41 1001 Wennberg, Paul California Institute of Technology Gas Phase Peroxynitric Acid from DC-8 TC4 1 1 2007 07 02 2007 07 20 0 start_UTC, s 3 1 1 1 999999 999999 999999 stop_UTC, s mid_UTC, s PNA, pptv 0 24 PI_CONTACT_INFO: Address: California Institute of Technology. MC 150-21. 1200 E. California Blvd, Pasadena, CA, 91125. Phone: (626) 395-2447. Fax: (626) 585-1917. email: wennberg@gps.caltech.edu PLATFORM: NASA DC-8 airborne laboratory. LOCATION: Aircraft location data in file TN_20070702.DC8. ASSOCIATED_DATA: N/A INSTRUMENT_INFO: Chemical Ionization Mass Spectrometer. Direct measurements in ambient air. DATA_INFO: Measurements are reported as 0.5 sec averages and in units of pptv. CAUTION: Do not extrapolate data outside of given time interval as these are discrete measurements. Calibration was conducted ~once per hour during the flight using H2O2 and HNO3 calibrants, and proxied to PNA using laboratory calibrations. Absolute calibration was obtained in the laboratory by thermal decomposition and NO2 measurement. Zeros were conducted ~3 times per hour by passing ambient air through a filter containing nylon wool coated with NaHCO3. UNCERTAINTY: +-(100% of measuremlent value + 20 pptv) ULOD_FLAG: -7777 ULOD_VALUE: N/A LLOD_FLAG: -8888 LLOD_VALUE: N/A; N/A; N/A; DM_CONTACT_INFO: John Crounse. California Institute of Technology. Department of Chemistry and Chemical Engineering. MC 150-21. 1200 E. California Blvd. Pasadena, CA 91125. Phone: (626) 395-6868. Fax: (626) 585-1917. email: crounjd@caltech.edu. PROJECT_INFO: TC4 study; 13 July-13 August 2007; Study of cloud processing and tropical convection processes STIPULATIONS_ON_USE: Use of these data requires PI notification and adherence to the TC4 data protocol. OTHER_COMMENTS: N/A REVISION: R0 R0: Preliminary Data Revision 0. Water correction has been applied using CIT-CIMS water. Reduction code 1.5 start_UTC(s) stop_UTC(s) mid_UTC(s) PNA(pptv) 67092.84 67093.34 67093.09 45.5 67104.84 67105.34 67105.09 22.9 67116.84 67117.34 67117.09 34.4 67128.91 67129.41 67129.16 18.5 67140.84 67141.34 67141.09 20.4 67152.72 67153.22 67152.97 66.4 67164.72 67165.22 67164.97 28.7 67176.72 67177.22 67176.97 31.3 67188.72 67189.22 67188.97 45.3 67200.72 67201.22 67200.97 6.7 67212.78 67213.28 67213.03 32.2 67224.84 67225.34 67225.09 57.7 67236.84 67237.34 67237.09 49.0 67248.91 67249.41 67249.16 29.0 67260.91 67261.41 67261.16 23.9 67272.72 67273.22 67272.97 55.9 67284.72 67285.22 67284.97 27.7 67296.72 67297.22 67296.97 61.1 67308.78 67309.28 67309.03 19.0 67320.72 67321.22 67320.97 34.0 67332.72 67333.22 67332.97 35.4 67344.72 67345.22 67344.97 41.5 67356.72 67357.22 67356.97 52.3 67368.84 67369.34 67369.09 36.8 67380.78 67381.28 67381.03 12.1 67392.78 67393.28 67393.03 4.8 67404.72 67405.22 67404.97 32.4 67416.78 67417.28 67417.03 19.6 67428.72 67429.22 67428.97 52.5 67440.72 67441.22 67440.97 48.5 67452.72 67453.22 67452.97 53.0 67464.72 67465.22 67464.97 42.1 67476.72 67477.22 67476.97 28.8 67488.78 67489.28 67489.03 508.1 67500.72 67501.22 67500.97 25.8 67512.72 67513.22 67512.97 14.5 67524.78 67525.28 67525.03 -23.0 67536.72 67537.22 67536.97 3.4 67548.78 67549.28 67549.03 -15.9 67560.72 67561.22 67560.97 24.3 67572.78 67573.28 67573.03 0.9 67584.72 67585.22 67584.97 1.0 67596.72 67597.22 67596.97 -1.5 67608.78 67609.28 67609.03 -18.9 67620.72 67621.22 67620.97 3.4 67632.72 67633.22 67632.97 -19.6 67644.72 67645.22 67644.97 14.9 67656.72 67657.22 67656.97 -5.5 67668.72 67669.22 67668.97 -5.9 67680.72 67681.22 67680.97 -3.4 67692.78 67693.28 67693.03 -32.3 67704.72 67705.22 67704.97 -4.9 67716.72 67717.22 67716.97 -6.7 67728.72 67729.22 67728.97 -20.4 67740.72 67741.22 67740.97 -7.3 67752.78 67753.28 67753.03 -16.7 67764.72 67765.22 67764.97 26.4 67776.72 67777.22 67776.97 18.0 67788.72 67789.22 67788.97 -0.5 67800.72 67801.22 67800.97 -2.7 67812.72 67813.22 67812.97 -3.2 67824.72 67825.22 67824.97 -12.0 67836.72 67837.22 67836.97 18.6 67848.72 67849.22 67848.97 2.4 67860.72 67861.22 67860.97 -16.4 67872.72 67873.22 67872.97 10.9 67884.72 67885.22 67884.97 -7.2 67896.72 67897.22 67896.97 -1.5 67908.78 67909.28 67909.03 -19.5 67920.72 67921.22 67920.97 -13.7 67932.78 67933.28 67933.03 -1.7 67944.72 67945.22 67944.97 -15.1 67956.72 67957.22 67956.97 9.1 67968.78 67969.28 67969.03 -13.1 67980.78 67981.28 67981.03 7.4 68072.03 68072.53 68072.28 1.4 68083.97 68084.47 68084.22 6.1 68095.97 68096.47 68096.22 5.7 68107.97 68108.47 68108.22 -20.0 68120.03 68120.53 68120.28 12.7 68131.97 68132.47 68132.22 -24.0 68143.97 68144.47 68144.22 -7.4 68156.03 68156.53 68156.28 7.2 68167.97 68168.47 68168.22 7.1 68179.97 68180.47 68180.22 -1.6 68191.84 68192.34 68192.09 7.5 68203.84 68204.34 68204.09 9.8 68215.97 68216.47 68216.22 2.5 68227.97 68228.47 68228.22 3.7 68240.03 68240.53 68240.28 -2.6 68251.97 68252.47 68252.22 14.0 68263.97 68264.47 68264.22 9.1 68276.03 68276.53 68276.28 -2.7 68287.97 68288.47 68288.22 -26.1 68299.91 68300.41 68300.16 21.3 68311.84 68312.34 68312.09 3.2 68323.91 68324.41 68324.16 -11.9 68335.91 68336.41 68336.16 -15.8 68347.84 68348.34 68348.09 -12.5 68360.03 68360.53 68360.28 -21.0 68372.03 68372.53 68372.28 -19.9 68383.97 68384.47 68384.22 -9.4 68395.97 68396.47 68396.22 1.1 68407.97 68408.47 68408.22 5.3 68419.84 68420.34 68420.09 22.0 68431.84 68432.34 68432.09 4.2 68443.84 68444.34 68444.09 -14.7 68455.84 68456.34 68456.09 -25.1 68467.84 68468.34 68468.09 19.7 68479.84 68480.34 68480.09 -8.0 72367.84 72368.34 72368.09 17.8 72379.84 72380.34 72380.09 19.5 72391.84 72392.34 72392.09 11.1 72403.84 72404.34 72404.09 15.4 72415.91 72416.41 72416.16 9.9 72515.72 72516.22 72515.97 16.5 72527.72 72528.22 72527.97 19.0 72539.72 72540.22 72539.97 18.8 72551.72 72552.22 72551.97 17.1 72563.78 72564.28 72564.03 16.9 72575.78 72576.28 72576.03 22.8 72587.72 72588.22 72587.97 6.9 72599.72 72600.22 72599.97 20.3 72611.78 72612.28 72612.03 26.5 72623.78 72624.28 72624.03 25.6 72635.72 72636.22 72635.97 16.2 72647.72 72648.22 72647.97 17.7 72659.72 72660.22 72659.97 25.6 72671.72 72672.22 72671.97 28.1 72683.72 72684.22 72683.97 32.9 72695.78 72696.28 72696.03 29.6 72707.78 72708.28 72708.03 28.7 72719.72 72720.22 72719.97 28.1 72731.72 72732.22 72731.97 46.1 72743.72 72744.22 72743.97 15.0 72755.72 72756.22 72755.97 13.4 72767.72 72768.22 72767.97 19.4 72779.72 72780.22 72779.97 6.7 72791.72 72792.22 72791.97 14.5 72803.72 72804.22 72803.97 7.6 72815.72 72816.22 72815.97 18.1 72827.72 72828.22 72827.97 28.4 72839.72 72840.22 72839.97 17.7 72894.41 72894.91 72894.66 15.0 72906.34 72906.84 72906.59 13.6 72918.34 72918.84 72918.59 20.3 72930.41 72930.91 72930.66 15.4 72942.34 72942.84 72942.59 21.4 72954.34 72954.84 72954.59 15.5 72966.34 72966.84 72966.59 13.4 72978.41 72978.91 72978.66 11.2 72990.34 72990.84 72990.59 21.3 73002.41 73002.91 73002.66 15.5 73014.34 73014.84 73014.59 8.1 73026.41 73026.91 73026.66 9.4 73038.41 73038.91 73038.66 9.7 73050.34 73050.84 73050.59 6.2 73062.34 73062.84 73062.59 5.0 73074.34 73074.84 73074.59 21.7 73086.34 73086.84 73086.59 11.6 73098.34 73098.84 73098.59 22.1 73110.34 73110.84 73110.59 14.6 73122.34 73122.84 73122.59 7.2 73134.41 73134.91 73134.66 17.7 73146.34 73146.84 73146.59 14.5 73158.41 73158.91 73158.66 15.9 73170.34 73170.84 73170.59 9.2 73182.41 73182.91 73182.66 5.0 73194.34 73194.84 73194.59 4.8 73206.41 73206.91 73206.66 -2.4 73218.34 73218.84 73218.59 4.7 73230.34 73230.84 73230.59 11.1 73347.91 73348.41 73348.16 6.4 73359.91 73360.41 73360.16 -7.3 73371.91 73372.41 73372.16 -0.4 73383.91 73384.41 73384.16 -2.2 73395.91 73396.41 73396.16 -6.2 73468.91 73469.41 73469.16 -1.3 73480.91 73481.41 73481.16 -8.4 73492.84 73493.34 73493.09 15.5 73504.91 73505.41 73505.16 3.0 73516.91 73517.41 73517.16 -11.6 73528.84 73529.34 73529.09 6.4 73540.84 73541.34 73541.09 1.8 73552.91 73553.41 73553.16 -4.7 73564.91 73565.41 73565.16 7.4 73576.91 73577.41 73577.16 0.2 73588.91 73589.41 73589.16 2.7 73600.84 73601.34 73601.09 3.9 73612.84 73613.34 73613.09 1.3 73624.84 73625.34 73625.09 -4.2 73636.84 73637.34 73637.09 8.4 73648.84 73649.34 73649.09 2.6 73660.84 73661.34 73661.09 11.4 73672.84 73673.34 73673.09 8.9 73684.84 73685.34 73685.09 8.7 73696.91 73697.41 73697.16 4.1 73708.84 73709.34 73709.09 29.3 73720.84 73721.34 73721.09 4.8 73732.84 73733.34 73733.09 -4.1 73744.91 73745.41 73745.16 -5.7 73756.91 73757.41 73757.16 -3.2 73826.78 73827.28 73827.03 -1.8 73838.72 73839.22 73838.97 7.0 73850.72 73851.22 73850.97 4.4 73862.72 73863.22 73862.97 -0.2 73874.72 73875.22 73874.97 -1.6 73886.72 73887.22 73886.97 7.1 73898.78 73899.28 73899.03 1.9 73910.78 73911.28 73911.03 -5.1 73922.78 73923.28 73923.03 -7.2 73934.78 73935.28 73935.03 10.0 73946.78 73947.28 73947.03 -0.2 73958.78 73959.28 73959.03 -0.3 73970.72 73971.22 73970.97 9.3 73982.78 73983.28 73983.03 5.8 73994.78 73995.28 73995.03 -4.0 74006.78 74007.28 74007.03 1.2 74018.78 74019.28 74019.03 35.0 74030.78 74031.28 74031.03 3.8 74042.78 74043.28 74043.03 35.7 74054.78 74055.28 74055.03 87.2 74066.78 74067.28 74067.03 76.9 74078.72 74079.22 74078.97 125.8 74090.78 74091.28 74091.03 135.4 74102.78 74103.28 74103.03 108.7 74114.78 74115.28 74115.03 83.0 74126.78 74127.28 74127.03 119.0 74138.78 74139.28 74139.03 101.2 74150.78 74151.28 74151.03 164.8 74162.78 74163.28 74163.03 114.4 74174.78 74175.28 74175.03 86.7 74186.78 74187.28 74187.03 205.5 74198.78 74199.28 74199.03 149.2 74210.72 74211.22 74210.97 256.4 74222.72 74223.22 74222.97 221.1 74234.78 74235.28 74235.03 167.3 74246.78 74247.28 74247.03 192.6 74337.91 74338.41 74338.16 141.9 74349.84 74350.34 74350.09 149.0 74361.84 74362.34 74362.09 150.9 74373.91 74374.41 74374.16 65.9 74385.84 74386.34 74386.09 96.4 74397.84 74398.34 74398.09 134.1 74409.84 74410.34 74410.09 130.4 74421.91 74422.41 74422.16 86.6 74433.91 74434.41 74434.16 86.1 74445.84 74446.34 74446.09 113.7 74457.78 74458.28 74458.03 37.9 74469.72 74470.22 74469.97 -3.4 74481.91 74482.41 74482.16 -5.9 74493.91 74494.41 74494.16 6.3 74505.84 74506.34 74506.09 5.3 74517.91 74518.41 74518.16 8.9 74529.84 74530.34 74530.09 5.9 74541.84 74542.34 74542.09 2.6 74553.84 74554.34 74554.09 13.6 74565.78 74566.28 74566.03 1.1 74577.78 74578.28 74578.03 -1.5 74589.72 74590.22 74589.97 1.1 74601.78 74602.28 74602.03 10.3 74613.72 74614.22 74613.97 -1.9 74625.91 74626.41 74626.16 -9.6 74689.59 74690.09 74689.84 -1.4 74701.59 74702.09 74701.84 5.7 74713.66 74714.16 74713.91 4.6 74725.66 74726.16 74725.91 -2.5 74737.59 74738.09 74737.84 -0.2 74749.59 74750.09 74749.84 1.8 74761.59 74762.09 74761.84 -3.8 74773.66 74774.16 74773.91 0.6 74785.59 74786.09 74785.84 2.6 74797.59 74798.09 74797.84 5.0 74809.59 74810.09 74809.84 1.7 74821.66 74822.16 74821.91 1.8 74833.66 74834.16 74833.91 -0.4 74845.66 74846.16 74845.91 1.3 74857.59 74858.09 74857.84 5.7 74869.66 74870.16 74869.91 11.0 74881.59 74882.09 74881.84 1.5 74893.59 74894.09 74893.84 3.0 74905.59 74906.09 74905.84 9.8 74917.66 74918.16 74917.91 -7.2 74929.59 74930.09 74929.84 -8.1 74941.59 74942.09 74941.84 -1.6 74953.59 74954.09 74953.84 -8.8 74965.59 74966.09 74965.84 -3.6 74994.47 74994.97 74994.72 6.3 75006.47 75006.97 75006.72 -1.2 75018.47 75018.97 75018.72 0.1 75030.47 75030.97 75030.72 2.7 75042.47 75042.97 75042.72 2.1 75054.47 75054.97 75054.72 7.3 75066.53 75067.03 75066.78 -0.8 75078.47 75078.97 75078.72 -5.0 75090.47 75090.97 75090.72 -2.3 75102.47 75102.97 75102.72 -1.9 75114.47 75114.97 75114.72 -3.3 75126.47 75126.97 75126.72 11.6 75138.47 75138.97 75138.72 -7.2 75150.47 75150.97 75150.72 -7.7 75162.47 75162.97 75162.72 -3.8 75174.47 75174.97 75174.72 -2.1 75186.47 75186.97 75186.72 -3.2 75198.47 75198.97 75198.72 6.8 75210.53 75211.03 75210.78 -5.0 75222.47 75222.97 75222.72 10.0 75234.47 75234.97 75234.72 11.5 75414.84 75415.34 75415.09 -2.8 75618.72 75619.22 75618.97 9.6 75630.72 75631.22 75630.97 11.2 75642.78 75643.28 75643.03 9.0 75654.72 75655.22 75654.97 8.3 75666.72 75667.22 75666.97 17.1 75678.78 75679.28 75679.03 21.4 75690.72 75691.22 75690.97 18.8 75702.72 75703.22 75702.97 19.3 75714.72 75715.22 75714.97 20.7 75726.72 75727.22 75726.97 15.8 75738.72 75739.22 75738.97 19.6 75750.72 75751.22 75750.97 31.3 75762.72 75763.22 75762.97 9.1 75774.72 75775.22 75774.97 16.2 75786.78 75787.28 75787.03 22.0 75798.72 75799.22 75798.97 4.3 75810.78 75811.28 75811.03 7.3 75822.78 75823.28 75823.03 10.9 75834.72 75835.22 75834.97 18.7 75846.72 75847.22 75846.97 20.1 75921.84 75922.34 75922.09 11.8 75933.84 75934.34 75934.09 3.3 75945.84 75946.34 75946.09 9.2 75957.84 75958.34 75958.09 8.9 75969.84 75970.34 75970.09 66.0 75981.84 75982.34 75982.09 13.6 75993.84 75994.34 75994.09 -0.0 76005.84 76006.34 76006.09 9.3 76017.84 76018.34 76018.09 21.8 76029.84 76030.34 76030.09 -6.2 76041.84 76042.34 76042.09 5.4 76053.84 76054.34 76054.09 0.8 76065.84 76066.34 76066.09 8.9 76077.84 76078.34 76078.09 20.3 76089.84 76090.34 76090.09 24.7 76101.84 76102.34 76102.09 6.6 76113.91 76114.41 76114.16 25.3 76125.84 76126.34 76126.09 9.1 76137.91 76138.41 76138.16 30.7 76149.84 76150.34 76150.09 28.6 77187.66 77188.16 77187.91 11.1 77199.59 77200.09 77199.84 15.9 77211.59 77212.09 77211.84 18.9 77223.59 77224.09 77223.84 19.7 77235.47 77235.97 77235.72 11.0 77247.47 77247.97 77247.72 6.9 77259.47 77259.97 77259.72 14.6 77271.53 77272.03 77271.78 14.8 77283.47 77283.97 77283.72 9.7 77295.47 77295.97 77295.72 22.3 77307.53 77308.03 77307.78 12.3 77319.47 77319.97 77319.72 20.3 77331.59 77332.09 77331.84 15.4 77343.66 77344.16 77343.91 5.9 77355.53 77356.03 77355.78 8.0 77796.84 77797.34 77797.09 9.3 77808.84 77809.34 77809.09 21.2 77820.91 77821.41 77821.16 5.6 77832.84 77833.34 77833.09 8.5 77844.84 77845.34 77845.09 10.0 77856.84 77857.34 77857.09 11.9 77868.84 77869.34 77869.09 18.3 77880.84 77881.34 77881.09 25.6 77892.84 77893.34 77893.09 17.9 77904.72 77905.22 77904.97 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