94,1001 "ATLAS, ELLIOT; NAVARRO, MARIA " University of Miami MIXING RATIOS FROM WHOLE AIR SAMPLER ATTREX-3 1,1 2014,2,12,2014,9,9 0 UT_MID,secs 49 1,1,1,1,1,1,1,1,1,1,1,1,1,1,1,1,1,1,1,1,1,1,1,1,1,1,1,1,1,1,1,1,1,1,1,1,1,1,1,1,1,1,1,1,1,1,1,1,1 -9999,-9999,-9999,-9999,-9999,-9999,-9999,-9999,-9999,-9999,-9999,-9999,-9999,-9999,-9999,-9999,-9999,-9999,-9999,-9999,-9999,-9999,-9999,-9999,-9999,-9999,-9999,-9999,-9999,-9999,-9999,-9999,-9999,-9999,-9999,-9999,-9999,-9999,-9999,-9999,-9999,-9999,-9999,-9999,-9999,-9999,-9999,-9999,-9999 UT_START,secs UT_STOP,secs C2H6_Ethane,pmol/mol C2H2_Ethyne,pmol/mol C3H8_Propane,pmol/mol C4H10_Isobutane,pmol/mol C4H10_nButane,pmol/mol C5H12_Isopentane,pmol/mol C5H12_nPentane,pmol/mol C5H8_Isoprene,pmol/mol C6H6_Benzene,pmol/mol OCS_Carbonyl_sulfide,pmol/mol C2H6S_Dimethyl_sulfide,pmol/mol CCl2F2_CFC_12,pmol/mol CCl3F_CFC_11,pmol/mol CCl2FCCl2F_CFC112,pmol/mol CCl3CClF2_CFC_112a,pmol/mol C2Cl3F3_CFC_113,pmol/mol C2Cl2F4_CFC_114,pmol/mol CHClF2_HCFC_22,pmol/mol CH3CClF2_HCFC_142b,pmol/mol CH3CCl2F_HCFC_141b,pmol/mol CH2FCF3_HFC_134a,pmol/mol C4H5F5_HFC365mfc,pmol/mol CH3Cl_Methyl_chloride,pmol/mol CH3Br_Methyl_bromide,pmol/mol CH3I_Methyl_iodide,pmol/mol CH2Cl2_Methylene_chloride,pmol/mol CHCl3_Chloroform,pmol/mol CH3CCl3_Methyl_chloroform,pmol/mol CCl4_Carbon_tetrachloride,pmol/mol C2H4Cl2_1_2_Dichloroethane,pmol/mol C2HCl3_Trichloroethylene,pmol/mol C2Cl4_Tetrachloroethylene,pmol/mol C6H5Cl_Chlorobenzene,pmol/mol CBrClF2_Halon_1211,pmol/mol C2Br2F4_Halon_2402,pmol/mol CH2BrCl_Bromochloromethane,pmol/mol CH2Br2_Methylene_bromide,pmol/mol CHBrCl2_Bromodichloromethane,pmol/mol CHBr2Cl_Dibromochloromethane,pmol/mol CHBr3_Bromoform,pmol/mol CH3ONO2_Methyl_nitrate,pmol/mol C2H5ONO2_Ethyl_nitrate,pmol/mol C3H7NO3_Isopropyl_nitrate,pmol/mol C4H9NO3_2_Butyl_nitrate,pmol/mol C4H9NO3_n_Butyl_nitrate,pmol/mol C5H11NO3_3_pentyl_nitrate,pmol/mol C5H11NO3_2_pentyl_nitrate,pmol/mol 0 31 PI_CONTACT_INFO: Elliot Atlas; eatlas@rsmas.miami.edu; 305-421-4128 PLATFORM: NASA Global Hawk LOCATION: N/A ASSOCIATED_DATA: N/A INSTRUMENT_INFO: Global Hawk Advanced Whole Air Sampler; 90 samples/flight DATA_INFO: Units are pmol/mol UNCERTAINTY: Precision/accuracy is compound/concentration dependent, range from <2% to 20% ULOD_FLAG: -7777 ULOD_VALUE: N/A LLOD_FLAG: -8888 LLOD_VALUE: N/A DM_CONTACT_INFO: eatlas@rsmas.miami.edu PROJECT_INFO: ATTREX-3 STIPULATIONS_ON_USE: None OTHER_COMMENTS: UT_START IS THE TIME THE CANISTER BEGAN FILLING ; UT_MID IS THE AVERAGE OF THE START AND STOP TIMES; UT_STOP IS THE TIME THE CANISTER FINISHED FILLING; Mixing ratios are pmol/mol for all gases "To improve precision, measurements of CFC114 were used to adjust apparent outliers. This typically adjusted values by 5% or less. " Negative mixing ratios for some gases may be reported in cases when a small blank value is subtracted from all the sample values.; Calibration scales are under review for the new working standard that was used during ATTREX. Small changes might be expected in future revisions. Additional compounds may be added to future revisions after more detailed review of the raw data. "Currently, the DMS (C2H6S_Dimethyl_sulfide) calibration is based on an old standard that still requires verification; HFC365mfc calibration is based on comparison to NOAA (S.Montzka, B. Hall)." "Occasional contamination and/or analytical artifacts were identified in some cases, and these values have been removed in this version; " "However, small artifacts may still remain for some compounds and the user should contact the prinicipal investigator to clarify missing or questionable data.; " "Further, single point ""fliers"" may still be found in the data and may not be included in future versions. Use caution (and please contact the PI)." "A merged data set will be produced, and interested parties should contact the PI." REVISION: R0 R0: No revisions UT_MID,UT_START,UT_STOP,C2H6_Ethane,C2H2_Ethyne,C3H8_Propane,C4H10_Isobutane,C4H10_nButane,C5H12_Isopentane,C5H12_nPentane,C5H8_Isoprene,C6H6_Benzene,OCS_Carbonyl_sulfide,C2H6S_Dimethyl_sulfide,CCl2F2_CFC_12,CCl3F_CFC_11,CCl2FCCl2F_CFC112,CCl3CClF2_CFC_112a,C2Cl3F3_CFC_113,C2Cl2F4_CFC_114,CHClF2_HCFC_22,CH3CClF2_HCFC_142b,CH3CCl2F_HCFC_141b,CH2FCF3_HFC_134a,C4H5F5_HFC365mfc,CH3Cl_Methyl_chloride,CH3Br_Methyl_bromide,CH3I_Methyl_iodide,CH2Cl2_Methylene_chloride,CHCl3_Chloroform,CH3CCl3_Methyl_chloroform,CCl4_Carbon_tetrachloride,C2H4Cl2_1_2_Dichloroethane,C2HCl3_Trichloroethylene,C2Cl4_Tetrachloroethylene,C6H5Cl_Chlorobenzene,CBrClF2_Halon_1211,C2Br2F4_Halon_2402,CH2BrCl_Bromochloromethane,CH2Br2_Methylene_bromide,CHBrCl2_Bromodichloromethane,CHBr2Cl_Dibromochloromethane,CHBr3_Bromoform,CH3ONO2_Methyl_nitrate,C2H5ONO2_Ethyl_nitrate,C3H7NO3_Isopropyl_nitrate,C4H9NO3_2_Butyl_nitrate,C4H9NO3_n_Butyl_nitrate,C5H11NO3_3_pentyl_nitrate,C5H11NO3_2_pentyl_nitrate 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