46, 1001 Brune, William; Thames, Alexander; Miller, David; Brosius, Alexandra Penn State University ATHOS - Airborne Tropospheric Hydrogen Oxides Sensor ATom 1, 1 2018, 05, 03, 2018, 11, 28 0 Start_UTC, seconds, seconds since UTC midnight on day of takeoff 4 1, 1, 1, 1 -9999.000, -9999.000, -9999.000, -9999.000 Stop_UTC, seconds, seconds since UTC midnight on day of takeoff Mid_UTC, seconds, seconds since UTC midnight on day of takeoff OH_ATHOS, pptv, OH mixing ratio in pptv HO2_ATHOS, pptv, HO2 mixing ratio in pptv 0 28 PI_CONTACT_INFO: Address: 503 Walker Building, University Park, PA 16802; email: whb2@psu.edu 814-865-3286 PLATFORM: NASA - DC-8 Aircraft - sampling underneath aircraft forward cargo bay LOCATION: ATom IV: Science Flight #5 -- NAN - CHC ASSOCIATED_DATA: N/A INSTRUMENT_INFO: OH/HO2 from Laser Induced Fluorescence. DATA_INFO: Units are pptv for OH and HO2. UNCERTAINTY: HOx absolute accuracy ~+/- 32% (actually a multiplicative factor of 1/1.32 to 1.32), 2 sigma confidence. ULOD_FLAG: -7777 ULOD_VALUE: N/A LLOD_FLAG: -8888 LLOD_VALUE: N/A DM_CONTACT_INFO: William H. Brune, Penn State, whb2@psu.edu; 814-865-3286 PROJECT_INFO: NSF/NASA ATom Mission. 2016 - 2018; Multiple Locations STIPULATIONS_ON_USE: No restrictions. Contact PI or DM with any questions. OTHER_COMMENTS: Final Data. Future modifications to the calibration are possible but unlikely. - Calibrating ATHOS with the new OH-removing inlet (OHSI) has been difficult, particularly for low pressure (high altitude). - The ATHOS HOx calibrations are pressure-dependent, changing a factor of 3-5 over the atmospheric pressure range. - The laboratory calibration uses different inlet hole sizes to simulate atmospheric pressure changes. - For 2 years, we tried various calibration approaches with the OHSI in place, but none gave repeatable results for high altitude measurements. - In the laboratory calibrations, it proved to be impossible to simulate the atmospheric airflow with the OHSI on and the smaller inlet sizes. - In the end, we found that our previous calibration method gave the most repeatable and reliable results. - In-flight diagnostics show that OH loss on the OHSI is negligible. - For details, please see Faloona et al., J. Atmos. Chem., 47, 139-167, 2004. REVISION: R2 R2: Final Data (see OTHER_COMMENTS) R1: Final Data (see OTHER_COMMENTS) R0: No comments for this revision. Start_UTC, Stop_UTC, Mid_UTC, OH_ATHOS, HO2_ATHOS 75476, 75505, 75491, -9999.000, -9999.000 75506, 75535, 75521, -9999.000, -9999.000 75536, 75565, 75551, -9999.000, -9999.000 75566, 75595, 75581, -9999.000, -9999.000 75596, 75625, 75611, 0.134, 17.563 75626, 75655, 75641, 0.134, 16.579 75656, 75685, 75671, 0.166, 15.592 75686, 75715, 75701, 0.071, 17.231 75716, 75745, 75731, 0.071, 15.271 75746, 75775, 75761, 0.089, 13.387 75776, 75805, 75791, 0.089, 11.504 75806, 75835, 75821, 0.089, 7.032 75836, 75865, 75851, 0.032, 6.495 75866, 75895, 75881, 0.059, 5.920 75896, 75925, 75911, 0.059, 5.346 75926, 75955, 75941, 0.084, 4.771 75956, 75985, 75971, 0.084, 4.195 75986, 76015, 76001, 0.084, 3.622 76016, 76045, 76031, 0.050, 3.049 76046, 76075, 76061, 0.050, 3.950 76077, 76106, 76092, 0.087, 3.749 76107, 76136, 76122, 0.061, 3.233 76137, 76166, 76152, 0.061, 2.718 76167, 76196, 76182, 0.006, 2.348 76197, 76226, 76212, 0.006, 2.485 76227, 76256, 76242, 0.040, 2.666 76257, 76286, 76272, 0.040, 2.847 76287, 76316, 76302, 0.040, 2.606 76317, 76346, 76332, 0.011, 2.710 76347, 76376, 76362, 0.031, 2.350 76377, 76406, 76392, 0.031, 1.990 76407, 76436, 76422, 0.031, 3.022 76437, 76466, 76452, 0.053, 2.596 76467, 76496, 76482, 0.042, 2.858 76497, 76526, 76512, 0.042, 3.118 76527, 76556, 76542, 0.047, 2.895 76557, 76586, 76572, 0.047, 2.383 76587, 76616, 76602, 0.079, 2.802 76617, 76646, 76632, 0.079, 3.217 76647, 76676, 76662, 0.083, 3.557 76677, 76706, 76692, 0.083, 3.844 76707, 76736, 76722, 0.107, 3.807 76738, 76767, 76753, 0.107, 3.770 76873, 76902, 76888, -9999.000, 7.394 76903, 76932, 76918, 0.134, 7.191 76933, 76962, 76948, 0.132, 6.384 76963, 76992, 76978, 0.132, 5.580 76993, 77022, 77008, 0.132, 6.758 77023, 77052, 77038, 0.178, 5.948 77053, 77082, 77068, 0.178, 6.035 77084, 77113, 77099, 0.136, 6.123 77114, 77143, 77129, 0.116, 7.525 77144, 77173, 77159, 0.116, 6.639 77174, 77203, 77189, 0.134, 6.400 77204, 77233, 77219, 0.134, 6.160 77234, 77263, 77249, 0.134, 5.859 77264, 77293, 77279, 0.103, 5.971 77294, 77323, 77309, 0.103, 5.611 77324, 77353, 77339, 0.119, 5.251 77354, 77383, 77369, 0.119, 6.786 77384, 77413, 77399, 0.143, 5.218 77414, 77443, 77429, 0.143, 5.110 77444, 77473, 77459, 0.073, 5.000 77474, 77503, 77489, 0.062, 4.804 77504, 77533, 77519, 0.062, 5.691 77534, 77563, 77549, 0.062, 4.850 77564, 77593, 77579, 0.077, 4.007 77594, 77623, 77609, 0.119, 6.583 77624, 77653, 77639, 0.119, 5.998 77654, 77683, 77669, 0.091, 4.883 77684, 77713, 77699, 0.091, 3.768 77714, 77743, 77729, 0.093, 4.428 77745, 77774, 77760, 0.093, 4.742 77775, 77804, 77790, 0.110, 4.533 77805, 77834, 77820, 0.110, 4.325 77835, 77864, 77850, 0.111, 4.592 77865, 77894, 77880, 0.111, 4.362 77895, 77924, 77910, 0.111, 4.114 77925, 77954, 77940, 0.083, 3.866 77955, 77984, 77970, 0.083, 5.269 77985, 78014, 78000, 0.083, 4.103 78015, 78044, 78030, 0.083, 6.304 78045, 78074, 78060, 0.083, 8.497 78075, 78104, 78090, 0.083, 8.785 78105, 78134, 78120, -9999.000, 19.015 78135, 78164, 78150, 0.346, 12.632 78165, 78194, 78180, 0.346, 6.312 78195, 78224, 78210, 0.157, 11.011 78225, 78254, 78240, 0.157, 11.572 78255, 78284, 78270, 0.154, 11.288 78285, 78314, 78300, 0.154, 11.005 78315, 78344, 78330, 0.154, 13.212 78345, 78374, 78360, 0.147, 10.292 78375, 78404, 78390, 0.147, 11.104 78406, 78435, 78421, 0.144, 11.921 78436, 78465, 78451, 0.144, 12.536 78466, 78495, 78481, 0.142, 13.620 78496, 78525, 78511, 0.142, 11.870 78526, 78555, 78541, 0.106, 10.114 78556, 78585, 78571, 0.088, 13.177 78586, 78615, 78601, 0.088, 10.798 78616, 78645, 78631, 0.088, 10.907 78646, 78675, 78661, 0.101, 11.016 78676, 78705, 78691, 0.149, 14.828 78706, 78735, 78721, 0.149, 12.407 78736, 78765, 78751, 0.131, 12.056 78766, 78795, 78781, 0.131, 11.704 78796, 78825, 78811, 0.131, 13.062 78826, 78855, 78841, 0.109, 10.480 78856, 78885, 78871, 0.109, 9.926 78886, 78915, 78901, 0.100, 9.371 78916, 78945, 78931, 0.100, 11.506 78946, 78975, 78961, 0.127, 10.056 78976, 79005, 78991, 0.089, 9.471 79006, 79035, 79021, 0.089, 8.887 79036, 79065, 79051, 0.089, 8.376 79066, 79095, 79081, 0.101, 5.948 79097, 79126, 79112, 0.069, 5.657 79127, 79156, 79142, 0.069, 5.367 79157, 79186, 79172, 0.069, 4.356 79187, 79216, 79202, 0.108, 4.107 79217, 79246, 79232, 0.118, 3.707 79247, 79276, 79262, 0.118, 3.308 79277, 79306, 79292, 0.038, 3.491 79307, 79336, 79322, 0.038, 2.983 79337, 79366, 79352, 0.038, 2.756 79367, 79396, 79382, 0.058, 2.527 79397, 79426, 79412, 0.083, 3.415 79427, 79456, 79442, 0.083, 3.097 79457, 79486, 79472, 0.050, 2.756 79487, 79516, 79502, 0.050, 2.415 79517, 79546, 79532, 0.100, 3.953 79547, 79576, 79562, 0.100, 2.991 79577, 79606, 79592, 0.100, 2.786 79607, 79636, 79622, 0.105, 2.581 79637, 79666, 79652, 0.105, 3.571 79667, 79696, 79682, 0.147, 2.233 79697, 79726, 79712, 0.147, 2.477 79727, 79756, 79742, 0.142, 2.721 79758, 79787, 79773, 0.155, 3.499 79788, 79817, 79803, 0.155, 2.802 79818, 79847, 79833, 0.155, 2.323 79848, 79877, 79863, -9999.000, -9999.000 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0.187, 4.237 80803, 80832, 80818, 0.187, 5.958 80833, 80862, 80848, 0.168, 6.019 80863, 80892, 80878, 0.127, 5.397 80893, 80922, 80908, 0.127, 4.776 80923, 80952, 80938, 0.117, 5.695 80953, 80982, 80968, 0.117, 6.178 80983, 81012, 80998, 0.156, 5.431 81014, 81043, 81029, 0.156, 4.683 81044, 81073, 81059, 0.156, 5.736 81073, 81102, 81088, 0.138, 6.083 81104, 81133, 81119, 0.141, 5.885 81134, 81163, 81149, 0.141, 5.687 81164, 81193, 81179, 0.104, 6.263 81194, 81223, 81209, 0.104, 5.812 81224, 81253, 81239, 0.104, 5.511 81254, 81283, 81269, 0.113, 5.209 81284, 81313, 81299, 0.101, 5.698 81314, 81343, 81329, 0.101, 5.878 81344, 81373, 81359, 0.101, 5.993 81374, 81403, 81389, 0.065, 6.108 81404, 81433, 81419, 0.074, 7.316 81434, 81463, 81449, 0.074, 5.886 81464, 81493, 81479, 0.070, 5.983 81494, 81523, 81509, 0.070, 6.081 81524, 81553, 81539, 0.093, 6.462 81554, 81583, 81569, 0.093, 7.187 81584, 81613, 81599, 0.093, 6.422 81614, 81643, 81629, 0.076, 5.654 81644, 81673, 81659, 0.072, 7.266 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0.062, 8.038 82546, 82575, 82561, 0.062, 7.550 82576, 82605, 82591, 0.057, 7.061 82606, 82635, 82621, 0.083, 6.893 82636, 82665, 82651, 0.083, 9.305 82666, 82695, 82681, 0.083, 8.220 82696, 82725, 82711, 0.089, 7.136 82726, 82755, 82741, 0.089, 7.027 82756, 82785, 82771, 0.057, 8.090 82786, 82815, 82801, 0.074, 6.984 82816, 82845, 82831, 0.074, 5.886 82846, 82875, 82861, 0.085, 6.756 82876, 82905, 82891, 0.085, 6.214 82906, 82935, 82921, 0.085, 5.988 82936, 82965, 82951, 0.124, 5.761 82966, 82995, 82981, 0.110, 5.356 82996, 83025, 83011, 0.110, 6.374 83026, 83055, 83041, 0.110, 5.480 83057, 83086, 83072, 0.094, 4.583 83087, 83116, 83102, 0.133, 5.289 83117, 83146, 83132, 0.133, 5.395 83147, 83176, 83162, 0.108, 6.045 83177, 83206, 83192, 0.108, 6.695 83207, 83236, 83222, 0.125, 6.184 83237, 83266, 83252, 0.125, 6.167 83267, 83296, 83282, 0.136, 5.751 83297, 83326, 83312, 0.136, 5.334 83327, 83356, 83342, 0.103, 6.918 83357, 83386, 83372, 0.103, 5.673 83387, 83416, 83402, 0.114, 5.429 83417, 83446, 83432, 0.114, 5.186 83447, 83476, 83462, 0.114, 6.102 83477, 83506, 83492, 0.133, 6.058 83507, 83536, 83522, 0.133, 5.830 83537, 83566, 83552, 0.132, 5.602 83567, 83596, 83582, 0.132, 5.505 83597, 83626, 83612, 0.145, 5.171 83627, 83656, 83642, 0.171, 4.485 83657, 83686, 83672, 0.171, 3.802 83688, 83717, 83703, 0.169, 4.160 83717, 83746, 83732, 0.169, 4.539 83747, 83776, 83762, 0.169, 4.074 83778, 83807, 83793, 0.180, 3.607 83808, 83837, 83823, 0.146, 5.120 83838, 83867, 83853, 0.146, 4.645 83868, 83897, 83883, 0.146, 4.387 83898, 83927, 83913, 0.228, 4.127 84018, 84047, 84033, 0.182, 5.491 84048, 84077, 84063, 0.182, 5.362 84078, 84107, 84093, 0.198, 5.319 84108, 84137, 84123, 0.198, 5.276 84138, 84167, 84153, 0.198, 5.701 84168, 84197, 84183, 0.231, 4.941 84198, 84227, 84213, 0.231, 4.855 84228, 84257, 84243, 0.201, 4.770 84258, 84287, 84273, 0.201, 5.528 84288, 84317, 84303, 0.181, 5.300 84318, 84347, 84333, 0.114, 5.723 84348, 84377, 84363, 0.114, 6.146 84379, 84408, 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0.144, 1.789 99567, 99596, 99582, 0.135, 1.781 99597, 99626, 99612, 0.140, 2.156 99627, 99656, 99642, 0.140, 1.583 99657, 99686, 99672, 0.140, 1.592 99687, 99716, 99702, 0.184, 1.602 99717, 99746, 99732, 0.184, 2.403 99747, 99776, 99762, 0.182, 1.979 99777, 99806, 99792, 0.182, 1.910 99807, 99836, 99822, 0.147, 1.841 99837, 99866, 99852, 0.147, 1.529 99867, 99896, 99882, 0.146, 1.685 99897, 99926, 99912, 0.146, 1.506 99927, 99956, 99942, 0.137, 1.327 99957, 99986, 99972, 0.147, 2.031 99987, 100016, 100002, 0.147, 2.268 100017, 100046, 100032, 0.147, 2.727 100048, 100077, 100063, 0.137, 3.188 100078, 100107, 100093, 0.089, 4.593 100108, 100137, 100123, 0.089, 4.449 100138, 100167, 100153, 0.089, 3.797 100168, 100197, 100183, 0.080, 3.141 100198, 100227, 100213, 0.080, 3.882 100228, 100257, 100243, 0.106, 4.026 100258, 100287, 100273, 0.106, 3.570 100288, 100317, 100303, 0.071, 3.112 100318, 100347, 100333, 0.071, 4.096 100348, 100377, 100363, 0.046, 4.388 100378, 100407, 100393, 0.046, 3.579 100408, 100437, 100423, 0.026, 2.769 100438, 100467, 100453, 0.026, 3.702 100468, 100497, 100483, 0.040, 3.716 100498, 100527, 100513, 0.027, 3.550 100528, 100557, 100543, 0.027, 3.384 100558, 100587, 100573, 0.027, 4.172 100588, 100617, 100603, 0.047, 4.048 100618, 100647, 100633, 0.026, 3.924 100648, 100677, 100663, 0.026, 3.800 100678, 100707, 100693, 0.026, 4.911 100708, 100737, 100723, 0.025, 4.236 100739, 100768, 100754, 0.046, 3.988 100769, 100798, 100784, 0.046, 3.742 100799, 100828, 100814, 0.046, 5.370 100829, 100858, 100844, 0.059, 5.333 100859, 100888, 100874, 0.059, 4.991 100889, 100918, 100904, 0.030, 4.645 100919, 100948, 100934, 0.030, 6.095 100949, 100978, 100964, 0.011, 5.763 100979, 101008, 100994, 0.011, 5.573 101009, 101038, 101024, 0.017, 5.383 101039, 101068, 101054, 0.031, 4.728 101069, 101098, 101084, 0.031, 7.001 101099, 101128, 101114, 0.058, 5.782 101129, 101158, 101144, 0.058, 4.562 101159, 101188, 101174, 0.037, 5.383 101189, 101218, 101204, 0.037, 5.798 101219, 101248, 101234, 0.025, 5.691 101249, 101278, 101264, 0.025, 5.583 101279, 101308, 101294, 0.025, 5.181 101309, 101338, 101324, 0.054, 5.094 101339, 101368, 101354, 0.021, 4.868 101369, 101398, 101384, 0.021, 4.642 101399, 101428, 101414, 0.021, 5.507 101430, 101459, 101445, -0.028, 5.094 101460, 101489, 101475, -0.028, 4.818 101490, 101519, 101505, 0.016, 4.543 101520, 101549, 101535, 0.016, 4.267 101550, 101579, 101565, 0.037, 3.991 101580, 101609, 101595, 0.014, 3.715 101610, 101639, 101625, 0.014, 3.439 101640, 101669, 101655, 0.014, 3.738 101670, 101699, 101685, 0.039, 5.111 101700, 101729, 101715, 0.032, 4.627 101730, 101759, 101745, 0.032, 4.147 101760, 101789, 101775, 0.028, 6.535 101790, 101819, 101805, 0.028, 4.965 101820, 101849, 101835, 0.073, 3.896 101850, 101879, 101865, 0.073, 2.827 101880, 101909, 101895, 0.012, 4.451 101910, 101939, 101925, 0.012, 3.872 101940, 101969, 101955, 0.012, 3.227 101970, 101999, 101985, 0.001, 2.578 102000, 102029, 102015, 0.001, 2.857 102030, 102059, 102045, 0.007, 2.433 102060, 102089, 102075, 0.007, 3.206 102090, 102119, 102105, 0.002, 3.979 102121, 102150, 102136, 0.017, 4.012 102151, 102180, 102166, 0.017, 3.327 102181, 102210, 102196, 0.042, 2.971 102211, 102240, 102226, 0.042, 2.615 102241, 102270, 102256, 0.026, 4.405 102271, 102300, 102286, 0.026, 3.809 102301, 102330, 102316, 0.026, 3.070 102331, 102360, 102346, 0.040, 2.331 102361, 102390, 102376, 0.040, 3.022 102391, 102420, 102406, 0.027, 2.904 102421, 102450, 102436, 0.024, 3.088 102451, 102480, 102466, 0.024, 3.271 102481, 102510, 102496, 0.024, 3.223 102511, 102540, 102526, 0.029, 2.456 102541, 102570, 102556, 0.024, 2.308 102571, 102600, 102586, 0.024, 2.160 102601, 102630, 102616, 0.024, 3.534 102631, 102660, 102646, 0.115, 2.662 102661, 102690, 102676, 0.115, 2.524 102691, 102720, 102706, 0.119, 2.387 102721, 102750, 102736, 0.100, 2.094 102751, 102780, 102766, 0.100, 1.228 102781, 102810, 102796, 0.100, 1.712 102812, 102841, 102827, -9999.000, 2.199 102842, 102871, 102857, -9999.000, 2.189 102872, 102901, 102887, 0.021, 2.909 102902, 102931, 102917, 0.021, 2.515 102932, 102961, 102947, 0.015, 2.119 102962, 102991, 102977, 0.138, 2.394 102992, 103021, 103007, 0.138, 2.503 103022, 103051, 103037, 0.138, 2.120 103052, 103081, 103067, 0.064, 1.736 103082, 103111, 103097, -0.013, 2.679 103112, 103141, 103127, -0.013, 2.274 103142, 103171, 103157, -0.013, 2.748 103172, 103201, 103187, 0.003, 3.226 103202, 103231, 103217, -0.006, 3.751 103232, 103261, 103247, -0.006, 3.175 103262, 103291, 103277, -0.006, 3.036 103292, 103321, 103307, 0.006, 2.896 103322, 103351, 103337, -0.019, 3.284 103352, 103381, 103367, -0.019, 3.174 103382, 103411, 103397, 0.017, 2.875 103412, 103441, 103427, 0.017, 2.576 103443, 103472, 103458, 0.005, 1.726 103473, 103502, 103488, 0.005, 1.580 103503, 103532, 103518, 0.005, 1.882 103533, 103562, 103548, 0.025, 2.184 103563, 103592, 103578, -9999.000, 3.126 103593, 103622, 103608, -9999.000, 1.978 103623, 103652, 103638, -9999.000, -9999.000 103653, 103682, 103668, -9999.000, -9999.000