41 1001 Wennberg, Paul California Institute of Technology Gas Phase Nitric Acid from DC-8 TC4 1 1 2007 07 02 2007 07 02 0 start_UTC, s 3 1 1 1 999999 999999 999999 stop_UTC, s mid_UTC, s HNO3, pptv 0 24 PI_CONTACT_INFO: Address: California Institute of Technology. MC 150-21. 1200 E. California Blvd, Pasadena, CA, 91125. Phone: (626) 395-2447. Fax: (626) 585-1917. email: wennberg@gps.caltech.edu PLATFORM: NASA DC-8 airborne laboratory. LOCATION: Aircraft location data in file TN_20070702.DC8. ASSOCIATED_DATA: N/A INSTRUMENT_INFO: Chemical Ionization Mass Spectrometer. Direct measurements in ambient air. DATA_INFO: Measurements are reported as 0.5 sec averages and in units of pptv. CAUTION: Do not extrapolate data outside of given time interval as these are discrete measurements. Calibration was conducted ~once per hour during the flight using isotopically labeled nitric acid evolved from a perm tube held at constant temperature. Absolute calibration was obtained by collection in water and subsequent ion chromatography. Zeros were conducted ~3 times per hour by passing ambient air through a filter containing nylon wool coated with NaHCO3. UNCERTAINTY: +-(50% of measuremlent value + 50 pptv) ULOD_FLAG: -7777 ULOD_VALUE: N/A LLOD_FLAG: -8888 LLOD_VALUE: N/A; N/A; N/A; DM_CONTACT_INFO: John Crounse. California Institute of Technology. Department of Chemistry and Chemical Engineering. MC 150-21. 1200 E. California Blvd. Pasadena, CA 91125. Phone: (626) 395-6868. Fax: (626) 585-1917. email: crounjd@caltech.edu. PROJECT_INFO: TC4 study; 13 July-13 August 2007; Study of cloud processing and tropical convection processes STIPULATIONS_ON_USE: Use of these data requires PI notification and adherence to the TC4 data protocol. OTHER_COMMENTS: N/A REVISION: R0 R0: Preliminary Data Revision 0. Water correction has been applied using CIT-CIMS water. Reduction code 1.5 start_UTC(s) stop_UTC(s) mid_UTC(s) HNO3(pptv) 67090.34 67090.84 67090.59 1042.0 67102.34 67102.84 67102.59 1027.6 67114.34 67114.84 67114.59 977.3 67126.34 67126.84 67126.59 998.9 67138.34 67138.84 67138.59 993.8 67150.34 67150.84 67150.59 1007.7 67162.22 67162.72 67162.47 998.5 67174.22 67174.72 67174.47 931.9 67186.22 67186.72 67186.47 921.6 67198.22 67198.72 67198.47 949.8 67210.22 67210.72 67210.47 898.3 67222.34 67222.84 67222.59 941.4 67234.41 67234.91 67234.66 908.9 67246.34 67246.84 67246.59 948.6 67258.41 67258.91 67258.66 951.4 67270.22 67270.72 67270.47 952.9 67282.22 67282.72 67282.47 958.3 67294.28 67294.78 67294.53 948.4 67306.28 67306.78 67306.53 1010.1 67318.22 67318.72 67318.47 946.7 67330.22 67330.72 67330.47 1032.7 67342.28 67342.78 67342.53 954.1 67354.22 67354.72 67354.47 1026.4 67366.22 67366.72 67366.47 1100.5 67378.22 67378.72 67378.47 1177.7 67390.22 67390.72 67390.47 1179.1 67402.22 67402.72 67402.47 1218.8 67414.22 67414.72 67414.47 1058.7 67426.22 67426.72 67426.47 1211.3 67438.22 67438.72 67438.47 1159.6 67450.22 67450.72 67450.47 836.0 67462.22 67462.72 67462.47 614.3 67474.22 67474.72 67474.47 528.2 67486.22 67486.72 67486.47 450.7 67498.22 67498.72 67498.47 444.6 67510.28 67510.78 67510.53 321.5 67522.22 67522.72 67522.47 286.4 67534.22 67534.72 67534.47 306.2 67546.22 67546.72 67546.47 266.6 67558.22 67558.72 67558.47 256.9 67570.22 67570.72 67570.47 302.9 67582.22 67582.72 67582.47 316.3 67594.22 67594.72 67594.47 246.7 67606.28 67606.78 67606.53 263.7 67618.22 67618.72 67618.47 263.8 67630.28 67630.78 67630.53 213.4 67642.22 67642.72 67642.47 242.2 67654.28 67654.78 67654.53 181.9 67666.22 67666.72 67666.47 174.4 67678.22 67678.72 67678.47 173.1 67690.22 67690.72 67690.47 180.1 67702.22 67702.72 67702.47 173.3 67714.28 67714.78 67714.53 161.1 67726.22 67726.72 67726.47 176.1 67738.22 67738.72 67738.47 176.9 67750.22 67750.72 67750.47 172.7 67762.22 67762.72 67762.47 159.6 67774.22 67774.72 67774.47 156.2 67786.22 67786.72 67786.47 225.3 67798.22 67798.72 67798.47 189.4 67810.28 67810.78 67810.53 185.6 67822.22 67822.72 67822.47 115.9 67834.22 67834.72 67834.47 146.8 67846.22 67846.72 67846.47 112.3 67858.22 67858.72 67858.47 132.6 67870.22 67870.72 67870.47 160.5 67882.22 67882.72 67882.47 136.8 67894.22 67894.72 67894.47 322.2 67906.22 67906.72 67906.47 344.4 67918.22 67918.72 67918.47 316.0 67930.22 67930.72 67930.47 428.3 67942.22 67942.72 67942.47 240.0 67954.22 67954.72 67954.47 187.4 67966.22 67966.72 67966.47 166.4 67978.22 67978.72 67978.47 184.7 68069.53 68070.03 68069.78 316.5 68081.47 68081.97 68081.72 295.0 68093.47 68093.97 68093.72 253.5 68105.47 68105.97 68105.72 219.2 68117.47 68117.97 68117.72 143.3 68129.47 68129.97 68129.72 86.2 68141.53 68142.03 68141.78 136.1 68153.47 68153.97 68153.72 288.5 68165.47 68165.97 68165.72 164.6 68177.47 68177.97 68177.72 160.9 68189.41 68189.91 68189.66 104.7 68201.34 68201.84 68201.59 61.9 68213.47 68213.97 68213.72 55.8 68225.47 68225.97 68225.72 73.0 68237.53 68238.03 68237.78 98.2 68249.53 68250.03 68249.78 62.6 68261.47 68261.97 68261.72 61.0 68273.47 68273.97 68273.72 88.0 68285.53 68286.03 68285.78 86.3 68297.47 68297.97 68297.72 54.6 68309.34 68309.84 68309.59 72.7 68321.41 68321.91 68321.66 97.0 68333.34 68333.84 68333.59 109.4 68345.34 68345.84 68345.59 95.5 68357.34 68357.84 68357.59 80.9 68369.53 68370.03 68369.78 86.1 68381.47 68381.97 68381.72 112.6 68393.47 68393.97 68393.72 101.2 68405.47 68405.97 68405.72 154.2 68417.34 68417.84 68417.59 75.4 68429.34 68429.84 68429.59 29.7 68441.41 68441.91 68441.66 -29.8 68453.34 68453.84 68453.59 -25.3 68465.34 68465.84 68465.59 40.2 68477.34 68477.84 68477.59 45.4 72365.41 72365.91 72365.66 54.7 72377.41 72377.91 72377.66 16.4 72389.34 72389.84 72389.59 75.7 72401.41 72401.91 72401.66 60.2 72413.41 72413.91 72413.66 67.1 72513.22 72513.72 72513.47 111.3 72525.28 72525.78 72525.53 7.1 72537.28 72537.78 72537.53 52.9 72549.28 72549.78 72549.53 66.3 72561.28 72561.78 72561.53 74.8 72573.28 72573.78 72573.53 30.2 72585.28 72585.78 72585.53 49.8 72597.28 72597.78 72597.53 25.2 72609.28 72609.78 72609.53 24.4 72621.28 72621.78 72621.53 36.6 72633.28 72633.78 72633.53 24.4 72645.28 72645.78 72645.53 38.6 72657.28 72657.78 72657.53 47.1 72669.22 72669.72 72669.47 98.1 72681.28 72681.78 72681.53 13.7 72693.28 72693.78 72693.53 67.4 72705.28 72705.78 72705.53 101.6 72717.28 72717.78 72717.53 134.0 72729.28 72729.78 72729.53 122.3 72741.28 72741.78 72741.53 21.0 72753.28 72753.78 72753.53 47.1 72765.28 72765.78 72765.53 39.6 72777.28 72777.78 72777.53 47.4 72789.28 72789.78 72789.53 71.2 72801.28 72801.78 72801.53 45.7 72813.28 72813.78 72813.53 27.6 72825.22 72825.72 72825.47 74.7 72837.22 72837.72 72837.47 76.1 72891.91 72892.41 72892.16 51.5 72903.91 72904.41 72904.16 22.9 72915.91 72916.41 72916.16 25.2 72927.91 72928.41 72928.16 13.7 72939.91 72940.41 72940.16 26.3 72951.91 72952.41 72952.16 38.9 72963.91 72964.41 72964.16 20.0 72975.91 72976.41 72976.16 24.7 72987.91 72988.41 72988.16 44.1 72999.91 73000.41 73000.16 43.7 73011.91 73012.41 73012.16 49.6 73023.91 73024.41 73024.16 22.9 73035.91 73036.41 73036.16 7.8 73047.91 73048.41 73048.16 40.7 73059.91 73060.41 73060.16 42.3 73071.91 73072.41 73072.16 18.2 73083.91 73084.41 73084.16 21.7 73095.91 73096.41 73096.16 37.5 73107.91 73108.41 73108.16 33.8 73119.91 73120.41 73120.16 82.3 73131.91 73132.41 73132.16 46.8 73143.91 73144.41 73144.16 75.4 73155.91 73156.41 73156.16 84.7 73167.91 73168.41 73168.16 54.7 73179.84 73180.34 73180.09 53.3 73191.91 73192.41 73192.16 30.6 73203.84 73204.34 73204.09 15.0 73215.84 73216.34 73216.09 -8.2 73227.91 73228.41 73228.16 -50.5 73345.34 73345.84 73345.59 -11.9 73357.34 73357.84 73357.59 -24.7 73369.34 73369.84 73369.59 183.0 73381.34 73381.84 73381.59 90.6 73393.41 73393.91 73393.66 79.5 73466.34 73466.84 73466.59 119.5 73478.34 73478.84 73478.59 115.5 73490.34 73490.84 73490.59 79.9 73502.41 73502.91 73502.66 56.7 73514.34 73514.84 73514.59 115.4 73526.34 73526.84 73526.59 85.8 73538.41 73538.91 73538.66 73.3 73550.34 73550.84 73550.59 69.3 73562.34 73562.84 73562.59 93.4 73574.41 73574.91 73574.66 30.9 73586.34 73586.84 73586.59 52.3 73598.41 73598.91 73598.66 82.8 73610.41 73610.91 73610.66 14.5 73622.41 73622.91 73622.66 -8.0 73634.41 73634.91 73634.66 34.6 73646.34 73646.84 73646.59 109.2 73658.41 73658.91 73658.66 145.7 73670.41 73670.91 73670.66 91.4 73682.34 73682.84 73682.59 132.7 73694.34 73694.84 73694.59 88.9 73706.41 73706.91 73706.66 148.8 73718.41 73718.91 73718.66 107.1 73730.34 73730.84 73730.59 78.2 73742.34 73742.84 73742.59 70.9 73754.41 73754.91 73754.66 12.9 73824.28 73824.78 73824.53 78.5 73836.28 73836.78 73836.53 4.7 73848.28 73848.78 73848.53 79.6 73860.28 73860.78 73860.53 78.4 73872.28 73872.78 73872.53 41.0 73884.28 73884.78 73884.53 11.9 73896.22 73896.72 73896.47 52.4 73908.28 73908.78 73908.53 -0.2 73920.22 73920.72 73920.47 49.4 73932.28 73932.78 73932.53 27.6 73944.28 73944.78 73944.53 28.8 73956.22 73956.72 73956.47 39.5 73968.28 73968.78 73968.53 11.8 73980.28 73980.78 73980.53 60.0 73992.22 73992.72 73992.47 23.5 74016.28 74016.78 74016.53 1337.9 74028.28 74028.78 74028.53 456.7 74040.22 74040.72 74040.47 1167.7 74052.28 74052.78 74052.53 2070.0 74064.22 74064.72 74064.47 2309.7 74076.28 74076.78 74076.53 3117.9 74088.22 74088.72 74088.47 3523.3 74100.22 74100.72 74100.47 3421.1 74112.22 74112.72 74112.47 3384.7 74124.22 74124.72 74124.47 3350.0 74136.22 74136.72 74136.47 3677.9 74148.22 74148.72 74148.47 3634.1 74160.22 74160.72 74160.47 3867.6 74172.22 74172.72 74172.47 3911.1 74184.22 74184.72 74184.47 3873.0 74196.22 74196.72 74196.47 4169.5 74208.22 74208.72 74208.47 4347.0 74220.28 74220.78 74220.53 4708.5 74232.22 74232.72 74232.47 4614.6 74244.22 74244.72 74244.47 4428.1 74335.34 74335.84 74335.59 2717.8 74347.34 74347.84 74347.59 2827.1 74359.41 74359.91 74359.66 2570.0 74371.41 74371.91 74371.66 2262.1 74383.34 74383.84 74383.59 2467.5 74395.34 74395.84 74395.59 2146.8 74407.34 74407.84 74407.59 2697.4 74419.41 74419.91 74419.66 1980.1 74431.34 74431.84 74431.59 1620.4 74443.41 74443.91 74443.66 3691.9 74455.28 74455.78 74455.53 3411.8 74467.28 74467.78 74467.53 598.6 74479.34 74479.84 74479.59 251.9 74491.41 74491.91 74491.66 157.0 74503.41 74503.91 74503.66 160.8 74515.34 74515.84 74515.59 146.0 74527.34 74527.84 74527.59 68.2 74539.34 74539.84 74539.59 41.7 74551.34 74551.84 74551.59 49.4 74563.34 74563.84 74563.59 -2.0 74575.22 74575.72 74575.47 24.7 74587.22 74587.72 74587.47 24.1 74599.22 74599.72 74599.47 -36.3 74623.22 74623.72 74623.47 -13.6 74687.09 74687.59 74687.34 44.9 74699.09 74699.59 74699.34 20.9 74711.09 74711.59 74711.34 65.2 74723.09 74723.59 74723.34 432.6 74735.16 74735.66 74735.41 172.0 74747.09 74747.59 74747.34 186.3 74759.09 74759.59 74759.34 189.7 74771.16 74771.66 74771.41 138.9 74783.16 74783.66 74783.41 155.8 74795.16 74795.66 74795.41 106.0 74807.16 74807.66 74807.41 201.8 74819.16 74819.66 74819.41 14.1 74831.16 74831.66 74831.41 67.0 74843.16 74843.66 74843.41 94.5 74855.16 74855.66 74855.41 122.8 74867.09 74867.59 74867.34 117.3 74879.16 74879.66 74879.41 41.0 74891.09 74891.59 74891.34 91.2 74903.09 74903.59 74903.34 96.0 74915.09 74915.59 74915.34 135.3 74927.16 74927.66 74927.41 40.9 74939.09 74939.59 74939.34 107.3 74951.09 74951.59 74951.34 105.9 74963.09 74963.59 74963.34 117.1 74991.97 74992.47 74992.22 76.5 75004.03 75004.53 75004.28 71.4 75016.03 75016.53 75016.28 61.8 75028.03 75028.53 75028.28 32.5 75039.97 75040.47 75040.22 98.0 75052.03 75052.53 75052.28 102.5 75064.03 75064.53 75064.28 126.2 75076.03 75076.53 75076.28 68.3 75087.97 75088.47 75088.22 83.0 75100.03 75100.53 75100.28 81.2 75112.03 75112.53 75112.28 59.0 75124.03 75124.53 75124.28 85.5 75136.03 75136.53 75136.28 99.0 75148.03 75148.53 75148.28 94.8 75160.03 75160.53 75160.28 106.9 75172.03 75172.53 75172.28 46.2 75183.97 75184.47 75184.22 100.3 75196.03 75196.53 75196.28 75.9 75208.03 75208.53 75208.28 54.0 75219.97 75220.47 75220.22 23.9 75231.97 75232.47 75232.22 57.1 75412.41 75412.91 75412.66 269.8 75616.28 75616.78 75616.53 153.2 75628.28 75628.78 75628.53 136.2 75640.28 75640.78 75640.53 135.5 75652.22 75652.72 75652.47 190.7 75664.28 75664.78 75664.53 166.4 75676.22 75676.72 75676.47 156.2 75688.28 75688.78 75688.53 177.3 75700.28 75700.78 75700.53 106.8 75712.28 75712.78 75712.53 145.9 75724.28 75724.78 75724.53 145.6 75736.22 75736.72 75736.47 150.8 75748.28 75748.78 75748.53 160.1 75760.22 75760.72 75760.47 212.2 75772.28 75772.78 75772.53 147.2 75784.22 75784.72 75784.47 74.9 75796.28 75796.78 75796.53 149.7 75808.28 75808.78 75808.53 145.0 75820.22 75820.72 75820.47 69.3 75832.22 75832.72 75832.47 165.8 75844.28 75844.78 75844.53 83.5 75919.41 75919.91 75919.66 91.8 75931.34 75931.84 75931.59 165.1 75943.41 75943.91 75943.66 141.7 75955.34 75955.84 75955.59 98.2 75967.34 75967.84 75967.59 212.4 75979.34 75979.84 75979.59 162.6 75991.34 75991.84 75991.59 89.9 76003.41 76003.91 76003.66 112.0 76015.41 76015.91 76015.66 126.6 76027.34 76027.84 76027.59 100.5 76039.34 76039.84 76039.59 95.9 76051.34 76051.84 76051.59 103.3 76063.34 76063.84 76063.59 76.9 76075.34 76075.84 76075.59 85.5 76087.34 76087.84 76087.59 144.9 76099.41 76099.91 76099.66 91.5 76111.34 76111.84 76111.59 110.1 76123.34 76123.84 76123.59 52.8 76135.34 76135.84 76135.59 102.9 76147.41 76147.91 76147.66 118.2 76809.34 76809.84 76809.59 263.8 76821.41 76821.91 76821.66 199.7 77185.16 77185.66 77185.41 70.1 77197.09 77197.59 77197.34 104.2 77209.16 77209.66 77209.41 77.4 77221.16 77221.66 77221.41 82.4 77233.16 77233.66 77233.41 48.5 77245.03 77245.53 77245.28 59.4 77257.03 77257.53 77257.28 0.3 77269.03 77269.53 77269.28 -70.2 77281.03 77281.53 77281.28 14.8 77293.03 77293.53 77293.28 4.5 77305.03 77305.53 77305.28 -5.5 77316.97 77317.47 77317.22 102.9 77329.16 77329.66 77329.41 37.8 77341.16 77341.66 77341.41 -37.6 77352.97 77353.47 77353.22 27.5 77794.41 77794.91 77794.66 52.0 77806.41 77806.91 77806.66 17.8 77818.41 77818.91 77818.66 40.3 77830.41 77830.91 77830.66 -2.2 77842.41 77842.91 77842.66 16.7 77854.34 77854.84 77854.59 32.0 77866.41 77866.91 77866.66 44.3 77878.34 77878.84 77878.59 31.6 77890.34 77890.84 77890.59 36.8 77902.28 77902.78 77902.53 -7.0 77914.28 77914.78 77914.53 33.0 77926.28 77926.78 77926.53 44.3 77938.41 77938.91 77938.66 31.0 77950.34 77950.84 77950.59 62.5 77962.34 77962.84 77962.59 10.4 77974.41 77974.91 77974.66 35.2 77986.41 77986.91 77986.66 134.0 77998.34 77998.84 77998.59 62.7 78010.41 78010.91 78010.66 49.9 78022.28 78022.78 78022.53 134.9 78034.22 78034.72 78034.47 -31.6 78046.28 78046.78 78046.53 -49.4 78058.28 78058.78 78058.53 22.1 78070.28 78070.78 78070.53 70.1 78082.28 78082.78 78082.53 -62.6 78094.41 78094.91 78094.66 36.0 78106.41 78106.91 78106.66 111.4 78118.41 78118.91 78118.66 12.2 78130.22 78130.72 78130.47 94.0 78154.22 78154.72 78154.47 20.3 78166.28 78166.78 78166.53 73.5 78202.22 78202.72 78202.47 97.1 78350.22 78350.72 78350.47 47.6 78362.28 78362.78 78362.53 66.0 78374.28 78374.78 78374.53 31.6 78386.22 78386.72 78386.47 159.1 78398.28 78398.78 78398.53 66.4 78410.28 78410.78 78410.53 -14.4 78422.22 78422.72 78422.47 88.6 78434.28 78434.78 78434.53 49.2 78446.28 78446.78 78446.53 154.4 78458.22 78458.72 78458.47 128.6 78470.22 78470.72 78470.47 108.5 78482.28 78482.78 78482.53 57.5 78494.22 78494.72 78494.47 117.9 78506.22 78506.72 78506.47 83.9 78518.28 78518.78 78518.53 63.2 78530.22 78530.72 78530.47 50.7 78542.28 78542.78 78542.53 105.8 78554.22 78554.72 78554.47 145.9 78566.22 78566.72 78566.47 36.6 78578.28 78578.78 78578.53 -2.6 78590.22 78590.72 78590.47 34.9 78602.22 78602.72 78602.47 44.1 78614.22 78614.72 78614.47 117.7 78626.22 78626.72 78626.47 16.6 78638.22 78638.72 78638.47 83.6 78650.22 78650.72 78650.47 39.0 78662.22 78662.72 78662.47 27.8 78674.22 78674.72 78674.47 0.6 78686.28 78686.78 78686.53 37.8 78783.34 78783.84 78783.59 100.6 78795.41 78795.91 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