46, 1001 Brune, William; Thames, Alexander; Miller, David; Brosius, Alexandra Penn State University ATHOS - Airborne Tropospheric Hydrogen Oxides Sensor ATom 1, 1 2018, 04, 27, 2018, 11, 28 0 Start_UTC, seconds, seconds since UTC midnight on day of takeoff 4 1, 1, 1, 1 -9999.000, -9999.000, -9999.000, -9999.000 Stop_UTC, seconds, seconds since UTC midnight on day of takeoff Mid_UTC, seconds, seconds since UTC midnight on day of takeoff OH_ATHOS, pptv, OH mixing ratio in pptv HO2_ATHOS, pptv, HO2 mixing ratio in pptv 0 28 PI_CONTACT_INFO: Address: 503 Walker Building, University Park, PA 16802; email: whb2@psu.edu 814-865-3286 PLATFORM: NASA - DC-8 Aircraft - sampling underneath aircraft forward cargo bay LOCATION: ATom IV: Science Flight #2 -- PMD - ANC ASSOCIATED_DATA: N/A INSTRUMENT_INFO: OH/HO2 from Laser Induced Fluorescence. DATA_INFO: Units are pptv for OH and HO2. UNCERTAINTY: HOx absolute accuracy ~+/- 32% (actually a multiplicative factor of 1/1.32 to 1.32), 2 sigma confidence. ULOD_FLAG: -7777 ULOD_VALUE: N/A LLOD_FLAG: -8888 LLOD_VALUE: N/A DM_CONTACT_INFO: William H. Brune, Penn State, whb2@psu.edu; 814-865-3286 PROJECT_INFO: NSF/NASA ATom Mission. 2016 - 2018; Multiple Locations STIPULATIONS_ON_USE: No restrictions. Contact PI or DM with any questions. OTHER_COMMENTS: Final Data. Future modifications to the calibration are possible but unlikely. - Calibrating ATHOS with the new OH-removing inlet (OHSI) has been difficult, particularly for low pressure (high altitude). - The ATHOS HOx calibrations are pressure-dependent, changing a factor of 3-5 over the atmospheric pressure range. - The laboratory calibration uses different inlet hole sizes to simulate atmospheric pressure changes. - For 2 years, we tried various calibration approaches with the OHSI in place, but none gave repeatable results for high altitude measurements. - In the laboratory calibrations, it proved to be impossible to simulate the atmospheric airflow with the OHSI on and the smaller inlet sizes. - In the end, we found that our previous calibration method gave the most repeatable and reliable results. - In-flight diagnostics show that OH loss on the OHSI is negligible. - For details, please see Faloona et al., J. Atmos. Chem., 47, 139-167, 2004. REVISION: R2 R2: Final Data (see OTHER_COMMENTS) R1: Final Data (see OTHER_COMMENTS) R0: No comments for this revision. Start_UTC, Stop_UTC, Mid_UTC, OH_ATHOS, HO2_ATHOS 57775, 57804, 57790, -9999.000, -9999.000 57805, 57834, 57820, -9999.000, -9999.000 57835, 57864, 57850, -9999.000, -9999.000 57865, 57894, 57880, -9999.000, -9999.000 57895, 57924, 57910, 0.291, 15.559 57925, 57954, 57940, 0.291, 24.797 57955, 57984, 57970, 0.220, 24.724 57985, 58014, 58000, 0.165, 18.132 58015, 58044, 58030, 0.165, 19.391 58045, 58074, 58060, 0.165, 20.645 58075, 58104, 58090, 0.134, 15.868 58105, 58134, 58120, 0.255, 18.905 58135, 58164, 58150, 0.255, 13.589 58165, 58194, 58180, 0.255, 8.274 58195, 58224, 58210, 0.188, 2.958 58225, 58254, 58240, 0.188, 4.652 58255, 58284, 58270, 0.135, 6.347 58285, 58314, 58300, 0.135, 8.035 58315, 58344, 58330, 0.179, 9.916 58346, 58375, 58361, 0.128, 11.389 58376, 58405, 58391, 0.128, 10.782 58406, 58435, 58421, 0.105, 10.176 58436, 58465, 58451, 0.105, 10.952 58466, 58495, 58481, 0.092, 12.167 58496, 58525, 58511, 0.092, 9.880 58526, 58555, 58541, 0.092, 7.594 58556, 58585, 58571, 0.111, 7.344 58586, 58615, 58601, 0.225, 8.304 58616, 58645, 58631, 0.225, 8.375 58646, 58675, 58661, 0.225, 8.445 58676, 58705, 58691, 0.180, 9.527 58706, 58735, 58721, 0.168, 8.865 58736, 58765, 58751, 0.168, 8.639 58766, 58795, 58781, 0.168, 8.414 58796, 58825, 58811, 0.194, 9.745 58826, 58855, 58841, 0.177, 10.126 58856, 58885, 58871, 0.177, 9.691 58886, 58915, 58901, 0.177, 9.257 58916, 58945, 58931, 0.172, 9.325 58946, 58975, 58961, 0.247, 9.032 58976, 59005, 58991, 0.247, 8.783 59006, 59035, 59021, 0.247, 8.534 59036, 59065, 59051, 0.165, 8.068 59067, 59096, 59082, 0.134, 10.072 59097, 59126, 59112, 0.134, 9.064 59127, 59156, 59142, 0.134, 8.056 59157, 59186, 59172, 0.141, 9.556 59187, 59216, 59202, 0.111, 9.040 59217, 59246, 59232, 0.111, 8.870 59247, 59276, 59262, 0.111, 8.701 59277, 59306, 59292, 0.112, 8.940 59307, 59336, 59322, 0.112, 9.691 59337, 59366, 59352, 0.198, 9.314 59367, 59396, 59382, 0.110, 8.938 59397, 59426, 59412, 0.110, 8.563 59427, 59456, 59442, 0.138, 8.186 59457, 59486, 59472, 0.138, 7.809 59487, 59516, 59502, 0.138, 7.433 59517, 59546, 59532, 0.090, 9.651 59547, 59576, 59562, 0.090, 9.728 59577, 59606, 59592, 0.116, 9.505 59607, 59636, 59622, 0.155, 9.282 59637, 59666, 59652, 0.155, 8.666 59813, 59842, 59828, 0.133, 9.474 59844, 59873, 59859, 0.133, 8.890 59874, 59903, 59889, 0.133, 8.313 59904, 59933, 59919, 0.116, 10.057 59934, 59963, 59949, 0.225, 10.114 59964, 59993, 59979, 0.225, 9.666 59994, 60023, 60009, 0.225, 9.217 60024, 60053, 60039, 0.210, 9.880 60054, 60083, 60069, 0.223, 8.936 60084, 60113, 60099, 0.223, 7.865 60114, 60143, 60129, 0.223, 6.794 60144, 60173, 60159, -9999.000, 7.346 60174, 60203, 60189, -9999.000, -9999.000 60204, 60233, 60219, -9999.000, -9999.000 60234, 60263, 60249, -9999.000, -9999.000 60264, 60293, 60279, -9999.000, -9999.000 60295, 60324, 60310, -9999.000, -9999.000 60325, 60354, 60340, -9999.000, -9999.000 60355, 60384, 60370, -9999.000, -9999.000 60385, 60414, 60400, -9999.000, 6.813 60415, 60444, 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