46, 1001 Brune, William; Thames, Alexander; Miller, David; Brosius, Alexandra Penn State University ATHOS - Airborne Tropospheric Hydrogen Oxides Sensor ATom 1, 1 2018, 05, 14, 2018, 11, 28 0 Start_UTC, seconds, seconds since UTC midnight on day of takeoff 4 1, 1, 1, 1 -9999.000, -9999.000, -9999.000, -9999.000 Stop_UTC, seconds, seconds since UTC midnight on day of takeoff Mid_UTC, seconds, seconds since UTC midnight on day of takeoff OH_ATHOS, pptv, OH mixing ratio in pptv HO2_ATHOS, pptv, HO2 mixing ratio in pptv 0 28 PI_CONTACT_INFO: Address: 503 Walker Building, University Park, PA 16802; email: whb2@psu.edu 814-865-3286 PLATFORM: NASA - DC-8 Aircraft - sampling underneath aircraft forward cargo bay LOCATION: ATom IV: Science Flight #9 -- REC - TER ASSOCIATED_DATA: N/A INSTRUMENT_INFO: OH/HO2 from Laser Induced Fluorescence. DATA_INFO: Units are pptv for OH and HO2. UNCERTAINTY: HOx absolute accuracy ~+/- 32% (actually a multiplicative factor of 1/1.32 to 1.32), 2 sigma confidence. ULOD_FLAG: -7777 ULOD_VALUE: N/A LLOD_FLAG: -8888 LLOD_VALUE: N/A DM_CONTACT_INFO: William H. Brune, Penn State, whb2@psu.edu; 814-865-3286 PROJECT_INFO: NSF/NASA ATom Mission. 2016 - 2018; Multiple Locations STIPULATIONS_ON_USE: No restrictions. Contact PI or DM with any questions. OTHER_COMMENTS: Final Data. Future modifications to the calibration are possible but unlikely. - Calibrating ATHOS with the new OH-removing inlet (OHSI) has been difficult, particularly for low pressure (high altitude). - The ATHOS HOx calibrations are pressure-dependent, changing a factor of 3-5 over the atmospheric pressure range. - The laboratory calibration uses different inlet hole sizes to simulate atmospheric pressure changes. - For 2 years, we tried various calibration approaches with the OHSI in place, but none gave repeatable results for high altitude measurements. - In the laboratory calibrations, it proved to be impossible to simulate the atmospheric airflow with the OHSI on and the smaller inlet sizes. - In the end, we found that our previous calibration method gave the most repeatable and reliable results. - In-flight diagnostics show that OH loss on the OHSI is negligible. - For details, please see Faloona et al., J. Atmos. Chem., 47, 139-167, 2004. REVISION: R2 R2: Final Data (see OTHER_COMMENTS) R1: Final Data (see OTHER_COMMENTS) R0: No comments for this revision. Start_UTC, Stop_UTC, Mid_UTC, OH_ATHOS, HO2_ATHOS 37675, 37704, 37690, -9999.000, -9999.000 37705, 37734, 37720, -9999.000, -9999.000 37735, 37764, 37750, -9999.000, -9999.000 37765, 37794, 37780, -9999.000, -9999.000 37795, 37824, 37810, 0.111, 16.960 37825, 37854, 37840, 0.111, 18.554 37855, 37884, 37870, 0.059, 18.021 37885, 37914, 37900, 0.059, 15.933 37915, 37944, 37930, 0.115, 13.852 37945, 37974, 37960, 0.115, 13.166 37975, 38004, 37990, 0.092, 12.473 38005, 38034, 38020, 0.092, 11.788 38035, 38064, 38050, 0.092, 11.102 38065, 38094, 38080, 0.111, 10.413 38096, 38125, 38111, 0.085, 9.725 38126, 38155, 38141, 0.085, 9.038 38156, 38185, 38171, 0.085, 8.350 38186, 38215, 38201, 0.103, 9.461 38216, 38245, 38231, 0.103, 8.968 38246, 38275, 38261, 0.109, 8.232 38276, 38305, 38291, 0.055, 7.496 38306, 38335, 38321, 0.055, 8.338 38336, 38365, 38351, 0.055, 8.522 38366, 38395, 38381, 0.095, 7.573 38396, 38425, 38411, 0.075, 6.627 38426, 38455, 38441, 0.075, 4.140 38456, 38485, 38471, 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