43 1001 Wennberg, Paul California Institute of Technology Gas Phase Peroxynitric Acid from DC-8 TC4 1 1 2007 07 13 2011 09 07 0 start_UTC, s 3 1 1 1 999999 999999 999999 stop_UTC, s mid_UTC, s PNA, pptv 0 26 PI_CONTACT_INFO: Address: California Institute of Technology. MC 150-21. 1200 E. California Blvd, Pasadena, CA, 91125. Phone: (626) 395-2447. Fax: (626) 585-1917. email: wennberg@gps.caltech.edu PLATFORM: NASA DC-8 airborne laboratory. LOCATION: Aircraft location data in file TN_20070713.DC8. ASSOCIATED_DATA: N/A INSTRUMENT_INFO: Chemical Ionization Mass Spectrometer. Direct measurements in ambient air. DATA_INFO: Measurements are reported as 0.5 sec averages and in units of pptv. CAUTION: Do not extrapolate data outside of given time interval as these are discrete measurements. Calibration was conducted ~once per hour during the flight using H2O2 and HNO3 calibrants, and proxied to PNA using laboratory calibrations. Absolute calibration was obtained in the laboratory by thermal decomposition and NO2 measurement. Zeros were conducted ~3 times per hour by passing ambient air through a filter containing nylon wool coated with NaHCO3. UNCERTAINTY: +-(100% of measuremlent value + 20 pptv) ULOD_FLAG: 7777777 ULOD_VALUE: N/A LLOD_FLAG: 8888888 LLOD_VALUE: N/A; N/A; N/A; DM_CONTACT_INFO: John Crounse. California Institute of Technology. Department of Chemistry and Chemical Engineering. MC 150-21. 1200 E. California Blvd. Pasadena, CA 91125. Phone: (626) 395-6868. Fax: (626) 585-1917. email: crounjd@caltech.edu. PROJECT_INFO: TC4 study; 13 July-13 August 2007; Study of cloud processing and tropical convection processes STIPULATIONS_ON_USE: Use of these data requires PI notification and adherence to the TC4 data protocol. OTHER_COMMENTS: N/A REVISION: R1 R1: ULOD and LLOD flags changed to positive values, to conform to Ames format 2.1 specifications. R0: Preliminary Data Revision 0. Water correction has been applied using CIT-CIMS water. Reduction code 1.5 start_UTC stop_UTC mid_UTC PNA 54309.84 54310.34 54310.09 3.1 54321.84 54322.34 54322.09 10.2 54333.91 54334.41 54334.16 15.3 54345.91 54346.41 54346.16 -2.4 54357.84 54358.34 54358.09 8.6 54369.78 54370.28 54370.03 4.5 54381.72 54382.22 54381.97 6.4 54393.72 54394.22 54393.97 19.6 54405.72 54406.22 54405.97 11.3 54417.72 54418.22 54417.97 7.9 54429.78 54430.28 54430.03 20.9 54441.84 54442.34 54442.09 10.8 54453.84 54454.34 54454.09 9.0 54465.84 54466.34 54466.09 123.0 54477.91 54478.41 54478.16 72.0 54489.78 54490.28 54490.03 89.8 54501.78 54502.28 54502.03 96.5 54513.78 54514.28 54514.03 69.7 54525.78 54526.28 54526.03 100.3 54537.78 54538.28 54538.03 54.0 54549.78 54550.28 54550.03 83.2 54561.78 54562.28 54562.03 57.6 54573.78 54574.28 54574.03 131.9 54585.91 54586.41 54586.16 112.4 54597.78 54598.28 54598.03 59.5 54609.78 54610.28 54610.03 97.8 54621.78 54622.28 54622.03 62.1 54633.78 54634.28 54634.03 116.1 54645.78 54646.28 54646.03 57.9 54657.78 54658.28 54658.03 17.6 54669.78 54670.28 54670.03 28.1 54681.72 54682.22 54681.97 50.7 54693.72 54694.22 54693.97 37.4 54705.78 54706.28 54706.03 14.2 54717.72 54718.22 54717.97 49.3 54729.72 54730.22 54729.97 72.3 54741.78 54742.28 54742.03 28.8 54753.72 54754.22 54753.97 7.5 54765.78 54766.28 54766.03 19.7 54777.72 54778.22 54777.97 44.9 54789.72 54790.22 54789.97 36.9 54801.72 54802.22 54801.97 35.2 54813.78 54814.28 54814.03 10.3 54825.72 54826.22 54825.97 12.6 54837.78 54838.28 54838.03 12.6 54849.72 54850.22 54849.97 9.7 54861.78 54862.28 54862.03 22.9 54873.72 54874.22 54873.97 33.0 54885.72 54886.22 54885.97 2.5 54897.72 54898.22 54897.97 31.4 54909.78 54910.28 54910.03 14.5 54921.78 54922.28 54922.03 24.8 54933.78 54934.28 54934.03 10.6 54945.78 54946.28 54946.03 6.2 54957.78 54958.28 54958.03 18.0 54969.72 54970.22 54969.97 15.5 54981.78 54982.28 54982.03 3.8 54993.78 54994.28 54994.03 1.5 55005.72 55006.22 55005.97 16.4 55017.78 55018.28 55018.03 11.4 55029.78 55030.28 55030.03 8.2 55041.72 55042.22 55041.97 16.1 55053.78 55054.28 55054.03 12.2 55065.72 55066.22 55065.97 14.0 55077.72 55078.22 55077.97 9.2 55089.72 55090.22 55089.97 11.1 55101.78 55102.28 55102.03 256.3 55113.78 55114.28 55114.03 5.9 55125.72 55126.22 55125.97 6.0 55137.72 55138.22 55137.97 15.0 55149.72 55150.22 55149.97 9.0 55161.72 55162.22 55161.97 -13.8 55173.78 55174.28 55174.03 24.6 55185.72 55186.22 55185.97 13.3 55197.72 55198.22 55197.97 11.2 56738.41 56738.91 56738.66 38.0 56750.34 56750.84 56750.59 29.4 56762.34 56762.84 56762.59 31.0 56774.34 56774.84 56774.59 37.1 56786.34 56786.84 56786.59 29.7 56798.41 56798.91 56798.66 34.2 56810.34 56810.84 56810.59 35.5 56822.34 56822.84 56822.59 31.5 56834.34 56834.84 56834.59 32.4 56846.34 56846.84 56846.59 32.4 56858.41 56858.91 56858.66 24.9 56870.41 56870.91 56870.66 30.5 56882.34 56882.84 56882.59 31.7 56894.41 56894.91 56894.66 34.8 56906.34 56906.84 56906.59 38.8 56918.34 56918.84 56918.59 29.6 56930.34 56930.84 56930.59 40.4 56942.34 56942.84 56942.59 39.5 56954.41 56954.91 56954.66 48.4 56966.34 56966.84 56966.59 33.7 56978.34 56978.84 56978.59 36.1 56990.34 56990.84 56990.59 33.7 57002.34 57002.84 57002.59 30.0 57014.34 57014.84 57014.59 37.6 57026.34 57026.84 57026.59 29.2 57038.34 57038.84 57038.59 42.1 57050.34 57050.84 57050.59 33.2 57062.34 57062.84 57062.59 34.1 57074.34 57074.84 57074.59 36.3 57086.34 57086.84 57086.59 35.5 57098.34 57098.84 57098.59 36.5 57110.34 57110.84 57110.59 41.8 57122.34 57122.84 57122.59 32.6 57134.41 57134.91 57134.66 52.1 57146.34 57146.84 57146.59 41.5 57158.34 57158.84 57158.59 37.6 57333.84 57334.34 57334.09 62.0 57345.84 57346.34 57346.09 58.5 57357.84 57358.34 57358.09 61.7 57369.84 57370.34 57370.09 52.9 57381.72 57382.22 57381.97 71.6 57393.72 57394.22 57393.97 58.7 57405.72 57406.22 57405.97 78.5 57417.78 57418.28 57418.03 77.5 57429.72 57430.22 57429.97 90.6 57453.72 57454.22 57453.97 75.6 57465.72 57466.22 57465.97 76.7 57477.84 57478.34 57478.09 57.6 57489.72 57490.22 57489.97 74.4 57501.72 57502.22 57501.97 65.4 57513.72 57514.22 57513.97 71.7 57525.72 57526.22 57525.97 86.8 57537.72 57538.22 57537.97 79.9 57549.72 57550.22 57549.97 69.6 57561.72 57562.22 57561.97 79.1 57573.78 57574.28 57574.03 87.2 57585.72 57586.22 57585.97 84.6 57597.72 57598.22 57597.97 76.9 57609.72 57610.22 57609.97 85.6 57621.72 57622.22 57621.97 81.3 57633.72 57634.22 57633.97 79.1 57645.78 57646.28 57646.03 73.6 57657.72 57658.22 57657.97 93.8 57669.72 57670.22 57669.97 92.0 57681.78 57682.28 57682.03 73.0 57693.72 57694.22 57693.97 75.7 57705.72 57706.22 57705.97 83.6 57717.78 57718.28 57718.03 75.0 57729.72 57730.22 57729.97 71.2 57741.72 57742.22 57741.97 84.1 57753.72 57754.22 57753.97 82.0 57765.78 57766.28 57766.03 66.8 57777.78 57778.28 57778.03 71.1 57789.84 57790.34 57790.09 73.5 57801.84 57802.34 57802.09 68.9 57813.91 57814.41 57814.16 61.6 57825.84 57826.34 57826.09 69.9 57837.84 57838.34 57838.09 65.1 57849.84 57850.34 57850.09 97.8 57861.84 57862.34 57862.09 97.0 57873.84 57874.34 57874.09 74.6 57885.91 57886.41 57886.16 58.2 57897.84 57898.34 57898.09 92.6 57909.91 57910.41 57910.16 85.7 57921.84 57922.34 57922.09 88.2 57933.84 57934.34 57934.09 72.4 57945.84 57946.34 57946.09 68.2 57957.84 57958.34 57958.09 84.6 57969.84 57970.34 57970.09 71.1 57981.84 57982.34 57982.09 70.0 57993.84 57994.34 57994.09 63.6 58005.84 58006.34 58006.09 67.7 58017.91 58018.41 58018.16 78.3 58029.84 58030.34 58030.09 65.5 58041.84 58042.34 58042.09 67.3 58053.91 58054.41 58054.16 69.6 58065.84 58066.34 58066.09 73.2 58077.84 58078.34 58078.09 67.8 58089.84 58090.34 58090.09 66.0 58101.84 58102.34 58102.09 74.5 58113.84 58114.34 58114.09 88.7 58125.84 58126.34 58126.09 87.9 58137.84 58138.34 58138.09 84.8 58149.84 58150.34 58150.09 89.6 58161.84 58162.34 58162.09 94.8 58173.91 58174.41 58174.16 85.0 58185.84 58186.34 58186.09 93.9 58197.84 58198.34 58198.09 85.0 58209.84 58210.34 58210.09 86.8 58221.84 58222.34 58222.09 77.6 58711.84 58712.34 58712.09 91.9 58723.84 58724.34 58724.09 108.7 58735.84 58736.34 58736.09 105.5 58747.84 58748.34 58748.09 105.7 58759.91 58760.41 58760.16 101.8 58771.84 58772.34 58772.09 94.9 58783.84 58784.34 58784.09 109.8 58795.84 58796.34 58796.09 89.3 58807.91 58808.41 58808.16 78.6 58819.72 58820.22 58819.97 103.5 58831.78 58832.28 58832.03 98.6 58843.72 58844.22 58843.97 98.0 58855.91 58856.41 58856.16 114.8 58867.84 58868.34 58868.09 104.7 58879.84 58880.34 58880.09 98.8 58891.84 58892.34 58892.09 106.3 58903.84 58904.34 58904.09 107.0 58915.84 58916.34 58916.09 82.7 58927.72 58928.22 58927.97 103.3 58939.72 58940.22 58939.97 103.6 58951.72 58952.22 58951.97 100.5 58963.72 58964.22 58963.97 103.4 58975.72 58976.22 58975.97 96.7 58987.72 58988.22 58987.97 90.0 58999.84 59000.34 59000.09 67.3 59011.84 59012.34 59012.09 77.3 59023.84 59024.34 59024.09 97.1 59035.84 59036.34 59036.09 85.2 59047.78 59048.28 59048.03 78.3 59059.78 59060.28 59060.03 91.1 59071.72 59072.22 59071.97 111.8 59083.72 59084.22 59083.97 102.1 59095.72 59096.22 59095.97 87.7 59107.78 59108.28 59108.03 77.3 59119.91 59120.41 59120.16 82.6 59131.84 59132.34 59132.09 83.6 59143.91 59144.41 59144.16 93.0 59155.84 59156.34 59156.09 79.9 59167.84 59168.34 59168.09 95.4 59179.84 59180.34 59180.09 85.0 59191.84 59192.34 59192.09 87.3 59203.84 59204.34 59204.09 90.0 59215.84 59216.34 59216.09 85.7 59227.84 59228.34 59228.09 96.0 59239.84 59240.34 59240.09 86.6 59251.84 59252.34 59252.09 90.4 59263.84 59264.34 59264.09 79.8 59275.84 59276.34 59276.09 98.8 59287.84 59288.34 59288.09 98.3 59299.91 59300.41 59300.16 87.9 59311.91 59312.41 59312.16 90.4 59323.91 59324.41 59324.16 88.0 59335.84 59336.34 59336.09 96.6 59347.84 59348.34 59348.09 90.8 59359.84 59360.34 59360.09 95.2 59371.84 59372.34 59372.09 94.8 59383.91 59384.41 59384.16 75.8 59395.91 59396.41 59396.16 95.2 59407.84 59408.34 59408.09 100.2 59419.84 59420.34 59420.09 96.8 59431.84 59432.34 59432.09 104.9 59443.84 59444.34 59444.09 93.1 59455.84 59456.34 59456.09 98.2 59467.84 59468.34 59468.09 99.5 59479.84 59480.34 59480.09 99.5 59491.84 59492.34 59492.09 90.4 59503.84 59504.34 59504.09 103.3 59515.84 59516.34 59516.09 103.7 59527.84 59528.34 59528.09 88.4 59539.91 59540.41 59540.16 105.4 59551.84 59552.34 59552.09 105.3 59563.91 59564.41 59564.16 106.6 59575.84 59576.34 59576.09 102.7 59587.84 59588.34 59588.09 95.1 59599.91 59600.41 59600.16 95.1 59690.16 59690.66 59690.41 58.8 59702.09 59702.59 59702.34 68.2 59714.09 59714.59 59714.34 70.6 59726.09 59726.59 59726.34 51.6 59738.09 59738.59 59738.34 63.6 59750.16 59750.66 59750.41 85.4 59762.09 59762.59 59762.34 88.2 59774.09 59774.59 59774.34 85.9 59786.09 59786.59 59786.34 77.9 59798.09 59798.59 59798.34 82.8 59810.09 59810.59 59810.34 59.1 59821.97 59822.47 59822.22 78.1 59834.09 59834.59 59834.34 48.9 59846.16 59846.66 59846.41 68.3 59858.09 59858.59 59858.34 56.0 59870.09 59870.59 59870.34 59.8 59882.09 59882.59 59882.34 67.0 59894.09 59894.59 59894.34 65.1 59906.09 59906.59 59906.34 55.3 59918.09 59918.59 59918.34 47.7 59929.97 59930.47 59930.22 61.3 59942.03 59942.53 59942.28 75.7 59954.03 59954.53 59954.28 74.4 59965.97 59966.47 59966.22 63.6 59978.16 59978.66 59978.41 72.9 59990.09 59990.59 59990.34 69.8 60002.09 60002.59 60002.34 47.5 60014.09 60014.59 60014.34 68.5 60026.16 60026.66 60026.41 71.3 60038.03 60038.53 60038.28 68.2 60049.97 60050.47 60050.22 48.8 60061.97 60062.47 60062.22 69.2 60073.97 60074.47 60074.22 55.2 60085.97 60086.47 60086.22 84.5 60097.97 60098.47 60098.22 76.8 60110.03 60110.53 60110.28 80.0 60122.03 60122.53 60122.28 85.7 60134.09 60134.59 60134.34 88.3 60146.09 60146.59 60146.34 76.4 60157.97 60158.47 60158.22 74.9 60169.97 60170.47 60170.22 65.5 60181.97 60182.47 60182.22 79.3 60193.97 60194.47 60194.22 59.9 60205.97 60206.47 60206.22 80.1 60217.97 60218.47 60218.22 87.0 60229.97 60230.47 60230.22 67.3 60241.97 60242.47 60242.22 82.3 60253.97 60254.47 60254.22 64.8 60266.03 60266.53 60266.28 110.8 60278.03 60278.53 60278.28 75.4 60289.97 60290.47 60290.22 73.2 60302.03 60302.53 60302.28 89.4 60313.97 60314.47 60314.22 95.3 60325.97 60326.47 60326.22 97.4 60338.03 60338.53 60338.28 86.0 60349.97 60350.47 60350.22 80.2 60361.97 60362.47 60362.22 84.0 60373.97 60374.47 60374.22 81.8 60385.97 60386.47 60386.22 80.1 60397.97 60398.47 60398.22 89.6 60409.97 60410.47 60410.22 77.6 60421.97 60422.47 60422.22 71.3 60433.97 60434.47 60434.22 88.2 60445.97 60446.47 60446.22 83.5 60458.03 60458.53 60458.28 66.7 60470.03 60470.53 60470.28 80.7 60481.97 60482.47 60482.22 71.8 60493.97 60494.47 60494.22 85.7 60505.97 60506.47 60506.22 78.4 60517.97 60518.47 60518.22 78.3 60529.97 60530.47 60530.22 79.1 60541.97 60542.47 60542.22 85.3 60554.03 60554.53 60554.28 101.4 60565.97 60566.47 60566.22 94.0 60578.03 60578.53 60578.28 73.6 60668.84 60669.34 60669.09 66.1 60680.84 60681.34 60681.09 56.2 60692.84 60693.34 60693.09 64.2 60704.84 60705.34 60705.09 55.3 60716.84 60717.34 60717.09 41.3 60728.84 60729.34 60729.09 51.0 60740.91 60741.41 60741.16 49.0 60752.84 60753.34 60753.09 44.3 60764.84 60765.34 60765.09 38.2 60776.84 60777.34 60777.09 41.3 60788.91 60789.41 60789.16 59.0 60800.84 60801.34 60801.09 53.2 60812.84 60813.34 60813.09 48.6 60824.84 60825.34 60825.09 47.9 60836.84 60837.34 60837.09 57.5 60848.91 60849.41 60849.16 50.3 60860.91 60861.41 60861.16 64.9 60872.84 60873.34 60873.09 54.8 60884.84 60885.34 60885.09 58.7 60896.84 60897.34 60897.09 47.9 60908.84 60909.34 60909.09 60.2 60920.72 60921.22 60920.97 52.0 60932.72 60933.22 60932.97 51.3 60944.72 60945.22 60944.97 60.5 60956.84 60957.34 60957.09 62.9 60968.91 60969.41 60969.16 62.6 60980.91 60981.41 60981.16 55.8 60992.91 60993.41 60993.16 60.0 61004.91 61005.41 61005.16 64.4 61016.91 61017.41 61017.16 56.7 61028.72 61029.22 61028.97 64.9 61040.78 61041.28 61041.03 70.3 61052.72 61053.22 61052.97 71.7 61064.78 61065.28 61065.03 77.4 61076.72 61077.22 61076.97 83.0 61088.72 61089.22 61088.97 56.4 61100.72 61101.22 61100.97 63.8 61112.84 61113.34 61113.09 55.3 61124.84 61125.34 61125.09 49.3 61136.78 61137.28 61137.03 45.2 61148.72 61149.22 61148.97 55.0 61160.72 61161.22 61160.97 57.9 61172.72 61173.22 61172.97 58.2 61184.78 61185.28 61185.03 46.2 61196.72 61197.22 61196.97 55.4 61208.72 61209.22 61208.97 52.8 61220.72 61221.22 61220.97 49.9 61232.72 61233.22 61232.97 60.0 61244.72 61245.22 61244.97 51.9 61256.72 61257.22 61256.97 51.9 61268.72 61269.22 61268.97 59.2 61280.78 61281.28 61281.03 57.0 61292.72 61293.22 61292.97 66.0 61304.72 61305.22 61304.97 64.1 61316.72 61317.22 61316.97 63.3 61328.72 61329.22 61328.97 76.5 61340.78 61341.28 61341.03 66.1 61352.78 61353.28 61353.03 59.4 61364.78 61365.28 61365.03 66.4 61376.78 61377.28 61377.03 55.7 61388.72 61389.22 61388.97 56.0 61400.72 61401.22 61400.97 72.8 61412.72 61413.22 61412.97 63.1 61424.72 61425.22 61424.97 66.7 61436.72 61437.22 61436.97 67.2 61448.72 61449.22 61448.97 73.3 61460.78 61461.28 61461.03 53.3 61472.72 61473.22 61472.97 67.6 61484.72 61485.22 61484.97 67.2 61496.72 61497.22 61496.97 74.2 61508.78 61509.28 61509.03 62.8 61520.72 61521.22 61520.97 66.4 61532.78 61533.28 61533.03 75.4 61544.72 61545.22 61544.97 67.1 61556.78 61557.28 61557.03 62.1 61568.72 61569.22 61568.97 77.1 61732.09 61732.59 61732.34 73.1 61744.09 61744.59 61744.34 87.4 61756.09 61756.59 61756.34 90.6 61768.09 61768.59 61768.34 87.4 61780.09 61780.59 61780.34 81.3 61792.09 61792.59 61792.34 93.3 61803.97 61804.47 61804.22 87.9 61815.97 61816.47 61816.22 88.4 61827.97 61828.47 61828.22 90.4 61839.97 61840.47 61840.22 94.6 61852.03 61852.53 61852.28 91.0 61863.97 61864.47 61864.22 101.8 61876.09 61876.59 61876.34 86.1 61888.09 61888.59 61888.34 88.3 61900.09 61900.59 61900.34 85.6 61911.97 61912.47 61912.22 84.5 61924.03 61924.53 61924.28 78.7 61935.97 61936.47 61936.22 84.2 61948.03 61948.53 61948.28 88.7 61959.97 61960.47 61960.22 69.1 61971.97 61972.47 61972.22 76.7 61983.97 61984.47 61984.22 84.9 61996.03 61996.53 61996.28 80.0 62008.03 62008.53 62008.28 91.7 62019.97 62020.47 62020.22 71.3 62031.97 62032.47 62032.22 80.6 62043.97 62044.47 62044.22 90.3 62055.97 62056.47 62056.22 86.3 62068.03 62068.53 62068.28 79.9 62079.97 62080.47 62080.22 85.2 62091.97 62092.47 62092.22 80.5 62103.97 62104.47 62104.22 84.6 62116.03 62116.53 62116.28 98.5 62127.97 62128.47 62128.22 93.2 62140.03 62140.53 62140.28 63.1 62151.97 62152.47 62152.22 50.7 62163.97 62164.47 62164.22 75.6 62175.97 62176.47 62176.22 72.7 62187.97 62188.47 62188.22 51.0 62199.97 62200.47 62200.22 60.3 62211.97 62212.47 62212.22 76.4 62223.97 62224.47 62224.22 81.6 62235.97 62236.47 62236.22 71.9 62247.97 62248.47 62248.22 80.9 62259.97 62260.47 62260.22 82.7 62272.03 62272.53 62272.28 94.8 62283.97 62284.47 62284.22 80.9 62295.97 62296.47 62296.22 75.1 62307.97 62308.47 62308.22 70.8 62320.03 62320.53 62320.28 52.4 62331.97 62332.47 62332.22 60.3 62343.97 62344.47 62344.22 68.9 62355.97 62356.47 62356.22 78.0 62367.97 62368.47 62368.22 68.2 62379.97 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