41 1001 Wennberg, Paul California Institute of Technology Gas Phase Nitric Acid from DC-8 TC4 1 1 2007 07 13 2007 07 13 0 start_UTC, s 3 1 1 1 999999 999999 999999 stop_UTC, s mid_UTC, s HNO3, pptv 0 24 PI_CONTACT_INFO: Address: California Institute of Technology. MC 150-21. 1200 E. California Blvd, Pasadena, CA, 91125. Phone: (626) 395-2447. Fax: (626) 585-1917. email: wennberg@gps.caltech.edu PLATFORM: NASA DC-8 airborne laboratory. LOCATION: Aircraft location data in file TN_20070713.DC8. ASSOCIATED_DATA: N/A INSTRUMENT_INFO: Chemical Ionization Mass Spectrometer. Direct measurements in ambient air. DATA_INFO: Measurements are reported as 0.5 sec averages and in units of pptv. CAUTION: Do not extrapolate data outside of given time interval as these are discrete measurements. Calibration was conducted ~once per hour during the flight using isotopically labeled nitric acid evolved from a perm tube held at constant temperature. Absolute calibration was obtained by collection in water and subsequent ion chromatography. Zeros were conducted ~3 times per hour by passing ambient air through a filter containing nylon wool coated with NaHCO3. UNCERTAINTY: +-(50% of measuremlent value + 50 pptv) ULOD_FLAG: -7777 ULOD_VALUE: N/A LLOD_FLAG: -8888 LLOD_VALUE: N/A; N/A; N/A; DM_CONTACT_INFO: John Crounse. California Institute of Technology. Department of Chemistry and Chemical Engineering. MC 150-21. 1200 E. California Blvd. Pasadena, CA 91125. Phone: (626) 395-6868. Fax: (626) 585-1917. email: crounjd@caltech.edu. PROJECT_INFO: TC4 study; 13 July-13 August 2007; Study of cloud processing and tropical convection processes STIPULATIONS_ON_USE: Use of these data requires PI notification and adherence to the TC4 data protocol. OTHER_COMMENTS: N/A REVISION: R0 R0: Preliminary Data Revision 0. Water correction has been applied using CIT-CIMS water. Reduction code 1.5 start_UTC(s) stop_UTC(s) mid_UTC(s) HNO3(pptv) 54307.41 54307.91 54307.66 210.6 54319.41 54319.91 54319.66 181.7 54331.41 54331.91 54331.66 163.5 54343.41 54343.91 54343.66 193.1 54355.41 54355.91 54355.66 140.9 54367.41 54367.91 54367.66 143.2 54379.28 54379.78 54379.53 104.2 54391.28 54391.78 54391.53 113.2 54403.28 54403.78 54403.53 116.1 54415.28 54415.78 54415.53 95.3 54427.28 54427.78 54427.53 96.3 54439.41 54439.91 54439.66 93.0 54451.41 54451.91 54451.66 57.5 54463.41 54463.91 54463.66 111.7 54475.41 54475.91 54475.66 400.2 54487.28 54487.78 54487.53 368.9 54499.28 54499.78 54499.53 380.9 54511.28 54511.78 54511.53 342.7 54523.28 54523.78 54523.53 374.0 54535.28 54535.78 54535.53 341.3 54547.28 54547.78 54547.53 296.4 54559.28 54559.78 54559.53 285.3 54571.28 54571.78 54571.53 630.6 54583.22 54583.72 54583.47 753.7 54595.28 54595.78 54595.53 821.7 54607.28 54607.78 54607.53 781.3 54619.28 54619.78 54619.53 989.8 54631.28 54631.78 54631.53 1351.5 54643.28 54643.78 54643.53 764.2 54655.28 54655.78 54655.53 316.4 54667.28 54667.78 54667.53 278.6 54679.28 54679.78 54679.53 277.1 54691.28 54691.78 54691.53 219.8 54703.28 54703.78 54703.53 238.3 54715.28 54715.78 54715.53 246.1 54727.28 54727.78 54727.53 242.0 54739.28 54739.78 54739.53 207.1 54751.28 54751.78 54751.53 235.0 54763.28 54763.78 54763.53 205.9 54775.28 54775.78 54775.53 215.2 54787.28 54787.78 54787.53 237.9 54799.28 54799.78 54799.53 260.9 54811.28 54811.78 54811.53 195.1 54823.28 54823.78 54823.53 164.8 54835.28 54835.78 54835.53 156.0 54847.28 54847.78 54847.53 173.2 54859.28 54859.78 54859.53 142.8 54871.28 54871.78 54871.53 189.5 54883.28 54883.78 54883.53 172.1 54895.28 54895.78 54895.53 191.4 54907.28 54907.78 54907.53 160.5 54919.28 54919.78 54919.53 158.4 54931.28 54931.78 54931.53 160.2 54943.28 54943.78 54943.53 109.2 54955.28 54955.78 54955.53 94.0 54967.28 54967.78 54967.53 96.7 54979.28 54979.78 54979.53 107.1 54991.28 54991.78 54991.53 95.8 55003.28 55003.78 55003.53 82.8 55015.28 55015.78 55015.53 113.5 55027.28 55027.78 55027.53 76.0 55039.28 55039.78 55039.53 53.7 55051.28 55051.78 55051.53 110.1 55063.28 55063.78 55063.53 97.1 55075.28 55075.78 55075.53 110.0 55087.28 55087.78 55087.53 86.9 56735.91 56736.41 56736.16 124.9 56747.91 56748.41 56748.16 97.3 56759.91 56760.41 56760.16 103.6 56771.91 56772.41 56772.16 123.5 56783.91 56784.41 56784.16 85.6 56795.91 56796.41 56796.16 73.7 56807.91 56808.41 56808.16 95.2 56819.91 56820.41 56820.16 97.8 56831.91 56832.41 56832.16 57.6 56843.91 56844.41 56844.16 83.9 56855.91 56856.41 56856.16 127.0 56867.91 56868.41 56868.16 91.2 56879.91 56880.41 56880.16 48.3 56891.91 56892.41 56892.16 69.9 56903.91 56904.41 56904.16 84.6 56915.91 56916.41 56916.16 86.1 56927.91 56928.41 56928.16 111.0 56939.91 56940.41 56940.16 120.5 56951.91 56952.41 56952.16 133.8 56963.91 56964.41 56964.16 154.8 56975.91 56976.41 56976.16 127.5 56987.91 56988.41 56988.16 104.8 56999.91 57000.41 57000.16 90.2 57011.91 57012.41 57012.16 107.6 57023.91 57024.41 57024.16 105.1 57035.91 57036.41 57036.16 101.9 57047.91 57048.41 57048.16 80.8 57059.91 57060.41 57060.16 112.3 57071.91 57072.41 57072.16 73.0 57083.91 57084.41 57084.16 107.8 57095.91 57096.41 57096.16 119.9 57107.91 57108.41 57108.16 128.1 57119.91 57120.41 57120.16 127.4 57131.91 57132.41 57132.16 141.5 57143.91 57144.41 57144.16 109.3 57155.91 57156.41 57156.16 98.5 57331.41 57331.91 57331.66 47.6 57343.41 57343.91 57343.66 28.1 57355.41 57355.91 57355.66 72.8 57367.41 57367.91 57367.66 16.1 57379.28 57379.78 57379.53 40.7 57391.28 57391.78 57391.53 45.3 57403.28 57403.78 57403.53 194.7 57415.28 57415.78 57415.53 374.2 57427.28 57427.78 57427.53 332.4 57439.28 57439.78 57439.53 267.8 57451.28 57451.78 57451.53 133.6 57463.28 57463.78 57463.53 80.3 57475.41 57475.91 57475.66 74.8 57487.28 57487.78 57487.53 56.7 57499.28 57499.78 57499.53 47.2 57511.28 57511.78 57511.53 72.5 57523.28 57523.78 57523.53 81.5 57535.28 57535.78 57535.53 112.8 57547.28 57547.78 57547.53 92.0 57559.28 57559.78 57559.53 97.5 57571.28 57571.78 57571.53 122.1 57583.28 57583.78 57583.53 210.5 57595.28 57595.78 57595.53 216.1 57607.28 57607.78 57607.53 203.2 57619.28 57619.78 57619.53 202.3 57631.28 57631.78 57631.53 194.5 57643.28 57643.78 57643.53 223.6 57655.28 57655.78 57655.53 222.2 57667.28 57667.78 57667.53 190.9 57679.28 57679.78 57679.53 189.5 57691.28 57691.78 57691.53 170.8 57703.28 57703.78 57703.53 170.9 57715.28 57715.78 57715.53 227.5 57727.28 57727.78 57727.53 148.6 57739.28 57739.78 57739.53 141.4 57751.28 57751.78 57751.53 157.9 57763.28 57763.78 57763.53 157.0 57775.28 57775.78 57775.53 138.9 57787.41 57787.91 57787.66 118.4 57799.41 57799.91 57799.66 126.9 57811.41 57811.91 57811.66 92.1 57823.41 57823.91 57823.66 154.5 57835.41 57835.91 57835.66 169.9 57847.41 57847.91 57847.66 148.2 57859.41 57859.91 57859.66 154.5 57871.41 57871.91 57871.66 169.6 57883.41 57883.91 57883.66 126.4 57895.41 57895.91 57895.66 133.4 57907.41 57907.91 57907.66 127.6 57919.41 57919.91 57919.66 142.7 57931.41 57931.91 57931.66 107.1 57943.41 57943.91 57943.66 115.6 57955.41 57955.91 57955.66 121.0 57967.41 57967.91 57967.66 147.7 57979.41 57979.91 57979.66 130.0 57991.41 57991.91 57991.66 122.7 58003.41 58003.91 58003.66 84.6 58015.41 58015.91 58015.66 102.9 58027.41 58027.91 58027.66 107.2 58039.41 58039.91 58039.66 107.1 58051.41 58051.91 58051.66 84.4 58063.41 58063.91 58063.66 80.0 58075.41 58075.91 58075.66 113.0 58087.41 58087.91 58087.66 86.3 58099.41 58099.91 58099.66 84.0 58111.41 58111.91 58111.66 118.4 58123.41 58123.91 58123.66 143.4 58135.41 58135.91 58135.66 150.6 58147.41 58147.91 58147.66 157.3 58159.41 58159.91 58159.66 172.4 58171.41 58171.91 58171.66 164.9 58183.41 58183.91 58183.66 171.4 58195.41 58195.91 58195.66 74.8 58207.41 58207.91 58207.66 110.1 58219.41 58219.91 58219.66 206.6 58709.41 58709.91 58709.66 117.0 58721.41 58721.91 58721.66 101.8 58733.41 58733.91 58733.66 83.4 58745.41 58745.91 58745.66 114.0 58757.41 58757.91 58757.66 90.6 58769.41 58769.91 58769.66 110.8 58781.41 58781.91 58781.66 123.6 58793.41 58793.91 58793.66 120.6 58805.34 58805.84 58805.59 152.1 58817.28 58817.78 58817.53 120.6 58829.28 58829.78 58829.53 122.4 58841.22 58841.72 58841.47 121.7 58853.41 58853.91 58853.66 141.0 58865.41 58865.91 58865.66 102.8 58877.41 58877.91 58877.66 117.5 58889.41 58889.91 58889.66 139.3 58901.41 58901.91 58901.66 130.7 58913.41 58913.91 58913.66 152.4 58925.41 58925.91 58925.66 152.9 58937.28 58937.78 58937.53 125.4 58949.28 58949.78 58949.53 136.2 58961.28 58961.78 58961.53 136.6 58973.28 58973.78 58973.53 122.7 58985.28 58985.78 58985.53 165.1 58997.28 58997.78 58997.53 194.7 59009.41 59009.91 59009.66 171.3 59021.41 59021.91 59021.66 144.7 59033.41 59033.91 59033.66 144.0 59045.28 59045.78 59045.53 149.4 59057.28 59057.78 59057.53 153.2 59069.28 59069.78 59069.53 163.6 59081.28 59081.78 59081.53 147.8 59093.28 59093.78 59093.53 150.0 59105.28 59105.78 59105.53 98.5 59117.41 59117.91 59117.66 69.0 59129.41 59129.91 59129.66 98.1 59141.41 59141.91 59141.66 112.0 59153.41 59153.91 59153.66 105.6 59165.41 59165.91 59165.66 115.3 59177.41 59177.91 59177.66 108.4 59189.41 59189.91 59189.66 131.8 59201.41 59201.91 59201.66 104.9 59213.41 59213.91 59213.66 52.6 59225.41 59225.91 59225.66 86.5 59237.41 59237.91 59237.66 103.0 59249.41 59249.91 59249.66 72.3 59261.41 59261.91 59261.66 152.7 59273.41 59273.91 59273.66 202.2 59285.41 59285.91 59285.66 176.6 59297.41 59297.91 59297.66 151.0 59309.41 59309.91 59309.66 195.2 59321.41 59321.91 59321.66 174.5 59333.41 59333.91 59333.66 151.7 59345.41 59345.91 59345.66 126.0 59357.41 59357.91 59357.66 148.7 59369.41 59369.91 59369.66 102.8 59381.41 59381.91 59381.66 106.2 59393.41 59393.91 59393.66 107.0 59405.41 59405.91 59405.66 83.3 59417.41 59417.91 59417.66 118.1 59429.41 59429.91 59429.66 325.1 59441.41 59441.91 59441.66 288.4 59453.41 59453.91 59453.66 263.0 59465.41 59465.91 59465.66 300.3 59477.41 59477.91 59477.66 308.8 59489.41 59489.91 59489.66 415.1 59501.41 59501.91 59501.66 189.9 59513.41 59513.91 59513.66 404.4 59525.34 59525.84 59525.59 145.9 59537.41 59537.91 59537.66 359.1 59549.34 59549.84 59549.59 454.3 59561.41 59561.91 59561.66 495.4 59573.41 59573.91 59573.66 489.4 59585.41 59585.91 59585.66 523.7 59597.34 59597.84 59597.59 521.0 59687.66 59688.16 59687.91 23.3 59699.66 59700.16 59699.91 11.2 59711.66 59712.16 59711.91 43.5 59723.66 59724.16 59723.91 39.5 59735.66 59736.16 59735.91 32.3 59747.66 59748.16 59747.91 25.4 59759.66 59760.16 59759.91 1.3 59771.66 59772.16 59771.91 -7.6 59783.66 59784.16 59783.91 8.2 59795.66 59796.16 59795.91 -39.6 59807.66 59808.16 59807.91 2.3 59819.53 59820.03 59819.78 -3.2 59831.66 59832.16 59831.91 31.6 59843.66 59844.16 59843.91 -26.5 59855.66 59856.16 59855.91 16.9 59867.66 59868.16 59867.91 18.6 59879.66 59880.16 59879.91 17.1 59891.66 59892.16 59891.91 21.4 59903.66 59904.16 59903.91 10.1 59915.66 59916.16 59915.91 25.6 59927.66 59928.16 59927.91 9.7 59939.53 59940.03 59939.78 40.7 59951.53 59952.03 59951.78 67.4 59963.53 59964.03 59963.78 68.9 59975.53 59976.03 59975.78 79.4 59987.66 59988.16 59987.91 99.0 59999.66 60000.16 59999.91 92.7 60011.66 60012.16 60011.91 131.0 60023.66 60024.16 60023.91 58.0 60035.66 60036.16 60035.91 51.8 60047.53 60048.03 60047.78 40.7 60059.53 60060.03 60059.78 112.1 60071.53 60072.03 60071.78 88.7 60083.53 60084.03 60083.78 83.1 60095.53 60096.03 60095.78 104.7 60107.53 60108.03 60107.78 84.8 60119.53 60120.03 60119.78 82.1 60131.66 60132.16 60131.91 47.9 60143.66 60144.16 60143.91 41.2 60155.53 60156.03 60155.78 39.7 60167.53 60168.03 60167.78 55.8 60179.53 60180.03 60179.78 59.9 60191.53 60192.03 60191.78 65.3 60203.53 60204.03 60203.78 69.3 60215.53 60216.03 60215.78 42.2 60227.53 60228.03 60227.78 52.9 60239.53 60240.03 60239.78 54.5 60251.53 60252.03 60251.78 59.2 60263.53 60264.03 60263.78 19.8 60275.53 60276.03 60275.78 27.3 60287.53 60288.03 60287.78 15.2 60299.53 60300.03 60299.78 5.3 60311.53 60312.03 60311.78 32.2 60323.53 60324.03 60323.78 9.1 60335.53 60336.03 60335.78 5.9 60347.53 60348.03 60347.78 31.5 60359.53 60360.03 60359.78 32.7 60371.53 60372.03 60371.78 39.0 60383.53 60384.03 60383.78 39.7 60395.53 60396.03 60395.78 19.1 60407.53 60408.03 60407.78 56.9 60419.53 60420.03 60419.78 53.4 60431.53 60432.03 60431.78 34.6 60443.53 60444.03 60443.78 34.3 60455.53 60456.03 60455.78 58.2 60467.53 60468.03 60467.78 73.0 60479.53 60480.03 60479.78 67.7 60491.53 60492.03 60491.78 76.1 60503.53 60504.03 60503.78 110.8 60515.53 60516.03 60515.78 139.6 60527.47 60527.97 60527.72 166.9 60539.53 60540.03 60539.78 126.7 60551.53 60552.03 60551.78 103.8 60563.53 60564.03 60563.78 91.5 60575.53 60576.03 60575.78 93.6 60666.41 60666.91 60666.66 43.9 60678.41 60678.91 60678.66 66.3 60690.41 60690.91 60690.66 174.9 60702.41 60702.91 60702.66 197.3 60714.41 60714.91 60714.66 374.5 60726.41 60726.91 60726.66 555.7 60738.41 60738.91 60738.66 157.0 60750.41 60750.91 60750.66 121.5 60762.41 60762.91 60762.66 119.0 60774.41 60774.91 60774.66 184.4 60786.41 60786.91 60786.66 106.5 60798.41 60798.91 60798.66 154.3 60810.41 60810.91 60810.66 118.9 60822.41 60822.91 60822.66 116.7 60834.41 60834.91 60834.66 110.1 60846.41 60846.91 60846.66 133.9 60858.41 60858.91 60858.66 119.9 60870.41 60870.91 60870.66 130.8 60882.41 60882.91 60882.66 138.3 60894.41 60894.91 60894.66 126.5 60906.41 60906.91 60906.66 163.8 60918.28 60918.78 60918.53 129.4 60930.28 60930.78 60930.53 159.3 60942.28 60942.78 60942.53 140.7 60954.28 60954.78 60954.53 173.2 60966.41 60966.91 60966.66 180.8 60978.41 60978.91 60978.66 195.8 60990.41 60990.91 60990.66 139.9 61002.41 61002.91 61002.66 173.9 61014.41 61014.91 61014.66 166.7 61026.28 61026.78 61026.53 148.6 61038.28 61038.78 61038.53 161.7 61050.28 61050.78 61050.53 176.7 61062.28 61062.78 61062.53 167.3 61074.28 61074.78 61074.53 163.5 61086.28 61086.78 61086.53 195.3 61098.28 61098.78 61098.53 222.4 61110.41 61110.91 61110.66 199.6 61122.41 61122.91 61122.66 221.5 61134.41 61134.91 61134.66 248.5 61146.28 61146.78 61146.53 254.3 61158.28 61158.78 61158.53 238.2 61170.28 61170.78 61170.53 249.8 61182.28 61182.78 61182.53 237.0 61194.28 61194.78 61194.53 247.6 61206.28 61206.78 61206.53 227.9 61218.28 61218.78 61218.53 228.8 61230.28 61230.78 61230.53 276.3 61242.28 61242.78 61242.53 237.5 61254.28 61254.78 61254.53 265.6 61266.28 61266.78 61266.53 216.9 61278.28 61278.78 61278.53 206.9 61290.28 61290.78 61290.53 238.1 61302.28 61302.78 61302.53 238.5 61314.28 61314.78 61314.53 214.8 61326.28 61326.78 61326.53 235.0 61338.28 61338.78 61338.53 230.5 61350.28 61350.78 61350.53 260.6 61362.28 61362.78 61362.53 279.6 61374.28 61374.78 61374.53 248.4 61386.28 61386.78 61386.53 256.7 61398.28 61398.78 61398.53 288.7 61410.28 61410.78 61410.53 262.3 61422.28 61422.78 61422.53 240.6 61434.28 61434.78 61434.53 249.5 61446.28 61446.78 61446.53 254.5 61458.28 61458.78 61458.53 226.8 61470.28 61470.78 61470.53 254.2 61482.28 61482.78 61482.53 272.5 61494.28 61494.78 61494.53 248.4 61506.28 61506.78 61506.53 237.3 61518.28 61518.78 61518.53 275.0 61530.28 61530.78 61530.53 299.8 61542.28 61542.78 61542.53 231.0 61554.28 61554.78 61554.53 222.7 61566.28 61566.78 61566.53 226.9 61729.66 61730.16 61729.91 167.4 61741.66 61742.16 61741.91 173.5 61753.66 61754.16 61753.91 190.4 61765.66 61766.16 61765.91 270.4 61777.66 61778.16 61777.91 220.2 61789.66 61790.16 61789.91 264.1 61801.47 61801.97 61801.72 253.1 61813.53 61814.03 61813.78 193.4 61825.53 61826.03 61825.78 207.3 61837.53 61838.03 61837.78 263.0 61849.53 61850.03 61849.78 267.6 61861.53 61862.03 61861.78 231.7 61873.66 61874.16 61873.91 244.9 61885.66 61886.16 61885.91 230.1 61897.66 61898.16 61897.91 201.2 61909.53 61910.03 61909.78 228.1 61921.53 61922.03 61921.78 234.9 61933.53 61934.03 61933.78 288.6 61945.47 61945.97 61945.72 303.4 61957.53 61958.03 61957.78 324.8 61969.53 61970.03 61969.78 303.4 61981.53 61982.03 61981.78 317.2 61993.53 61994.03 61993.78 307.7 62005.53 62006.03 62005.78 300.9 62017.53 62018.03 62017.78 296.2 62029.53 62030.03 62029.78 325.9 62041.47 62041.97 62041.72 338.2 62053.53 62054.03 62053.78 335.7 62065.53 62066.03 62065.78 309.1 62077.53 62078.03 62077.78 328.8 62089.53 62090.03 62089.78 287.5 62101.47 62101.97 62101.72 306.1 62113.47 62113.97 62113.72 290.7 62125.53 62126.03 62125.78 275.6 62137.53 62138.03 62137.78 297.9 62149.53 62150.03 62149.78 212.3 62161.53 62162.03 62161.78 299.3 62173.53 62174.03 62173.78 153.1 62185.53 62186.03 62185.78 189.2 62197.53 62198.03 62197.78 249.7 62209.53 62210.03 62209.78 257.8 62221.53 62222.03 62221.78 253.3 62233.53 62234.03 62233.78 223.5 62245.53 62246.03 62245.78 248.8 62257.53 62258.03 62257.78 247.1 62269.53 62270.03 62269.78 233.8 62281.53 62282.03 62281.78 194.6 62293.47 62293.97 62293.72 245.3 62305.53 62306.03 62305.78 217.3 62317.53 62318.03 62317.78 239.0 62329.53 62330.03 62329.78 263.5 62341.53 62342.03 62341.78 258.9 62353.53 62354.03 62353.78 267.2 62365.53 62366.03 62365.78 282.2 62377.53 62378.03 62377.78 275.5 62389.53 62390.03 62389.78 267.7 62401.53 62402.03 62401.78 299.0 62413.53 62414.03 62413.78 281.1 62425.53 62426.03 62425.78 283.7 62437.53 62438.03 62437.78 284.3 62449.53 62450.03 62449.78 260.9 62461.53 62462.03 62461.78 232.5 62473.53 62474.03 62473.78 265.4 62485.53 62486.03 62485.78 254.5 62497.53 62498.03 62497.78 257.5 62509.53 62510.03 62509.78 250.0 62521.66 62522.16 62521.91 249.0 62533.66 62534.16 62533.91 241.4 62545.66 62546.16 62545.91 227.9 62557.66 62558.16 62557.91 280.1 62569.66 62570.16 62569.91 266.7 62581.66 62582.16 62581.91 249.9 62593.66 62594.16 62593.91 242.5 62605.66 62606.16 62605.91 217.0 62617.66 62618.16 62617.91 219.0 63121.66 63122.16 63121.91 216.2 63133.66 63134.16 63133.91 206.9 63145.66 63146.16 63145.91 361.9 63157.66 63158.16 63157.91 368.7 63169.66 63170.16 63169.91 364.0 63181.66 63182.16 63181.91 376.1 63193.66 63194.16 63193.91 395.6 63205.66 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