43 1001 Wennberg, Paul California Institute of Technology Gas Phase Hydrogen Peroxide from DC-8 TC4 1 1 2007 07 13 2011 09 07 0 start_UTC, s 3 1 1 1 999999 999999 999999 stop_UTC, s mid_UTC, s H2O2, pptv 0 26 PI_CONTACT_INFO: Address: California Institute of Technology. MC 150-21. 1200 E. California Blvd, Pasadena, CA, 91125. Phone: (626) 395-2447. Fax: (626) 585-1917. email: wennberg@gps.caltech.edu PLATFORM: NASA DC-8 airborne laboratory. LOCATION: Aircraft location data in file TN_20070713.DC8. ASSOCIATED_DATA: N/A INSTRUMENT_INFO: Chemical Ionization Mass Spectrometer. Direct measurements in ambient air. DATA_INFO: Measurements are reported as 0.5 sec averages and in units of pptv. CAUTION: Do not extrapolate data outside of given time interval as these are discrete measurements. Calibration was conducted ~once per hour during the flight using H2O2 obtained from vapor pressure over urea hydrogen peroxide held at constant temperature. Absolute calibration was obtained by collection in water and subsequent wet chemistry. Zeros were conducted ~3 times per hour by passing ambient air through a filter containing nylon wool coated with NaHCO3. UNCERTAINTY: +-(50% of measuremlent value + 150 pptv) ULOD_FLAG: 7777777 ULOD_VALUE: N/A LLOD_FLAG: 8888888 LLOD_VALUE: N/A; N/A; N/A; DM_CONTACT_INFO: John Crounse. California Institute of Technology. Department of Chemistry and Chemical Engineering. MC 150-21. 1200 E. California Blvd. Pasadena, CA 91125. Phone: (626) 395-6868. Fax: (626) 585-1917. email: crounjd@caltech.edu. PROJECT_INFO: TC4 study; 13 July-13 August 2007; Study of cloud processing and tropical convection processes STIPULATIONS_ON_USE: Use of these data requires PI notification and adherence to the TC4 data protocol. OTHER_COMMENTS: N/A REVISION: R1 R1: ULOD and LLOD flags changed to positive values, to conform to Ames format 2.1 specifications. R0: Preliminary Data Revision 0. Water correction has been applied using CIT-CIMS water. Reduction code 1.5 start_UTC stop_UTC mid_UTC H2O2 54299.84 54300.34 54300.09 42.7 54311.84 54312.34 54312.09 69.1 54323.84 54324.34 54324.09 58.9 54335.84 54336.34 54336.09 21.2 54347.84 54348.34 54348.09 22.2 54359.84 54360.34 54360.09 -0.6 54371.72 54372.22 54371.97 -0.7 54383.72 54384.22 54383.97 -12.3 54395.78 54396.28 54396.03 47.3 54407.72 54408.22 54407.97 14.3 54419.78 54420.28 54420.03 -12.0 54431.78 54432.28 54432.03 -4.5 54443.91 54444.41 54444.16 -35.4 54455.84 54456.34 54456.09 0.6 54467.84 54468.34 54468.09 631.0 54479.78 54480.28 54480.03 683.7 54491.72 54492.22 54491.97 566.4 54503.72 54504.22 54503.97 527.7 54515.72 54516.22 54515.97 539.4 54527.72 54528.22 54527.97 598.5 54539.78 54540.28 54540.03 676.9 54551.78 54552.28 54552.03 685.6 54563.78 54564.28 54564.03 753.6 54575.72 54576.22 54575.97 1235.7 54587.84 54588.34 54588.09 1282.5 54599.78 54600.28 54600.03 1337.6 54611.78 54612.28 54612.03 1457.8 54623.72 54624.22 54623.97 1477.1 54635.72 54636.22 54635.97 1116.1 54647.72 54648.22 54647.97 1029.5 54659.72 54660.22 54659.97 1016.8 54671.72 54672.22 54671.97 1040.2 54683.72 54684.22 54683.97 887.5 54695.78 54696.28 54696.03 827.4 54707.78 54708.28 54708.03 555.3 54719.72 54720.22 54719.97 970.5 54731.72 54732.22 54731.97 951.3 54743.78 54744.28 54744.03 854.7 54755.78 54756.28 54756.03 717.6 54767.72 54768.22 54767.97 400.7 54779.72 54780.22 54779.97 528.7 54791.72 54792.22 54791.97 663.5 54803.72 54804.22 54803.97 476.0 54815.72 54816.22 54815.97 375.3 54827.72 54828.22 54827.97 375.9 54839.72 54840.22 54839.97 441.2 54851.72 54852.22 54851.97 438.2 54863.72 54864.22 54863.97 459.1 54875.78 54876.28 54876.03 578.0 54887.72 54888.22 54887.97 511.4 54899.72 54900.22 54899.97 445.7 54911.78 54912.28 54912.03 472.0 54923.72 54924.22 54923.97 468.8 54935.72 54936.22 54935.97 437.7 54947.72 54948.22 54947.97 420.5 54959.72 54960.22 54959.97 428.0 54971.72 54972.22 54971.97 412.1 54983.72 54984.22 54983.97 409.5 54995.72 54996.22 54995.97 415.4 55007.72 55008.22 55007.97 380.3 55019.72 55020.22 55019.97 347.0 55031.72 55032.22 55031.97 287.4 55043.72 55044.22 55043.97 304.9 55055.78 55056.28 55056.03 322.5 55067.72 55068.22 55067.97 356.7 55079.72 55080.22 55079.97 379.0 56740.34 56740.84 56740.59 55.5 56752.34 56752.84 56752.59 39.9 56764.34 56764.84 56764.59 82.2 56776.34 56776.84 56776.59 74.6 56788.34 56788.84 56788.59 106.6 56800.34 56800.84 56800.59 77.8 56812.34 56812.84 56812.59 91.8 56824.34 56824.84 56824.59 71.5 56836.34 56836.84 56836.59 78.6 56848.41 56848.91 56848.66 97.2 56860.34 56860.84 56860.59 59.1 56872.41 56872.91 56872.66 144.6 56884.34 56884.84 56884.59 111.5 56896.34 56896.84 56896.59 58.6 56908.34 56908.84 56908.59 96.7 56920.41 56920.91 56920.66 136.3 56932.41 56932.91 56932.66 99.8 56944.34 56944.84 56944.59 69.1 56956.34 56956.84 56956.59 20.2 56968.34 56968.84 56968.59 75.7 56980.34 56980.84 56980.59 55.6 56992.34 56992.84 56992.59 47.7 57004.34 57004.84 57004.59 32.0 57016.41 57016.91 57016.66 50.2 57028.34 57028.84 57028.59 47.6 57040.34 57040.84 57040.59 77.9 57052.34 57052.84 57052.59 76.4 57064.34 57064.84 57064.59 37.1 57076.34 57076.84 57076.59 94.8 57088.41 57088.91 57088.66 145.7 57100.34 57100.84 57100.59 38.4 57112.34 57112.84 57112.59 98.4 57124.34 57124.84 57124.59 102.6 57136.41 57136.91 57136.66 83.3 57148.34 57148.84 57148.59 31.9 57160.41 57160.91 57160.66 151.9 57335.84 57336.34 57336.09 138.1 57347.91 57348.41 57348.16 118.0 57359.84 57360.34 57360.09 142.0 57371.84 57372.34 57372.09 139.6 57383.72 57384.22 57383.97 179.8 57395.72 57396.22 57395.97 161.0 57407.78 57408.28 57408.03 34.1 57419.72 57420.22 57419.97 54.4 57431.72 57432.22 57431.97 24.5 57443.72 57444.22 57443.97 78.0 57455.72 57456.22 57455.97 95.4 57467.72 57468.22 57467.97 161.0 57479.84 57480.34 57480.09 169.0 57491.72 57492.22 57491.97 159.0 57503.78 57504.28 57504.03 171.5 57515.72 57516.22 57515.97 132.6 57527.72 57528.22 57527.97 121.7 57539.72 57540.22 57539.97 105.4 57551.72 57552.22 57551.97 89.0 57563.72 57564.22 57563.97 118.8 57575.72 57576.22 57575.97 94.4 57587.72 57588.22 57587.97 51.8 57599.78 57600.28 57600.03 54.6 57611.72 57612.22 57611.97 39.6 57623.72 57624.22 57623.97 75.3 57635.72 57636.22 57635.97 73.2 57647.72 57648.22 57647.97 58.2 57659.72 57660.22 57659.97 75.4 57671.72 57672.22 57671.97 57.2 57683.72 57684.22 57683.97 85.1 57695.72 57696.22 57695.97 74.8 57707.72 57708.22 57707.97 69.3 57719.72 57720.22 57719.97 78.5 57731.72 57732.22 57731.97 75.8 57743.72 57744.22 57743.97 94.1 57755.72 57756.22 57755.97 78.8 57767.72 57768.22 57767.97 71.2 57779.78 57780.28 57780.03 114.8 57791.84 57792.34 57792.09 82.9 57803.84 57804.34 57804.09 110.8 57815.91 57816.41 57816.16 59.8 57827.91 57828.41 57828.16 81.8 57839.84 57840.34 57840.09 66.5 57851.84 57852.34 57852.09 109.5 57863.84 57864.34 57864.09 84.4 57875.84 57876.34 57876.09 101.8 57887.91 57888.41 57888.16 96.8 57899.91 57900.41 57900.16 112.8 57911.84 57912.34 57912.09 136.3 57923.84 57924.34 57924.09 90.8 57935.84 57936.34 57936.09 109.7 57947.84 57948.34 57948.09 92.7 57959.84 57960.34 57960.09 81.2 57971.84 57972.34 57972.09 52.8 57983.91 57984.41 57984.16 109.1 57995.84 57996.34 57996.09 107.5 58007.84 58008.34 58008.09 131.6 58019.91 58020.41 58020.16 118.1 58031.84 58032.34 58032.09 125.4 58043.84 58044.34 58044.09 113.2 58055.84 58056.34 58056.09 137.2 58067.91 58068.41 58068.16 90.6 58079.84 58080.34 58080.09 107.6 58091.91 58092.41 58092.16 119.6 58103.91 58104.41 58104.16 111.7 58115.91 58116.41 58116.16 136.4 58127.84 58128.34 58128.09 129.4 58139.91 58140.41 58140.16 130.5 58151.84 58152.34 58152.09 142.3 58163.84 58164.34 58164.09 127.0 58175.84 58176.34 58176.09 127.2 58187.84 58188.34 58188.09 216.6 58199.91 58200.41 58200.16 254.6 58211.84 58212.34 58212.09 277.9 58223.84 58224.34 58224.09 249.0 58713.84 58714.34 58714.09 10.1 58725.84 58726.34 58726.09 9.5 58737.84 58738.34 58738.09 56.8 58749.91 58750.41 58750.16 -6.8 58761.91 58762.41 58762.16 1.3 58773.84 58774.34 58774.09 -18.3 58785.91 58786.41 58786.16 14.1 58797.84 58798.34 58798.09 23.5 58809.84 58810.34 58810.09 54.8 58821.72 58822.22 58821.97 84.4 58833.72 58834.22 58833.97 38.1 58845.72 58846.22 58845.97 50.0 58857.84 58858.34 58858.09 53.1 58869.91 58870.41 58870.16 71.7 58881.84 58882.34 58882.09 37.4 58893.91 58894.41 58894.16 8.0 58905.84 58906.34 58906.09 -6.4 58917.84 58918.34 58918.09 12.3 58929.78 58930.28 58930.03 11.5 58941.72 58942.22 58941.97 54.3 58953.72 58954.22 58953.97 59.4 58965.72 58966.22 58965.97 61.4 58977.72 58978.22 58977.97 76.9 58989.72 58990.22 58989.97 43.4 59001.84 59002.34 59002.09 28.1 59013.84 59014.34 59014.09 27.6 59025.84 59026.34 59026.09 15.6 59037.72 59038.22 59037.97 23.6 59049.72 59050.22 59049.97 45.4 59061.72 59062.22 59061.97 15.2 59073.72 59074.22 59073.97 35.0 59085.78 59086.28 59086.03 47.6 59097.78 59098.28 59098.03 17.0 59109.84 59110.34 59110.09 76.0 59121.84 59122.34 59122.09 79.1 59133.84 59134.34 59134.09 56.2 59145.84 59146.34 59146.09 63.6 59157.84 59158.34 59158.09 60.2 59169.84 59170.34 59170.09 60.4 59181.84 59182.34 59182.09 33.7 59193.84 59194.34 59194.09 44.1 59205.84 59206.34 59206.09 140.1 59217.84 59218.34 59218.09 137.8 59229.84 59230.34 59230.09 151.2 59241.84 59242.34 59242.09 101.2 59253.84 59254.34 59254.09 150.3 59265.84 59266.34 59266.09 102.1 59277.84 59278.34 59278.09 76.9 59289.84 59290.34 59290.09 113.7 59301.84 59302.34 59302.09 110.3 59313.84 59314.34 59314.09 104.8 59325.84 59326.34 59326.09 141.8 59337.84 59338.34 59338.09 106.8 59349.84 59350.34 59350.09 155.5 59361.84 59362.34 59362.09 122.8 59373.91 59374.41 59374.16 160.2 59385.84 59386.34 59386.09 171.8 59397.91 59398.41 59398.16 169.1 59409.84 59410.34 59410.09 170.9 59421.84 59422.34 59422.09 87.7 59433.91 59434.41 59434.16 62.4 59445.84 59446.34 59446.09 74.2 59457.84 59458.34 59458.09 68.2 59469.84 59470.34 59470.09 175.6 59481.91 59482.41 59482.16 70.2 59493.84 59494.34 59494.09 170.6 59505.84 59506.34 59506.09 119.3 59517.84 59518.34 59518.09 81.8 59529.84 59530.34 59530.09 87.9 59541.84 59542.34 59542.09 125.9 59553.84 59554.34 59554.09 71.8 59565.91 59566.41 59566.16 58.9 59577.91 59578.41 59578.16 32.6 59589.84 59590.34 59590.09 35.5 59601.84 59602.34 59602.09 41.5 59692.09 59692.59 59692.34 121.8 59704.09 59704.59 59704.34 113.2 59716.09 59716.59 59716.34 124.3 59728.16 59728.66 59728.41 145.0 59740.09 59740.59 59740.34 163.9 59752.09 59752.59 59752.34 160.1 59764.09 59764.59 59764.34 133.1 59776.09 59776.59 59776.34 124.4 59788.09 59788.59 59788.34 140.2 59800.09 59800.59 59800.34 110.6 59812.09 59812.59 59812.34 120.1 59823.97 59824.47 59824.22 90.9 59836.09 59836.59 59836.34 81.0 59848.09 59848.59 59848.34 120.0 59860.16 59860.66 59860.41 81.3 59872.16 59872.66 59872.41 114.3 59884.16 59884.66 59884.41 83.9 59896.09 59896.59 59896.34 97.8 59908.09 59908.59 59908.34 88.5 59920.09 59920.59 59920.34 89.7 59931.97 59932.47 59932.22 89.7 59943.97 59944.47 59944.22 93.8 59955.97 59956.47 59956.22 71.4 59967.97 59968.47 59968.22 66.9 59980.16 59980.66 59980.41 84.3 59992.09 59992.59 59992.34 70.1 60004.16 60004.66 60004.41 53.8 60016.09 60016.59 60016.34 109.4 60028.16 60028.66 60028.41 76.7 60039.97 60040.47 60040.22 89.6 60051.97 60052.47 60052.22 77.5 60063.97 60064.47 60064.22 80.0 60075.97 60076.47 60076.22 87.7 60087.97 60088.47 60088.22 75.9 60099.97 60100.47 60100.22 82.0 60111.97 60112.47 60112.22 75.7 60124.09 60124.59 60124.34 72.0 60136.16 60136.66 60136.41 86.2 60147.97 60148.47 60148.22 86.7 60159.97 60160.47 60160.22 96.1 60171.97 60172.47 60172.22 80.4 60183.97 60184.47 60184.22 87.9 60195.97 60196.47 60196.22 73.2 60207.97 60208.47 60208.22 70.3 60219.97 60220.47 60220.22 61.4 60231.97 60232.47 60232.22 74.3 60243.97 60244.47 60244.22 72.6 60256.03 60256.53 60256.28 98.1 60267.97 60268.47 60268.22 113.2 60279.97 60280.47 60280.22 128.4 60292.03 60292.53 60292.28 104.0 60303.97 60304.47 60304.22 161.4 60315.97 60316.47 60316.22 132.0 60327.97 60328.47 60328.22 157.4 60340.03 60340.53 60340.28 146.2 60351.97 60352.47 60352.22 131.6 60363.97 60364.47 60364.22 84.9 60375.97 60376.47 60376.22 114.6 60387.97 60388.47 60388.22 115.1 60399.97 60400.47 60400.22 59.0 60411.97 60412.47 60412.22 93.8 60423.97 60424.47 60424.22 84.2 60435.97 60436.47 60436.22 104.3 60448.03 60448.53 60448.28 123.4 60459.97 60460.47 60460.22 104.3 60471.97 60472.47 60472.22 99.0 60483.97 60484.47 60484.22 99.4 60495.97 60496.47 60496.22 97.7 60507.97 60508.47 60508.22 95.0 60519.97 60520.47 60520.22 98.0 60531.97 60532.47 60532.22 103.7 60544.03 60544.53 60544.28 87.5 60555.97 60556.47 60556.22 102.3 60567.97 60568.47 60568.22 118.8 60579.97 60580.47 60580.22 104.0 60670.84 60671.34 60671.09 108.2 60682.91 60683.41 60683.16 119.0 60694.84 60695.34 60695.09 121.1 60706.84 60707.34 60707.09 104.4 60718.84 60719.34 60719.09 124.2 60730.84 60731.34 60731.09 100.7 60742.91 60743.41 60743.16 77.6 60754.84 60755.34 60755.09 75.3 60766.84 60767.34 60767.09 50.0 60778.84 60779.34 60779.09 74.2 60790.84 60791.34 60791.09 82.3 60802.84 60803.34 60803.09 84.4 60814.84 60815.34 60815.09 65.0 60826.91 60827.41 60827.16 73.8 60838.84 60839.34 60839.09 101.6 60850.84 60851.34 60851.09 91.5 60862.84 60863.34 60863.09 88.4 60874.84 60875.34 60875.09 78.6 60886.84 60887.34 60887.09 67.0 60898.84 60899.34 60899.09 86.3 60910.84 60911.34 60911.09 98.1 60922.72 60923.22 60922.97 59.7 60934.72 60935.22 60934.97 66.2 60946.72 60947.22 60946.97 67.6 60958.84 60959.34 60959.09 60.8 60970.91 60971.41 60971.16 27.5 60982.84 60983.34 60983.09 31.4 60994.91 60995.41 60995.16 48.9 61006.84 61007.34 61007.09 51.1 61018.84 61019.34 61019.09 85.6 61030.72 61031.22 61030.97 79.7 61042.72 61043.22 61042.97 83.1 61054.72 61055.22 61054.97 45.1 61066.72 61067.22 61066.97 64.4 61078.78 61079.28 61079.03 9.3 61090.72 61091.22 61090.97 31.0 61102.84 61103.34 61103.09 48.5 61114.84 61115.34 61115.09 40.9 61126.84 61127.34 61127.09 -3.5 61138.72 61139.22 61138.97 30.3 61150.78 61151.28 61151.03 -8.3 61162.72 61163.22 61162.97 7.0 61174.72 61175.22 61174.97 14.8 61186.72 61187.22 61186.97 4.5 61198.72 61199.22 61198.97 -1.6 61210.72 61211.22 61210.97 -6.6 61222.72 61223.22 61222.97 6.8 61234.72 61235.22 61234.97 32.7 61246.78 61247.28 61247.03 21.3 61258.72 61259.22 61258.97 20.1 61270.78 61271.28 61271.03 -6.9 61282.72 61283.22 61282.97 2.4 61294.72 61295.22 61294.97 11.8 61306.72 61307.22 61306.97 29.8 61318.72 61319.22 61318.97 -6.6 61330.78 61331.28 61331.03 21.6 61342.72 61343.22 61342.97 43.1 61354.72 61355.22 61354.97 -5.7 61366.78 61367.28 61367.03 21.0 61378.78 61379.28 61379.03 -11.8 61390.78 61391.28 61391.03 13.7 61402.78 61403.28 61403.03 8.6 61414.72 61415.22 61414.97 36.6 61426.78 61427.28 61427.03 17.6 61438.72 61439.22 61438.97 31.2 61450.78 61451.28 61451.03 -4.4 61462.72 61463.22 61462.97 26.4 61474.72 61475.22 61474.97 19.9 61486.72 61487.22 61486.97 14.4 61498.78 61499.28 61499.03 33.7 61510.72 61511.22 61510.97 23.4 61522.72 61523.22 61522.97 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