47, 1001 Brune, William; Thames, Alexander; Miller, David; Brosius, Alexandra Penn State University ATHOS - Airborne Tropospheric Hydrogen Oxides Sensor ATom 1, 1 2017, 10, 17, 2019, 05, 24 0 Start_UTC, seconds, seconds since UTC midnight on day of takeoff 4 1, 1, 1, 1 -9999.000, -9999.000, -9999.000, -9999.000 Stop_UTC, seconds, seconds since UTC midnight on day of takeoff Mid_UTC, seconds, seconds since UTC midnight on day of takeoff OH_ATHOS, pptv, OH mixing ratio in pptv HO2_ATHOS, pptv, HO2 mixing ratio in pptv 0 29 PI_CONTACT_INFO: Address: 503 Walker Building, University Park, PA 16802; email: whb2@psu.edu 814-865-3286 PLATFORM: NASA - DC-8 Aircraft - sampling underneath aircraft forward cargo bay LOCATION: ATom III: Science Flight #8 -- PUQ - ASI ASSOCIATED_DATA: N/A INSTRUMENT_INFO: OH/HO2 from Laser Induced Fluorescence. DATA_INFO: Units are pptv for OH and HO2. UNCERTAINTY: HOx absolute accuracy ~+/- 35% (actually a multiplicative factor of 1/1.35 to 1.35), 2 sigma confidence. ULOD_FLAG: -7777 ULOD_VALUE: N/A LLOD_FLAG: -8888 LLOD_VALUE: N/A DM_CONTACT_INFO: William H. Brune, Penn State, whb2@psu.edu; 814-865-3286 PROJECT_INFO: NSF/NASA ATom Mission. 2016 - 2018; Multiple Locations STIPULATIONS_ON_USE: No restrictions. Contact PI or DM with any questions. OTHER_COMMENTS: Final Data. Future modifications to the calibration are possible but unlikely. - Calibrating ATHOS with the new OH-removing inlet (OHSI) has been difficult, particularly for low pressure (high altitude). - The ATHOS HOx calibrations are pressure-dependent, changing a factor of 3-5 over the atmospheric pressure range. - The laboratory calibration uses different inlet hole sizes to simulate atmospheric pressure changes. - For 2 years, we tried various calibration approaches with the OHSI in place, but none gave repeatable results for high altitude measurements. - In the laboratory calibrations, it proved to be impossible to simulate the atmospheric airflow with the OHSI on and the smaller inlet sizes. - In the end, we found that our previous calibration method gave the most repeatable and reliable results. - In-flight diagnostics show that OH loss on the OHSI is negligible. - For details, please see Faloona et al., J. Atmos. Chem., 47, 139-167, 2004. REVISION: R3 R3: Final Data (see OTHER_COMMENTS) R2: Final Data (see OTHER_COMMENTS) R1: Final Data (see OTHER_COMMENTS) R0: No comments for this revision. Start_UTC, Stop_UTC, Mid_UTC, OH_ATHOS, HO2_ATHOS 35811, 35830, 35821, -9999.000, -9999.000 35831, 35850, 35841, -9999.000, -9999.000 35851, 35870, 35861, -9999.000, -9999.000 35871, 35890, 35881, -9999.000, -9999.000 35891, 35910, 35901, -9999.000, -9999.000 35911, 35930, 35921, -9999.000, -9999.000 35931, 35950, 35941, -9999.000, -9999.000 35951, 35970, 35961, -0.002, -9999.000 35971, 35990, 35981, -0.002, 0.975 35991, 36010, 36001, 0.010, 0.817 36011, 36030, 36021, 0.010, 1.258 36031, 36050, 36041, 0.028, 0.989 36051, 36070, 36061, 0.028, 0.719 36071, 36090, 36081, 0.007, 0.790 36091, 36110, 36101, -0.030, -9999.000 36111, 36130, 36121, -0.030, 3.528 36131, 36150, 36141, 0.023, -9999.000 36151, 36170, 36161, 0.023, -9999.000 36171, 36190, 36181, -9999.000, -9999.000 36191, 36210, 36201, -9999.000, -9999.000 36211, 36230, 36221, -9999.000, -9999.000 36231, 36250, 36241, -0.039, 0.588 36251, 36270, 36261, 0.000, 0.555 36271, 36290, 36281, 0.000, 0.710 36291, 36310, 36301, -0.013, 0.865 36311, 36330, 36321, -0.013, 0.810 36331, 36350, 36341, 0.018, 0.755 36351, 36370, 36361, 0.018, 0.699 36371, 36390, 36381, -0.010, 0.644 36391, 36410, 36401, -0.010, 0.589 36412, 36431, 36422, -0.011, 0.533 36432, 36451, 36442, -0.011, 0.477 36452, 36471, 36462, 0.013, 0.422 36472, 36491, 36482, 0.013, -0.320 36492, 36511, 36502, 0.011, -0.237 36512, 36531, 36522, 0.011, -0.154 36532, 36551, 36542, 0.011, -0.070 36552, 36571, 36562, 0.006, 0.885 36572, 36591, 36582, 0.006, 1.361 36592, 36611, 36602, -0.022, 0.699 36612, 36631, 36622, -0.022, 0.038 36632, 36651, 36642, -0.031, 0.415 36652, 36671, 36662, -0.031, 0.456 36672, 36691, 36682, -0.001, 0.230 36692, 36711, 36702, 0.040, 0.004 36712, 36731, 36722, 0.040, 0.395 36732, 36751, 36742, 0.040, 0.775 36752, 36771, 36762, 0.059, 0.568 36772, 36791, 36782, 0.012, 0.360 36792, 36811, 36802, 0.012, 0.574 36812, 36831, 36822, 0.012, 0.682 36832, 36851, 36842, 0.019, 0.464 36852, 36871, 36862, 0.019, 0.248 36872, 36891, 36882, 0.109, 0.088 36892, 36911, 36902, 0.109, 0.870 36912, 36931, 36922, 0.101, 0.491 36932, 36951, 36942, 0.101, 0.111 36952, 36971, 36962, -9999.000, 2.995 36972, 36991, 36982, -9999.000, -0.472 36992, 37011, 37002, -9999.000, -0.144 37012, 37031, 37022, -0.007, 0.185 37032, 37051, 37042, -0.007, 0.904 37052, 37071, 37062, -0.007, 1.586 37072, 37091, 37082, -0.018, 1.007 37092, 37111, 37102, -0.005, 0.429 37112, 37131, 37122, -0.005, 0.846 37132, 37151, 37142, -0.005, 0.965 37152, 37171, 37162, 0.023, 0.889 37173, 37192, 37183, 0.023, 0.814 37193, 37212, 37203, -0.016, -0.294 37213, 37232, 37223, -0.014, 0.014 37233, 37252, 37243, -0.014, 0.664 37253, 37272, 37263, -0.014, 1.314 37273, 37292, 37283, 0.012, 1.177 37293, 37312, 37303, 0.012, 1.111 37313, 37332, 37323, 0.018, 1.365 37333, 37352, 37343, 0.018, 1.611 37353, 37372, 37363, 0.007, 1.389 37373, 37392, 37383, 0.007, 1.167 37393, 37412, 37403, 0.022, 0.946 37413, 37432, 37423, 0.022, 0.724 37433, 37452, 37443, 0.028, 0.502 37453, 37472, 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