47, 1001 Brune, William; Thames, Alexander; Miller, David; Brosius, Alexandra Penn State University ATHOS - Airborne Tropospheric Hydrogen Oxides Sensor ATom 1, 1 2017, 10, 19, 2019, 05, 24 0 Start_UTC, seconds, seconds since UTC midnight on day of takeoff 4 1, 1, 1, 1 -9999.000, -9999.000, -9999.000, -9999.000 Stop_UTC, seconds, seconds since UTC midnight on day of takeoff Mid_UTC, seconds, seconds since UTC midnight on day of takeoff OH_ATHOS, pptv, OH mixing ratio in pptv HO2_ATHOS, pptv, HO2 mixing ratio in pptv 0 29 PI_CONTACT_INFO: Address: 503 Walker Building, University Park, PA 16802; email: whb2@psu.edu 814-865-3286 PLATFORM: NASA - DC-8 Aircraft - sampling underneath aircraft forward cargo bay LOCATION: ATom III: Science Flight #9 -- ASI - SID ASSOCIATED_DATA: N/A INSTRUMENT_INFO: OH/HO2 from Laser Induced Fluorescence. DATA_INFO: Units are pptv for OH and HO2. UNCERTAINTY: HOx absolute accuracy ~+/- 35% (actually a multiplicative factor of 1/1.35 to 1.35), 2 sigma confidence. ULOD_FLAG: -7777 ULOD_VALUE: N/A LLOD_FLAG: -8888 LLOD_VALUE: N/A DM_CONTACT_INFO: William H. Brune, Penn State, whb2@psu.edu; 814-865-3286 PROJECT_INFO: NSF/NASA ATom Mission. 2016 - 2018; Multiple Locations STIPULATIONS_ON_USE: No restrictions. Contact PI or DM with any questions. OTHER_COMMENTS: Final Data. Future modifications to the calibration are possible but unlikely. - Calibrating ATHOS with the new OH-removing inlet (OHSI) has been difficult, particularly for low pressure (high altitude). - The ATHOS HOx calibrations are pressure-dependent, changing a factor of 3-5 over the atmospheric pressure range. - The laboratory calibration uses different inlet hole sizes to simulate atmospheric pressure changes. - For 2 years, we tried various calibration approaches with the OHSI in place, but none gave repeatable results for high altitude measurements. - In the laboratory calibrations, it proved to be impossible to simulate the atmospheric airflow with the OHSI on and the smaller inlet sizes. - In the end, we found that our previous calibration method gave the most repeatable and reliable results. - In-flight diagnostics show that OH loss on the OHSI is negligible. - For details, please see Faloona et al., J. Atmos. Chem., 47, 139-167, 2004. REVISION: R3 R3: Final Data (see OTHER_COMMENTS) R2: Final Data (see OTHER_COMMENTS) R1: Final Data (see OTHER_COMMENTS) R0: No comments for this revision. Start_UTC, Stop_UTC, Mid_UTC, OH_ATHOS, HO2_ATHOS 30908, 30927, 30918, -9999.000, -9999.000 30928, 30947, 30938, -9999.000, -9999.000 30948, 30967, 30958, -9999.000, -9999.000 30968, 30987, 30978, -9999.000, -9999.000 30988, 31007, 30998, -9999.000, -9999.000 31008, 31027, 31018, -9999.000, -9999.000 31028, 31047, 31038, -9999.000, 14.923 31048, 31067, 31058, -9999.000, -9999.000 31068, 31087, 31078, -9999.000, -9999.000 31088, 31107, 31098, 0.079, 15.569 31108, 31127, 31118, 0.079, 14.355 31128, 31147, 31138, 0.096, 17.167 31148, 31167, 31158, 0.096, 20.889 31168, 31187, 31178, 0.096, 24.610 31188, 31207, 31198, 0.122, 25.395 31209, 31228, 31219, 0.159, 25.340 31229, 31248, 31239, 0.159, 25.286 31249, 31268, 31259, 0.158, 25.232 31269, 31288, 31279, 0.158, 25.178 31289, 31308, 31299, 0.158, 25.123 31309, 31328, 31319, 0.170, 25.069 31329, 31348, 31339, 0.170, 25.015 31349, 31368, 31359, 0.208, 20.494 31369, 31388, 31379, 0.208, 24.515 31389, 31408, 31399, 0.180, 23.176 31409, 31428, 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