47, 1001 Brune, William; Thames, Alexander; Miller, David; Brosius, Alexandra Penn State University ATHOS - Airborne Tropospheric Hydrogen Oxides Sensor ATom 1, 1 2018, 05, 03, 2019, 05, 24 0 Start_UTC, seconds, seconds since UTC midnight on day of takeoff 4 1, 1, 1, 1 -9999.000, -9999.000, -9999.000, -9999.000 Stop_UTC, seconds, seconds since UTC midnight on day of takeoff Mid_UTC, seconds, seconds since UTC midnight on day of takeoff OH_ATHOS, pptv, OH mixing ratio in pptv HO2_ATHOS, pptv, HO2 mixing ratio in pptv 0 29 PI_CONTACT_INFO: Address: 503 Walker Building, University Park, PA 16802; email: whb2@psu.edu 814-865-3286 PLATFORM: NASA - DC-8 Aircraft - sampling underneath aircraft forward cargo bay LOCATION: ATom IV: Science Flight #5 -- NAN - CHC ASSOCIATED_DATA: N/A INSTRUMENT_INFO: OH/HO2 from Laser Induced Fluorescence. DATA_INFO: Units are pptv for OH and HO2. UNCERTAINTY: HOx absolute accuracy ~+/- 35% (actually a multiplicative factor of 1/1.35 to 1.35), 2 sigma confidence. ULOD_FLAG: -7777 ULOD_VALUE: N/A LLOD_FLAG: -8888 LLOD_VALUE: N/A DM_CONTACT_INFO: William H. Brune, Penn State, whb2@psu.edu; 814-865-3286 PROJECT_INFO: NSF/NASA ATom Mission. 2016 - 2018; Multiple Locations STIPULATIONS_ON_USE: No restrictions. Contact PI or DM with any questions. OTHER_COMMENTS: Final Data. Future modifications to the calibration are possible but unlikely. - Calibrating ATHOS with the new OH-removing inlet (OHSI) has been difficult, particularly for low pressure (high altitude). - The ATHOS HOx calibrations are pressure-dependent, changing a factor of 3-5 over the atmospheric pressure range. - The laboratory calibration uses different inlet hole sizes to simulate atmospheric pressure changes. - For 2 years, we tried various calibration approaches with the OHSI in place, but none gave repeatable results for high altitude measurements. - In the laboratory calibrations, it proved to be impossible to simulate the atmospheric airflow with the OHSI on and the smaller inlet sizes. - In the end, we found that our previous calibration method gave the most repeatable and reliable results. - In-flight diagnostics show that OH loss on the OHSI is negligible. - For details, please see Faloona et al., J. Atmos. Chem., 47, 139-167, 2004. REVISION: R3 R3: Final Data (see OTHER_COMMENTS) R2: Final Data (see OTHER_COMMENTS) R1: Final Data (see OTHER_COMMENTS) R0: No comments for this revision. Start_UTC, Stop_UTC, Mid_UTC, OH_ATHOS, HO2_ATHOS 75476, 75505, 75491, -9999.000, -9999.000 75506, 75535, 75521, -9999.000, -9999.000 75536, 75565, 75551, -9999.000, -9999.000 75566, 75595, 75581, -9999.000, -9999.000 75596, 75625, 75611, 0.134, 14.757 75626, 75655, 75641, 0.134, 14.140 75656, 75685, 75671, 0.166, 13.522 75686, 75715, 75701, 0.071, 14.991 75716, 75745, 75731, 0.071, 13.482 75746, 75775, 75761, 0.089, 12.012 75776, 75805, 75791, 0.089, 10.543 75806, 75835, 75821, 0.089, 6.540 75836, 75865, 75851, 0.032, 6.136 75866, 75895, 75881, 0.059, 5.621 75896, 75925, 75911, 0.059, 5.108 75926, 75955, 75941, 0.084, 4.593 75956, 75985, 75971, 0.084, 4.078 75986, 76015, 76001, 0.084, 3.565 76016, 76045, 76031, 0.050, 3.052 76046, 76075, 76061, 0.050, 3.963 76077, 76106, 76092, 0.087, 3.781 76107, 76136, 76122, 0.061, 3.294 76137, 76166, 76152, 0.061, 2.808 76167, 76196, 76182, 0.006, 2.454 76197, 76226, 76212, 0.006, 2.626 76227, 76256, 76242, 0.040, 2.842 76257, 76286, 76272, 0.040, 3.058 76287, 76316, 76302, 0.040, 2.814 76317, 76346, 76332, 0.011, 2.935 76347, 76376, 76362, 0.031, 2.555 76377, 76406, 76392, 0.031, 2.176 76407, 76436, 76422, 0.031, 3.311 76437, 76466, 76452, 0.053, 2.856 76467, 76496, 76482, 0.042, 3.154 76497, 76526, 76512, 0.042, 3.451 76527, 76556, 76542, 0.047, 3.214 76557, 76586, 76572, 0.047, 2.653 76587, 76616, 76602, 0.079, 3.123 76617, 76646, 76632, 0.079, 3.589 76647, 76676, 76662, 0.083, 3.975 76677, 76706, 76692, 0.083, 4.298 76707, 76736, 76722, 0.107, 4.263 76738, 76767, 76753, 0.107, 4.229 76873, 76902, 76888, -9999.000, 8.276 76903, 76932, 76918, 0.134, 8.041 76933, 76962, 76948, 0.132, 7.142 76963, 76992, 76978, 0.132, 6.245 76993, 77022, 77008, 0.132, 7.568 77023, 77052, 77038, 0.178, 6.657 77053, 77082, 77068, 0.178, 6.756 77084, 77113, 77099, 0.136, 6.856 77114, 77143, 77129, 0.116, 8.430 77144, 77173, 77159, 0.116, 7.436 77174, 77203, 77189, 0.134, 7.169 77204, 77233, 77219, 0.134, 6.901 77234, 77263, 77249, 0.134, 6.572 77264, 77293, 77279, 0.103, 6.692 77294, 77323, 77309, 0.103, 6.289 77324, 77353, 77339, 0.119, 5.886 77354, 77383, 77369, 0.119, 7.610 77384, 77413, 77399, 0.143, 5.845 77414, 77443, 77429, 0.143, 5.718 77444, 77473, 77459, 0.073, 5.590 77474, 77503, 77489, 0.062, 5.365 77504, 77533, 77519, 0.062, 6.336 77534, 77563, 77549, 0.062, 5.393 77564, 77593, 77579, 0.077, 4.446 77594, 77623, 77609, 0.119, 7.277 77624, 77653, 77639, 0.119, 6.602 77654, 77683, 77669, 0.091, 5.362 77684, 77713, 77699, 0.091, 4.122 77714, 77743, 77729, 0.093, 4.825 77745, 77774, 77760, 0.093, 5.134 77775, 77804, 77790, 0.110, 4.883 77805, 77834, 77820, 0.110, 4.632 77835, 77864, 77850, 0.111, 4.891 77865, 77894, 77880, 0.111, 4.611 77895, 77924, 77910, 0.111, 4.314 77925, 77954, 77940, 0.083, 4.018 77955, 77984, 77970, 0.083, 5.434 77985, 78014, 78000, 0.083, 4.195 78015, 78044, 78030, 0.083, 6.352 78045, 78074, 78060, 0.083, 8.502 78075, 78104, 78090, 0.083, 8.706 78105, 78134, 78120, -9999.000, 18.612 78135, 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79006, 79035, 79021, 0.089, 8.301 79036, 79065, 79051, 0.089, 7.961 79066, 79095, 79081, 0.101, 5.743 79097, 79126, 79112, 0.069, 5.549 79127, 79156, 79142, 0.069, 5.355 79157, 79186, 79172, 0.069, 4.419 79187, 79216, 79202, 0.108, 4.227 79217, 79246, 79232, 0.118, 3.859 79247, 79276, 79262, 0.118, 3.493 79277, 79306, 79292, 0.038, 3.717 79307, 79336, 79322, 0.038, 3.191 79337, 79366, 79352, 0.038, 2.959 79367, 79396, 79382, 0.058, 2.725 79397, 79426, 79412, 0.083, 3.699 79427, 79456, 79442, 0.083, 3.367 79457, 79486, 79472, 0.050, 3.008 79487, 79516, 79502, 0.050, 2.649 79517, 79546, 79532, 0.100, 4.343 79547, 79576, 79562, 0.100, 3.301 79577, 79606, 79592, 0.100, 3.089 79607, 79636, 79622, 0.105, 2.875 79637, 79666, 79652, 0.105, 3.992 79667, 79696, 79682, 0.147, 2.503 79697, 79726, 79712, 0.147, 2.781 79727, 79756, 79742, 0.142, 3.060 79758, 79787, 79773, 0.155, 3.942 79788, 79817, 79803, 0.155, 3.158 79818, 79847, 79833, 0.155, 2.624 79848, 79877, 79863, -9999.000, -9999.000 79878, 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80803, 80832, 80818, 0.187, 6.728 80833, 80862, 80848, 0.168, 6.789 80863, 80892, 80878, 0.127, 6.090 80893, 80922, 80908, 0.127, 5.392 80923, 80952, 80938, 0.117, 6.432 80953, 80982, 80968, 0.117, 6.969 80983, 81012, 80998, 0.156, 6.124 81014, 81043, 81029, 0.156, 5.279 81044, 81073, 81059, 0.156, 6.462 81073, 81102, 81088, 0.138, 6.836 81104, 81133, 81119, 0.141, 6.601 81134, 81163, 81149, 0.141, 6.366 81164, 81193, 81179, 0.104, 6.999 81194, 81223, 81209, 0.104, 6.473 81224, 81253, 81239, 0.104, 6.116 81254, 81283, 81269, 0.113, 5.758 81284, 81313, 81299, 0.101, 6.274 81314, 81343, 81329, 0.101, 6.433 81344, 81373, 81359, 0.101, 6.521 81374, 81403, 81389, 0.065, 6.609 81404, 81433, 81419, 0.074, 7.864 81434, 81463, 81449, 0.074, 6.280 81464, 81493, 81479, 0.070, 6.330 81494, 81523, 81509, 0.070, 6.379 81524, 81553, 81539, 0.093, 6.717 81554, 81583, 81569, 0.093, 7.398 81584, 81613, 81599, 0.093, 6.548 81614, 81643, 81629, 0.076, 5.695 81644, 81673, 81659, 0.072, 7.243 81674, 81703, 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82546, 82575, 82561, 0.062, 7.026 82576, 82605, 82591, 0.057, 6.689 82606, 82635, 82621, 0.083, 6.642 82636, 82665, 82651, 0.083, 9.116 82666, 82695, 82681, 0.083, 8.171 82696, 82725, 82711, 0.089, 7.227 82726, 82755, 82741, 0.089, 7.199 82756, 82785, 82771, 0.057, 8.352 82786, 82815, 82801, 0.074, 7.257 82816, 82845, 82831, 0.074, 6.170 82846, 82875, 82861, 0.085, 7.137 82876, 82905, 82891, 0.085, 6.606 82906, 82935, 82921, 0.085, 6.398 82936, 82965, 82951, 0.124, 6.188 82966, 82995, 82981, 0.110, 5.785 82996, 83025, 83011, 0.110, 6.913 83026, 83055, 83041, 0.110, 5.973 83057, 83086, 83072, 0.094, 5.029 83087, 83116, 83102, 0.133, 5.830 83117, 83146, 83132, 0.133, 5.956 83147, 83176, 83162, 0.108, 6.694 83177, 83206, 83192, 0.108, 7.432 83207, 83236, 83222, 0.125, 6.892 83237, 83266, 83252, 0.125, 6.879 83267, 83296, 83282, 0.136, 6.420 83297, 83326, 83312, 0.136, 5.961 83327, 83356, 83342, 0.103, 7.742 83357, 83386, 83372, 0.103, 6.355 83387, 83416, 83402, 0.114, 6.091 83417, 83446, 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