.78 50680.28 50680.03 104.2 50693.78 50694.28 50694.03 74.2 50707.72 50708.22 50707.97 95.2 50721.72 50722.22 50721.97 92.5 50735.78 50736.28 50736.03 114.1 50749.72 50750.22 50749.97 114.7 50763.78 50764.28 50764.03 123.0 50777.72 50778.22 50777.97 101.5 50791.72 50792.22 50791.97 110.3 50805.72 50806.22 50805.97 118.0 50819.72 50820.22 50819.97 96.7 50833.78 50834.28 50834.03 124.3 50847.72 50848.22 50847.97 106.7 50861.72 50862.22 50861.97 132.5 50875.78 50876.28 50876.03 112.5 50889.72 50890.22 50889.97 142.8 50903.72 50904.22 50903.97 126.8 50917.72 50918.22 50917.97 127.3 50931.72 50932.22 50931.97 109.2 50945.72 50946.22 50945.97 106.4 50959.78 50960.28 50960.03 97.8 50973.72 50974.22 50973.97 116.7 50987.78 50988.28 50988.03 98.3 51001.72 51002.22 51001.97 113.3 51015.72 51016.22 51015.97 113.9 51029.78 51030.28 51030.03 157.2 51043.72 51044.22 51043.97 111.8 51057.72 51058.22 51057.97 113.8 51071.72 51072.22 51071.97 111.9 51085.72 51086.22 51085.97 98.4 51099.78 51100.28 51100.03 150.6 51113.72 51114.22 51113.97 133.1 51127.72 51128.22 51127.97 112.5 51141.72 51142.22 51141.97 108.1 51155.72 51156.22 51155.97 115.6 51169.72 51170.22 51169.97 117.2 51183.72 51184.22 51183.97 126.2 51197.78 51198.28 51198.03 125.7 51211.72 51212.22 51211.97 115.2 51225.78 51226.28 51226.03 137.7 51239.72 51240.22 51239.97 115.4 51253.78 51254.28 51254.03 130.8 51267.72 51268.22 51267.97 141.1 51281.72 51282.22 51281.97 146.1 51295.72 51296.22 51295.97 144.6 51309.72 51310.22 51309.97 141.4 51323.72 51324.22 51323.97 156.7 51337.72 51338.22 51337.97 148.7 51351.72 51352.22 51351.97 122.9 51365.72 51366.22 51365.97 155.8 51379.72 51380.22 51379.97 137.9 51576.84 51577.34 51577.09 112.3 51590.84 51591.34 51591.09 120.8 51604.84 51605.34 51605.09 140.4 51618.84 51619.34 51619.09 142.6 51632.91 51633.41 51633.16 164.5 51646.72 51647.22 51646.97 117.6 51660.78 51661.28 51661.03 137.2 51688.78 51689.28 51689.03 120.4 51702.72 51703.22 51702.97 122.8 51716.84 51717.34 51717.09 164.5 51730.84 51731.34 51731.09 154.3 51744.91 51745.41 51745.16 157.2 51758.72 51759.22 51758.97 158.1 51772.78 51773.28 51773.03 151.2 51786.78 51787.28 51787.03 155.1 51800.72 51801.22 51800.97 153.1 51814.72 51815.22 51814.97 170.4 51828.78 51829.28 51829.03 145.2 51842.72 51843.22 51842.97 141.0 51856.78 51857.28 51857.03 154.6 51870.72 51871.22 51870.97 147.3 51884.72 51885.22 51884.97 136.7 51898.72 51899.22 51898.97 146.8 51912.72 51913.22 51912.97 142.1 51926.72 51927.22 51926.97 138.5 51940.72 51941.22 51940.97 133.3 51954.72 51955.22 51954.97 119.6 51968.72 51969.22 51968.97 154.0 51982.72 51983.22 51982.97 140.5 51996.78 51997.28 51997.03 122.3 52010.78 52011.28 52011.03 132.8 52024.72 52025.22 52024.97 133.1 52038.72 52039.22 52038.97 132.5 52052.72 52053.22 52052.97 123.1 52066.72 52067.22 52066.97 117.4 52080.78 52081.28 52081.03 129.9 52094.72 52095.22 52094.97 125.2 52108.72 52109.22 52108.97 137.6 52122.72 52123.22 52122.97 138.2 52136.72 52137.22 52136.97 147.1 52150.72 52151.22 52150.97 136.1 52164.72 52165.22 52164.97 144.5 52178.72 52179.22 52178.97 115.0 52192.78 52193.28 52193.03 139.2 52206.72 52207.22 52206.97 123.2 52220.78 52221.28 52221.03 132.2 52234.72 52235.22 52234.97 139.2 52248.72 52249.22 52248.97 136.9 52262.72 52263.22 52262.97 138.8 52276.72 52277.22 52276.97 135.7 52290.72 52291.22 52290.97 148.9 52304.78 52305.28 52305.03 134.0 52318.72 52319.22 52318.97 130.7 52332.78 52333.28 52333.03 149.8 52346.72 52347.22 52346.97 152.0 52360.72 52361.22 52360.97 149.7 52374.72 52375.22 52374.97 155.5 52388.72 52389.22 52388.97 151.8 52402.78 52403.28 52403.03 129.2 52416.72 52417.22 52416.97 143.9 52430.72 52431.22 52430.97 152.1 52444.72 52445.22 52444.97 138.0 52458.72 52459.22 52458.97 134.7 52472.72 52473.22 52472.97 163.8 52575.91 52576.41 52576.16 147.8 52589.84 52590.34 52590.09 134.6 52603.84 52604.34 52604.09 131.9 52617.84 52618.34 52618.09 146.3 52631.84 52632.34 52632.09 139.1 52645.78 52646.28 52646.03 136.4 52659.78 52660.28 52660.03 125.6 52673.72 52674.22 52673.97 125.8 52687.72 52688.22 52687.97 134.7 52701.72 52702.22 52701.97 120.7 52715.91 52716.41 52716.16 135.2 52729.84 52730.34 52730.09 129.0 52743.84 52744.34 52744.09 123.5 52757.78 52758.28 52758.03 112.8 52771.72 52772.22 52771.97 87.1 52785.78 52786.28 52786.03 126.2 52799.72 52800.22 52799.97 135.4 52813.78 52814.28 52814.03 154.6 52827.78 52828.28 52828.03 159.8 52841.72 52842.22 52841.97 132.8 52855.72 52856.22 52855.97 120.1 52869.72 52870.22 52869.97 145.8 52883.78 52884.28 52884.03 121.3 52897.72 52898.22 52897.97 144.4 52911.72 52912.22 52911.97 130.2 52925.72 52926.22 52925.97 138.5 52939.72 52940.22 52939.97 133.1 52953.72 52954.22 52953.97 155.3 52967.72 52968.22 52967.97 140.5 52981.72 52982.22 52981.97 159.1 52995.72 52996.22 52995.97 168.8 53009.72 53010.22 53009.97 172.8 53023.72 53024.22 53023.97 180.0 53037.72 53038.22 53037.97 149.2 53051.72 53052.22 53051.97 77.4 53065.72 53066.22 53065.97 83.7 53079.78 53080.28 53080.03 71.8 53093.72 53094.22 53093.97 43.9 53107.72 53108.22 53107.97 46.6 53121.72 53122.22 53121.97 64.7 53135.78 53136.28 53136.03 70.6 53149.72 53150.22 53149.97 90.1 53163.72 53164.22 53163.97 89.4 53177.72 53178.22 53177.97 91.9 53191.72 53192.22 53191.97 131.4 53205.72 53206.22 53205.97 132.9 53219.72 53220.22 53219.97 131.0 53233.78 53234.28 53234.03 60.9 53247.72 53248.22 53247.97 89.8 53261.78 53262.28 53262.03 91.2 53275.72 53276.22 53275.97 79.3 53289.72 53290.22 53289.97 83.4 53303.78 53304.28 53304.03 79.6 53317.78 53318.28 53318.03 83.8 53331.78 53332.28 53332.03 74.7 53345.72 53346.22 53345.97 80.8 53359.78 53360.28 53360.03 64.2 53373.78 53374.28 53374.03 79.5 53387.72 53388.22 53387.97 74.8 53401.78 53402.28 53402.03 72.1 53415.72 53416.22 53415.97 93.1 53429.78 53430.28 53430.03 107.8 53443.72 53444.22 53443.97 101.0 53457.72 53458.22 53457.97 105.4 53471.72 53472.22 53471.97 105.3 53570.91 53571.41 53571.16 103.0 53584.84 53585.34 53585.09 98.7 53598.91 53599.41 53599.16 91.4 53612.91 53613.41 53613.16 107.7 53626.84 53627.34 53627.09 88.0 53640.84 53641.34 53641.09 96.3 53654.91 53655.41 53655.16 85.4 53668.84 53669.34 53669.09 103.5 53682.84 53683.34 53683.09 96.5 53696.84 53697.34 53697.09 98.7 53710.91 53711.41 53711.16 106.3 53724.91 53725.41 53725.16 95.9 53738.84 53739.34 53739.09 98.7 53752.84 53753.34 53753.09 104.2 53766.84 53767.34 53767.09 75.9 53780.84 53781.34 53781.09 101.3 53794.84 53795.34 53795.09 97.3 53808.84 53809.34 53809.09 98.3 53822.84 53823.34 53823.09 105.1 53836.91 53837.41 53837.16 98.9 53850.84 53851.34 53851.09 125.0 53864.84 53865.34 53865.09 96.3 53878.84 53879.34 53879.09 87.6 53892.91 53893.41 53893.16 110.8 53906.84 53907.34 53907.09 97.3 53920.91 53921.41 53921.16 112.2 53934.84 53935.34 53935.09 108.2 53948.91 53949.41 53949.16 139.6 53962.84 53963.34 53963.09 113.8 53976.84 53977.34 53977.09 94.6 53990.84 53991.34 53991.09 100.2 54004.84 54005.34 54005.09 112.9 54018.84 54019.34 54019.09 93.0 54032.84 54033.34 54033.09 114.4 54046.84 54047.34 54047.09 101.8 54060.84 54061.34 54061.09 104.8 54074.84 54075.34 54075.09 106.6 54088.91 54089.41 54089.16 109.1 54102.84 54103.34 54103.09 113.1 54116.84 54117.34 54117.09 106.0 54130.84 54131.34 54131.09 106.5 54144.91 54145.41 54145.16 109.0 54158.84 54159.34 54159.09 109.7 54172.84 54173.34 54173.09 126.2 54186.84 54187.34 54187.09 108.1 54200.84 54201.34 54201.09 103.9 54214.84 54215.34 54215.09 56.1 54228.84 54229.34 54229.09 82.1 54242.84 54243.34 54243.09 112.6 54256.84 54257.34 54257.09 115.5 54270.84 54271.34 54271.09 97.6 54284.84 54285.34 54285.09 92.4 54298.84 54299.34 54299.09 88.8 54312.84 54313.34 54313.09 77.9 54326.84 54327.34 54327.09 75.8 54340.84 54341.34 54341.09 114.4 54354.91 54355.41 54355.16 109.3 54368.84 54369.34 54369.09 109.3 54382.84 54383.34 54383.09 100.1 54396.84 54397.34 54397.09 116.8 54410.91 54411.41 54411.16 110.8 54424.84 54425.34 54425.09 96.4 54438.91 54439.41 54439.16 98.8 54452.84 54453.34 54453.09 101.4 54466.84 54467.34 54467.09 102.4 54996.84 54997.34 54997.09 62.8 55010.84 55011.34 55011.09 60.9 55024.84 55025.34 55025.09 69.2 55038.84 55039.34 55039.09 77.2 55052.84 55053.34 55053.09 88.3 55066.84 55067.34 55067.09 92.4 55080.91 55081.41 55081.16 96.5 55094.84 55095.34 55095.09 90.4 55108.84 55109.34 55109.09 61.3 55122.84 55123.34 55123.09 98.3 55136.91 55137.41 55137.16 86.3 55150.84 55151.34 55151.09 62.9 55164.84 55165.34 55165.09 69.6 55178.84 55179.34 55179.09 68.4 55192.84 55193.34 55193.09 61.6 55206.84 55207.34 55207.09 52.2 55220.84 55221.34 55221.09 66.3 55234.84 55235.34 55235.09 87.6 55248.84 55249.34 55249.09 85.3 55262.84 55263.34 55263.09 89.1 55276.78 55277.28 55277.03 86.7 55290.91 55291.41 55291.16 62.7 55304.91 55305.41 55305.16 65.3 55318.84 55319.34 55319.09 42.8 55332.84 55333.34 55333.09 48.2 55346.84 55347.34 55347.09 48.6 55360.84 55361.34 55361.09 47.9 55374.84 55375.34 55375.09 48.3 55388.78 55389.28 55389.03 28.2 55402.78 55403.28 55403.03 60.1 55416.72 55417.22 55416.97 77.2 55430.84 55431.34 55431.09 51.6 55444.84 55445.34 55445.09 60.0 55458.84 55459.34 55459.09 57.3 55472.84 55473.34 55473.09 43.7 55486.84 55487.34 55487.09 49.3 55500.72 55501.22 55500.97 50.6 55514.72 55515.22 55514.97 52.8 55528.72 55529.22 55528.97 37.2 55542.72 55543.22 55542.97 73.9 55556.72 55557.22 55556.97 45.4 55570.84 55571.34 55571.09 40.1 55584.84 55585.34 55585.09 50.4 55598.84 55599.34 55599.09 46.8 55612.72 55613.22 55612.97 61.6 55626.72 55627.22 55626.97 80.1 55640.78 55641.28 55641.03 53.7 55654.72 55655.22 55654.97 44.5 55668.72 55669.22 55668.97 47.7 55682.78 55683.28 55683.03 44.1 55696.72 55697.22 55696.97 26.1 55710.72 55711.22 55710.97 59.5 55724.72 55725.22 55724.97 33.2 55738.72 55739.22 55738.97 60.6 55752.72 55753.22 55752.97 58.6 55766.72 55767.22 55766.97 80.7 55780.72 55781.22 55780.97 73.0 55794.78 55795.28 55795.03 83.8 55808.72 55809.22 55808.97 106.7 55822.72 55823.22 55822.97 85.5 55836.72 55837.22 55836.97 83.2 55850.78 55851.28 55851.03 88.7 55864.72 55865.22 55864.97 79.8 55878.72 55879.22 55878.97 109.6 55892.72 55893.22 55892.97 74.3 55992.84 55993.34 55993.09 84.2 56006.91 56007.41 56007.16 66.5 56020.84 56021.34 56021.09 54.0 56034.84 56035.34 56035.09 68.1 56048.84 56049.34 56049.09 83.1 56062.84 56063.34 56063.09 84.5 56076.84 56077.34 56077.09 68.8 56090.84 56091.34 56091.09 88.1 56104.91 56105.41 56105.16 88.9 56118.84 56119.34 56119.09 82.6 56132.84 56133.34 56133.09 108.2 56146.84 56147.34 56147.09 77.7 56160.84 56161.34 56161.09 78.4 56174.91 56175.41 56175.16 96.4 56188.84 56189.34 56189.09 89.8 56202.84 56203.34 56203.09 66.4 56216.91 56217.41 56217.16 79.6 56230.84 56231.34 56231.09 91.2 56244.84 56245.34 56245.09 83.0 56258.84 56259.34 56259.09 85.9 56272.84 56273.34 56273.09 108.7 56286.91 56287.41 56287.16 90.5 56300.91 56301.41 56301.16 111.7 56314.84 56315.34 56315.09 95.7 56328.84 56329.34 56329.09 100.7 56342.84 56343.34 56343.09 66.3 56356.84 56357.34 56357.09 95.2 56370.84 56371.34 56371.09 73.6 56384.84 56385.34 56385.09 82.1 56398.84 56399.34 56399.09 86.3 56412.84 56413.34 56413.09 66.7 56426.84 56427.34 56427.09 90.3 56440.84 56441.34 56441.09 95.6 56454.91 56455.41 56455.16 86.1 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