40, 1001 Wennberg, P.O. California Institute of Technology Gas phase Methyl Hydrogen Peroxide (CH3OOH) from DC8 ATom 1 1, 1 2016, 08, 20, 2018, 03, 09 0 UTCstart, seconds of day 3 1, 1, 1 -9999, -9999, -9999 UTCstop, seconds of day UTCmid, seconds of day MHP_CIT, pptv, volume_mixing_ratio_of_methyl_hydrogen_peroxide_in_air 0 23 PI_CONTACT_INFO: Address: California Institute of Technology. MC 131-24. 1200 E. California Blvd, Pasadena, CA, 91125. Email: wennberg@gps.caltech.edu PLATFORM: NASA DC-8 aircraft LOCATION: DC-8 location data available at https://espoarchive.nasa.gov/archive/browse/atom/DC8/MMS-1HZ ASSOCIATED_DATA: See http://espoarchive.nasa.gov/archive/browse/atom INSTRUMENT_INFO: CIT-Triple-CIMS: Chemical Ionization Triple Quadrupole Mass Spectrometer. Direct measurements of methyl hydrogen peroxide (MHP) vapor in air. DATA_INFO: Measurements are reported as 1 second averages every 10-15 seconds and in units of parts per trillion (pptv). CAUTION: Do not extrapolate data outside of given time interval as these are discrete measurements. Mixing ratio are calculated by fraction of standard addition of an isotopic label. Absolute calibration based on FT-IR cross section of 3.20e-19 cm^2 molecule-1 at 2963.8 cm-1 (Niki et al.,1983) UNCERTAINTY: 25 pptv [+-30% of measurement]. Accuracy is humidity dependent. ULOD_FLAG: -7777 ULOD_VALUE: N/A LLOD_FLAG: -8888 LLOD_VALUE: N/A DM_CONTACT_INFO: Michelle J. Kim, California Institute of Technology M/C 131-24. 1200 E. California Blvd. Pasadena, CA 91125. Email: mjk@caltech.edu PROJECT_INFO: ATOM I study; July-Aug 2016 STIPULATIONS_ON_USE: Data is publicly available. Adherence to the ATom data protocol is required. OTHER_COMMENTS: Final Data. REVISION: R2 R2: Revision 2 data computed as fraction of labeled standard addition.. R1: Revision 1 data computed based on laboratory calibrations. UTCstart, UTCstop, UTCmid, MHP_CIT 32601.5, 32602.6, 32602.0, -9999 32627.0, 32628.1, 32627.6, -9999 32638.1, 32639.2, 32638.6, -9999 32651.4, 32652.5, 32651.9, -9999 32665.2, 32666.4, 32665.8, -9999 32676.3, 32677.4, 32676.9, -9999 32689.6, 32690.7, 32690.1, -9999 32703.2, 32704.4, 32703.8, -9999 32714.3, 32715.4, 32714.9, -9999 32727.6, 32728.7, 32728.1, -9999 32777.3, 32778.4, 32777.9, 1521 32788.4, 32789.6, 32789.0, 1402 32801.6, 32802.8, 32802.2, 1938 32815.3, 32816.4, 32815.9, 1685 32826.4, 32827.5, 32827.0, 1529 32839.7, 32840.8, 32840.3, 1887 32853.6, 32854.7, 32854.1, 1501 32864.6, 32865.8, 32865.2, 1503 32877.9, 32879.1, 32878.5, 1856 32891.8, 32892.9, 32892.3, 858 32902.8, 32904.0, 32903.4, 1315 32916.1, 32917.2, 32916.7, 1239 32930.0, 32931.1, 32930.6, 943 32941.0, 32942.2, 32941.6, 782 32954.3, 32955.4, 32954.9, 725 32968.0, 32969.1, 32968.6, 890 32979.1, 32980.2, 32979.7, 731 32992.4, 32993.5, 32992.9, 845 33006.1, 33007.2, 33006.6, 933 33017.2, 33018.3, 33017.7, 645 33030.5, 33031.6, 33031.0, 875 33044.3, 33045.4, 33044.8, 923 33055.4, 33056.5, 33055.9, 921 33068.6, 33069.8, 33069.2, 840 33082.3, 33083.4, 33082.9, 711 33093.4, 33094.5, 33093.9, 946 33106.6, 33107.8, 33107.2, 1245 33120.4, 33121.5, 33120.9, 881 33133.1, 33134.3, 33133.7, 692 33146.4, 33147.6, 33147.0, 1019 33160.2, 33161.3, 33160.8, 927 33171.4, 33172.5, 33171.9, 562 33184.7, 33185.8, 33185.2, 993 33198.4, 33199.6, 33199.0, 692 33209.5, 33210.6, 33210.1, 775 33222.7, 33223.9, 33223.3, 833 33236.5, 33237.6, 33237.0, 923 33247.5, 33248.6, 33248.1, 490 33260.8, 33261.9, 33261.3, 840 33274.5, 33275.6, 33275.1, 802 33285.6, 33286.7, 33286.1, 774 33298.9, 33300.0, 33299.4, 610 33312.7, 33313.9, 33313.3, 744 33323.8, 33325.0, 33324.4, 871 33337.1, 33338.2, 33337.7, 625 33374.5, 33375.6, 33375.0, -9999 33385.6, 33386.7, 33386.2, -9999 33398.9, 33400.1, 33399.5, -9999 33412.7, 33413.8, 33413.2, -9999 33423.8, 33424.9, 33424.3, -9999 33437.1, 33438.2, 33437.6, -9999 33450.9, 33452.0, 33451.4, -9999 33462.0, 33463.1, 33462.5, -9999 33475.4, 33476.5, 33475.9, -9999 33489.1, 33490.2, 33489.7, -9999 33500.2, 33501.4, 33500.8, -9999 33513.5, 33514.7, 33514.1, -9999 33562.6, 33563.8, 33563.2, 337 33573.7, 33574.8, 33574.3, 397 33587.0, 33588.2, 33587.6, 323 33600.8, 33602.0, 33601.4, 227 33611.9, 33613.1, 33612.5, 281 33625.3, 33626.4, 33625.8, 163 33639.0, 33640.2, 33639.6, 170 33650.2, 33651.3, 33650.7, 157 33663.5, 33664.6, 33664.0, 222 33677.3, 33678.4, 33677.8, 124 33688.4, 33689.5, 33688.9, 99 33701.7, 33702.8, 33702.2, 134 33715.5, 33716.6, 33716.1, 120 33726.6, 33727.7, 33727.2, 59 33739.9, 33741.1, 33740.5, 106 33753.7, 33754.8, 33754.2, 130 33764.8, 33766.0, 33765.4, 109 33778.1, 33779.3, 33778.7, 149 33791.9, 33793.0, 33792.5, 123 33803.0, 33804.2, 33803.6, 131 33816.3, 33817.4, 33816.9, 66 33830.1, 33831.3, 33830.7, 105 33841.2, 33842.3, 33841.8, 126 33854.5, 33855.6, 33855.1, 100 33868.3, 33869.5, 33868.9, 115 33879.5, 33880.6, 33880.0, 129 33892.8, 33893.9, 33893.3, 123 33906.5, 33907.7, 33907.1, 120 33917.7, 33918.8, 33918.2, 153 33931.0, 33932.1, 33931.5, 110 33944.8, 33945.9, 33945.3, 150 33955.9, 33957.0, 33956.4, 136 33969.1, 33970.3, 33969.7, 123 33983.0, 33984.1, 33983.5, 88 33994.0, 33995.2, 33994.6, 123 34007.3, 34008.4, 34007.9, 108 34021.0, 34022.1, 34021.6, 110 34032.1, 34033.2, 34032.7, 107 34045.4, 34046.6, 34046.0, 96 34059.2, 34060.4, 34059.8, 102 34070.3, 34071.5, 34070.9, 86 34083.6, 34084.7, 34084.2, 75 34097.4, 34098.6, 34098.0, 33 34108.5, 34109.7, 34109.1, 61 34123.5, 34124.6, 34124.0, 71 34137.3, 34138.5, 34137.9, 82 34148.4, 34149.5, 34149.0, 55 34161.7, 34162.8, 34162.3, 84 34175.6, 34176.7, 34176.1, 113 34186.7, 34187.8, 34187.2, 58 34199.9, 34201.1, 34200.5, 74 34213.8, 34214.9, 34214.3, 113 34225.0, 34226.1, 34225.5, 154 34238.2, 34239.4, 34238.8, 124 34252.0, 34253.1, 34252.5, 142 34263.1, 34264.2, 34263.6, 98 34276.4, 34277.5, 34276.9, 97 34290.2, 34291.4, 34290.8, 100 34301.4, 34302.5, 34302.0, 108 34314.7, 34315.8, 34315.3, 96 34328.4, 34329.6, 34329.0, 123 34339.5, 34340.7, 34340.1, 106 34352.9, 34354.0, 34353.5, 101 34388.7, 34389.8, 34389.3, -9999 34399.8, 34401.0, 34400.4, -9999 34413.2, 34414.3, 34413.8, -9999 34427.1, 34428.2, 34427.7, -9999 34438.3, 34439.4, 34438.8, -9999 34451.5, 34452.7, 34452.1, -9999 34487.4, 34488.5, 34488.0, 85 34498.5, 34499.6, 34499.1, 70 34511.8, 34512.9, 34512.4, 80 34525.6, 34526.7, 34526.1, 120 34536.8, 34537.9, 34537.3, 73 34550.1, 34551.2, 34550.6, 132 34563.8, 34564.9, 34564.4, 97 34575.0, 34576.1, 34575.5, 92 34588.3, 34589.4, 34588.8, 108 34602.0, 34603.1, 34602.6, 114 34613.1, 34614.3, 34613.7, 119 34626.4, 34627.5, 34627.0, 92 34640.3, 34641.4, 34640.8, 68 34651.4, 34652.5, 34652.0, 74 34664.7, 34665.8, 34665.3, 104 34678.5, 34679.6, 34679.0, 80 34689.5, 34690.6, 34690.1, 83 34702.8, 34703.9, 34703.4, 73 34716.6, 34717.8, 34717.2, 67 34727.7, 34728.9, 34728.3, 94 34741.0, 34742.1, 34741.6, 89 34754.7, 34755.8, 34755.3, 99 34765.8, 34766.9, 34766.4, 88 34779.0, 34780.2, 34779.6, 74 34792.9, 34794.0, 34793.5, 41 34805.6, 34806.7, 34806.1, 63 34818.8, 34820.0, 34819.4, 81 34832.6, 34833.7, 34833.1, 59 34843.7, 34844.8, 34844.3, 41 34857.0, 34858.2, 34857.6, 87 34870.8, 34871.9, 34871.4, 57 34881.9, 34883.1, 34882.5, 52 34895.2, 34896.3, 34895.8, 63 34909.0, 34910.2, 34909.6, 68 34920.1, 34921.2, 34920.6, 47 34933.3, 34934.4, 34933.9, 49 34947.1, 34948.2, 34947.6, 40 34958.2, 34959.3, 34958.8, 41 34971.5, 34972.7, 34972.1, 65 34985.3, 34986.4, 34985.8, 60 34996.4, 34997.5, 34996.9, 91 35009.7, 35010.8, 35010.3, 74 35023.5, 35024.6, 35024.1, 45 35034.7, 35035.8, 35035.2, 39 35047.9, 35049.0, 35048.5, 65 35061.7, 35062.8, 35062.3, 30 35072.8, 35073.9, 35073.3, 91 35086.0, 35087.2, 35086.6, 57 35099.7, 35100.9, 35100.3, 139 35110.8, 35112.0, 35111.4, 173 35124.2, 35125.3, 35124.7, 193 35138.0, 35139.1, 35138.5, 174 35149.1, 35150.2, 35149.6, 222 35162.4, 35163.5, 35163.0, 361 35176.2, 35177.3, 35176.7, 299 35187.3, 35188.4, 35187.8, 358 35200.5, 35201.6, 35201.1, 259 35214.2, 35215.3, 35214.8, 268 35225.3, 35226.4, 35225.8, 309 35238.6, 35239.7, 35239.1, 293 35252.4, 35253.5, 35253.0, 295 35263.5, 35264.7, 35264.1, 212 35276.9, 35278.0, 35277.4, 275 35290.7, 35291.8, 35291.2, 323 35301.8, 35302.9, 35302.3, 311 35315.0, 35316.2, 35315.6, 338 35328.8, 35330.0, 35329.4, 384 35339.9, 35341.1, 35340.5, 500 35353.2, 35354.3, 35353.7, 387 35390.4, 35391.6, 35391.0, -9999 35401.6, 35402.7, 35402.1, -9999 35414.9, 35416.0, 35415.4, -9999 35428.6, 35429.8, 35429.2, -9999 35439.8, 35440.9, 35440.4, -9999 35453.1, 35454.2, 35453.6, -9999 35466.8, 35468.0, 35467.4, -9999 35477.9, 35479.1, 35478.5, -9999 35491.3, 35492.4, 35491.8, -9999 35506.5, 35507.7, 35507.1, -9999 35517.6, 35518.8, 35518.2, -9999 35530.9, 35532.0, 35531.5, -9999 35577.3, 35578.4, 35577.8, 807 35588.4, 35589.5, 35588.9, 924 35601.7, 35602.8, 35602.2, 833 35615.5, 35616.6, 35616.1, 1206 35626.6, 35627.7, 35627.1, 1090 35639.8, 35641.0, 35640.4, 1011 35653.7, 35654.8, 35654.3, 919 35664.8, 35666.0, 35665.4, 1052 35678.2, 35679.3, 35678.7, 863 35691.9, 35693.0, 35692.5, 1875 35703.0, 35704.2, 35703.6, 1463 35716.4, 35717.5, 35716.9, 1250 35730.1, 35731.3, 35730.7, 1475 35741.2, 35742.4, 35741.8, 1091 35754.6, 35755.7, 35755.1, 975 35768.3, 35769.5, 35768.9, 678 35779.5, 35780.6, 35780.0, 671 35792.7, 35793.9, 35793.3, 1198 35806.6, 35807.7, 35807.1, 1153 35817.7, 35818.8, 35818.3, 1222 35831.0, 35832.1, 35831.6, 1195 35844.8, 35845.9, 35845.4, 949 35855.9, 35857.1, 35856.5, 1299 35869.3, 35870.4, 35869.8, 1530 35883.0, 35884.1, 35883.6, 1313 35894.1, 35895.2, 35894.7, 1141 35907.4, 35908.5, 35908.0, 1403 35921.2, 35922.4, 35921.8, 1163 35932.3, 35933.5, 35932.9, 619 35945.6, 35946.8, 35946.2, 878 35959.4, 35960.6, 35960.0, 1104 35970.6, 35971.9, 35971.2, 509 35984.2, 35985.3, 35984.7, 645 35998.1, 35999.2, 35998.7, 556 36009.2, 36010.4, 36009.8, 665 36022.5, 36023.7, 36023.1, 1016 36036.4, 36037.5, 36037.0, 869 36047.5, 36048.7, 36048.1, 822 36060.9, 36062.0, 36061.4, 1067 36074.6, 36075.8, 36075.2, 736 36085.7, 36086.9, 36086.3, 755 36099.0, 36100.2, 36099.6, 791 36112.8, 36114.0, 36113.4, 705 36124.0, 36125.1, 36124.6, 595 36137.3, 36138.5, 36137.9, 654 36151.2, 36152.4, 36151.8, 551 36162.4, 36163.5, 36162.9, 781 36175.7, 36176.8, 36176.3, 371 36189.4, 36190.6, 36190.0, 683 36200.6, 36201.7, 36201.2, 744 36213.9, 36215.0, 36214.4, 737 36229.3, 36230.4, 36229.8, 835 36240.4, 36241.5, 36241.0, 954 36253.6, 36254.8, 36254.2, 827 36267.3, 36268.4, 36267.9, 907 36278.4, 36279.5, 36278.9, 815 36291.7, 36292.8, 36292.3, 652 36305.6, 36306.7, 36306.1, 646 36316.7, 36317.8, 36317.2, 1122 36329.9, 36331.1, 36330.5, 1006 36343.7, 36344.9, 36344.3, 935 36354.8, 36356.0, 36355.4, 883 36368.2, 36369.3, 36368.7, 1585 36404.2, 36405.3, 36404.8, -9999 36415.2, 36416.4, 36415.8, -9999 36428.5, 36429.6, 36429.1, -9999 36442.2, 36443.3, 36442.8, -9999 36453.2, 36454.4, 36453.8, -9999 36466.5, 36467.7, 36467.1, -9999 36502.3, 36503.5, 36502.9, 1114 36513.4, 36514.5, 36514.0, 1152 36526.7, 36527.9, 36527.3, 706 36540.5, 36541.6, 36541.1, 973 36551.6, 36552.7, 36552.1, 796 36564.9, 36566.0, 36565.4, 879 36578.7, 36579.9, 36579.3, 909 36589.8, 36590.9, 36590.4, 1328 36603.0, 36604.2, 36603.6, 1112 36616.8, 36617.9, 36617.3, 848 36627.9, 36629.0, 36628.4, 1328 36641.1, 36642.3, 36641.7, 1027 36655.0, 36656.1, 36655.6, 726 36666.1, 36667.2, 36666.7, 729 36679.4, 36680.5, 36679.9, 672 36693.2, 36694.3, 36693.8, 776 36704.4, 36705.5, 36704.9, 643 36717.6, 36718.8, 36718.2, 1001 36731.4, 36732.5, 36732.0, 687 36742.5, 36743.6, 36743.1, 774 36755.8, 36757.0, 36756.4, 652 36769.6, 36770.8, 36770.2, 510 36780.7, 36781.9, 36781.3, 555 36794.0, 36795.1, 36794.6, 613 36807.8, 36809.0, 36808.4, 505 36819.0, 36820.1, 36819.5, 574 36832.3, 36833.4, 36832.8, 449 36846.1, 36847.2, 36846.6, 384 36857.2, 36858.3, 36857.7, 528 36870.4, 36871.6, 36871.0, 586 36884.3, 36885.4, 36884.8, 538 36895.4, 36896.5, 36895.9, 597 36910.2, 36911.3, 36910.7, 495 36923.9, 36925.1, 36924.5, 542 36935.1, 36936.2, 36935.6, 585 36948.4, 36949.5, 36948.9, 565 36962.2, 36963.3, 36962.8, 478 36973.2, 36974.4, 36973.8, 588 36986.6, 36987.7, 36987.1, 436 37000.4, 37001.5, 37000.9, 754 37011.4, 37012.6, 37012.0, 686 37024.8, 37025.9, 37025.3, 668 37038.6, 37039.7, 37039.2, 651 37049.7, 37050.8, 37050.2, 575 37063.0, 37064.1, 37063.6, 306 37076.8, 37077.9, 37077.4, 331 37087.9, 37089.0, 37088.4, 236 37101.1, 37102.3, 37101.7, 378 37114.8, 37116.0, 37115.4, 315 37125.9, 37127.1, 37126.5, 205 37139.2, 37140.4, 37139.8, 267 37153.1, 37154.2, 37153.6, 316 37164.2, 37165.3, 37164.8, 232 37177.5, 37178.7, 37178.1, 237 37191.3, 37192.4, 37191.8, 315 37202.4, 37203.5, 37202.9, 242 37215.6, 37216.7, 37216.2, 266 37229.3, 37230.5, 37229.9, 220 37240.4, 37241.5, 37240.9, 251 37253.6, 37254.7, 37254.2, 293 37267.3, 37268.5, 37267.9, 178 37278.4, 37279.5, 37279.0, 190 37291.7, 37292.8, 37292.3, 228 37305.5, 37306.6, 37306.1, 157 37316.6, 37317.7, 37317.1, 152 37329.8, 37331.0, 37330.4, 225 37343.6, 37344.7, 37344.1, 186 37354.7, 37355.8, 37355.2, 175 37368.0, 37369.1, 37368.6, 155 37405.3, 37406.4, 37405.9, -9999 37416.4, 37417.6, 37417.0, -9999 37429.7, 37430.9, 37430.3, -9999 37443.5, 37444.6, 37444.0, -9999 37454.6, 37455.7, 37455.1, -9999 37467.9, 37469.0, 37468.4, -9999 37481.8, 37482.9, 37482.4, -9999 37492.9, 37494.1, 37493.5, -9999 37506.3, 37507.4, 37506.8, -9999 37520.0, 37521.1, 37520.5, -9999 37531.1, 37532.2, 37531.6, -9999 37544.4, 37545.5, 37545.0, -9999 37593.5, 37594.6, 37594.0, 75 37604.6, 37605.7, 37605.1, 109 37617.8, 37619.0, 37618.4, 83 37633.3, 37634.4, 37633.8, 79 37644.3, 37645.5, 37644.9, 115 37657.6, 37658.8, 37658.2, 71 37671.5, 37672.7, 37672.1, 56 37682.6, 37683.8, 37683.2, 48 37695.9, 37697.0, 37696.4, 52 37709.7, 37710.9, 37710.3, 127 37720.8, 37722.0, 37721.4, 117 37734.1, 37735.3, 37734.7, 79 37748.0, 37749.1, 37748.5, 66 37759.1, 37760.3, 37759.7, 100 37772.5, 37773.6, 37773.0, 130 37786.4, 37787.5, 37786.9, 139 37797.5, 37798.6, 37798.1, 139 37810.7, 37811.9, 37811.3, 147 37824.6, 37825.7, 37825.2, 168 37835.7, 37836.9, 37836.3, 147 37849.0, 37850.2, 37849.6, 151 37862.8, 37863.9, 37863.3, 127 37873.9, 37875.0, 37874.4, 146 37887.2, 37888.3, 37887.7, 271 37901.0, 37902.1, 37901.5, 236 37912.1, 37913.2, 37912.7, 243 37925.4, 37926.6, 37926.0, 264 37939.2, 37940.4, 37939.8, 266 37950.3, 37951.4, 37950.9, 331 37963.6, 37964.7, 37964.1, 315 37977.4, 37978.6, 37978.0, 428 37988.5, 37989.7, 37989.1, 320 38001.8, 38003.0, 38002.4, 303 38015.6, 38016.8, 38016.2, 336 38026.7, 38027.9, 38027.3, 214 38040.0, 38041.1, 38040.5, 262 38053.7, 38054.8, 38054.2, 288 38064.8, 38065.9, 38065.3, 339 38078.1, 38079.2, 38078.6, 322 38091.9, 38093.0, 38092.4, 365 38103.0, 38104.1, 38103.5, 364 38116.2, 38117.4, 38116.8, 448 38130.1, 38131.2, 38130.7, 470 38141.2, 38142.3, 38141.7, 426 38154.5, 38155.6, 38155.0, 401 38168.3, 38169.4, 38168.9, 521 38179.4, 38180.5, 38180.0, 520 38192.7, 38193.9, 38193.3, 492 38206.5, 38207.7, 38207.1, 160 38217.6, 38218.8, 38218.2, 154 38230.9, 38232.0, 38231.5, 198 38244.7, 38245.9, 38245.3, 141 38255.8, 38257.0, 38256.4, 161 38269.1, 38270.3, 38269.7, 410 38282.9, 38284.1, 38283.5, 369 38294.0, 38295.2, 38294.6, 455 38308.9, 38310.1, 38309.5, 603 38322.9, 38324.0, 38323.4, 514 38334.1, 38335.2, 38334.6, 656 38347.3, 38348.5, 38347.9, 809 38361.2, 38362.4, 38361.8, 602 38372.3, 38373.5, 38372.9, 808 38385.7, 38386.8, 38386.2, 776 38421.5, 38422.6, 38422.1, -9999 38432.6, 38433.8, 38433.2, -9999 38446.0, 38447.1, 38446.5, -9999 38459.7, 38460.9, 38460.3, -9999 38470.8, 38471.9, 38471.4, -9999 38484.1, 38485.2, 38484.7, -9999 38497.9, 38499.1, 38498.5, -9999 38509.1, 38510.2, 38509.6, -9999 38522.4, 38523.5, 38522.9, -9999 38536.2, 38537.3, 38536.7, -9999 38547.3, 38548.4, 38547.9, -9999 38560.6, 38561.7, 38561.1, -9999 38605.2, 38606.4, 38605.8, 521 38616.3, 38617.5, 38616.9, 958 38629.6, 38630.8, 38630.2, 1156 38643.4, 38644.6, 38644.0, 1152 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