79 1001 ELKINS, JAMES; WAMSLEY, PAULA; HURST, DALE; ROMASHKIN, PAVEL; DUTTON, GEOFF U.S. DEPT OF COMMERCE, NOAA / CMDL / NITROUS OXIDE AND HALOCOMPOUNDS DIVISION ACATS STRAT 1 1 1995 10 31 1998 07 23 0 ELAPSED TIME IN SECONDS FROM 00:00:00 GMT ON SAMPLE DATE 7 1.0 1.0 1.0 1.0 1.0 1.0 1.0 9999.00 9999.000 9999.000 9999.000 9999.000 9999.000 9999.000 Mean Age of Air (year) Total Br (ppt) Total Organic Br (ppt) Total Inorganic Br (ppt) Total Cl (ppb) Total Organic Cl (ppb) Total Inorganic Cl (ppb) 57 Total chlorine and bromine are based on in situ measurements of organic species from either the Airborne Chromatograph for Atmospheric Trace Species (ACATS-IV) [see Elkins et al., 1996] or the Lightweight Airborne Chromatograph Experiment (LACE). Mean age of the air in years from the tropical tropopause is calculated using tropospheric trends from Geller et al., [1997] and a formula from Volk et al., [1997]. Total chlorine calculations are based on total chlorine from Montzka et al., [1996] and model generated correlations from Woodbridge et al. [1995] are used for the missing chlorine species, HCFC-22 and CH3Cl. Total bromine calculations are from Wamsley et al., [1997] where missing bromine organic species (CH3Br, halon-2402, halon-1301, CH2Cl2, and CH2BrCl) are calculated from correlations of NCAR WAS data versus CFC-11 are used. All values derived from theta < 380 were excluded, because of influence from the troposphere. All calculations of total halogen and inorganic halogen assume no inorganic input from the troposphere (Cly, Bry=0). References: Elkins, J. W., D. W. Fahey, J. M. Gilligan, G. S. Dutton, T. J. Baring, C. M. Volk, R. E. Dunn, R. C. Myers, S. A. Montzka, P. R. Wamsley, A. H. Hayden, J. H. Butler, T. M. Thompson, T. H. Swanson, E. J. Dlugokencky, P. C. Novelli, D. F. Hurst, J. M. Lobert, S. J. Ciciora, R. J. McLaughlin, T. L. Thompson, R. H. Winkler, P. J. Fraser, L. P. Steele and M. P. Lucarelli, Airborne gas chromatograph for in situ measurements of long-lived species in the upper troposphere and lower stratosphere, Geophysical Research Letters, 23, 347-350, 1996 Geller, L. S., J. W. Elkins, J. M. Lobert, A. D. Clarke, D. F. Hurst, J. H. Butler and R. C. Myers, Tropospheric SF6: Observed latitudinal distribution and trends, derived emissions and interhemispheric exchange time, Geophysical Research Letters, 24, 1997. Montzka, S.A., J.H. Butler, R.C. Myers, T.M. Thompson, T.H. Swanson, A.D. Clarke, L.T. Lock, J.W. Elkins, Decline in the tropospheric abundance of halogen from halocarbons: Implications for stratospheric ozone depletion., Science, 272, 1318-1322, 1996. Volk, C. M., J. W. Elkins, D. W. Fahey, G. S. Dutton, J. M. Gilligan, M. Loewenstein, J. R. Podolske, K. R. Chan, and M. R. Gunson, Evaluation of source gas lifetimes from stratospheric observations, Journal of Geophysical Research, 102, 25543-64,1997. Wamsley, P. R., J. W. Elkins, D. W. Fahey, G. S. Dutton, C. M. Volk, R. C. Myers, S. A. Montzka, J. H. Butler, A. D. Clarke, P. J. Fraser, L. P. Steele, M. P. Lucarelli, E. L. Atlas, S. M. Schauffler, D. R. Blake, F. S. Rowland, W. T. Sturges, J. M. Lee, S. A. Penkett, A. Engel, R. M. Stimpfle, K. R. Chan, D. K. Weisenstein, M. K. W. Ko and R. J. Salawitch, Distribution of halon-1211 in the upper troposphere and lower stratosphere and the 1994 total bromine budget, Journal of Geophysical Research, 103, 1513-26, 1998. Woodbridge, E. L., J. W. Elkins, D. W. Fahey, L. E. Heidt, S. Solomon, T. J. Baring T. M. Gilpin, W. H. Pollock, S. M. Schauffler, E. L. Atlas, M. Loewenstein, J. R. Podolske, C. R. Webster, R. D. May, J. M. Gilligan, S. A. Montzka, K. A. Boering and R. J. Salawitch, Estimates of total organic and inorganic chlorine in the lower stratosphere from in situ and flask measurements, Journal of Geophysical Research, 100, 3057-3064, 1995. To calculate HCFC-22 ALIAS CH4 was used. ACATS did not measure SF6 on this flight. Mean age of air cannot be calculated. ACATS did not measure CCl4. A derived CCl4 from CFC-11 correlation is used in place. ACATS did not measure CH3CCl3. A derived CH3CCl3 from CFC-11 correlation is used in place. 1 GMTs Age TotalBr CBry Bry TotalCl CCly Cly 66904 9999.00 9999.000 9999.000 9999.000 9999.000 9999.000 9999.000 66964 9999.00 9999.000 9999.000 9999.000 9999.000 9999.000 9999.000 67024 9999.00 9999.000 9999.000 9999.000 9999.000 9999.000 9999.000 67084 9999.00 9999.000 9999.000 9999.000 9999.000 9999.000 9999.000 67144 9999.00 9999.000 9999.000 9999.000 9999.000 9999.000 9999.000 67204 9999.00 9999.000 9999.000 9999.000 9999.000 9999.000 9999.000 67264 9999.00 9999.000 9999.000 9999.000 9999.000 9999.000 9999.000 67324 9999.00 9999.000 9999.000 9999.000 9999.000 9999.000 9999.000 67384 9999.00 9999.000 9999.000 9999.000 9999.000 9999.000 9999.000 67444 9999.00 9999.000 9999.000 9999.000 9999.000 9999.000 9999.000 67504 9999.00 9999.000 9999.000 9999.000 9999.000 9999.000 9999.000 67564 9999.00 9999.000 9999.000 9999.000 9999.000 9999.000 9999.000 67804 9999.00 9999.000 9999.000 9999.000 9999.000 9999.000 9999.000 67864 9999.00 9999.000 9999.000 9999.000 9999.000 9999.000 9999.000 67924 9999.00 9999.000 9999.000 9999.000 9999.000 9999.000 9999.000 67984 9999.00 9999.000 9999.000 9999.000 9999.000 9999.000 9999.000 68044 9999.00 9999.000 9999.000 9999.000 9999.000 9999.000 9999.000 68104 9999.00 9999.000 9999.000 9999.000 9999.000 9999.000 9999.000 68164 9999.00 9999.000 9999.000 9999.000 9999.000 9999.000 9999.000 68224 9999.00 9999.000 9999.000 9999.000 9999.000 9999.000 9999.000 68284 9999.00 9999.000 9999.000 9999.000 9999.000 9999.000 9999.000 68344 9999.00 9999.000 9999.000 9999.000 9999.000 9999.000 9999.000 68404 9999.00 9999.000 9999.000 9999.000 9999.000 9999.000 9999.000 68464 9999.00 9999.000 9999.000 9999.000 9999.000 9999.000 9999.000 68524 9999.00 9999.000 9999.000 9999.000 9999.000 9999.000 9999.000 68704 9999.00 9999.000 9999.000 9999.000 9999.000 9999.000 9999.000 68764 9999.00 9999.000 9999.000 9999.000 9999.000 9999.000 9999.000 68824 9999.00 9999.000 9999.000 9999.000 9999.000 9999.000 9999.000 68884 9999.00 9999.000 9999.000 9999.000 9999.000 9999.000 9999.000 68944 9999.00 9999.000 9999.000 9999.000 9999.000 9999.000 9999.000 69004 9999.00 9999.000 9999.000 9999.000 9999.000 9999.000 9999.000 69064 9999.00 9999.000 9999.000 9999.000 9999.000 9999.000 9999.000 69124 9999.00 9999.000 9999.000 9999.000 9999.000 9999.000 9999.000 69184 9999.00 9999.000 9999.000 9999.000 9999.000 9999.000 9999.000 69244 9999.00 9999.000 9999.000 9999.000 9999.000 9999.000 9999.000 69304 9999.00 9999.000 9999.000 9999.000 9999.000 9999.000 9999.000 69364 9999.00 9999.000 9999.000 9999.000 9999.000 9999.000 9999.000 69424 9999.00 9999.000 9999.000 9999.000 9999.000 9999.000 9999.000 69604 9999.00 9999.000 9999.000 9999.000 9999.000 9999.000 9999.000 69664 9999.00 9999.000 9999.000 9999.000 9999.000 9999.000 9999.000 69724 9999.00 9999.000 9999.000 9999.000 9999.000 9999.000 9999.000 69784 9999.00 9999.000 9999.000 9999.000 9999.000 9999.000 9999.000 69844 9999.00 9999.000 9999.000 9999.000 9999.000 9999.000 9999.000 69904 9999.00 9999.000 9999.000 9999.000 9999.000 9999.000 9999.000 69964 9999.00 9999.000 9999.000 9999.000 9999.000 9999.000 9999.000 70024 9999.00 9999.000 9999.000 9999.000 9999.000 9999.000 9999.000 70084 9999.00 9999.000 9999.000 9999.000 9999.000 9999.000 9999.000 70144 9999.00 9999.000 9999.000 9999.000 9999.000 9999.000 9999.000 70204 9999.00 9999.000 9999.000 9999.000 9999.000 9999.000 9999.000 70264 9999.00 9999.000 9999.000 9999.000 9999.000 9999.000 9999.000 70324 9999.00 9999.000 9999.000 9999.000 9999.000 9999.000 9999.000 70504 9999.00 9999.000 9999.000 9999.000 9999.000 9999.000 9999.000 70564 9999.00 9999.000 9999.000 9999.000 9999.000 9999.000 9999.000 70624 9999.00 9999.000 9999.000 9999.000 9999.000 9999.000 9999.000 70684 9999.00 9999.000 9999.000 9999.000 9999.000 9999.000 9999.000 70744 9999.00 9999.000 9999.000 9999.000 9999.000 9999.000 9999.000 70804 9999.00 9999.000 9999.000 9999.000 9999.000 9999.000 9999.000 70864 9999.00 9999.000 9999.000 9999.000 9999.000 9999.000 9999.000 70924 9999.00 9999.000 9999.000 9999.000 9999.000 9999.000 9999.000 70984 9999.00 9999.000 9999.000 9999.000 9999.000 9999.000 9999.000 71044 9999.00 9999.000 9999.000 9999.000 9999.000 9999.000 9999.000 71404 9999.00 9999.000 9999.000 9999.000 9999.000 9999.000 9999.000 71464 9999.00 9999.000 9999.000 9999.000 9999.000 9999.000 9999.000 71524 9999.00 9999.000 9999.000 9999.000 9999.000 9999.000 9999.000 71584 9999.00 9999.000 9999.000 9999.000 9999.000 9999.000 9999.000 71644 9999.00 9999.000 9999.000 9999.000 9999.000 9999.000 9999.000 71704 9999.00 9999.000 9999.000 9999.000 9999.000 9999.000 9999.000 71764 9999.00 9999.000 9999.000 9999.000 9999.000 9999.000 9999.000 71824 9999.00 9999.000 9999.000 9999.000 9999.000 9999.000 9999.000 71884 9999.00 9999.000 9999.000 9999.000 9999.000 9999.000 9999.000 71944 9999.00 9999.000 9999.000 9999.000 9999.000 9999.000 9999.000 72004 9999.00 9999.000 9999.000 9999.000 9999.000 9999.000 9999.000 72064 9999.00 9999.000 9999.000 9999.000 9999.000 9999.000 9999.000 72124 9999.00 9999.000 9999.000 9999.000 9999.000 9999.000 9999.000 72304 9999.00 9999.000 9999.000 9999.000 9999.000 9999.000 9999.000 72364 9999.00 9999.000 9999.000 9999.000 9999.000 9999.000 9999.000 72424 9999.00 9999.000 9999.000 9999.000 9999.000 9999.000 9999.000 72484 9999.00 9999.000 9999.000 9999.000 9999.000 9999.000 9999.000 72544 9999.00 9999.000 9999.000 9999.000 9999.000 9999.000 9999.000 72604 9999.00 9999.000 9999.000 9999.000 9999.000 9999.000 9999.000 72664 9999.00 9999.000 9999.000 9999.000 9999.000 9999.000 9999.000 72724 9999.00 9999.000 9999.000 9999.000 9999.000 9999.000 9999.000 72784 9999.00 9999.000 9999.000 9999.000 9999.000 9999.000 9999.000 72844 9999.00 9999.000 9999.000 9999.000 9999.000 9999.000 9999.000 72904 9999.00 9999.000 9999.000 9999.000 9999.000 9999.000 9999.000 72964 9999.00 9999.000 9999.000 9999.000 9999.000 9999.000 9999.000 73204 9999.00 9999.000 9999.000 9999.000 9999.000 9999.000 9999.000 73264 9999.00 9999.000 9999.000 9999.000 9999.000 9999.000 9999.000 73324 9999.00 9999.000 9999.000 9999.000 9999.000 9999.000 9999.000 73384 9999.00 9999.000 9999.000 9999.000 9999.000 9999.000 9999.000 73444 9999.00 9999.000 9999.000 9999.000 9999.000 9999.000 9999.000 73504 9999.00 9999.000 9999.000 9999.000 9999.000 9999.000 9999.000 73564 9999.00 9999.000 9999.000 9999.000 9999.000 9999.000 9999.000 73624 9999.00 9999.000 9999.000 9999.000 9999.000 9999.000 9999.000 73684 9999.00 9999.000 9999.000 9999.000 9999.000 9999.000 9999.000 73744 9999.00 9999.000 9999.000 9999.000 9999.000 9999.000 9999.000 73804 9999.00 9999.000 9999.000 9999.000 9999.000 9999.000 9999.000 73864 9999.00 9999.000 9999.000 9999.000 9999.000 9999.000 9999.000 73924 9999.00 9999.000 9999.000 9999.000 9999.000 9999.000 9999.000 74104 9999.00 9999.000 9999.000 9999.000 9999.000 9999.000 9999.000 74164 9999.00 9999.000 9999.000 9999.000 9999.000 9999.000 9999.000 74224 9999.00 9999.000 9999.000 9999.000 9999.000 9999.000 9999.000 74284 9999.00 9999.000 9999.000 9999.000 9999.000 9999.000 9999.000 74464 9999.00 9999.000 9999.000 9999.000 9999.000 9999.000 9999.000 74524 9999.00 9999.000 9999.000 9999.000 9999.000 9999.000 9999.000 74584 9999.00 9999.000 9999.000 9999.000 9999.000 9999.000 9999.000 74644 9999.00 9999.000 9999.000 9999.000 9999.000 9999.000 9999.000 74704 9999.00 9999.000 9999.000 9999.000 9999.000 9999.000 9999.000 74764 9999.00 9999.000 9999.000 9999.000 9999.000 9999.000 9999.000 74824 9999.00 9999.000 9999.000 9999.000 9999.000 9999.000 9999.000 75004 9999.00 9999.000 9999.000 9999.000 9999.000 9999.000 9999.000 75064 9999.00 9999.000 9999.000 9999.000 9999.000 9999.000 9999.000 75124 9999.00 9999.000 9999.000 9999.000 9999.000 9999.000 9999.000 75184 9999.00 9999.000 9999.000 9999.000 9999.000 9999.000 9999.000 75244 9999.00 9999.000 9999.000 9999.000 9999.000 9999.000 9999.000 75304 9999.00 9999.000 9999.000 9999.000 9999.000 9999.000 9999.000 75364 9999.00 9999.000 9999.000 9999.000 9999.000 9999.000 9999.000 75424 9999.00 9999.000 9999.000 9999.000 9999.000 9999.000 9999.000 75484 9999.00 9999.000 9999.000 9999.000 9999.000 9999.000 9999.000 75544 9999.00 9999.000 9999.000 9999.000 9999.000 9999.000 9999.000 75604 9999.00 9999.000 9999.000 9999.000 9999.000 9999.000 9999.000 75664 9999.00 9999.000 9999.000 9999.000 9999.000 9999.000 9999.000 75724 9999.00 9999.000 9999.000 9999.000 9999.000 9999.000 9999.000 75904 9999.00 9999.000 9999.000 9999.000 9999.000 9999.000 9999.000 75964 9999.00 9999.000 9999.000 9999.000 9999.000 9999.000 9999.000 76024 9999.00 9999.000 9999.000 9999.000 9999.000 9999.000 9999.000 76084 9999.00 9999.000 15.935 9999.000 9999.000 9999.000 9999.000 76144 9999.00 9999.000 9999.000 9999.000 9999.000 9999.000 9999.000 76204 9999.00 9999.000 9999.000 9999.000 9999.000 9999.000 9999.000 76264 9999.00 9999.000 16.014 9999.000 9999.000 9999.000 9999.000 76324 9999.00 9999.000 9999.000 9999.000 9999.000 9999.000 9999.000 76384 9999.00 9999.000 9999.000 9999.000 9999.000 9999.000 9999.000 76444 9999.00 9999.000 16.596 9999.000 9999.000 9999.000 9999.000 76504 9999.00 9999.000 9999.000 9999.000 9999.000 9999.000 9999.000 76564 9999.00 9999.000 9999.000 9999.000 9999.000 9999.000 9999.000 76624 9999.00 9999.000 9999.000 9999.000 9999.000 9999.000 9999.000 76804 9999.00 9999.000 9999.000 9999.000 9999.000 9999.000 9999.000 76864 9999.00 9999.000 9999.000 9999.000 9999.000 9999.000 9999.000 76924 9999.00 9999.000 9999.000 9999.000 9999.000 9999.000 9999.000 76984 9999.00 9999.000 16.552 9999.000 9999.000 9999.000 9999.000 77044 9999.00 9999.000 9999.000 9999.000 9999.000 9999.000 9999.000 77104 9999.00 9999.000 9999.000 9999.000 9999.000 9999.000 9999.000 77164 9999.00 9999.000 16.296 9999.000 9999.000 9999.000 9999.000 77224 9999.00 9999.000 9999.000 9999.000 9999.000 9999.000 9999.000 77284 9999.00 9999.000 9999.000 9999.000 9999.000 9999.000 9999.000 77344 9999.00 9999.000 9999.000 9999.000 9999.000 9999.000 9999.000 77704 9999.00 9999.000 9999.000 9999.000 9999.000 9999.000 9999.000 77764 9999.00 9999.000 9999.000 9999.000 9999.000 9999.000 9999.000 77824 9999.00 9999.000 9999.000 9999.000 9999.000 9999.000 9999.000 77884 9999.00 9999.000 13.788 9999.000 9999.000 9999.000 9999.000 77944 9999.00 9999.000 9999.000 9999.000 9999.000 9999.000 9999.000 78004 9999.00 9999.000 9999.000 9999.000 9999.000 9999.000 9999.000 78064 9999.00 9999.000 11.527 9999.000 9999.000 9999.000 9999.000 78124 9999.00 9999.000 9999.000 9999.000 9999.000 9999.000 9999.000 78184 9999.00 9999.000 9999.000 9999.000 9999.000 9999.000 9999.000 78244 9999.00 9999.000 11.324 9999.000 9999.000 9999.000 9999.000 78304 9999.00 9999.000 9999.000 9999.000 9999.000 9999.000 9999.000 78364 9999.00 9999.000 9999.000 9999.000 9999.000 9999.000 9999.000 78424 9999.00 9999.000 9999.000 9999.000 9999.000 9999.000 9999.000 78604 9999.00 9999.000 9999.000 9999.000 9999.000 9999.000 9999.000 78664 9999.00 9999.000 9999.000 9999.000 9999.000 9999.000 9999.000 78724 9999.00 9999.000 9999.000 9999.000 9999.000 9999.000 9999.000 78784 9999.00 9999.000 11.738 9999.000 9999.000 9999.000 9999.000 78844 9999.00 9999.000 9999.000 9999.000 9999.000 9999.000 9999.000 78904 9999.00 9999.000 9999.000 9999.000 9999.000 9999.000 9999.000 78964 9999.00 9999.000 11.081 9999.000 9999.000 9999.000 9999.000 79024 9999.00 9999.000 9999.000 9999.000 9999.000 9999.000 9999.000 79084 9999.00 9999.000 9999.000 9999.000 9999.000 9999.000 9999.000 79144 9999.00 9999.000 12.765 9999.000 9999.000 9999.000 9999.000 79204 9999.00 9999.000 9999.000 9999.000 9999.000 9999.000 9999.000 79264 9999.00 9999.000 9999.000 9999.000 9999.000 9999.000 9999.000 79324 9999.00 9999.000 9999.000 9999.000 9999.000 9999.000 9999.000 79504 9999.00 9999.000 9999.000 9999.000 9999.000 9999.000 9999.000 79564 9999.00 9999.000 9999.000 9999.000 9999.000 9999.000 9999.000 79624 9999.00 9999.000 9999.000 9999.000 9999.000 9999.000 9999.000 79684 9999.00 9999.000 12.557 9999.000 9999.000 9999.000 9999.000 79744 9999.00 9999.000 9999.000 9999.000 9999.000 9999.000 9999.000 79804 9999.00 9999.000 9999.000 9999.000 9999.000 9999.000 9999.000 79864 9999.00 9999.000 12.059 9999.000 9999.000 9999.000 9999.000 79924 9999.00 9999.000 9999.000 9999.000 9999.000 9999.000 9999.000 79984 9999.00 9999.000 9999.000 9999.000 9999.000 9999.000 9999.000 80044 9999.00 9999.000 9.441 9999.000 9999.000 9999.000 9999.000 80104 9999.00 9999.000 9999.000 9999.000 9999.000 9999.000 9999.000 80164 9999.00 9999.000 9999.000 9999.000 9999.000 9999.000 9999.000 80224 9999.00 9999.000 9999.000 9999.000 9999.000 9999.000 9999.000 80404 9999.00 9999.000 9999.000 9999.000 9999.000 9999.000 9999.000 80464 9999.00 9999.000 9999.000 9999.000 9999.000 9999.000 9999.000 80524 9999.00 9999.000 9999.000 9999.000 9999.000 9999.000 9999.000 80584 9999.00 9999.000 8.397 9999.000 9999.000 9999.000 9999.000 80644 9999.00 9999.000 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