43 1001 Wennberg, Paul California Institute of Technology Gas Phase Hydrogen Cyanide from DC-8 TC4 1 1 2007 07 13 2011 09 07 0 start_UTC, s 3 1 1 1 999999 999999 999999 stop_UTC, s mid_UTC, s HCN, pptv 0 26 PI_CONTACT_INFO: Address: California Institute of Technology. MC 150-21. 1200 E. California Blvd, Pasadena, CA, 91125. Phone: (626) 395-2447. Fax: (626) 585-1917. email: wennberg@gps.caltech.edu PLATFORM: NASA DC-8 airborne laboratory. LOCATION: Aircraft location data in file TN_20070713.DC8. ASSOCIATED_DATA: N/A INSTRUMENT_INFO: Chemical Ionization Mass Spectrometer. Direct measurements in ambient air. DATA_INFO: Measurements are reported as 0.5 sec averages and in units of pptv. CAUTION: Do not extrapolate data outside of given time interval as these are discrete measurements. Calibration was conducted ~once per hour during the flight using H2O2 and HNO3 calibrants, and proxied to HCN using laboratory calibrations. Absolute calibration was obtained in the laboratory by FTIR spectroscopy. Zeros were conducted ~3 times per hour by passing ambient air through a filter containing nylon wool coated with NaHCO3. UNCERTAINTY: +-(50% of measuremlent value + 50 pptv) ULOD_FLAG: 7777777 ULOD_VALUE: N/A LLOD_FLAG: 8888888 LLOD_VALUE: N/A; N/A; N/A; DM_CONTACT_INFO: John Crounse. California Institute of Technology. Department of Chemistry and Chemical Engineering. MC 150-21. 1200 E. California Blvd. Pasadena, CA 91125. Phone: (626) 395-6868. Fax: (626) 585-1917. email: crounjd@caltech.edu. PROJECT_INFO: TC4 study; 13 July-13 August 2007; Study of cloud processing and tropical convection processes STIPULATIONS_ON_USE: Use of these data requires PI notification and adherence to the TC4 data protocol. OTHER_COMMENTS: N/A REVISION: R1 R1: ULOD and LLOD flags changed to positive values, to conform to Ames format 2.1 specifications. R0: Preliminary Data Revision 0. Water correction has been applied using CIT-CIMS water. Reduction code 1.5 start_UTC stop_UTC mid_UTC HCN 54299.41 54299.91 54299.66 13.8 54311.34 54311.84 54311.59 19.4 54323.41 54323.91 54323.66 26.0 54335.34 54335.84 54335.59 18.2 54347.41 54347.91 54347.66 13.8 54359.34 54359.84 54359.59 12.9 54371.28 54371.78 54371.53 15.4 54383.22 54383.72 54383.47 17.2 54395.28 54395.78 54395.53 21.1 54407.22 54407.72 54407.47 18.2 54419.22 54419.72 54419.47 12.4 54431.22 54431.72 54431.47 22.1 54443.34 54443.84 54443.59 20.8 54455.34 54455.84 54455.59 17.4 54467.41 54467.91 54467.66 211.9 54479.41 54479.91 54479.66 267.4 54491.22 54491.72 54491.47 277.8 54503.22 54503.72 54503.47 245.1 54515.28 54515.78 54515.53 281.0 54527.22 54527.72 54527.47 241.7 54539.22 54539.72 54539.47 204.7 54551.28 54551.78 54551.53 197.0 54563.22 54563.72 54563.47 198.2 54575.22 54575.72 54575.47 289.6 54587.34 54587.84 54587.59 287.7 54599.28 54599.78 54599.53 298.2 54611.22 54611.72 54611.47 350.8 54623.28 54623.78 54623.53 347.3 54635.28 54635.78 54635.53 280.1 54647.22 54647.72 54647.47 187.3 54659.28 54659.78 54659.53 162.0 54671.28 54671.78 54671.53 160.0 54683.22 54683.72 54683.47 187.7 54695.22 54695.72 54695.47 170.7 54707.22 54707.72 54707.47 204.9 54719.22 54719.72 54719.47 194.7 54731.22 54731.72 54731.47 204.3 54743.22 54743.72 54743.47 175.0 54755.28 54755.78 54755.53 166.2 54767.22 54767.72 54767.47 167.9 54779.22 54779.72 54779.47 127.1 54791.22 54791.72 54791.47 118.0 54803.22 54803.72 54803.47 154.4 54815.22 54815.72 54815.47 149.9 54827.28 54827.78 54827.53 139.0 54839.22 54839.72 54839.47 154.5 54851.22 54851.72 54851.47 160.3 54863.28 54863.78 54863.53 154.7 54875.28 54875.78 54875.53 154.9 54887.22 54887.72 54887.47 141.8 54899.22 54899.72 54899.47 137.0 54911.22 54911.72 54911.47 117.3 54923.22 54923.72 54923.47 122.8 54935.22 54935.72 54935.47 119.3 54947.28 54947.78 54947.53 120.7 54959.22 54959.72 54959.47 126.8 54971.22 54971.72 54971.47 134.6 54983.28 54983.78 54983.53 130.4 54995.22 54995.72 54995.47 139.6 55007.22 55007.72 55007.47 118.0 55019.22 55019.72 55019.47 111.3 55031.22 55031.72 55031.47 111.4 55043.22 55043.72 55043.47 130.9 55055.22 55055.72 55055.47 124.6 55067.28 55067.78 55067.53 130.6 55079.22 55079.72 55079.47 118.7 56739.84 56740.34 56740.09 321.4 56751.84 56752.34 56752.09 330.1 56763.84 56764.34 56764.09 307.4 56775.84 56776.34 56776.09 293.5 56787.84 56788.34 56788.09 337.2 56799.84 56800.34 56800.09 307.3 56811.84 56812.34 56812.09 338.0 56823.84 56824.34 56824.09 318.4 56835.84 56836.34 56836.09 327.3 56847.84 56848.34 56848.09 325.0 56859.84 56860.34 56860.09 341.0 56871.84 56872.34 56872.09 370.6 56883.84 56884.34 56884.09 317.7 56895.84 56896.34 56896.09 346.8 56907.84 56908.34 56908.09 352.3 56919.84 56920.34 56920.09 361.8 56931.84 56932.34 56932.09 342.7 56943.84 56944.34 56944.09 361.5 56955.84 56956.34 56956.09 361.0 56967.84 56968.34 56968.09 357.8 56979.84 56980.34 56980.09 332.7 56991.84 56992.34 56992.09 321.4 57003.84 57004.34 57004.09 296.5 57015.84 57016.34 57016.09 365.9 57027.84 57028.34 57028.09 321.7 57039.91 57040.41 57040.16 338.4 57051.84 57052.34 57052.09 348.6 57063.91 57064.41 57064.16 317.8 57075.84 57076.34 57076.09 314.8 57087.91 57088.41 57088.16 362.0 57099.84 57100.34 57100.09 357.1 57111.84 57112.34 57112.09 374.2 57123.91 57124.41 57124.16 350.0 57135.91 57136.41 57136.16 365.5 57147.91 57148.41 57148.16 406.9 57159.91 57160.41 57160.16 398.0 57335.41 57335.91 57335.66 427.1 57347.41 57347.91 57347.66 418.2 57359.34 57359.84 57359.59 454.6 57371.34 57371.84 57371.59 462.9 57383.22 57383.72 57383.47 460.4 57395.28 57395.78 57395.53 484.4 57407.22 57407.72 57407.47 540.2 57419.28 57419.78 57419.53 536.6 57431.22 57431.72 57431.47 536.3 57443.22 57443.72 57443.47 472.4 57455.22 57455.72 57455.47 399.5 57467.22 57467.72 57467.47 425.7 57479.34 57479.84 57479.59 430.4 57491.28 57491.78 57491.53 466.8 57503.22 57503.72 57503.47 423.7 57515.28 57515.78 57515.53 459.3 57527.28 57527.78 57527.53 447.3 57539.22 57539.72 57539.47 426.1 57551.28 57551.78 57551.53 435.9 57563.22 57563.72 57563.47 429.6 57575.22 57575.72 57575.47 428.7 57587.22 57587.72 57587.47 429.5 57599.22 57599.72 57599.47 447.9 57611.22 57611.72 57611.47 501.8 57623.22 57623.72 57623.47 426.0 57635.28 57635.78 57635.53 447.4 57647.28 57647.78 57647.53 455.1 57659.22 57659.72 57659.47 453.2 57671.22 57671.72 57671.47 452.9 57683.22 57683.72 57683.47 471.7 57695.28 57695.78 57695.53 488.8 57707.22 57707.72 57707.47 449.6 57719.22 57719.72 57719.47 470.0 57731.28 57731.78 57731.53 434.8 57743.22 57743.72 57743.47 444.0 57755.22 57755.72 57755.47 449.5 57767.22 57767.72 57767.47 451.0 57779.22 57779.72 57779.47 421.3 57791.41 57791.91 57791.66 466.6 57803.34 57803.84 57803.59 428.8 57815.34 57815.84 57815.59 450.2 57827.34 57827.84 57827.59 455.3 57839.34 57839.84 57839.59 401.9 57851.41 57851.91 57851.66 454.1 57863.41 57863.91 57863.66 466.0 57875.34 57875.84 57875.59 480.8 57887.34 57887.84 57887.59 444.1 57899.34 57899.84 57899.59 442.9 57911.34 57911.84 57911.59 452.1 57923.34 57923.84 57923.59 452.3 57935.34 57935.84 57935.59 441.9 57947.34 57947.84 57947.59 437.9 57959.34 57959.84 57959.59 464.8 57971.34 57971.84 57971.59 457.2 57983.34 57983.84 57983.59 437.9 57995.34 57995.84 57995.59 460.4 58007.34 58007.84 58007.59 435.2 58019.34 58019.84 58019.59 433.6 58031.34 58031.84 58031.59 425.5 58043.34 58043.84 58043.59 462.4 58055.41 58055.91 58055.66 432.6 58067.34 58067.84 58067.59 441.3 58079.34 58079.84 58079.59 434.1 58091.34 58091.84 58091.59 449.9 58103.34 58103.84 58103.59 441.7 58115.34 58115.84 58115.59 411.0 58127.34 58127.84 58127.59 448.6 58139.34 58139.84 58139.59 431.7 58151.34 58151.84 58151.59 445.2 58163.34 58163.84 58163.59 433.0 58175.34 58175.84 58175.59 408.2 58187.41 58187.91 58187.66 345.5 58199.34 58199.84 58199.59 303.7 58211.34 58211.84 58211.59 308.4 58223.34 58223.84 58223.59 285.9 58713.34 58713.84 58713.59 265.8 58725.41 58725.91 58725.66 302.6 58737.34 58737.84 58737.59 352.7 58749.34 58749.84 58749.59 361.7 58761.34 58761.84 58761.59 352.6 58773.41 58773.91 58773.66 379.0 58785.34 58785.84 58785.59 374.4 58797.34 58797.84 58797.59 373.6 58809.41 58809.91 58809.66 358.9 58821.22 58821.72 58821.47 367.7 58833.22 58833.72 58833.47 301.6 58845.22 58845.72 58845.47 301.1 58857.41 58857.91 58857.66 315.7 58869.34 58869.84 58869.59 308.6 58881.34 58881.84 58881.59 310.9 58893.41 58893.91 58893.66 325.8 58905.34 58905.84 58905.59 316.3 58917.34 58917.84 58917.59 301.4 58929.22 58929.72 58929.47 332.4 58941.22 58941.72 58941.47 335.3 58953.22 58953.72 58953.47 340.7 58965.22 58965.72 58965.47 301.9 58977.28 58977.78 58977.53 315.9 58989.28 58989.78 58989.53 291.6 59001.41 59001.91 59001.66 332.4 59013.34 59013.84 59013.59 309.1 59025.34 59025.84 59025.59 324.3 59037.22 59037.72 59037.47 311.5 59049.22 59049.72 59049.47 343.7 59061.22 59061.72 59061.47 345.3 59073.22 59073.72 59073.47 339.1 59085.22 59085.72 59085.47 331.4 59097.22 59097.72 59097.47 351.4 59109.34 59109.84 59109.59 323.2 59121.34 59121.84 59121.59 293.1 59133.34 59133.84 59133.59 301.2 59145.34 59145.84 59145.59 341.0 59157.34 59157.84 59157.59 352.2 59169.34 59169.84 59169.59 349.8 59181.41 59181.91 59181.66 348.5 59193.34 59193.84 59193.59 333.6 59205.34 59205.84 59205.59 338.0 59217.34 59217.84 59217.59 309.7 59229.34 59229.84 59229.59 317.4 59241.41 59241.91 59241.66 336.4 59253.34 59253.84 59253.59 313.8 59265.34 59265.84 59265.59 330.4 59277.41 59277.91 59277.66 326.8 59289.34 59289.84 59289.59 334.2 59301.41 59301.91 59301.66 314.9 59313.41 59313.91 59313.66 342.6 59325.34 59325.84 59325.59 346.3 59337.41 59337.91 59337.66 324.6 59349.41 59349.91 59349.66 324.7 59361.41 59361.91 59361.66 317.5 59373.41 59373.91 59373.66 305.8 59385.34 59385.84 59385.59 339.0 59397.34 59397.84 59397.59 296.9 59409.41 59409.91 59409.66 334.3 59421.34 59421.84 59421.59 344.6 59433.34 59433.84 59433.59 338.9 59445.41 59445.91 59445.66 304.3 59457.34 59457.84 59457.59 321.7 59469.34 59469.84 59469.59 298.6 59481.34 59481.84 59481.59 328.3 59493.34 59493.84 59493.59 331.0 59505.34 59505.84 59505.59 324.1 59517.34 59517.84 59517.59 349.1 59529.41 59529.91 59529.66 332.1 59541.34 59541.84 59541.59 327.0 59553.41 59553.91 59553.66 352.6 59565.34 59565.84 59565.59 353.9 59577.41 59577.91 59577.66 352.0 59589.34 59589.84 59589.59 378.9 59601.34 59601.84 59601.59 371.5 59691.59 59692.09 59691.84 324.1 59703.59 59704.09 59703.84 325.0 59715.59 59716.09 59715.84 303.4 59727.59 59728.09 59727.84 351.7 59739.59 59740.09 59739.84 350.8 59751.59 59752.09 59751.84 370.5 59763.59 59764.09 59763.84 356.2 59775.59 59776.09 59775.84 359.0 59787.66 59788.16 59787.91 350.5 59799.59 59800.09 59799.84 361.8 59811.59 59812.09 59811.84 347.8 59823.53 59824.03 59823.78 342.9 59835.59 59836.09 59835.84 321.3 59847.59 59848.09 59847.84 325.1 59859.59 59860.09 59859.84 294.1 59871.59 59872.09 59871.84 317.4 59883.59 59884.09 59883.84 346.5 59895.59 59896.09 59895.84 325.1 59907.59 59908.09 59907.84 289.8 59919.59 59920.09 59919.84 303.9 59931.47 59931.97 59931.72 314.0 59943.47 59943.97 59943.72 318.6 59955.47 59955.97 59955.72 308.5 59967.53 59968.03 59967.78 340.9 59979.66 59980.16 59979.91 319.3 59991.59 59992.09 59991.84 297.8 60003.59 60004.09 60003.84 305.7 60015.59 60016.09 60015.84 343.1 60027.59 60028.09 60027.84 328.1 60039.47 60039.97 60039.72 308.1 60051.47 60051.97 60051.72 290.6 60063.47 60063.97 60063.72 333.0 60075.47 60075.97 60075.72 320.2 60087.53 60088.03 60087.78 349.4 60099.47 60099.97 60099.72 298.1 60111.47 60111.97 60111.72 300.7 60123.66 60124.16 60123.91 289.2 60135.66 60136.16 60135.91 317.7 60147.53 60148.03 60147.78 313.5 60159.47 60159.97 60159.72 321.3 60171.53 60172.03 60171.78 313.7 60183.47 60183.97 60183.72 314.9 60195.53 60196.03 60195.78 314.5 60207.47 60207.97 60207.72 322.8 60219.47 60219.97 60219.72 317.4 60231.47 60231.97 60231.72 286.4 60243.47 60243.97 60243.72 318.7 60255.47 60255.97 60255.72 282.6 60267.47 60267.97 60267.72 335.8 60279.47 60279.97 60279.72 318.7 60291.47 60291.97 60291.72 338.4 60303.47 60303.97 60303.72 338.2 60315.53 60316.03 60315.78 345.6 60327.47 60327.97 60327.72 328.0 60339.53 60340.03 60339.78 348.2 60351.47 60351.97 60351.72 353.3 60363.53 60364.03 60363.78 325.7 60375.53 60376.03 60375.78 304.7 60387.53 60388.03 60387.78 323.9 60399.53 60400.03 60399.78 345.2 60411.47 60411.97 60411.72 321.9 60423.53 60424.03 60423.78 317.1 60435.47 60435.97 60435.72 313.5 60447.47 60447.97 60447.72 338.8 60459.47 60459.97 60459.72 322.8 60471.47 60471.97 60471.72 301.8 60483.53 60484.03 60483.78 311.0 60495.47 60495.97 60495.72 331.2 60507.53 60508.03 60507.78 282.4 60519.47 60519.97 60519.72 321.0 60531.47 60531.97 60531.72 343.0 60543.47 60543.97 60543.72 343.8 60555.47 60555.97 60555.72 348.7 60567.47 60567.97 60567.72 357.5 60579.53 60580.03 60579.78 322.1 60670.41 60670.91 60670.66 324.9 60682.41 60682.91 60682.66 280.2 60694.34 60694.84 60694.59 315.9 60706.34 60706.84 60706.59 307.2 60718.34 60718.84 60718.59 272.2 60730.34 60730.84 60730.59 312.1 60742.41 60742.91 60742.66 313.8 60754.41 60754.91 60754.66 329.1 60766.34 60766.84 60766.59 323.2 60778.41 60778.91 60778.66 336.4 60790.34 60790.84 60790.59 342.4 60802.41 60802.91 60802.66 320.9 60814.34 60814.84 60814.59 338.0 60826.41 60826.91 60826.66 324.7 60838.34 60838.84 60838.59 357.2 60850.34 60850.84 60850.59 362.1 60862.41 60862.91 60862.66 378.2 60874.41 60874.91 60874.66 369.7 60886.34 60886.84 60886.59 311.0 60898.41 60898.91 60898.66 408.5 60910.41 60910.91 60910.66 394.5 60922.28 60922.78 60922.53 406.8 60934.22 60934.72 60934.47 411.9 60946.28 60946.78 60946.53 433.2 60958.34 60958.84 60958.59 393.4 60970.34 60970.84 60970.59 429.5 60982.34 60982.84 60982.59 466.4 60994.34 60994.84 60994.59 431.1 61006.34 61006.84 61006.59 429.2 61018.41 61018.91 61018.66 466.9 61030.22 61030.72 61030.47 394.4 61042.22 61042.72 61042.47 384.9 61054.22 61054.72 61054.47 417.3 61066.28 61066.78 61066.53 382.0 61078.28 61078.78 61078.53 357.7 61090.22 61090.72 61090.47 347.1 61102.34 61102.84 61102.59 406.6 61114.34 61114.84 61114.59 330.0 61126.34 61126.84 61126.59 293.4 61138.22 61138.72 61138.47 259.0 61150.22 61150.72 61150.47 280.7 61162.22 61162.72 61162.47 282.7 61174.22 61174.72 61174.47 301.7 61186.22 61186.72 61186.47 298.3 61198.22 61198.72 61198.47 304.3 61210.22 61210.72 61210.47 289.3 61222.28 61222.78 61222.53 301.0 61234.22 61234.72 61234.47 291.0 61246.22 61246.72 61246.47 296.3 61258.22 61258.72 61258.47 283.6 61270.22 61270.72 61270.47 318.8 61282.28 61282.78 61282.53 362.0 61294.22 61294.72 61294.47 342.4 61306.22 61306.72 61306.47 344.8 61318.22 61318.72 61318.47 305.8 61330.22 61330.72 61330.47 395.8 61342.22 61342.72 61342.47 379.8 61354.28 61354.78 61354.53 442.1 61366.28 61366.78 61366.53 434.2 61378.28 61378.78 61378.53 418.4 61390.22 61390.72 61390.47 404.0 61402.22 61402.72 61402.47 421.6 61414.22 61414.72 61414.47 387.0 61426.28 61426.78 61426.53 369.6 61438.22 61438.72 61438.47 360.1 61450.22 61450.72 61450.47 322.4 61462.22 61462.72 61462.47 284.0 61474.28 61474.78 61474.53 319.5 61486.22 61486.72 61486.47 377.0 61498.22 61498.72 61498.47 420.8 61510.22 61510.72 61510.47 356.1 61522.28 61522.78 61522.53 435.8 61534.22 61534.72 61534.47 361.2 61546.22 61546.72 61546.47 351.0 61558.28 61558.78 61558.53 373.8 61570.22 61570.72 61570.47 320.7 61733.66 61734.16 61733.91 306.3 61745.59 61746.09 61745.84 361.1 61757.59 61758.09 61757.84 368.1 61769.59 61770.09 61769.84 393.5 61781.59 61782.09 61781.84 420.1 61793.59 61794.09 61793.84 422.4 61805.47 61805.97 61805.72 402.3 61817.47 61817.97 61817.72 416.4 61829.47 61829.97 61829.72 416.1 61841.47 61841.97 61841.72 415.9 61853.47 61853.97 61853.72 353.2 61865.47 61865.97 61865.72 347.3 61877.66 61878.16 61877.91 338.6 61889.59 61890.09 61889.84 356.7 61901.59 61902.09 61901.84 332.2 61913.47 61913.97 61913.72 359.4 61925.53 61926.03 61925.78 390.8 61937.47 61937.97 61937.72 388.8 61949.47 61949.97 61949.72 340.0 61961.47 61961.97 61961.72 369.7 61973.47 61973.97 61973.72 381.0 61985.47 61985.97 61985.72 337.6 61997.47 61997.97 61997.72 350.7 62009.47 62009.97 62009.72 359.5 62021.47 62021.97 62021.72 342.5 62033.47 62033.97 62033.72 325.1 62045.53 62046.03 62045.78 405.3 62057.47 62057.97 62057.72 399.5 62069.47 62069.97 62069.72 375.3 62081.47 62081.97 62081.72 377.5 62093.47 62093.97 62093.72 353.7 62105.47 62105.97 62105.72 367.8 62117.47 62117.97 62117.72 363.2 62129.47 62129.97 62129.72 365.5 62141.47 62141.97 62141.72 374.6 62153.47 62153.97 62153.72 352.0 62165.47 62165.97 62165.72 374.7 62177.47 62177.97 62177.72 323.2 62189.53 62190.03 62189.78 376.1 62201.47 62201.97 62201.72 365.0 62213.47 62213.97 62213.72 368.3 62225.53 62226.03 62225.78 363.1 62237.47 62237.97 62237.72 342.8 62249.53 62250.03 62249.78 340.9 62261.53 62262.03 62261.78 323.2 62273.53 62274.03 62273.78 373.2 62285.47 62285.97 62285.72 325.0 62297.47 62297.97 62297.72 321.3 62309.47 62309.97 62309.72 360.3 62321.47 62321.97 62321.72 348.8 62333.53 62334.03 62333.78 333.9 62345.47 62345.97 62345.72 352.1 62357.47 62357.97 62357.72 362.6 62369.47 62369.97 62369.72 322.5 62381.53 62382.03 62381.78 380.8 62393.53 62394.03 62393.78 335.0 62405.47 62405.97 62405.72 323.4 62417.47 62417.97 62417.72 314.0 62429.47 62429.97 62429.72 293.9 62441.53 62442.03 62441.78 316.3 62453.47 62453.97 62453.72 294.0 62465.47 62465.97 62465.72 328.3 62477.47 62477.97 62477.72 332.8 62489.47 62489.97 62489.72 318.7 62501.47 62501.97 62501.72 326.2 62513.47 62513.97 62513.72 346.5 62525.66 62526.16 62525.91 354.5 62537.59 62538.09 62537.84 369.0 62549.66 62550.16 62549.91 322.2 62561.59 62562.09 62561.84 354.3 62573.66 62574.16 62573.91 321.9 62585.59 62586.09 62585.84 381.9 62597.59 62598.09 62597.84 374.6 62609.59 62610.09 62609.84 398.8 62621.59 62622.09 62621.84 382.8 63125.59 63126.09 63125.84 354.9 63137.59 63138.09 63137.84 325.4 63149.59 63150.09 63149.84 402.9 63161.59 63162.09 63161.84 418.4 63173.59 63174.09 63173.84 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