47, 1001 Brune, William; Thames, Alexander; Miller, David; Brosius, Alexandra Penn State University ATHOS - Airborne Tropospheric Hydrogen Oxides Sensor ATom 1, 1 2018, 05, 18, 2019, 05, 24 0 Start_UTC, seconds, seconds since UTC midnight on day of takeoff 4 1, 1, 1, 1 -9999.000, -9999.000, -9999.000, -9999.000 Stop_UTC, seconds, seconds since UTC midnight on day of takeoff Mid_UTC, seconds, seconds since UTC midnight on day of takeoff OH_ATHOS, pptv, OH mixing ratio in pptv HO2_ATHOS, pptv, HO2 mixing ratio in pptv 0 29 PI_CONTACT_INFO: Address: 503 Walker Building, University Park, PA 16802; email: whb2@psu.edu 814-865-3286 PLATFORM: NASA - DC-8 Aircraft - sampling underneath aircraft forward cargo bay LOCATION: ATom IV: BONUS Flight #1 -- SFJ - BGR ASSOCIATED_DATA: N/A INSTRUMENT_INFO: OH/HO2 from Laser Induced Fluorescence. DATA_INFO: Units are pptv for OH and HO2. UNCERTAINTY: HOx absolute accuracy ~+/- 35% (actually a multiplicative factor of 1/1.35 to 1.35), 2 sigma confidence. ULOD_FLAG: -7777 ULOD_VALUE: N/A LLOD_FLAG: -8888 LLOD_VALUE: N/A DM_CONTACT_INFO: William H. Brune, Penn State, whb2@psu.edu; 814-865-3286 PROJECT_INFO: NSF/NASA ATom Mission. 2016 - 2018; Multiple Locations STIPULATIONS_ON_USE: No restrictions. Contact PI or DM with any questions. OTHER_COMMENTS: Final Data. Future modifications to the calibration are possible but unlikely. - Calibrating ATHOS with the new OH-removing inlet (OHSI) has been difficult, particularly for low pressure (high altitude). - The ATHOS HOx calibrations are pressure-dependent, changing a factor of 3-5 over the atmospheric pressure range. - The laboratory calibration uses different inlet hole sizes to simulate atmospheric pressure changes. - For 2 years, we tried various calibration approaches with the OHSI in place, but none gave repeatable results for high altitude measurements. - In the laboratory calibrations, it proved to be impossible to simulate the atmospheric airflow with the OHSI on and the smaller inlet sizes. - In the end, we found that our previous calibration method gave the most repeatable and reliable results. - In-flight diagnostics show that OH loss on the OHSI is negligible. - For details, please see Faloona et al., J. Atmos. Chem., 47, 139-167, 2004. REVISION: R3 R3: Final Data (see OTHER_COMMENTS) R2: Final Data (see OTHER_COMMENTS) R1: Final Data (see OTHER_COMMENTS) R0: No comments for this revision. Start_UTC, Stop_UTC, Mid_UTC, OH_ATHOS, HO2_ATHOS 44564, 44593, 44579, -9999.000, -9999.000 44594, 44623, 44609, -9999.000, 2.990 44624, 44653, 44639, -9999.000, 3.513 44654, 44683, 44669, -9999.000, 9.266 44685, 44714, 44700, 0.037, 8.950 44715, 44744, 44730, 0.027, 8.633 44745, 44774, 44760, 0.027, 2.982 44775, 44804, 44790, 0.027, 9.977 44805, 44834, 44820, 0.062, 8.481 44835, 44864, 44850, 0.062, 6.985 44865, 44894, 44880, 0.055, 7.118 44895, 44924, 44910, 0.092, 7.844 44925, 44954, 44940, 0.092, 7.639 44955, 44984, 44970, 0.073, 7.433 44985, 45014, 45000, 0.073, 8.630 45015, 45044, 45030, 0.073, 10.200 45045, 45074, 45060, 0.025, 9.114 45075, 45104, 45090, 0.025, 8.035 45105, 45134, 45120, 0.072, 9.575 45135, 45164, 45150, 0.072, 10.638 45165, 45194, 45180, 0.080, 9.122 45195, 45224, 45210, 0.150, 7.595 45225, 45254, 45240, 0.150, 7.938 45255, 45284, 45270, 0.095, 8.033 45285, 45314, 45300, 0.095, 8.248 45315, 45344, 45330, 0.095, 8.465 45345, 45374, 45360, 0.094, 7.590 45375, 45404, 45390, 0.052, 7.000 45405, 45434, 45420, 0.052, 6.945 45435, 45464, 45450, 0.052, 6.890 45465, 45494, 45480, 0.084, 6.335 45495, 45524, 45510, 0.139, 4.163 45525, 45554, 45540, 0.139, 3.066 45555, 45584, 45570, 0.139, 1.970 45586, 45615, 45601, 0.073, 2.166 45616, 45645, 45631, 0.063, 2.157 45646, 45675, 45661, 0.063, 1.950 45676, 45705, 45691, 0.063, 1.743 45706, 45735, 45721, 0.072, 2.081 45736, 45765, 45751, 0.078, 2.442 45766, 45795, 45781, 0.078, 2.063 45796, 45825, 45811, 0.078, 1.685 45826, 45855, 45841, 0.073, 1.863 45856, 45885, 45871, 0.034, 2.467 45886, 45915, 45901, 0.034, 2.261 45916, 45945, 45931, 0.034, 2.054 45946, 45975, 45961, 0.051, 1.990 45976, 46005, 45991, 0.029, 2.862 46006, 46035, 46021, 0.029, 2.482 46036, 46065, 46051, 0.064, 2.101 46066, 46095, 46081, 0.064, 2.367 46096, 46125, 46111, 0.080, 2.400 46126, 46155, 46141, 0.080, 2.078 46156, 46185, 46171, 0.080, 1.757 46186, 46215, 46201, 0.078, 2.331 46216, 46245, 46231, 0.065, 2.037 46246, 46275, 46261, 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