44 1001 Wennberg, Paul California Institute of Technology Gas Phase Nitric Acid from DC-8 TC4 1 1 2007 07 17 2011 09 07 0 start_UTC, s 3 1 1 1 999999 999999 999999 stop_UTC, s mid_UTC, s HNO3, pptv 0 27 PI_CONTACT_INFO: Address: California Institute of Technology. MC 150-21. 1200 E. California Blvd, Pasadena, CA, 91125. Phone: (626) 395-2447. Fax: (626) 585-1917. email: wennberg@gps.caltech.edu PLATFORM: NASA DC-8 airborne laboratory. LOCATION: Aircraft location data in file TN_20070717.DC8. ASSOCIATED_DATA: N/A INSTRUMENT_INFO: Chemical Ionization Mass Spectrometer. Direct measurements in ambient air. DATA_INFO: Measurements are reported as 0.5 sec averages and in units of pptv. CAUTION: Do not extrapolate data outside of given time interval as these are discrete measurements. Calibration was conducted ~once per hour during the flight using isotopically labeled nitric acid evolved from a perm tube held at constant temperature. Absolute calibration was obtained by collection in water and subsequent ion chromatography. Zeros were conducted ~3 times per hour by passing ambient air through a filter containing nylon wool coated with NaHCO3. UNCERTAINTY: +-(50% of measuremlent value + 50 pptv) ULOD_FLAG: 7777777 ULOD_VALUE: N/A LLOD_FLAG: 8888888 LLOD_VALUE: N/A; N/A; N/A; DM_CONTACT_INFO: John Crounse. California Institute of Technology. Department of Chemistry and Chemical Engineering. MC 150-21. 1200 E. California Blvd. Pasadena, CA 91125. Phone: (626) 395-6868. Fax: (626) 585-1917. email: crounjd@caltech.edu. PROJECT_INFO: TC4 study; 13 July-13 August 2007; Study of cloud processing and tropical convection processes STIPULATIONS_ON_USE: Use of these data requires PI notification and adherence to the TC4 data protocol. OTHER_COMMENTS: N/A REVISION: R2 R2: ULOD and LLOD flags changed to positive values, to conform to Ames format 2.1 specifications. R1: Preliminary Data Revision 0. Water correction has been applied using CIT-CIMS water. Reduction code 1.5 R0: N/A start_UTC stop_UTC mid_UTC HNO3 46622.41 46622.91 46622.66 28.3 46634.41 46634.91 46634.66 -26.8 46646.41 46646.91 46646.66 2.4 46658.41 46658.91 46658.66 286.2 46670.41 46670.91 46670.66 182.3 46682.41 46682.91 46682.66 200.4 46694.41 46694.91 46694.66 137.2 46706.41 46706.91 46706.66 137.0 46718.41 46718.91 46718.66 177.0 46730.28 46730.78 46730.53 157.8 46742.28 46742.78 46742.53 190.8 46754.41 46754.91 46754.66 135.5 46766.41 46766.91 46766.66 159.2 46778.41 46778.91 46778.66 184.1 46790.41 46790.91 46790.66 113.6 46802.41 46802.91 46802.66 160.6 46814.41 46814.91 46814.66 144.8 46826.41 46826.91 46826.66 114.3 46838.28 46838.78 46838.53 139.7 46850.28 46850.78 46850.53 106.4 46862.28 46862.78 46862.53 82.9 46874.28 46874.78 46874.53 69.0 46886.28 46886.78 46886.53 80.1 46898.28 46898.78 46898.53 84.3 46910.41 46910.91 46910.66 97.3 46922.41 46922.91 46922.66 27.9 46934.41 46934.91 46934.66 23.8 46946.28 46946.78 46946.53 86.9 46958.28 46958.78 46958.53 112.6 46970.28 46970.78 46970.53 80.7 46982.28 46982.78 46982.53 54.2 46994.28 46994.78 46994.53 57.8 47006.28 47006.78 47006.53 68.7 47018.28 47018.78 47018.53 52.1 47030.28 47030.78 47030.53 34.0 47042.28 47042.78 47042.53 98.6 47054.28 47054.78 47054.53 11.8 47066.28 47066.78 47066.53 75.6 47078.28 47078.78 47078.53 59.6 47090.28 47090.78 47090.53 56.1 47102.28 47102.78 47102.53 65.3 47114.28 47114.78 47114.53 83.2 47126.28 47126.78 47126.53 67.0 47138.28 47138.78 47138.53 102.3 47150.28 47150.78 47150.53 58.6 47162.28 47162.78 47162.53 59.7 47174.28 47174.78 47174.53 74.0 47186.28 47186.78 47186.53 63.2 47198.28 47198.78 47198.53 71.9 47210.28 47210.78 47210.53 90.5 47222.28 47222.78 47222.53 81.5 47234.28 47234.78 47234.53 108.1 47246.28 47246.78 47246.53 79.1 47258.28 47258.78 47258.53 87.9 47270.28 47270.78 47270.53 133.6 47282.28 47282.78 47282.53 125.7 47294.28 47294.78 47294.53 124.3 47306.28 47306.78 47306.53 113.1 47318.28 47318.78 47318.53 83.4 47330.22 47330.72 47330.47 76.4 47342.22 47342.72 47342.47 68.7 47354.28 47354.78 47354.53 56.3 47366.22 47366.72 47366.47 70.1 47378.28 47378.78 47378.53 57.5 47390.22 47390.72 47390.47 33.9 47402.28 47402.78 47402.53 33.4 47414.28 47414.78 47414.53 22.2 47426.28 47426.78 47426.53 9.3 47438.28 47438.78 47438.53 -5.0 47450.28 47450.78 47450.53 13.5 47462.28 47462.78 47462.53 -8.7 47474.28 47474.78 47474.53 -10.5 47486.22 47486.72 47486.47 -8.6 47498.28 47498.78 47498.53 -9.7 47510.28 47510.78 47510.53 4.7 47599.41 47599.91 47599.66 22.6 47611.41 47611.91 47611.66 38.3 47623.41 47623.91 47623.66 44.9 47635.41 47635.91 47635.66 6171.8 47647.41 47647.91 47647.66 20.6 47659.34 47659.84 47659.59 56.8 47671.41 47671.91 47671.66 60.2 47683.34 47683.84 47683.59 1.1 47695.41 47695.91 47695.66 73.0 47707.41 47707.91 47707.66 98.1 47719.28 47719.78 47719.53 55.5 47731.28 47731.78 47731.53 68.6 47743.41 47743.91 47743.66 79.4 47755.34 47755.84 47755.59 42.5 47767.41 47767.91 47767.66 23.6 47779.41 47779.91 47779.66 24.4 47791.41 47791.91 47791.66 13.4 47803.41 47803.91 47803.66 9.5 47815.34 47815.84 47815.59 28.1 47827.28 47827.78 47827.53 -0.3 47839.28 47839.78 47839.53 12.8 47851.28 47851.78 47851.53 3.6 47863.28 47863.78 47863.53 18.8 47875.28 47875.78 47875.53 8.8 47887.28 47887.78 47887.53 -6.7 47899.41 47899.91 47899.66 -6.4 47911.41 47911.91 47911.66 20.2 47923.41 47923.91 47923.66 18.5 47935.28 47935.78 47935.53 21.8 47947.28 47947.78 47947.53 13.7 47959.28 47959.78 47959.53 9.3 47971.28 47971.78 47971.53 8.6 47983.28 47983.78 47983.53 20.9 47995.28 47995.78 47995.53 -3.9 48007.28 48007.78 48007.53 0.7 48019.22 48019.72 48019.47 29.8 48031.28 48031.78 48031.53 15.5 48043.28 48043.78 48043.53 -2.2 48055.28 48055.78 48055.53 33.3 48067.22 48067.72 48067.47 42.5 48079.28 48079.78 48079.53 42.6 48091.28 48091.78 48091.53 27.2 48103.28 48103.78 48103.53 33.9 48115.28 48115.78 48115.53 40.9 48127.28 48127.78 48127.53 21.2 48139.28 48139.78 48139.53 15.7 48151.28 48151.78 48151.53 29.3 48163.28 48163.78 48163.53 22.7 48175.22 48175.72 48175.47 61.8 48187.28 48187.78 48187.53 41.1 48199.28 48199.78 48199.53 39.8 48211.28 48211.78 48211.53 61.0 48223.28 48223.78 48223.53 46.8 48235.28 48235.78 48235.53 65.2 48247.28 48247.78 48247.53 15.3 48259.28 48259.78 48259.53 11.9 48271.28 48271.78 48271.53 21.4 48283.22 48283.72 48283.47 55.0 48295.28 48295.78 48295.53 29.9 48307.28 48307.78 48307.53 39.0 48319.28 48319.78 48319.53 28.1 48331.28 48331.78 48331.53 47.2 48343.28 48343.78 48343.53 55.4 48355.28 48355.78 48355.53 43.2 48367.28 48367.78 48367.53 60.6 48379.28 48379.78 48379.53 41.6 48391.22 48391.72 48391.47 79.0 48403.28 48403.78 48403.53 16.1 48415.28 48415.78 48415.53 9.9 48427.28 48427.78 48427.53 57.1 48439.28 48439.78 48439.53 8.7 48451.28 48451.78 48451.53 32.0 48463.28 48463.78 48463.53 17.7 48475.28 48475.78 48475.53 49.8 48487.28 48487.78 48487.53 27.8 48499.28 48499.78 48499.53 35.2 48590.41 48590.91 48590.66 19.7 48602.41 48602.91 48602.66 26.6 48614.41 48614.91 48614.66 -6.4 48626.34 48626.84 48626.59 17.5 48638.41 48638.91 48638.66 -4.8 48650.41 48650.91 48650.66 -6.2 48662.41 48662.91 48662.66 11.3 48674.41 48674.91 48674.66 5.3 48686.41 48686.91 48686.66 3.4 48698.28 48698.78 48698.53 13.3 48710.28 48710.78 48710.53 -4.6 48722.28 48722.78 48722.53 -6.2 48734.41 48734.91 48734.66 -14.1 48746.41 48746.91 48746.66 -18.4 48758.41 48758.91 48758.66 -6.0 48770.41 48770.91 48770.66 -10.4 48782.41 48782.91 48782.66 -13.2 48794.41 48794.91 48794.66 6.0 48806.28 48806.78 48806.53 9.2 48818.28 48818.78 48818.53 -7.6 48830.28 48830.78 48830.53 25.5 48842.28 48842.78 48842.53 13.5 48854.28 48854.78 48854.53 -2.8 48866.28 48866.78 48866.53 -4.6 48878.28 48878.78 48878.53 -0.6 48890.41 48890.91 48890.66 -1.5 48902.41 48902.91 48902.66 0.9 48914.41 48914.91 48914.66 -10.4 48926.28 48926.78 48926.53 -6.1 48938.28 48938.78 48938.53 -9.1 48950.28 48950.78 48950.53 -7.9 48962.28 48962.78 48962.53 1.7 48974.28 48974.78 48974.53 -1.4 48986.28 48986.78 48986.53 -8.0 48998.28 48998.78 48998.53 6.5 49010.28 49010.78 49010.53 -17.1 49022.28 49022.78 49022.53 -6.9 49034.28 49034.78 49034.53 3.5 49046.28 49046.78 49046.53 -6.2 49058.28 49058.78 49058.53 -12.4 49070.28 49070.78 49070.53 0.0 49082.28 49082.78 49082.53 -6.3 49094.28 49094.78 49094.53 -18.0 49106.28 49106.78 49106.53 -4.6 49118.28 49118.78 49118.53 3.9 49130.28 49130.78 49130.53 1.2 49142.28 49142.78 49142.53 1.1 49154.28 49154.78 49154.53 8.3 49166.28 49166.78 49166.53 5.6 49178.28 49178.78 49178.53 -0.9 49190.28 49190.78 49190.53 2.8 49202.28 49202.78 49202.53 5.9 49214.28 49214.78 49214.53 5.2 49226.28 49226.78 49226.53 -1.5 49238.28 49238.78 49238.53 -12.9 49250.28 49250.78 49250.53 7.2 49262.28 49262.78 49262.53 -0.5 49274.28 49274.78 49274.53 -10.7 49286.28 49286.78 49286.53 -7.6 49298.28 49298.78 49298.53 0.8 49310.28 49310.78 49310.53 12.0 49322.28 49322.78 49322.53 4.8 49334.28 49334.78 49334.53 -7.0 49346.28 49346.78 49346.53 6.8 49358.28 49358.78 49358.53 -9.3 49370.28 49370.78 49370.53 -13.0 49382.28 49382.78 49382.53 7.1 49394.28 49394.78 49394.53 19.1 49406.28 49406.78 49406.53 0.1 49418.28 49418.78 49418.53 -5.7 49430.28 49430.78 49430.53 22.6 49442.28 49442.78 49442.53 7.1 49454.28 49454.78 49454.53 12.5 49466.28 49466.78 49466.53 15.2 49478.28 49478.78 49478.53 -1.9 49490.28 49490.78 49490.53 10.7 49669.41 49669.91 49669.66 7.0 49681.41 49681.91 49681.66 1.7 49693.41 49693.91 49693.66 7.3 49705.41 49705.91 49705.66 3.3 49717.41 49717.91 49717.66 10.8 49729.41 49729.91 49729.66 8.5 49741.41 49741.91 49741.66 1.4 49753.41 49753.91 49753.66 3.6 49765.41 49765.91 49765.66 7.6 49777.41 49777.91 49777.66 -3.0 49789.41 49789.91 49789.66 5.6 49801.28 49801.78 49801.53 1.7 49813.41 49813.91 49813.66 11.2 49825.41 49825.91 49825.66 7.8 49837.41 49837.91 49837.66 6.7 49849.41 49849.91 49849.66 -2.1 49861.41 49861.91 49861.66 18.9 49873.41 49873.91 49873.66 11.4 49885.41 49885.91 49885.66 13.5 49897.41 49897.91 49897.66 0.3 49909.28 49909.78 49909.53 11.6 49921.28 49921.78 49921.53 3.9 49933.28 49933.78 49933.53 10.0 49945.28 49945.78 49945.53 2.0 49957.28 49957.78 49957.53 13.1 49969.41 49969.91 49969.66 -2.8 49981.41 49981.91 49981.66 -2.8 49993.41 49993.91 49993.66 2.2 50005.41 50005.91 50005.66 3.7 50017.28 50017.78 50017.53 9.8 50029.28 50029.78 50029.53 11.5 50041.28 50041.78 50041.53 -3.1 50053.28 50053.78 50053.53 -1.3 50065.28 50065.78 50065.53 -1.8 50077.28 50077.78 50077.53 -7.4 50089.28 50089.78 50089.53 5.1 50101.28 50101.78 50101.53 -2.7 50113.41 50113.91 50113.66 -2.3 50125.41 50125.91 50125.66 18.7 50137.28 50137.78 50137.53 5.8 50149.28 50149.78 50149.53 3.0 50161.28 50161.78 50161.53 -4.1 50173.28 50173.78 50173.53 18.2 50185.28 50185.78 50185.53 2.6 50197.28 50197.78 50197.53 14.1 50209.28 50209.78 50209.53 19.5 50221.28 50221.78 50221.53 5.0 50233.28 50233.78 50233.53 18.9 50245.28 50245.78 50245.53 18.7 50257.28 50257.78 50257.53 10.0 50269.28 50269.78 50269.53 -0.2 50281.28 50281.78 50281.53 22.7 50293.28 50293.78 50293.53 6.2 50305.28 50305.78 50305.53 14.8 50317.28 50317.78 50317.53 19.4 50329.28 50329.78 50329.53 12.7 50341.28 50341.78 50341.53 5.8 50353.28 50353.78 50353.53 6.7 50365.28 50365.78 50365.53 13.7 50377.28 50377.78 50377.53 4.4 50389.28 50389.78 50389.53 2.4 50401.28 50401.78 50401.53 10.7 50413.28 50413.78 50413.53 13.0 50425.28 50425.78 50425.53 6.0 50437.28 50437.78 50437.53 10.1 50449.28 50449.78 50449.53 3.4 50461.28 50461.78 50461.53 2.3 50473.28 50473.78 50473.53 0.8 50485.28 50485.78 50485.53 4.6 50497.28 50497.78 50497.53 21.4 50509.28 50509.78 50509.53 9.4 50521.28 50521.78 50521.53 -5.4 50533.28 50533.78 50533.53 5.2 50545.28 50545.78 50545.53 13.5 50557.28 50557.78 50557.53 13.4 50569.28 50569.78 50569.53 4.5 51084.41 51084.91 51084.66 15.0 51096.41 51096.91 51096.66 -5.8 51108.41 51108.91 51108.66 4.4 51120.41 51120.91 51120.66 5.5 51132.41 51132.91 51132.66 6.3 51144.41 51144.91 51144.66 7.1 51156.41 51156.91 51156.66 6.6 51168.41 51168.91 51168.66 6.7 51180.41 51180.91 51180.66 -8.4 51192.41 51192.91 51192.66 18.2 51204.41 51204.91 51204.66 26.3 51216.41 51216.91 51216.66 -0.2 51228.41 51228.91 51228.66 5.4 51240.41 51240.91 51240.66 0.4 51252.41 51252.91 51252.66 1.4 51264.41 51264.91 51264.66 -3.4 51276.41 51276.91 51276.66 14.5 51288.41 51288.91 51288.66 19.6 51300.41 51300.91 51300.66 17.8 51312.41 51312.91 51312.66 3.1 51324.41 51324.91 51324.66 11.6 51336.28 51336.78 51336.53 15.5 51348.28 51348.78 51348.53 4.6 51360.28 51360.78 51360.53 -3.4 51372.28 51372.78 51372.53 3.7 51384.41 51384.91 51384.66 16.9 51396.41 51396.91 51396.66 12.5 51408.41 51408.91 51408.66 18.0 51420.41 51420.91 51420.66 16.5 51432.41 51432.91 51432.66 21.1 51444.41 51444.91 51444.66 27.6 51456.28 51456.78 51456.53 13.0 51468.28 51468.78 51468.53 14.9 51480.28 51480.78 51480.53 26.9 51492.28 51492.78 51492.53 24.4 51504.28 51504.78 51504.53 29.4 51516.22 51516.72 51516.47 45.4 51528.41 51528.91 51528.66 19.7 51540.41 51540.91 51540.66 22.9 51552.41 51552.91 51552.66 16.4 51564.22 51564.72 51564.47 41.9 51576.28 51576.78 51576.53 34.4 51588.28 51588.78 51588.53 22.4 51600.28 51600.78 51600.53 36.0 51612.28 51612.78 51612.53 41.9 51624.28 51624.78 51624.53 39.9 51636.22 51636.72 51636.47 48.9 51648.28 51648.78 51648.53 23.7 51660.28 51660.78 51660.53 20.5 51672.28 51672.78 51672.53 19.5 51684.28 51684.78 51684.53 18.8 51696.28 51696.78 51696.53 35.8 51708.28 51708.78 51708.53 11.1 51720.28 51720.78 51720.53 21.4 51732.28 51732.78 51732.53 27.6 51744.28 51744.78 51744.53 1.8 51756.28 51756.78 51756.53 31.9 51768.28 51768.78 51768.53 4.4 51780.28 51780.78 51780.53 11.2 51792.28 51792.78 51792.53 9.8 51804.28 51804.78 51804.53 13.9 51816.28 51816.78 51816.53 14.6 51828.28 51828.78 51828.53 9.4 51840.28 51840.78 51840.53 19.7 51852.28 51852.78 51852.53 22.4 51864.28 51864.78 51864.53 3.9 51876.28 51876.78 51876.53 18.3 51888.28 51888.78 51888.53 32.6 51900.28 51900.78 51900.53 6.2 51912.28 51912.78 51912.53 20.7 51924.28 51924.78 51924.53 20.9 51936.28 51936.78 51936.53 -4.8 51948.28 51948.78 51948.53 26.8 51960.28 51960.78 51960.53 23.1 51972.28 51972.78 51972.53 18.1 51984.28 51984.78 51984.53 23.1 52077.41 52077.91 52077.66 -4.3 52089.41 52089.91 52089.66 9.7 52101.41 52101.91 52101.66 18.8 52113.41 52113.91 52113.66 14.5 52125.41 52125.91 52125.66 3.2 52137.41 52137.91 52137.66 -3.7 52149.41 52149.91 52149.66 5.1 52161.41 52161.91 52161.66 7.1 52173.41 52173.91 52173.66 -7.1 52209.41 52209.91 52209.66 10.7 52221.41 52221.91 52221.66 -8.7 52233.41 52233.91 52233.66 -14.1 52245.41 52245.91 52245.66 -0.5 52257.41 52257.91 52257.66 8.5 52269.41 52269.91 52269.66 -4.4 52281.41 52281.91 52281.66 6.1 52293.41 52293.91 52293.66 1.4 52305.41 52305.91 52305.66 13.9 52317.34 52317.84 52317.59 30.5 52329.28 52329.78 52329.53 -6.0 52341.28 52341.78 52341.53 6.2 52353.28 52353.78 52353.53 24.8 52365.28 52365.78 52365.53 7.9 52377.41 52377.91 52377.66 20.5 52389.41 52389.91 52389.66 -2.3 52401.34 52401.84 52401.59 21.8 52413.41 52413.91 52413.66 5.6 52425.41 52425.91 52425.66 17.3 52437.28 52437.78 52437.53 14.1 52449.28 52449.78 52449.53 10.9 52461.28 52461.78 52461.53 13.6 52473.28 52473.78 52473.53 0.2 52485.28 52485.78 52485.53 -8.9 52497.28 52497.78 52497.53 -6.5 52509.28 52509.78 52509.53 2.3 52521.41 52521.91 52521.66 -13.9 52533.41 52533.91 52533.66 9.2 52545.28 52545.78 52545.53 -1.8 52557.28 52557.78 52557.53 10.8 52569.22 52569.72 52569.47 18.8 52581.28 52581.78 52581.53 -7.6 52593.28 52593.78 52593.53 -1.8 52605.28 52605.78 52605.53 -4.1 52617.28 52617.78 52617.53 8.5 52629.28 52629.78 52629.53 22.1 52641.28 52641.78 52641.53 -17.6 52653.28 52653.78 52653.53 2.1 52665.28 52665.78 52665.53 2.1 52677.28 52677.78 52677.53 4.4 52689.28 52689.78 52689.53 18.9 52701.28 52701.78 52701.53 13.8 52713.28 52713.78 52713.53 -7.6 52725.28 52725.78 52725.53 1.5 52737.28 52737.78 52737.53 11.7 52749.28 52749.78 52749.53 9.7 52761.28 52761.78 52761.53 3.6 52773.28 52773.78 52773.53 19.5 52785.28 52785.78 52785.53 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72499.72 72499.47 78.8 72511.22 72511.72 72511.47 94.7 72523.22 72523.72 72523.47 165.7 72535.22 72535.72 72535.47 311.5 72547.28 72547.78 72547.53 147.2 72559.28 72559.78 72559.53 138.8 72571.28 72571.78 72571.53 116.7 72583.22 72583.72 72583.47 120.3 72595.22 72595.72 72595.47 119.7 72607.28 72607.78 72607.53 75.3 72619.22 72619.72 72619.47 99.8 72631.22 72631.72 72631.47 113.4 72643.28 72643.78 72643.53 137.2 72655.22 72655.72 72655.47 117.4 72667.22 72667.72 72667.47 133.4 72679.22 72679.72 72679.47 111.8 72691.28 72691.78 72691.53 154.3 72703.22 72703.72 72703.47 198.3 72715.22 72715.72 72715.47 212.2 72727.22 72727.72 72727.47 160.0 72739.22 72739.72 72739.47 153.1 72751.22 72751.72 72751.47 171.6 72763.28 72763.78 72763.53 164.7 72775.28 72775.78 72775.53 160.7 72787.22 72787.72 72787.47 157.8 72799.22 72799.72 72799.47 169.1 72811.22 72811.72 72811.47 166.4 72823.22 72823.72 72823.47 166.2 72835.22 72835.72 72835.47 171.5 72847.22 72847.72 72847.47 185.3 72859.28 72859.78 72859.53 188.3 72871.22 72871.72 72871.47 206.3 72883.22 72883.72 72883.47 221.9 72895.22 72895.72 72895.47 257.4 72907.28 72907.78 72907.53 234.9 72919.28 72919.78 72919.53 269.5 72931.22 72931.72 72931.47 293.9 72943.22 72943.72 72943.47 310.7 72955.22 72955.72 72955.47 300.8 72967.22 72967.72 72967.47 308.1 72979.22 72979.72 72979.47 245.7 72991.22 72991.72 72991.47 252.4 73003.22 73003.72 73003.47 259.7 73015.28 73015.78 73015.53 245.6 73027.28 73027.78 73027.53 240.9 73039.22 73039.72 73039.47 252.4 73051.28 73051.78 73051.53 246.5