43 1001 Wennberg, Paul California Institute of Technology Gas Phase Hydrogen Cyanide from DC-8 TC4 1 1 2007 07 02 2011 09 07 0 start_UTC, s 3 1 1 1 999999 999999 999999 stop_UTC, s mid_UTC, s HCN, pptv 0 26 PI_CONTACT_INFO: Address: California Institute of Technology. MC 150-21. 1200 E. California Blvd, Pasadena, CA, 91125. Phone: (626) 395-2447. Fax: (626) 585-1917. email: wennberg@gps.caltech.edu PLATFORM: NASA DC-8 airborne laboratory. LOCATION: Aircraft location data in file TN_20070702.DC8. ASSOCIATED_DATA: N/A INSTRUMENT_INFO: Chemical Ionization Mass Spectrometer. Direct measurements in ambient air. DATA_INFO: Measurements are reported as 0.5 sec averages and in units of pptv. CAUTION: Do not extrapolate data outside of given time interval as these are discrete measurements. Calibration was conducted ~once per hour during the flight using H2O2 and HNO3 calibrants, and proxied to HCN using laboratory calibrations. Absolute calibration was obtained in the laboratory by FTIR spectroscopy. Zeros were conducted ~3 times per hour by passing ambient air through a filter containing nylon wool coated with NaHCO3. UNCERTAINTY: +-(50% of measuremlent value + 50 pptv) ULOD_FLAG: 7777777 ULOD_VALUE: N/A LLOD_FLAG: 8888888 LLOD_VALUE: N/A; N/A; N/A; DM_CONTACT_INFO: John Crounse. California Institute of Technology. Department of Chemistry and Chemical Engineering. MC 150-21. 1200 E. California Blvd. Pasadena, CA 91125. Phone: (626) 395-6868. Fax: (626) 585-1917. email: crounjd@caltech.edu. PROJECT_INFO: TC4 study; 13 July-13 August 2007; Study of cloud processing and tropical convection processes STIPULATIONS_ON_USE: Use of these data requires PI notification and adherence to the TC4 data protocol. OTHER_COMMENTS: N/A REVISION: R1 R1: ULOD and LLOD flags changed to positive values, to conform to Ames format 2.1 specifications. R0: Preliminary Data Revision 0. Water correction has been applied using CIT-CIMS water. Reduction code 1.5 start_UTC stop_UTC mid_UTC HCN 67082.41 67082.91 67082.66 273.3 67094.34 67094.84 67094.59 257.1 67106.34 67106.84 67106.59 256.1 67118.34 67118.84 67118.59 254.0 67130.41 67130.91 67130.66 262.3 67142.34 67142.84 67142.59 298.8 67154.22 67154.72 67154.47 249.3 67166.28 67166.78 67166.53 228.6 67178.22 67178.72 67178.47 230.9 67190.28 67190.78 67190.53 226.8 67202.22 67202.72 67202.47 245.5 67214.22 67214.72 67214.47 237.0 67226.34 67226.84 67226.59 237.1 67238.34 67238.84 67238.59 226.2 67250.34 67250.84 67250.59 248.1 67262.28 67262.78 67262.53 256.8 67274.22 67274.72 67274.47 229.9 67286.28 67286.78 67286.53 239.2 67298.22 67298.72 67298.47 227.4 67310.22 67310.72 67310.47 238.9 67322.22 67322.72 67322.47 253.7 67334.22 67334.72 67334.47 235.3 67346.28 67346.78 67346.53 228.1 67358.22 67358.72 67358.47 249.2 67370.34 67370.84 67370.59 233.0 67382.28 67382.78 67382.53 219.4 67394.22 67394.72 67394.47 257.5 67406.22 67406.72 67406.47 250.8 67418.22 67418.72 67418.47 212.4 67430.22 67430.72 67430.47 263.4 67442.22 67442.72 67442.47 230.3 67454.22 67454.72 67454.47 152.2 67466.22 67466.72 67466.47 149.4 67478.22 67478.72 67478.47 143.9 67490.22 67490.72 67490.47 158.5 67502.22 67502.72 67502.47 159.7 67514.22 67514.72 67514.47 139.4 67526.28 67526.78 67526.53 198.4 67538.22 67538.72 67538.47 192.2 67550.22 67550.72 67550.47 160.2 67562.22 67562.72 67562.47 181.8 67574.28 67574.78 67574.53 157.6 67586.22 67586.72 67586.47 157.6 67598.22 67598.72 67598.47 210.7 67610.22 67610.72 67610.47 193.0 67622.22 67622.72 67622.47 177.0 67634.22 67634.72 67634.47 191.0 67646.22 67646.72 67646.47 181.5 67658.28 67658.78 67658.53 168.1 67670.22 67670.72 67670.47 183.4 67682.22 67682.72 67682.47 164.9 67694.22 67694.72 67694.47 171.4 67706.22 67706.72 67706.47 172.6 67718.22 67718.72 67718.47 176.8 67730.22 67730.72 67730.47 192.1 67742.28 67742.78 67742.53 187.9 67754.22 67754.72 67754.47 153.3 67766.22 67766.72 67766.47 175.9 67778.22 67778.72 67778.47 209.3 67790.22 67790.72 67790.47 216.8 67802.22 67802.72 67802.47 247.8 67814.22 67814.72 67814.47 226.9 67826.22 67826.72 67826.47 190.5 67838.28 67838.78 67838.53 189.8 67850.22 67850.72 67850.47 175.1 67862.22 67862.72 67862.47 170.0 67874.22 67874.72 67874.47 244.8 67886.22 67886.72 67886.47 244.5 67898.22 67898.72 67898.47 260.4 67910.22 67910.72 67910.47 203.7 67922.22 67922.72 67922.47 234.9 67934.22 67934.72 67934.47 265.9 67946.28 67946.78 67946.53 202.7 67958.22 67958.72 67958.47 212.8 67970.22 67970.72 67970.47 236.0 67982.22 67982.72 67982.47 239.8 68073.47 68073.97 68073.72 300.2 68085.47 68085.97 68085.72 314.9 68097.47 68097.97 68097.72 319.7 68109.47 68109.97 68109.72 169.5 68121.53 68122.03 68121.78 167.2 68133.47 68133.97 68133.72 130.6 68145.47 68145.97 68145.72 149.4 68157.53 68158.03 68157.78 299.4 68169.47 68169.97 68169.72 261.1 68181.47 68181.97 68181.72 265.9 68193.34 68193.84 68193.59 297.4 68205.41 68205.91 68205.66 254.3 68217.47 68217.97 68217.72 270.7 68229.47 68229.97 68229.72 276.4 68241.47 68241.97 68241.72 229.5 68253.53 68254.03 68253.78 205.9 68265.53 68266.03 68265.78 217.9 68277.47 68277.97 68277.72 183.2 68289.47 68289.97 68289.72 193.8 68301.34 68301.84 68301.59 183.6 68313.41 68313.91 68313.66 195.1 68325.41 68325.91 68325.66 157.2 68337.34 68337.84 68337.59 188.3 68349.34 68349.84 68349.59 184.9 68361.47 68361.97 68361.72 198.5 68373.47 68373.97 68373.72 187.6 68385.47 68385.97 68385.72 252.1 68397.47 68397.97 68397.72 251.5 68409.34 68409.84 68409.59 257.8 68421.34 68421.84 68421.59 258.3 68433.34 68433.84 68433.59 329.4 68445.34 68445.84 68445.59 274.6 68457.34 68457.84 68457.59 288.8 68469.41 68469.91 68469.66 140.7 68481.41 68481.91 68481.66 210.6 72369.34 72369.84 72369.59 294.5 72381.34 72381.84 72381.59 323.6 72393.41 72393.91 72393.66 323.3 72405.34 72405.84 72405.59 306.2 72417.34 72417.84 72417.59 295.9 72517.22 72517.72 72517.47 281.4 72529.22 72529.72 72529.47 323.4 72541.22 72541.72 72541.47 302.0 72553.22 72553.72 72553.47 262.3 72565.22 72565.72 72565.47 340.6 72577.28 72577.78 72577.53 253.8 72589.22 72589.72 72589.47 327.9 72601.28 72601.78 72601.53 372.4 72613.22 72613.72 72613.47 276.7 72625.28 72625.78 72625.53 260.2 72637.22 72637.72 72637.47 317.5 72649.22 72649.72 72649.47 363.3 72661.28 72661.78 72661.53 306.1 72673.22 72673.72 72673.47 296.6 72685.22 72685.72 72685.47 353.7 72697.22 72697.72 72697.47 365.9 72709.22 72709.72 72709.47 394.8 72721.28 72721.78 72721.53 417.8 72733.22 72733.72 72733.47 384.3 72745.22 72745.72 72745.47 306.3 72757.22 72757.72 72757.47 304.6 72769.22 72769.72 72769.47 302.7 72781.22 72781.72 72781.47 315.9 72793.22 72793.72 72793.47 305.2 72805.22 72805.72 72805.47 293.1 72817.22 72817.72 72817.47 278.8 72829.22 72829.72 72829.47 302.8 72841.22 72841.72 72841.47 285.0 72895.84 72896.34 72896.09 269.8 72907.84 72908.34 72908.09 262.5 72919.84 72920.34 72920.09 291.0 72931.84 72932.34 72932.09 243.4 72943.91 72944.41 72944.16 272.3 72955.84 72956.34 72956.09 248.3 72967.91 72968.41 72968.16 289.5 72979.84 72980.34 72980.09 248.8 72991.84 72992.34 72992.09 305.2 73003.91 73004.41 73004.16 291.1 73015.84 73016.34 73016.09 292.0 73027.84 73028.34 73028.09 272.2 73039.91 73040.41 73040.16 306.1 73051.84 73052.34 73052.09 256.7 73063.84 73064.34 73064.09 277.5 73075.84 73076.34 73076.09 277.7 73087.91 73088.41 73088.16 268.5 73099.84 73100.34 73100.09 247.3 73111.84 73112.34 73112.09 239.6 73123.84 73124.34 73124.09 293.8 73135.84 73136.34 73136.09 250.5 73147.84 73148.34 73148.09 308.3 73159.84 73160.34 73160.09 312.4 73171.91 73172.41 73172.16 203.8 73183.84 73184.34 73184.09 213.5 73195.84 73196.34 73196.09 214.6 73207.84 73208.34 73208.09 206.2 73219.91 73220.41 73220.16 253.7 73231.91 73232.41 73232.16 215.9 73349.41 73349.91 73349.66 191.7 73361.34 73361.84 73361.59 203.8 73373.34 73373.84 73373.59 251.2 73385.34 73385.84 73385.59 255.7 73397.41 73397.91 73397.66 259.6 73470.34 73470.84 73470.59 208.9 73482.34 73482.84 73482.59 227.6 73494.34 73494.84 73494.59 235.4 73506.34 73506.84 73506.59 273.7 73518.34 73518.84 73518.59 271.2 73530.41 73530.91 73530.66 228.6 73542.34 73542.84 73542.59 299.8 73554.34 73554.84 73554.59 271.0 73566.34 73566.84 73566.59 287.4 73578.34 73578.84 73578.59 307.5 73590.34 73590.84 73590.59 329.1 73602.34 73602.84 73602.59 255.3 73614.34 73614.84 73614.59 235.6 73626.34 73626.84 73626.59 268.9 73638.34 73638.84 73638.59 267.2 73650.34 73650.84 73650.59 289.3 73662.34 73662.84 73662.59 280.1 73674.34 73674.84 73674.59 217.9 73686.34 73686.84 73686.59 223.6 73698.41 73698.91 73698.66 187.7 73710.34 73710.84 73710.59 198.5 73722.41 73722.91 73722.66 226.8 73734.41 73734.91 73734.66 185.9 73746.41 73746.91 73746.66 193.2 73758.34 73758.84 73758.59 210.7 73828.22 73828.72 73828.47 157.2 73840.22 73840.72 73840.47 183.1 73852.22 73852.72 73852.47 189.6 73864.22 73864.72 73864.47 185.0 73876.22 73876.72 73876.47 212.9 73888.22 73888.72 73888.47 182.0 73900.22 73900.72 73900.47 202.4 73912.22 73912.72 73912.47 183.0 73924.22 73924.72 73924.47 186.6 73936.28 73936.78 73936.53 194.5 73948.22 73948.72 73948.47 212.0 73960.22 73960.72 73960.47 192.8 73972.22 73972.72 73972.47 187.7 73984.22 73984.72 73984.47 198.3 73996.22 73996.72 73996.47 195.0 74008.22 74008.72 74008.47 248.6 74020.22 74020.72 74020.47 248.8 74032.22 74032.72 74032.47 329.3 74044.22 74044.72 74044.47 290.1 74056.22 74056.72 74056.47 412.9 74068.28 74068.78 74068.53 455.9 74080.22 74080.72 74080.47 406.4 74092.22 74092.72 74092.47 444.8 74104.22 74104.72 74104.47 446.5 74116.28 74116.78 74116.53 447.0 74128.22 74128.72 74128.47 474.7 74140.22 74140.72 74140.47 441.8 74152.28 74152.78 74152.53 479.3 74164.22 74164.72 74164.47 444.2 74176.22 74176.72 74176.47 485.7 74188.22 74188.72 74188.47 491.6 74200.22 74200.72 74200.47 479.7 74212.22 74212.72 74212.47 524.3 74224.28 74224.78 74224.53 528.3 74236.22 74236.72 74236.47 500.5 74248.22 74248.72 74248.47 503.3 74339.34 74339.84 74339.59 514.6 74351.34 74351.84 74351.59 499.7 74363.34 74363.84 74363.59 440.0 74375.34 74375.84 74375.59 431.5 74387.41 74387.91 74387.66 483.8 74399.41 74399.91 74399.66 434.5 74411.34 74411.84 74411.59 423.7 74423.34 74423.84 74423.59 427.8 74435.34 74435.84 74435.59 325.1 74447.34 74447.84 74447.59 359.7 74459.22 74459.72 74459.47 229.9 74471.28 74471.78 74471.53 178.9 74483.34 74483.84 74483.59 202.6 74495.34 74495.84 74495.59 184.8 74507.34 74507.84 74507.59 176.0 74519.34 74519.84 74519.59 195.1 74531.34 74531.84 74531.59 171.4 74543.34 74543.84 74543.59 182.9 74555.34 74555.84 74555.59 164.1 74567.22 74567.72 74567.47 161.4 74579.22 74579.72 74579.47 175.1 74591.28 74591.78 74591.53 168.3 74603.22 74603.72 74603.47 175.2 74615.22 74615.72 74615.47 177.1 74627.34 74627.84 74627.59 152.0 74691.09 74691.59 74691.34 105.0 74703.09 74703.59 74703.34 99.5 74715.09 74715.59 74715.34 178.8 74727.09 74727.59 74727.34 154.5 74739.09 74739.59 74739.34 185.6 74751.09 74751.59 74751.34 183.7 74763.09 74763.59 74763.34 196.0 74775.09 74775.59 74775.34 223.9 74787.09 74787.59 74787.34 220.2 74799.09 74799.59 74799.34 188.3 74811.09 74811.59 74811.34 151.6 74823.09 74823.59 74823.34 61.4 74835.09 74835.59 74835.34 46.7 74847.09 74847.59 74847.34 178.8 74859.09 74859.59 74859.34 130.6 74871.09 74871.59 74871.34 130.4 74883.09 74883.59 74883.34 183.6 74895.09 74895.59 74895.34 167.4 74907.09 74907.59 74907.34 233.8 74919.09 74919.59 74919.34 225.1 74931.09 74931.59 74931.34 176.3 74943.09 74943.59 74943.34 154.7 74955.09 74955.59 74955.34 131.9 74967.16 74967.66 74967.41 144.6 74995.97 74996.47 74996.22 112.2 75008.03 75008.53 75008.28 133.0 75019.97 75020.47 75020.22 169.8 75031.97 75032.47 75032.22 148.8 75043.97 75044.47 75044.22 133.1 75056.03 75056.53 75056.28 141.0 75067.97 75068.47 75068.22 133.7 75079.97 75080.47 75080.22 118.7 75091.97 75092.47 75092.22 97.6 75103.97 75104.47 75104.22 114.5 75116.03 75116.53 75116.28 49.1 75127.97 75128.47 75128.22 71.4 75140.03 75140.53 75140.28 101.2 75151.97 75152.47 75152.22 104.7 75163.97 75164.47 75164.22 106.0 75175.97 75176.47 75176.22 102.9 75188.03 75188.53 75188.28 158.6 75199.97 75200.47 75200.22 124.8 75211.97 75212.47 75212.22 118.2 75223.97 75224.47 75224.22 110.8 75235.97 75236.47 75236.22 175.8 75416.34 75416.84 75416.59 128.2 75620.22 75620.72 75620.47 139.8 75632.22 75632.72 75632.47 145.5 75644.22 75644.72 75644.47 146.1 75656.22 75656.72 75656.47 172.4 75668.22 75668.72 75668.47 157.3 75680.28 75680.78 75680.53 176.1 75692.22 75692.72 75692.47 206.5 75704.22 75704.72 75704.47 206.4 75716.28 75716.78 75716.53 188.7 75728.22 75728.72 75728.47 166.8 75740.22 75740.72 75740.47 192.8 75752.22 75752.72 75752.47 212.7 75764.22 75764.72 75764.47 179.0 75776.22 75776.72 75776.47 171.0 75788.22 75788.72 75788.47 160.6 75800.22 75800.72 75800.47 164.5 75812.22 75812.72 75812.47 165.6 75824.22 75824.72 75824.47 126.9 75836.22 75836.72 75836.47 197.8 75848.22 75848.72 75848.47 140.3 75923.34 75923.84 75923.59 141.5 75935.34 75935.84 75935.59 126.6 75947.41 75947.91 75947.66 109.6 75959.34 75959.84 75959.59 149.5 75971.34 75971.84 75971.59 49.8 75983.34 75983.84 75983.59 79.0 75995.41 75995.91 75995.66 138.3 76007.34 76007.84 76007.59 148.7 76019.34 76019.84 76019.59 164.3 76031.34 76031.84 76031.59 152.9 76043.41 76043.91 76043.66 148.6 76055.41 76055.91 76055.66 145.9 76067.34 76067.84 76067.59 146.7 76079.34 76079.84 76079.59 237.8 76091.41 76091.91 76091.66 256.0 76103.34 76103.84 76103.59 208.5 76115.34 76115.84 76115.59 204.6 76127.34 76127.84 76127.59 207.6 76139.34 76139.84 76139.59 209.4 76151.34 76151.84 76151.59 142.2 77189.09 77189.59 77189.34 201.4 77201.09 77201.59 77201.34 207.3 77213.09 77213.59 77213.34 219.0 77225.09 77225.59 77225.34 183.9 77236.97 77237.47 77237.22 220.4 77249.03 77249.53 77249.28 231.6 77260.97 77261.47 77261.22 195.6 77273.03 77273.53 77273.28 214.5 77285.03 77285.53 77285.28 283.2 77297.03 77297.53 77297.28 275.7 77308.97 77309.47 77309.22 264.8 77320.97 77321.47 77321.22 290.5 77333.09 77333.59 77333.34 264.7 77345.16 77345.66 77345.41 278.3 77357.03 77357.53 77357.28 261.6 77798.34 77798.84 77798.59 277.5 77810.34 77810.84 77810.59 297.5 77822.41 77822.91 77822.66 210.5 77834.34 77834.84 77834.59 234.0 77846.34 77846.84 77846.59 237.0 77858.34 77858.84 77858.59 315.7 77870.34 77870.84 77870.59 306.0 77882.41 77882.91 77882.66 388.2 77894.34 77894.84 77894.59 334.1 77906.22 77906.72 77906.47 299.6 77918.22 77918.72 77918.47 292.6 77930.28 77930.78 77930.53 281.3 77942.34 77942.84 77942.59 302.1 77954.34 77954.84 77954.59 368.4 77966.34 77966.84 77966.59 306.4 77978.34 77978.84 77978.59 266.9 77990.34 77990.84 77990.59 313.9 78002.34 78002.84 78002.59 300.2 78014.22 78014.72 78014.47 276.0 78026.22 78026.72 78026.47 243.8 78038.28 78038.78 78038.53 253.9 78050.22 78050.72 78050.47 214.5 78062.28 78062.78 78062.53 249.9 78074.22 78074.72 78074.47 230.9 78086.34 78086.84 78086.59 264.0 78098.41 78098.91 78098.66 175.5 78110.41 78110.91 78110.66 258.0 78122.34 78122.84 78122.59 289.1 78134.22 78134.72 78134.47 205.5 78146.28 78146.78 78146.53 241.4 78158.22 78158.72 78158.47 393.8 78170.28 78170.78 78170.53 339.4 78182.22 78182.72 78182.47 243.5 78194.22 78194.72 78194.47 259.4 78206.22 78206.72 78206.47 291.5 78354.22 78354.72 78354.47 191.1 78366.22 78366.72 78366.47 173.2 78378.22 78378.72 78378.47 206.0 78390.22 78390.72 78390.47 188.0 78402.28 78402.78 78402.53 191.4 78414.22 78414.72 78414.47 232.8 78426.22 78426.72 78426.47 238.8 78438.22 78438.72 78438.47 183.7 78450.22 78450.72 78450.47 153.3 78462.22 78462.72 78462.47 219.6 78474.22 78474.72 78474.47 235.1 78486.22 78486.72 78486.47 209.1 78498.22 78498.72 78498.47 222.9 78510.28 78510.78 78510.53 245.8 78522.22 78522.72 78522.47 282.7 78534.22 78534.72 78534.47 387.3 78546.22 78546.72 78546.47 368.9 78558.22 78558.72 78558.47 397.7 78570.22 78570.72 78570.47 351.0 78582.28 78582.78 78582.53 324.9 78594.22 78594.72 78594.47 405.5 78606.22 78606.72 78606.47 504.1 78618.28 78618.78 78618.53 412.5 78630.22 78630.72 78630.47 340.6 78642.22 78642.72 78642.47 448.3 78654.22 78654.72 78654.47 519.2 78666.28 78666.78 78666.53 497.8 78678.28 78678.78 78678.53 407.9 78690.22 78690.72 78690.47 399.9 78787.34 78787.84 78787.59 532.0 78799.34 78799.84 78799.59 516.1 78811.41 78811.91 78811.66 384.4 78929.34 78929.84 78929.59 412.6 78941.34 78941.84 78941.59 432.6 78953.41 78953.91 78953.66 456.1 78965.34 78965.84 78965.59 423.7 78977.34 78977.84 78977.59 455.3 78989.41 78989.91 78989.66 511.2 79001.34 79001.84 79001.59 454.6 79013.34 79013.84 79013.59 388.4 79025.34 79025.84 79025.59 463.3 79037.34 79037.84 79037.59 473.3 79049.34 79049.84 79049.59 365.6 79061.34 79061.84 79061.59 382.2 79073.34 79073.84 79073.59 480.9 79085.34 79085.84 79085.59 468.2 79097.34 79097.84 79097.59 405.7 79109.34 79109.84 79109.59 331.4 79121.41 79121.91 79121.66 374.0 79133.34 79133.84 79133.59 285.0 79145.34 79145.84 79145.59 226.5 79157.34 79157.84 79157.59 341.2 79169.41 79169.91 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