45, 1001 Brune, William; Thames, Alexander; Miller, David; Brosius, Alexandra Penn State University ATHOS - Airborne Tropospheric Hydrogen Oxides Sensor ATom 1, 1 2017, 10, 23, 2018, 10, 25 0 Start_UTC, seconds, seconds since UTC midnight on day of takeoff 4 1, 1, 1, 1 -9999.000, -9999.000, -9999.000, -9999.000 Stop_UTC, seconds, seconds since UTC midnight on day of takeoff Mid_UTC, seconds, seconds since UTC midnight on day of takeoff OH_ATHOS, pptv, OH mixing ratio in pptv HO2_ATHOS, pptv, HO2 mixing ratio in pptv 0 27 PI_CONTACT_INFO: Address: 503 Walker Building, University Park, PA 16802; email: whb2@psu.edu 814-865-3286 PLATFORM: NASA - DC-8 Aircraft - sampling underneath aircraft forward cargo bay LOCATION: ATom III: Science Flight #11 -- TER - BGR ASSOCIATED_DATA: N/A INSTRUMENT_INFO: OH/HO2 from Laser Induced Fluorescence. DATA_INFO: Units are pptv for OH and HO2. UNCERTAINTY: HOx absolute accuracy ~+/- 32% (actually a multiplicative factor of 1/1.32 to 1.32), 2 sigma confidence. ULOD_FLAG: -7777 ULOD_VALUE: N/A LLOD_FLAG: -8888 LLOD_VALUE: N/A DM_CONTACT_INFO: William H. Brune, Penn State, whb2@psu.edu; 814-865-3286 PROJECT_INFO: NSF/NASA ATom Mission. 2016 - 2018; Multiple Locations STIPULATIONS_ON_USE: No restrictions. Contact PI or DM with any questions. OTHER_COMMENTS: Final Data. Future modifications to the calibration are possible but unlikely. - Calibrating ATHOS with the new OH-removing inlet (OHSI) has been difficult, particularly for low pressure (high altitude). - The ATHOS HOx calibrations are pressure-dependent, changing a factor of 3-5 over the atmospheric pressure range. - The laboratory calibration uses different inlet hole sizes to simulate atmospheric pressure changes. - For 2 years, we tried various calibration approaches with the OHSI in place, but none gave repeatable results for high altitude measurements. - In the laboratory calibrations, it proved to be impossible to simulate the atmospheric airflow with the OHSI on and the smaller inlet sizes. - In the end, we found that our previous calibration method gave the most repeatable and reliable results. - In-flight diagnostics show that OH loss on the OHSI is negligible. - For details, please see Faloona et al., J. Atmos. Chem., 47, 139-167, 2004. REVISION: R1 R1: Final Data (see OTHER_COMMENTS) R0: No comments for this revision. Start_UTC, Stop_UTC, Mid_UTC, OH_ATHOS, HO2_ATHOS 34320, 34339, 34330, -9999.000, -9999.000 34340, 34359, 34350, -9999.000, -9999.000 34360, 34379, 34370, -9999.000, -9999.000 34380, 34399, 34390, -9999.000, -9999.000 34400, 34419, 34410, -9999.000, -9999.000 34420, 34439, 34430, -9999.000, -9999.000 34440, 34459, 34450, -9999.000, 5.355 34460, 34479, 34470, -9999.000, 5.069 34480, 34499, 34490, -9999.000, 6.252 34500, 34519, 34510, -9999.000, 7.347 34520, 34539, 34530, 0.039, 8.441 34540, 34559, 34550, 0.039, 8.442 34560, 34579, 34570, 0.030, 7.572 34580, 34599, 34590, 0.030, 6.634 34600, 34619, 34610, 0.027, 5.696 34620, 34639, 34630, 0.027, 6.922 34640, 34659, 34650, 0.060, 7.155 34660, 34679, 34670, 0.060, 6.723 34680, 34699, 34690, 0.029, 6.288 34700, 34719, 34710, 0.040, 6.237 34720, 34739, 34730, 0.040, 3.743 34740, 34759, 34750, 0.018, 1.248 34760, 34779, 34770, 0.018, 3.073 34780, 34799, 34790, 0.018, 3.909 34800, 34819, 34810, 0.024, 3.983 34820, 34839, 34830, 0.024, 4.493 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