41 1001 Wennberg, Paul California Institute of Technology Gas Phase Peroxynitric Acid from DC-8 TC4 1 1 2007 06 28 2007 07 20 0 start_UTC, s 3 1 1 1 999999 999999 999999 stop_UTC, s mid_UTC, s PNA, pptv 0 24 PI_CONTACT_INFO: Address: California Institute of Technology. MC 150-21. 1200 E. California Blvd, Pasadena, CA, 91125. Phone: (626) 395-2447. Fax: (626) 585-1917. email: wennberg@gps.caltech.edu PLATFORM: NASA DC-8 airborne laboratory. LOCATION: Aircraft location data in file TN_20070628.DC8. ASSOCIATED_DATA: N/A INSTRUMENT_INFO: Chemical Ionization Mass Spectrometer. Direct measurements in ambient air. DATA_INFO: Measurements are reported as 0.5 sec averages and in units of pptv. CAUTION: Do not extrapolate data outside of given time interval as these are discrete measurements. Calibration was conducted ~once per hour during the flight using H2O2 and HNO3 calibrants, and proxied to PNA using laboratory calibrations. Absolute calibration was obtained in the laboratory by thermal decomposition and NO2 measurement. Zeros were conducted ~3 times per hour by passing ambient air through a filter containing nylon wool coated with NaHCO3. UNCERTAINTY: +-(100% of measuremlent value + 20 pptv) ULOD_FLAG: -7777 ULOD_VALUE: N/A LLOD_FLAG: -8888 LLOD_VALUE: N/A; N/A; N/A; DM_CONTACT_INFO: John Crounse. California Institute of Technology. Department of Chemistry and Chemical Engineering. MC 150-21. 1200 E. California Blvd. Pasadena, CA 91125. Phone: (626) 395-6868. Fax: (626) 585-1917. email: crounjd@caltech.edu. PROJECT_INFO: TC4 study; 13 July-13 August 2007; Study of cloud processing and tropical convection processes STIPULATIONS_ON_USE: Use of these data requires PI notification and adherence to the TC4 data protocol. OTHER_COMMENTS: N/A REVISION: R0 R0: Preliminary Data Revision 0. Water correction has been applied using CIT-CIMS water. Reduction code 1.5 start_UTC(s) stop_UTC(s) mid_UTC(s) PNA(pptv) 76186.84 76187.34 76187.09 -4.2 76198.91 76199.41 76199.16 -7.1 76210.84 76211.34 76211.09 48.7 76222.84 76223.34 76223.09 48.4 76234.84 76235.34 76235.09 95.7 76246.91 76247.41 76247.16 20.2 76258.84 76259.34 76259.09 58.2 76270.84 76271.34 76271.09 54.6 76282.84 76283.34 76283.09 66.5 76294.72 76295.22 76294.97 38.8 76306.72 76307.22 76306.97 61.2 76318.84 76319.34 76319.09 61.9 76330.84 76331.34 76331.09 70.6 76342.84 76343.34 76343.09 81.5 76354.84 76355.34 76355.09 47.4 76366.84 76367.34 76367.09 78.2 76378.91 76379.41 76379.16 71.2 76390.84 76391.34 76391.09 57.6 76402.72 76403.22 76402.97 83.6 76414.72 76415.22 76414.97 56.6 76426.78 76427.28 76427.03 38.6 76438.78 76439.28 76439.03 38.7 76450.72 76451.22 76450.97 77.2 76462.84 76463.34 76463.09 59.3 76474.84 76475.34 76475.09 28.0 76486.91 76487.41 76487.16 14.1 76498.84 76499.34 76499.09 4.0 76510.72 76511.22 76510.97 8.1 76522.72 76523.22 76522.97 3.5 76534.78 76535.28 76535.03 -7.6 76546.72 76547.22 76546.97 13.8 76558.72 76559.22 76558.97 0.4 76570.72 76571.22 76570.97 2.7 76582.78 76583.28 76583.03 3.5 76594.78 76595.28 76595.03 0.6 76606.78 76607.28 76607.03 11.6 76618.72 76619.22 76618.97 -11.2 76630.78 76631.28 76631.03 12.5 76642.72 76643.22 76642.97 10.8 76654.72 76655.22 76654.97 0.7 76666.72 76667.22 76666.97 -6.8 76678.72 76679.22 76678.97 0.6 76690.72 76691.22 76690.97 7.4 76702.72 76703.22 76702.97 -0.4 76714.72 76715.22 76714.97 -0.2 76726.78 76727.28 76727.03 17.2 76738.72 76739.22 76738.97 -9.1 76750.72 76751.22 76750.97 6.3 76762.72 76763.22 76762.97 -7.0 76774.78 76775.28 76775.03 28.9 76786.72 76787.22 76786.97 50.9 76798.72 76799.22 76798.97 19.2 76810.72 76811.22 76810.97 28.6 76822.78 76823.28 76823.03 15.2 76834.78 76835.28 76835.03 40.9 76846.72 76847.22 76846.97 47.0 76858.72 76859.22 76858.97 56.9 76870.78 76871.28 76871.03 14.0 76882.72 76883.22 76882.97 42.5 76894.78 76895.28 76895.03 19.0 76906.72 76907.22 76906.97 44.7 76918.72 76919.22 76918.97 64.7 76930.72 76931.22 76930.97 59.9 76942.78 76943.28 76943.03 28.3 76954.72 76955.22 76954.97 23.3 76966.72 76967.22 76966.97 7.2 76978.78 76979.28 76979.03 15.8 76990.72 76991.22 76990.97 12.1 77002.72 77003.22 77002.97 7.4 77014.78 77015.28 77015.03 -1.6 77026.72 77027.22 77026.97 3.7 77038.72 77039.22 77038.97 -0.2 77050.72 77051.22 77050.97 -13.4 77062.72 77063.22 77062.97 -4.5 77074.72 77075.22 77074.97 -4.0 77173.84 77174.34 77174.09 19.8 77185.84 77186.34 77186.09 13.6 77197.84 77198.34 77198.09 -11.9 77209.91 77210.41 77210.16 29.3 77221.91 77222.41 77222.16 7.5 77233.91 77234.41 77234.16 -4.4 77245.91 77246.41 77246.16 18.6 77257.72 77258.22 77257.97 19.3 77269.72 77270.22 77269.97 2.3 77281.78 77282.28 77282.03 49.3 77293.72 77294.22 77293.97 8.0 77305.78 77306.28 77306.03 19.5 77317.84 77318.34 77318.09 5.0 77329.84 77330.34 77330.09 5.9 77341.91 77342.41 77342.16 0.9 77353.84 77354.34 77354.09 4.8 77365.72 77366.22 77365.97 25.5 77377.72 77378.22 77377.97 16.7 77389.72 77390.22 77389.97 2.6 77401.72 77402.22 77401.97 20.0 77413.72 77414.22 77413.97 -4.4 77425.72 77426.22 77425.97 43.4 77437.72 77438.22 77437.97 2.5 77449.72 77450.22 77449.97 19.7 77461.84 77462.34 77462.09 21.3 77473.72 77474.22 77473.97 5.7 77485.72 77486.22 77485.97 15.1 77497.78 77498.28 77498.03 5.9 77509.72 77510.22 77509.97 -12.5 77521.78 77522.28 77522.03 8.7 77533.72 77534.22 77533.97 8.7 77545.72 77546.22 77545.97 -0.6 77557.72 77558.22 77557.97 17.7 77569.72 77570.22 77569.97 15.1 77581.72 77582.22 77581.97 15.6 77593.78 77594.28 77594.03 31.8 77605.72 77606.22 77605.97 10.9 77617.78 77618.28 77618.03 3.5 77629.72 77630.22 77629.97 -1.7 77641.72 77642.22 77641.97 -0.6 77653.72 77654.22 77653.97 7.6 77665.72 77666.22 77665.97 1.3 77677.72 77678.22 77677.97 19.4 77689.72 77690.22 77689.97 27.4 77701.72 77702.22 77701.97 11.2 77713.72 77714.22 77713.97 36.5 77725.72 77726.22 77725.97 12.9 77737.72 77738.22 77737.97 19.8 77749.72 77750.22 77749.97 10.4 77761.78 77762.28 77762.03 11.9 77773.78 77774.28 77774.03 32.0 77785.78 77786.28 77786.03 21.7 77797.78 77798.28 77798.03 33.5 77809.72 77810.22 77809.97 34.7 77821.72 77822.22 77821.97 8.4 78559.72 78560.22 78559.97 13.8 78571.72 78572.22 78571.97 20.6 78583.78 78584.28 78584.03 14.3 78595.72 78596.22 78595.97 21.7 78607.72 78608.22 78607.97 15.6 78619.72 78620.22 78619.97 20.5 78631.72 78632.22 78631.97 21.7 78643.72 78644.22 78643.97 37.8 78655.72 78656.22 78655.97 25.9 78667.72 78668.22 78667.97 31.5 78679.78 78680.28 78680.03 46.0 78691.78 78692.28 78692.03 42.7 78703.72 78704.22 78703.97 25.2 78715.72 78716.22 78715.97 18.3 78727.72 78728.22 78727.97 24.1 78739.78 78740.28 78740.03 22.4 78751.72 78752.22 78751.97 15.7 78763.72 78764.22 78763.97 -2.2 78775.72 78776.22 78775.97 13.2 78787.72 78788.22 78787.97 18.4 78811.78 78812.28 78812.03 8.9 78823.72 78824.22 78823.97 12.4 78835.72 78836.22 78835.97 17.3 78847.72 78848.22 78847.97 1.8 78859.72 78860.22 78859.97 22.6 78871.72 78872.22 78871.97 8.1 78883.72 78884.22 78883.97 7.9 78895.72 78896.22 78895.97 20.7 78907.72 78908.22 78907.97 4.9 78919.72 78920.22 78919.97 8.0 78931.72 78932.22 78931.97 21.3 78943.72 78944.22 78943.97 18.3 78955.72 78956.22 78955.97 26.0 78967.72 78968.22 78967.97 -0.6 78979.72 78980.22 78979.97 11.5 79027.78 79028.28 79028.03 3.3 79039.72 79040.22 79039.97 -2.8 79051.72 79052.22 79051.97 -16.1 79063.72 79064.22 79063.97 -0.4 79075.78 79076.28 79076.03 -9.5 79194.84 79195.34 79195.09 -10.7 79206.84 79207.34 79207.09 7.2 79218.84 79219.34 79219.09 9.2 79230.91 79231.41 79231.16 -5.2 79242.84 79243.34 79243.09 1.6 79254.84 79255.34 79255.09 4.8 79266.91 79267.41 79267.16 -15.6 79278.91 79279.41 79279.16 13.7 79290.91 79291.41 79291.16 -6.7 79302.84 79303.34 79303.09 -4.4 79314.84 79315.34 79315.09 -4.6 79326.84 79327.34 79327.09 -7.4 79338.84 79339.34 79339.09 18.8 79350.84 79351.34 79351.09 5.5 79362.84 79363.34 79363.09 12.0 79374.84 79375.34 79375.09 -12.0 79386.84 79387.34 79387.09 -22.7 79398.84 79399.34 79399.09 9.5 79410.84 79411.34 79411.09 9.7 79422.84 79423.34 79423.09 -1.7 79434.84 79435.34 79435.09 -1.9 79446.91 79447.41 79447.16 6.7 79458.84 79459.34 79459.09 -3.9 79470.91 79471.41 79471.16 15.2 79482.84 79483.34 79483.09 -7.7 79494.84 79495.34 79495.09 -3.3 79506.91 79507.41 79507.16 15.8 79518.84 79519.34 79519.09 -2.7 79530.84 79531.34 79531.09 1.1 79542.84 79543.34 79543.09 -0.2 79554.84 79555.34 79555.09 5.5 79566.84 79567.34 79567.09 4.6 79578.84 79579.34 79579.09 15.3 79590.84 79591.34 79591.09 14.6 79602.84 79603.34 79603.09 6.0 79614.91 79615.41 79615.16 -2.8 79626.91 79627.41 79627.16 -7.6 79638.84 79639.34 79639.09 0.9 79650.84 79651.34 79651.09 7.4 79662.84 79663.34 79663.09 10.1 79674.84 79675.34 79675.09 7.5 79686.91 79687.41 79687.16 9.0 79698.91 79699.41 79699.16 0.7 79710.84 79711.34 79711.09 0.6 79722.84 79723.34 79723.09 7.5 79734.84 79735.34 79735.09 3.5 79746.91 79747.41 79747.16 17.8 79758.84 79759.34 79759.09 6.9 79770.84 79771.34 79771.09 3.5 79782.84 79783.34 79783.09 3.9 79794.84 79795.34 79795.09 10.8 79806.84 79807.34 79807.09 -13.2 79818.84 79819.34 79819.09 13.7 79830.84 79831.34 79831.09 1.1 79842.91 79843.41 79843.16 6.6 79854.84 79855.34 79855.09 -2.4 79866.84 79867.34 79867.09 3.3 79878.91 79879.41 79879.16 -2.4 79890.84 79891.34 79891.09 4.7 79902.84 79903.34 79903.09 2.1 79914.84 79915.34 79915.09 7.9 79926.84 79927.34 79927.09 -1.0 79938.84 79939.34 79939.09 5.0 79950.84 79951.34 79951.09 -5.6 79962.84 79963.34 79963.09 14.5 79974.91 79975.41 79975.16 -6.9 79986.84 79987.34 79987.09 -10.3 79998.84 79999.34 79999.09 3.9 80010.84 80011.34 80011.09 2.5 80022.84 80023.34 80023.09 6.5 80034.84 80035.34 80035.09 2.5 80046.84 80047.34 80047.09 16.1 80058.91 80059.41 80059.16 7.0 80070.84 80071.34 80071.09 -1.6 80082.91 80083.41 80083.16 -1.4 80614.84 80615.34 80615.09 6.4 80626.84 80627.34 80627.09 9.3 80638.91 80639.41 80639.16 11.4 80650.84 80651.34 80651.09 -7.0 80662.91 80663.41 80663.16 -1.0 80674.91 80675.41 80675.16 1.4 80686.84 80687.34 80687.09 15.2 80698.84 80699.34 80699.09 7.1 80710.84 80711.34 80711.09 12.8 80722.84 80723.34 80723.09 27.0 80734.84 80735.34 80735.09 26.3 80746.84 80747.34 80747.09 18.3 80758.84 80759.34 80759.09 2.3 80770.84 80771.34 80771.09 7.4 80782.84 80783.34 80783.09 2.8 80794.91 80795.41 80795.16 11.2 80806.84 80807.34 80807.09 10.5 80818.84 80819.34 80819.09 24.5 80830.84 80831.34 80831.09 14.6 80842.91 80843.41 80843.16 18.0 80854.84 80855.34 80855.09 13.6 80866.84 80867.34 80867.09 16.9 80878.72 80879.22 80878.97 20.0 80890.72 80891.22 80890.97 12.6 80902.84 80903.34 80903.09 6.4 80914.91 80915.41 80915.16 10.2 80926.84 80927.34 80927.09 -4.6 80938.84 80939.34 80939.09 -0.5 80950.84 80951.34 80951.09 12.0 80962.84 80963.34 80963.09 8.3 80974.91 80975.41 80975.16 4.3 80986.78 80987.28 80987.03 8.7 80998.72 80999.22 80998.97 4.8 81010.72 81011.22 81010.97 7.1 81022.78 81023.28 81023.03 21.1 81034.72 81035.22 81034.97 11.0 81046.72 81047.22 81046.97 18.1 81058.84 81059.34 81059.09 16.8 81070.84 81071.34 81071.09 21.4 81082.91 81083.41 81083.16 22.4 81094.72 81095.22 81094.97 10.8 81106.78 81107.28 81107.03 19.4 81118.72 81119.22 81118.97 20.5 81130.72 81131.22 81130.97 20.9 81142.72 81143.22 81142.97 24.5 81154.72 81155.22 81154.97 25.2 81166.78 81167.28 81167.03 36.2 81178.72 81179.22 81178.97 31.6 81190.78 81191.28 81191.03 28.9 81202.78 81203.28 81203.03 31.5 81214.78 81215.28 81215.03 28.0 81226.72 81227.22 81226.97 32.5 81238.72 81239.22 81238.97 12.0 81250.78 81251.28 81251.03 14.0 81262.72 81263.22 81262.97 29.7 81274.78 81275.28 81275.03 21.7 81286.72 81287.22 81286.97 11.4 81298.72 81299.22 81298.97 33.0 81310.72 81311.22 81310.97 18.5 81322.72 81323.22 81322.97 17.6 81334.72 81335.22 81334.97 22.0 81346.72 81347.22 81346.97 20.1 81358.72 81359.22 81358.97 26.8 81370.72 81371.22 81370.97 28.7 81382.78 81383.28 81383.03 20.3 81394.78 81395.28 81395.03 34.6 81406.72 81407.22 81406.97 17.4 81418.72 81419.22 81418.97 25.2 81430.72 81431.22 81430.97 26.8 81442.72 81443.22 81442.97 15.2 81454.72 81455.22 81454.97 24.6 81466.72 81467.22 81466.97 22.5 81478.78 81479.28 81479.03 25.4 81490.78 81491.28 81491.03 21.2 81502.72 81503.22 81502.97 30.1 81514.78 81515.28 81515.03 7.3 81616.84 81617.34 81617.09 38.0 81628.84 81629.34 81629.09 69.3 81640.84 81641.34 81641.09 50.8 81652.84 81653.34 81653.09 53.3 81664.84 81665.34 81665.09 70.8 81676.84 81677.34 81677.09 71.8 81688.84 81689.34 81689.09 57.1 81700.84 81701.34 81701.09 54.9 81712.91 81713.41 81713.16 38.7 81724.84 81725.34 81725.09 41.0 81736.84 81737.34 81737.09 21.3 81748.84 81749.34 81749.09 26.7 81760.84 81761.34 81761.09 23.0 81772.84 81773.34 81773.09 44.2 81784.84 81785.34 81785.09 35.1 81796.84 81797.34 81797.09 24.0 81808.84 81809.34 81809.09 21.1 81820.84 81821.34 81821.09 20.0 81832.84 81833.34 81833.09 23.4 81844.84 81845.34 81845.09 9.7 81856.84 81857.34 81857.09 15.8 81868.72 81869.22 81868.97 21.6 81880.72 81881.22 81880.97 12.0 81892.72 81893.22 81892.97 21.2 81904.84 81905.34 81905.09 16.9 81916.84 81917.34 81917.09 29.5 81928.91 81929.41 81929.16 23.2 81940.91 81941.41 81941.16 22.5 81952.91 81953.41 81953.16 11.0 81964.84 81965.34 81965.09 8.5 81976.72 81977.22 81976.97 15.7 81988.72 81989.22 81988.97 16.0 82000.72 82001.22 82000.97 21.4 82012.72 82013.22 82012.97 21.0 82024.72 82025.22 82024.97 16.0 82036.72 82037.22 82036.97 13.3 82048.72 82049.22 82048.97 14.4 82060.84 82061.34 82061.09 19.0 82072.84 82073.34 82073.09 17.1 82084.72 82085.22 82084.97 22.8 82096.72 82097.22 82096.97 13.6 82108.72 82109.22 82108.97 11.7 82120.72 82121.22 82120.97 11.0 82132.72 82133.22 82132.97 -2.3 82144.78 82145.28 82145.03 22.5 82156.72 82157.22 82156.97 21.1 82168.72 82169.22 82168.97 20.9 82180.72 82181.22 82180.97 6.3 82192.72 82193.22 82192.97 8.8 82204.72 82205.22 82204.97 12.9 82216.72 82217.22 82216.97 6.3 82228.72 82229.22 82228.97 7.4 82240.72 82241.22 82240.97 5.9 82252.72 82253.22 82252.97 10.1 82264.72 82265.22 82264.97 10.9 82276.78 82277.28 82277.03 0.7 82288.78 82289.28 82289.03 1.2 82300.78 82301.28 82301.03 21.7 82312.72 82313.22 82312.97 6.0 82324.72 82325.22 82324.97 10.4 82336.72 82337.22 82336.97 8.8 82348.72 82349.22 82348.97 8.1 82360.72 82361.22 82360.97 8.1 82372.72 82373.22 82372.97 13.2 82384.78 82385.28 82385.03 0.5 82396.78 82397.28 82397.03 4.3 82408.72 82409.22 82408.97 26.3 82420.78 82421.28 82421.03 16.6 82432.72 82433.22 82432.97 13.8 82444.72 82445.22 82444.97 9.9 82456.72 82457.22 82456.97 28.4 82468.72 82469.22 82468.97 12.8 82480.78 82481.28 82481.03 15.9 82492.72 82493.22 82492.97 11.5 82504.72 82505.22 82504.97 10.9 82516.78 82517.28 82517.03 6.6 82619.84 82620.34 82620.09 8.8 82631.84 82632.34 82632.09 17.0 82643.84 82644.34 82644.09 5.0 82655.84 82656.34 82656.09 19.4 82667.84 82668.34 82668.09 19.5 82679.91 82680.41 82680.16 20.7 82691.84 82692.34 82692.09 25.4 82703.84 82704.34 82704.09 23.5 82715.91 82716.41 82716.16 35.0 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