48, 1001 Brune, William; Thames, Alexander; Miller, David; Brosius, Alexandra Penn State University ATHOS - Airborne Tropospheric Hydrogen Oxides Sensor ATom 1, 1 2017, 02, 21, 2019, 05, 24 0 Start_UTC, seconds, seconds since UTC midnight on day of takeoff 4 1, 1, 1, 1 -9999.000, -9999.000, -9999.000, -9999.000 Stop_UTC, seconds, seconds since UTC midnight on day of takeoff Mid_UTC, seconds, seconds since UTC midnight on day of takeoff OH_ATHOS, pptv, OH mixing ratio in pptv HO2_ATHOS, pptv, HO2 mixing ratio in pptv 0 30 PI_CONTACT_INFO: Address: 503 Walker Building, University Park, PA 16802; email: whb2@psu.edu 814-865-3286 PLATFORM: NASA - DC-8 Aircraft - sampling underneath aircraft forward cargo bay LOCATION: ATom II: Science Flight #11 -- ANC - PMD ASSOCIATED_DATA: N/A INSTRUMENT_INFO: OH/HO2 from Laser Induced Fluorescence. DATA_INFO: Units are pptv for OH and HO2. UNCERTAINTY: HOx absolute accuracy ~+/- 35% (actually a multiplicative factor of 1/1.35 to 1.35), 2 sigma confidence. ULOD_FLAG: -7777 ULOD_VALUE: N/A LLOD_FLAG: -8888 LLOD_VALUE: N/A DM_CONTACT_INFO: William H. Brune, Penn State, whb2@psu.edu; 814-865-3286 PROJECT_INFO: NSF/NASA ATom Mission. 2016 - 2018; Multiple Locations STIPULATIONS_ON_USE: No restrictions. Contact PI or DM with any questions. OTHER_COMMENTS: Final Data. Future modifications to the calibration are possible but unlikely. - Calibrating ATHOS with the new OH-removing inlet (OHSI) has been difficult, particularly for low pressure (high altitude). - The ATHOS HOx calibrations are pressure-dependent, changing a factor of 3-5 over the atmospheric pressure range. - The laboratory calibration uses different inlet hole sizes to simulate atmospheric pressure changes. - For 2 years, we tried various calibration approaches with the OHSI in place, but none gave repeatable results for high altitude measurements. - In the laboratory calibrations, it proved to be impossible to simulate the atmospheric airflow with the OHSI on and the smaller inlet sizes. - In the end, we found that our previous calibration method gave the most repeatable and reliable results. - In-flight diagnostics show that OH loss on the OHSI is negligible. - For details, please see Faloona et al., J. Atmos. Chem., 47, 139-167, 2004. REVISION: R4 R4: Final Data (see OTHER_COMMENTS) R3: Final Data (see OTHER_COMMENTS) R2: Final Data (see OTHER_COMMENTS) R1: Final Data R0: No comments for this revision. Start_UTC, Stop_UTC, Mid_UTC, OH_ATHOS, HO2_ATHOS 64856, 64875, 64866, -9999.000, -9999.000 64876, 64895, 64886, -9999.000, -9999.000 64896, 64915, 64906, -9999.000, -9999.000 64916, 64935, 64926, -9999.000, -9999.000 64936, 64955, 64946, -9999.000, -9999.000 64956, 64975, 64966, -9999.000, -9999.000 64976, 64995, 64986, 0.020, 0.710 64996, 65015, 65006, 0.020, 0.259 65016, 65035, 65026, 0.027, 0.555 65036, 65055, 65046, 0.013, 0.851 65056, 65075, 65066, 0.013, 0.744 65076, 65095, 65086, -0.009, 1.146 65096, 65115, 65106, -0.009, 1.000 65116, 65135, 65126, -0.009, 0.854 65137, 65156, 65147, -0.030, 0.403 65157, 65176, 65167, -0.006, 0.176 65177, 65196, 65187, -0.006, 0.194 65197, 65216, 65207, -0.006, 0.213 65217, 65236, 65227, 0.013, 0.269 65237, 65256, 65247, 0.013, 0.325 65257, 65276, 65267, 0.020, 0.380 65277, 65296, 65287, 0.020, 0.436 65297, 65316, 65307, 0.038, 0.493 65317, 65336, 65327, 0.038, 0.548 65337, 65356, 65347, 0.004, 0.604 65357, 65376, 65367, 0.004, 0.660 65377, 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65968, -0.007, 1.076 65978, 65997, 65988, -0.007, 1.142 65998, 66017, 66008, -0.007, 1.208 66018, 66037, 66028, 0.008, 1.274 66038, 66057, 66048, 0.008, 2.036 66058, 66077, 66068, 0.007, 1.758 66078, 66097, 66088, 0.010, 1.480 66098, 66117, 66108, 0.010, 1.237 66118, 66137, 66128, 0.010, 1.765 66138, 66157, 66148, 0.039, 1.296 66158, 66177, 66168, 0.036, 0.823 66178, 66197, 66188, 0.036, 0.355 66198, 66217, 66208, 0.041, 0.435 66218, 66237, 66228, 0.041, 0.553 66238, 66257, 66248, 0.026, 0.670 66258, 66277, 66268, 0.026, 0.404 66278, 66297, 66288, 0.026, 0.617 66298, 66317, 66308, 0.039, 0.613 66318, 66337, 66328, 0.039, 0.608 66338, 66357, 66348, 0.034, 0.604 66358, 66377, 66368, 0.035, 0.676 66378, 66397, 66388, 0.035, 0.760 66398, 66417, 66408, 0.035, 0.845 66493, 66512, 66503, 0.045, 0.864 66513, 66532, 66523, 0.025, 1.062 66533, 66552, 66543, 0.025, 0.896 66553, 66572, 66563, 0.025, 0.730 66573, 66592, 66583, 0.028, 0.564 66593, 66612, 66603, 0.033, 1.149 66613, 66632, 66623, 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67214, 67233, 67224, 0.009, 2.568 67234, 67253, 67244, 0.009, 2.868 67254, 67273, 67264, 0.011, 2.666 67274, 67293, 67284, 0.051, 2.465 67294, 67313, 67304, 0.051, 2.239 67314, 67333, 67324, 0.051, 2.916 67334, 67353, 67344, 0.011, 2.727 67354, 67373, 67364, 0.031, 2.538 67374, 67393, 67384, 0.031, 2.350 67394, 67413, 67404, 0.031, 2.543 67414, 67433, 67424, 0.011, 2.186 67434, 67453, 67444, 0.011, 1.829 67455, 67474, 67465, 0.005, 1.744 67475, 67494, 67485, 0.007, 1.995 67495, 67514, 67505, 0.007, 1.715 67515, 67534, 67525, 0.007, 1.435 67535, 67554, 67545, 0.021, 1.155 67555, 67574, 67565, -0.016, 1.462 67575, 67594, 67585, -0.016, 1.270 67595, 67614, 67605, -0.016, 1.076 67615, 67634, 67625, 0.017, 1.295 67635, 67654, 67645, 0.017, 1.729 67655, 67674, 67665, -0.015, 1.507 67675, 67694, 67685, -0.015, 1.285 67695, 67714, 67705, 0.003, 1.063 67715, 67734, 67725, 0.003, 1.332 67735, 67754, 67745, 0.018, 1.839 67755, 67774, 67765, -0.006, 2.346 67775, 67794, 67785, -0.006, 1.859 67795, 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